Jawab soalan mengikut arahan yang diberikan dalam setiap bahagian. Questions should be answered according to the instructions given in each section.

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1 UNIVERSITI MALAYA UNIVERSITY OF MALAYA PEPERIKSAAN IJAZAH SARJANA MUDA SAINS EXAMINATION FOR THE DEGREE OF BACHELOR OF SCIENCE PEPERIKSAAN IJAZAH SARJANA MUDA SAINS DENGAN PENDIDIKAN EXAMINATION FOR THE DEGREE OF BACHELOR OF SCIENCE WITH EDUCATION SESI AKADEMIK 2013/2014 : SEMESTER 1 ACADEMIC SESSION 2013/2014 : SEMESTER 1 SCES2210 : KIMIA TAKORGANIK II INORGANIC CHEMISTRY II Disember 2013/Januari 2014 December 2013/January 2014 MASA : 2 jam TIME : 2 hours ARAHAN KEPADA CALON : INSTRUCTIONS TO CANDIDATES : Kertas soalan ini mengandungi Bahagian A, B dan C. This paper consists of Section A, B and C. Jawab soalan mengikut arahan yang diberikan dalam setiap bahagian. Questions should be answered according to the instructions given in each section. (Kertas soalan ini mengandungi 6 soalan dalam 6 halaman yang dicetak) (This question paper consists of 6 questions on 6 printed pages)

2 BAHAGIAN A (33 MARKAH) SECTION A (33 MARKS) Arahan: Jawab SEMUA soalan dalam bahagian ini. Instruction: Answer ALL questions in this section. 1. (a) Senaraikan semua operasi simetri bagi 1,2-diklorobenzena. List all the symmetry operations for 1,2-dichlorobenzene. Nyatakan kumpulan titik bagi spesies-spesies yang berikut. Jelaskan jawapan anda. State the point group of the following species. Explain your answers. (i) [CuCl 4 ] 2- (satah segi empat sama/square planar) (ii) O 3 Dengan menggunakan molekul XeCl 4 sebagai contoh, buktikan bahawa S 2 = i. Using XeCl 4 molecule as an example, prove that S 2 = i. (18 markah/marks) 2. Tentukan bilangan puncak yang dijangka dalam spektrum getaran bagi molekul CH 2 =CH 2 (kumpulan titik D 2h ). Determine the number of peaks expected in the vibrational spectrum of CH 2 =CH 2 (point group D 2h ). (15 markah/marks) BAHAGIAN B (34 MARKAH) SECTION B (34 MARKS) Arahan: Jawab SEMUA soalan dalam bahagian ini. Instruction: Answer ALL questions in this section. 3. Satu ion kompleks tetrahedral terbentuk daripada satu ion Ni 2+ dan empat ion Cl -. A tetrahedral complex ion is formed from one Ni 2+ ion and four Cl - ions. (a) Lukis formula struktur and tulis nama ion kompleks itu. Draw the structural formula and write the name of the complex ion. 2/6

3 (d) Guna teori medan hablur untuk menjelaskan pengikatan ion kompleks tersebut. Use the crystal field theory to explain the bonding of the complex ion. Tentukan momen magnet ion kompleks tersebut. Determine the magnetic moment of the complex ion. Deduksikan simbol ungkapan bagi ion Ni 2+ bebas pada keadaan asas. Deduce the term symbol for the free Ni 2+ ion in the ground state. (20 markah/marks) 4. Spektrum nampak bagi ion [Cr(CN) 6 ] 3- menunjukkan satu jalur yang amat lemah pada nombor gelombang 16,000 cm -1, dan dua jalur sederhana kuat pada nombor gelombang 17,700 cm -1 dan 23,800 cm -1. Guna gambar rajah Tanabe- Sugano yang betul untuk mengenal pasti peralihan elektron bagi jalur-jalur ini, dan hitung tenaga penstabilan medan hablur (dalam unit cm -1 ) bagi ion kompleks ini. The visible spectrum of [Cr(CN) 6 ] 3- ion shows a very weak band at wavenumber 16,000 cm -1 and two moderately strong bands at wavenumbers 17,700 cm -1 and 23,800 cm -1. Use the correct Tanabe-Sugano diagram to identify the electronic transitions for the bands, and calculate the crystal field stabilisation energy (in cm -1 ) for the complex ion. (14 markah/marks) 3/6

4 4/6

5 Jawab SEMUA soalan dalam bahagian ini. Answer ALL questions in this section. BAHAGIAN C (33 MARKAH) SECTION C (33 MARKS) 5. (a) Setiap unsur dalam Jadual Berkala mempunyai cas nukleus berkesan, Z eff, yang ditakrifkan oleh Aturan Slater. Each element in the Periodic Table has its own effective nuclear charge, Z eff, as described by Slater Rule. (i) (ii) Takrifkan Aturan Slater dan tuliskan persamaan yang mewakili aturan ini? Define Slater Rule and write its equation? Apakah keadaan pengoksidaan yang paling lazim untuk Ti? Jelaskan jawapan anda dengan menggunakan pengiraan Aturan Slater. What is the most common oxidation state of Ti? Explain your answer by using Slater Rule calculation Berikan dua contoh dari sifat anomali Be. Jelaskan jawapan anda. Give two examples of anomalous behavior of Be. Explain your answer. Apakah cara terbaik dan selamat untuk menjalankan tindak balas yang melibatkan logam Cs? What is the proper and safe way to conduct a reaction involving Cs metal? (12 markah/marks) 6. (a) Beberapa hablur logam blok p membentuk kumpulan ruang bukan berpusat simetri akibat kesan pasangan lengai. Takrifkan kesan pasangan lengai dan berikan dua contoh hablur. Several crystals of p-block metals belong to the non-centrosymmetric space group, partly due to their inert pair effect. Define inert pair effect and give two examples of the crystals. TiO 2 digunakan secara meluas sebagai bahan tambah dalam cat. Apakah warna TiO 2? Jelaskan jawapan anda. TiO 2 is widely used as an additive in paint. What is the color of TiO 2? explain your answer. 5/6

6 (d) (e) Apakah jenis kemagnetan yang dijangka bagi Cu 2 O dan CuO? Jelaskan jawapan anda. What type of magnetism is expected of Cu 2 O and CuO have? Explain your answers Terangkan mengapa saiz atom lantanida mengurang merentasi kala? Explain why the atomic sizes of the lanthanides decrease across the period? Selepas seketika, logam La menjadi berwarna gelap dan lengai. Jelaskan mengapa dan bincang bagaimana kereaktifannya boleh dijana semula. After some times, La metal became dark in color and inert. Explain why and discuss how to regenerate its reactivity. (21 markah/marks) TAMAT END 6/6

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