Jawab soalan mengikut arahan yang diberikan dalam setiap bahagian. Questions should be answered according to the instructions given in each section.

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1 UNIVERSITI MALAYA UNIVERSITY OF MALAYA PEPERIKSAAN IJAZAH SARJANA MUDA SAINS EXAMINATION FOR THE DEGREE OF BACHELOR OF SCIENCE PEPERIKSAAN IJAZAH SARJANA MUDA SAINS DENGAN PENDIDIKAN EXAMINATION FOR THE DEGREE OF BACHELOR OF SCIENCE WITH EDUCATION SESI AKADEMIK 2015/2016 : SEMESTER 2 ACADEMIC SESSION 2015/2016 : SEMESTER 2 SCES1230 : KIMIA FIZIK I PHYSICAL CHEMISTRY I Jun 2016 June 2016 Masa : 2 jam Time : 2 hours ARAHAN KEPADA CALON : INSTRUCTIONS TO CANDIDATES : Kertas soalan ini mengandungi Bahagian A dan B. This paper consists of Section A and B. Jawab soalan mengikut arahan yang diberikan dalam setiap bahagian. Questions should be answered according to the instructions given in each section. (Kertas soalan ini mengandungi 4 soalan dalam 7 halaman yang dicetak) (This question paper consists of 4 questions on 7 printed pages)

2 Jawab semua soalan dalam bahagian ini. Answer all questions in this Section. BAHAGIAN A (50 MARKAH) SECTION A (50 MARKS) 1. (a) Tulis persamaan untuk hukum termodinamik yang pertama, dan nyatakan sama ada setiap istilah pada persamaan tersebut adalah fungsi keadaan atau fungsi jalanan. Write the expression for the first law of thermodynamics, and state whether each term in the expression is a state function or a path function. (4 markah/marks) (b) Kirakan kerja yang dilakukan apabila 1 mol gas argon yang berada di sebuahsilinder pada isipadu 2.0 dm 3 pada suhu 25 C mengembang dengan suhu sekata dan berbalik ke isipadu 3.0 dm 3. Calculate the work done when 1 mol of argon gas confined in a cylinder of volume 2.0 dm 3 at 25 C expands isothermally and reversibly to 3.0 dm 3. (Nota/Note: R= JK 1 mol 1 ) (4 markah/marks) Apabila arus elektrik 2.3 A dari punca 12.5 V mengalir melalui satu pemanas di dalam sebuah kalorimeter selama 3 minit, suhu telah meningkat sebanyak 7.3 C. Di dalam satu ujikaji untuk mengukur haba yang dilepaskan oleh pembakaran satu sampel di dalam kalorimeter yang sama, suhu telah meningkat sebanyak 3.5 C. Berapakah haba yang dilepaskan oleh tindakbalas pembakaran sampel tersebut? When a current of 2.3 A from a 12.5 V source flows through a heater in a calorimeter for 3 minutes, the temperature increases by 7.3 C. In an experiment to measure the heat released by a combustion of a sample inside the same calorimeter, the temperature increases by 3.5 C. What is the heat released by the combustion reaction of the sample? (Nota/Note: 1 AVs = 1 J) (5 markah/marks) 2/7

3 (d) 3.0 mol gas oksigen telah dipanaskan dari 270 K ke 285 K pada tekanan 3.3 atm yang tetap. Diberi haba kapasiti pada tekanan tetap, C p, untuk gas oksigen adalah 29.4 JK 1 mol 1, kirakan nilai-nilai untuk: 3.0 moles of oxygen gas is heated from 270 K to 290 K at a constant pressure of 3.3 atm. Given that the heat capacity at constant pressure, C p, for oxygen gas is 29.4 JK 1 mol 1, calculate the values for (i) (ii) haba, q heat, q kapasiti haba pada isipadu tetap, C v heat capacity at constant volume, C v (iii) (iv) perubahan entalpi, H enthalpy change, H perubahan tenaga dalaman, U internal energy change, U Nota/Note: (Anggap satu keadaan yang ideal. R = JK 1 mol 1 ) (Assume an ideal behavior. R = JK 1 mol 1 ) 2. (a) Diberi persamaan-persamaan termokimia: Given the thermochemical equations: (12 markah/marks) C 3 H 6 (g) + H 2 (g) C 3 H 8 (g) C 3 H 8 (g) + 5O 2 (g) 3CO 2 (g) + 4 H 2 O (l) H 2 (g) + ½ O 2 (g) H 2 O (l) H 0 = -124 kj H 0 = kj H 0 = -286 kj Kirakan entalpi piawai bagi keseluruhan. propen, C 3 H 6, dan tunjukkan persamaan Calculate the standard enthalpy of combustion of propene, C 3 H 6, and show its overall equation. 3/7

4 (b) Diberi C v,m untuk gas hidrogen adalah JK 1 mol 1, kirakan perubahan entropi molar apabila gas hidrogen dipanaskan dari suhu 20 C ke 30 C pada isipadu yang tetap. Given that the C v,m of hydrogen gas is JK 1 mol 1, calculate the change in molar entropy when a hydrogen gas is heated from 20 C to 30 C at a constant volume. (3 markah/marks) (d) Jelaskan mengapa nilai haba kapasiti untuk suatu gas pada tekanan tetap, C p, adalah lebih besar dari nilai haba kapasitinya pada isipadu yang tetap, C v. Explain why the heat capacity for a gas at constant pressure, C p, is larger than the heat capacity at constant volume, C v (4 markah/marks) Pertimbangkan pengewapan air pada keadaan piawai (25 C pada tekanan 1 atm): Consider the vaporization of water at the standard state (25 C at 1 atm): H 2 O (l) H 2 O (g) H 0 = 44.0 k J mol 1 S 0 = J mol 1 K 1 Pada arah manakah pada persamaan tersebut akan berlaku perubahan yang spontan, dan pada suhu berapakah perubahan spontan itu akan berlaku? Which direction of the equation would the spontaneous change occur, and at what temperature does the spontaneous change take place? (e) Tuliskan perhubungan tenaga bebas Gibbs dan tenaga bebas Helmholtz, dan jelaskan aplikasi lain kedua-dua tenaga bebas ini selain daripada meramalkan halatuju sesuatu perubahan. Write the relationship between the Gibbs free energy and the Helmholtz free energy, and explain another applications of these two free energies other than predicting the direction of changes. 4/7

5 Jawab semua soalan dalam bahagian ini. Answer all questions in this Section. BAHAGIAN B (50 MARKAH) SECTION B (50 MARKS) 3. (a) Takrifkan kekonduksian molar ( m ) bagi sesuatu elektrolit dan lakarkan gambarajah untuk menunjukkan perubahan m dengan kepekatan c bagi suatu (i) elektrolit kuat dan (ii) elektrolit lemah. Define molar conductivity ( m ) of electrolyte and sketch the graph to show the change of m with concentration c for a (i) strong electrolyte and (ii) weak electrolyte. (b) Jadual berikut menunjukkan 0 bagi beberapa sebatian dalam larutan akues. The following table gives the 0 values for a number of compounds in aqueous solution. Sebatian/ Compound 0 / S cm 2 mol -1 HCl 37.7 NaCl 12.3 CH 3 COONa 7.6 Kirakan bagi 0 asid asetik, CH 3 COOH. Calculate 0 for acetic acid CH 3 COOH. Huraikan secara ringkas bagaimana potensi elektrod standard bagi sesuatu elektrod ditentukan. Explain briefly how is the standard electrode potential of a electrode being determined. 5/7

6 (d) Diberikan potensi elektrod standard berikut: The standard electrode potentials are given as follow: E 0 Fe2+ /Fe = 0.44V, dan/and E 0 Mg2+/Mg = -2.37V. Dengan menggunakan Persamaan Nernst, kirakan potensi elektrod setengah-sel pada 25 C: Use the Nernst Equation to calculate the electrode potential of the following halfcell at 25 C: (i) (ii) Fe/Fe 2+ (0.0500M), Mg/Mg 2+ (0.0100M) Jika dua setengah-sel itui digunakan untuk membuat bateri, yang manakah akan jadi anod dan yang manakah katod? If the two half-cells are being used to form a battery, which one would be the anode, and which one the cathode? (7 markah/marks) 4. (a) Takrifkan istilah tempoh setengah hayat, t 1/2. Pereputan unsur radioaktif mengikuti kinetik tertib pertama. Jika tempoh setengah hayat unsur 90 Sr ialah 28.1 tahun, berapa lamakah diperlukan supaya g unsur radioaktif itu mereput menjadi 1.25 g? Define the term half-life, t 1/2.. The decay of a radioactive element follows a first order kinetic. If the half life of 90 Sr is 28.1 years, how long will it take for a g sample of this radioactive element to decay to 1.25 g? (7 markah/marks) (b) Takrifkan istilah kadar tindak balas, dan tuliskan suatu ungkapan am bagi kadar tindak balas berikut. Define the term rate of reaction, and write a general expression for the rate of the following reaction, 3A + B 2C 6/7

7 Jadual berikut menunjukkan perubahan kepekatan selepas 5 saat. The follow table represents the change in concentration after 5 seconds. A B C Initial concentration (mol dm -3 ) Final concentration (mol dm -3 ) Kirakan kadar tindak balas dalam masa 5 saat itu. Calculate the rate of the reaction within 5 second SCES1230 (8 markah/marks) Etil asetat mengalami hidrolisis dalam larutan alkali akues seperti berikut. Ethyl acetate hydrolyzes in aqueous alkaline solution as follow. C 2 H 5 COOC 2 H 5 (ak) + OH - (ak) = C 2 H 5 COO - (ak) + C 2 H 5 OH (ak) C 2 H 5 COOC 2 H 5 (aq) + OH - (aq) = C 2 H 5 COO - (aq) + C 2 H 5 OH (aq) Data kadar tindak balas awal pada kepekatan berlainan telah di dapati dalam jadual berikut. Initial rate data were collected for different concentrations as shown in the table: No [C 2 H 5 COOC 2 H 5 ] [OH - ] Kadar/ mmol dm -3 s -1 mol dm -3 mol dm -3 Rate/ mmol dm -3 s Tentukan (i) tertib tindak balas, (ii) persamaan kinetic, dan (iii) pemalar kadar tindak balas. Determine (i) the order of reaction, (ii) its kinetic equation and (iii) the rate constant of the reaction. (10 markah/marks) TAMAT END 7/7

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