(Kertas soalan ini mengandungi 7 soalan dalam 7 halaman yang bercetak) (This question paper consists of 7 questions on 7 printed pages)

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1 UNIVERSITI MALAYA UNIVERSITY F MALAYA PEPERIKSAAN IJAZAH SARJANA MUDA SAINS EXAMINATIN FR THE DEGREE F BACHELR F SCIENCE SESI AKADEMIK 2016/2017 ACADEMIC SESSIN 2016/2017 : SEMESTER I : SEMESTER I SCES3336 : CECAIR HABLUR : LIQUID CRYSTALS Dis 2016/Jan 2017 Dec 2016/Jan 2017 Masa: 2 jam Time: 2 hours ARAHAN KEPADA CALN: INSTRUCTINS T CANDIDATES: Kertas soalan ini mengandungi Bahagian A dan B. This paper consists of Section A and B. Jawab soalan mengikut arahan yang diberikan di dalam setiap bahagian. Question should be answered according to the instructions given in each section. (Kertas soalan ini mengandungi 7 soalan dalam 7 halaman yang bercetak) (This question paper consists of 7 questions on 7 printed pages)

2 BAHAGIAN A (50 MARKAH) SECTIN A (50 MARKS) Jawab SEMUA soalan. Answer ALL questions. 1. (a) Beri definisi cecair hablur. State the definition of liquid crystals. (2 markah/marks) (b) Sila rujuk mesogen termotropik berikut:- Refer to the following thermotropic mesogen:- A B Cecair hablur termotropik umumnya diklasifikasikan berdasarkan bentuk molekul dari molekul konstituen. Thermotropic liquid crystals are generally classified based on the molecular shape of the constituent molecules. (i) Nyata jenis bentuk mesogen bagi molekul A dan B. State the type of mesogen shape for molecule A and B respectively. (2 markah/marks) (ii) Beri perbezaan di antara kedua-dua jenis bentuk mesogen di atas. Distinguish between these two mesogen shapes. (4 markah/marks) 2/7

3 (iii) Nyata dan lakar fasa cecair hablur yang boleh dibentuk oleh molekul B. State and sketch the liquid crystal phases that molecule B can form. (8 markah/marks) (c) Parameter tertib cecair hablur nematik yang berdasarkan pangkat kedua Legendre polinomial dinyatakan sebagai: The order parameter of a nematic liquid crystal which is based on the second rank Legendre polynomial is expressed as: Berikan definisi bagi β, dan jelaskan mengapa parameter tertib itu berdasarkan kepada pangkat kedua. Give the definition for β, and explain why the order parameter is based on the second rank order. (4 markah/marks) 2. (a) Dengan menggunakan persamaan berikut dari teori nsager dan rajah molekul berbentuk rod sebagai rujukan, huraikan secara ringkas bagaimana tanda anisotropi dielektrik, Δε ditentukan. Using the following equation from nsager s theory and the figure of a rodlike molecule as references, briefly describe how the sign of the dielectric anisotropy Δε is determined. ε = NFh [Δα Fμ2 θ 1 ε o kt (3cos2 )] S 2 dipole moment θ molecular long axis (7 markah/marks) 3/7

4 Terdapat tiga deformasi asas yang terdapat di dalam direktor nematik. There are three fundamental deformations found in the nematic directors. (i) Nyata tiga deformasi asas tersebut. Lakar gambarajah yang sesuai untuk meyokong jawapan anda. Indicate the three fundamental deformations. Sketch appropriate diagrams to support your answer. (ii) Deformasi manakah yang paling mudah untuk dicapai? Terangkan alasan anda. Which deformation is the easiest to achieve? Explain your reason. (2 markah/marks) 3. (a) Dengan bantuan gambarajah, terangkan cara operasi bagi paparan cecair hablur sebaran polimer. With the aid of a diagram, describe the operational mode of a polymer dispersed liquid crystal display. (b) Dengan bantuan gambarajah, terangkan cara operasi bagi paparan nematik super-terpiuh (STN-LCD). With the aid of a diagram, describe the operational mode of a supertwisted nematic display (STN-LCD). (c) Apakah kelebihan paparan nematik super-terpiuh (STN-LCD) berbanding paparan nematik terpiuh (TN-LCD)? What is the advantage of a supertwisted nematic display (STN-LCD) compared to the nematic twisted display (TN-LCD)? (3 markah/marks) 4/7

5 Temperature, SCES3336 BAHAGIAN B (50 MARKAH) SECTIN B (50 MARKS) Jawab SEMUA soalan. Answer ALL questions. 4. Gambarajah fasa bagi campuran binari untuk didodesil fosfatidilethanolamina dan air adalah ditunjukkan seperti dibawah. The phase diagram for binary mixtures of didodecyl phosphatidylethanolamine and water is shown below. N + P? V I (a) Dalam kelas apakah anda boleh kategorikan mesogen didodesil fosfatidilethanolamina ini dan apakah pendorong bagi pembentukan fasa? To which class of mesogen does didodecyl phosphatidylethanolamine belong, and what are the driving forces for the phase formation? (3 markah/marks) 5/7

6 (b) Apakah teknik analitikal yang membolehkan pengenalpastian fasa V I, H II dan L α serta apakah teknik yang tidak sesuai? Huraikan. Which analytical technique enables the identification of the phases V I, H II and L α, and which techniques are not suitable? Explain. (10 markah/marks) (c) Apakah kaedah yang mudah untuk menentukan fasa-fasa yang hadir bersama dalam komposisi yang ditanda dalam bulatan? Apakah yang anda jangkakan? What method enables an easy determination of the phases at the composition as marked in the dotted circle? What pattern do you expect? (d) Berikan satu contoh kegunaan bagi setiap fasa berikut: V I, H II dan L α. Give one example of application for each of the following phases: V I, H II and L α. 5. Penyambungan secara terus (dan linear) bagi kumpulan mesogenik yang tegar tidak akan menunjukkan tingkahlaku cecair hablur dalam polimer. Terangkan mengapa, dan berikan penyelesaian bagi menggunakan mesogenik tegar untuk cecair hablur polimer rantai-utama. The direct (and linear) combination of rigid mesogenic groups will not show liquid crystalline behaviour in polymers. Explain why, and provide a solution to use rigid mesogenic groups for main-chain liquid crystalline polymers, MCLCPs. (10 markah/marks) 6/7

7 6. Namakan segmen a-d dalam skema berikut. Untuk n=0 kelakuan fasa ialah smektik 255 I; cadangkan pengubahsuaian untuk merendahkan takat jernih. Name the segments a-d in the following scheme. For n = 0 the phase behaviour is smectic 255 I; suggest modifications to lower the clearing point. (7 markah/marks) 7. Mengapa lebih sukar menyelaraskan direktor bagi cecair hablur polimer rantai-sisi, SCLCP, berbanding dengan direktor cecair hablur berjisim molar rendah. Why is it more difficult to align the director for side-chain liquid crystal polymer, SCLCP, compared to that of low molar mass liquid crystals? (8 markah/marks) TAMAT END 7/7

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