Jawab soalan mengikut arahan yang diberikan dalam setiap bahagian. Questions should be answered according to the instructions given in each section.

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1 UNIVERSITI MALAYA UNIVERSITY OF MALAYA PEPERIKSAAN IJAZAH SARJANA MUDA SAINS EXAMINATION FOR THE DEGREE OF BACHELOR OF SCIENCE PEPERIKSAAN IJAZAH SARJANA MUDA SAINS DENGAN PENDIDIKAN EXAMINATION FOR THE DEGREE OF BACHELOR OF SCIENCE WITH EDUCATION SESI AKADEMIK 2015/2016 : SEMESTER 2 ACADEMIC SESSION 2015/2016 : SEMESTER 2 SCES1210 : KIMIA TAKORGANIK I INORGANIC CHEMISTRY I Jun 2016 June 2016 Masa : 2 jam Time : 2 hours ARAHAN KEPADA CALON : INSTRUCTIONS TO CANDIDATES : Kertas soalan ini mengandungi Bahagian A dan B. This paper consists of Section A and B. Jawab soalan mengikut arahan yang diberikan dalam setiap bahagian. Questions should be answered according to the instructions given in each section. (Kertas soalan ini mengandungi 6 soalan dalam 6 halaman yang dicetak) (This question paper consists of 6 questions on 6 printed pages)

2 Jawab SEMUA soalan dalam bahagian ini. Answer ALL questions from this section. BAHAGIAN A (50 MARKAH) SECTION A (50 MARKS) 1. (a) Dengan menggunakan kaedah VSEPR, lukiskan 3 struktur yang munasabah untuk ClF 3. Using VSEPR, draw the 3 possible structures for ClF 3. (b) Lukiskan gambarajah Lewis untuk BrF 5 dan ICl 4 -. Draw the Lewis diagram for BrF 5 and ICl 4 -. Lukiskan rajah Orbital Molekul untuk F 2. Tuliskan konfigurasi elektronik dan kirakan tertib ikatan F 2? Draw a Molecular Orbital diagram for F 2. Write down the electronic configuration and calculate the bond order of F 2? 2. (a) Garam litium seperti LiBr mempunyai kandungan air, manakala garam natrium dan kalium biasanya kontang. Terangkan. Certain lithium salts like LiBr is hydrated, while the corresponding sodium and potassium salts are generally anhydrous. Explain. (b) Jelaskan bagaimana hidroksida, nitrat, karbonat dan sulfat Kumpulan I adalah lebih stabil untuk unsur-unsur dibawah kumpulan ini. Give reason why hydroxide, nitrate, carbonate and sulfate of Group I are more stable for elements below the group. 2/6

3 Gas BeCl 2 berwujud sebagai monomer tetapi membentuk dimer dalam larutan dan mempunyai bentuk polimerik, [BeCl 2 ] n dalam bentuk pepejal. Berikan sebab bagi kelakuan ini dan jelaskan jenis ikatan dalam dimer ini. Gaseous BeCl 2 exists as a monomer but dimerized as it condenses into a liquid and has a polymerized form, [BeCl 2 ] n as in solid form. Give reasons for this behaviour and explain the type of bonding in the dimer. 3. Jelaskan untuk pemerhatian berikut: Explain the following observations: (i) Nitrogen membentuk pelbagai oksida berbanding dengan fosforus. Nitrogen forms a wide range of oxides as compared to phosphorus. (ii) Takat didih halida hidrogen : HF (20 o C), HCl (-85 o C), HBr (-67 o C) dan HI (-36 o C). Terangkan dengan ringkas variasi yang ditunjukkan. The variation observed for the boiling points of the hydrogen halides HF (20 o C), HCl (-85 o C), HBr (-67 o C) and HI (-36 o C). (iii) Sebatian PbCI 4 tak stabil jika dibandingkan dengan PbCI 2. PbCI 4 is an unstable compound when compared to PbCI 2. 3/6

4 BAHAGIAN B (50 MARKAH) SECTION B (50 MARKS) Jawab SEMUA soalan. Answer ALL questions. 4. (a) Terangkan sifat asid-bes dengan menggunakan konsep berikut: Explain acid-base behavior by using the following concepts: (i) (ii) (iii) Arrhenius Brönsted-Lowry Lewis (b) Label setiap spesies sebagai asid atau bes. Kenalpastikan pasangan konjugat asid-bes. Label each species as an acid or base. Identify the conjugate acid-base pairs. (i) OH - + HCl H 2 O + Cl - (ii) H 3 O + + PH 3 H 2 O + PH 4 + Apakah kekuatan bes relatif antara piridina dan 2-metilpiridina terhadap proton? Jelaskan jawapan anda. What is the relative base strength of pyridine and of 2-methylpyridine towards proton? Explain your answer. (d) Susunkan kestabilan aduk SnCl 2 dengan bes berikut mengikut tertib menaik. Jelaskan jawapan anda. Arrange the stability of the SnCl 2 adduct with the following base in ascending order. Explain your answer. Pyridine, 2-methylpyridine, 3-methylpyridine and 2,6-dimethylpyridine 4/6

5 5. Jawab soalan berikut berdasarkan gambarajah Latimer untuk Mn dalam larutan berasid. Answer the following questions using the Latimer diagram for Mn in acidic solution. (a) Tentukan nombor pengoksidaan untuk Mn dalam MnO 4 -, HMnO 4 - dan MnO 2. Determine the oxidation number for Mn in MnO 4 -, HMnO 4 - and MnO 2. (b) Jelaskan perbezaan antara proses konproporsionasi dan disproposionasi. Explain the differences between comproportionation and disproportionation. Antara spesies-spesies dalam gambar rajah di atas, yang manakah tidak stabil terhadap disproporsionasi. Which of the following species in the Latimer diagram above are unstable with respect to disproportionation. (d) Tentukan nilai A. Determine the value for A. (e) Tentukan nilai B. Determine the value for B. 5/6

6 6. (a) Nyatakan nama dan kegunaan gambar rajah diatas. State the name and the uses of the diagram above. (b) Apakah label yang patut wujud di paksi-x dan y? What are the labels for x and y-axis? (2 markah/marks) (d) Jelaskan maksud garis yang berbeza dalam gambar rajah diatas. Explain the meaning of the different lines in the diagram above. Berikan satu contoh untuk zon kakisan, imuniti dan pempasifan? Give one example for corrosion, immunity and passivation zone. (e) Tentukan nombor pengoksidaan untuk Fe dalam Fe 3 O 4. Determine the oxidation number for Fe in Fe 3 O 4. TAMAT END (1 markah/marks) 6/6

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