Answer the questions according to the instructions given in each section. Jawab soalan mengikut arahan yang diberikan dalam setiap bahagian.

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1 UNIVERSITY OF MALAYA UNIVERSITI MALAYA EXAMINATION FOR THE DEGREE OF BACHELOR OF SCIENCE PEPERIKSAAN IJAZAH SARJANA MUDA SAINS EXAMINATION FOR THE DEGREE OF BACHELOR OF SCIENCE WITH EDUCATION PEPERIKSAAN IJAZAH SARJANA MUDA SAINS DENGAN PENDIDIKAN ACADEMIC SESSION 2011/2012 : SEMESTER 2 SESI AKADEMIK 2011/2012 : SEMESTER 2 SCES2313/ SCEP2313 : NUCLEAR CHEMISTRY KIMIA NUKLEAR June 2012 Jun 2012 TIME : 2 hours MASA : 2 jam INSTRUCTIONS TO CANDIDATES : ARAHAN KEPADA CALON : This paper consists of Section A and B. Kertas soalan ini mengandungi Bahagian A dan B. Answer the questions according to the instructions given in each section. Jawab soalan mengikut arahan yang diberikan dalam setiap bahagian. (This question paper consists of 5 questions on 7 printed pages) (Kertas soalan ini mengandungi 5 soalan dalam 7 halaman yang dicetak)

2 SCES2313/ SCEP2313/02 SECTION A (50 MARKS) BAHAGIAN A (50 MARKAH) Answer ALL questions. Jawab SEMUA soalan. 1. (a) Complete the nuclear equation below: Lengkapkan skema persamaan nuklear berikut: 88 (10 marks/markah)

3 SCES2313/ SCEP2313/03 Predict the numbers of alpha and beta decay involved from the conversion of 234 Pa to 222 Rn Ramalkan bilangan reputan alfa dan beta yang terlibat dalam penukaran 234 Pa kepada 222 Rn. (5 marks/markah) 2. (a) A sunken wooden ship discovered near the coast of Hawaii gave 7.5 disintegrations of 14 C per minute per gram of carbon. Estimate the age of this ship. [Given: Carbon from living material gives 15.3 disintegrations of C per minute per gram of carbon. The half-life of carbon-14 is x 10 3 years] Sebuah perahu karam buatan kayu ditemui di persisiran pantai Hawaii memberikan bacaan 7.5 penyepaian 14 C per minit per gram karbon. Anggarkan usia perahu ini. [Dberi: Karbon daripada bahan bernyawa adalah 15.3 penyepaian 14 C per minit per gram karbon. Setengah-hayat untuk karbon-14 adalah x 10 3 tahun] (5 marks/markah) The mass of 40 Ca is given as amu and amu for 56 Fe. Determine which element is more stable. Support your answers with some calculations. Diberi jisim untuk 40 Ca adalah amu dan amu untuk 56 Fe. Tentukan unsur yang mana yang lebih stabil. Sokong jawapan anda melalui pengiraan. (10 marks/markah) 3. (a) Describe two methods used in producing nuclear particles for induce nuclear reactions. Perihalkan dua kaedah yang digunakan untuk menghasilkan zarahzarah-zarah untuk tindak balas nuklear teraruh. What is a charged particle accelerator? Explain the basic principles of how this instrument works. Apakah yang dimaksudkan dengan pemecut zarah bercas. Terangkan prinsip-prinsip asas bagaimana instrumen ini berfungsi. (20 marks/markah)

4 SCES2313/ SCEP2313/04 Useful constants: Avogadro s number (N A ) = x /mol mass of proton = amu mass of neutron = amu mass of electron = x 10-4 amu speed of light (c) = 3.0 x 10 8 m/s x amu = 1g 1 J = 1 kg m 2 /s 2 1 ev = x J 1 Mev = 10 6 ev

5 SCES2313/ SCEP2313/05

6 SCES2313/ SCEP2313/06 SECTION B (50 MARKS) BAHAGIAN B (50 MARKAH) Answer ALL questions. Jawab SEMUA soalan. 4. (a) Discuss the differences between fusion and fission reactions. Bincangkan perbezaan antara tindak balas perlakuran dengan tindak balas pembelahan In the fission of 235 U, many light nuclides will be formed. Plot a graph showing the percentage difference in yield of the nuclides against the mass number if: Dalam tindak balas pembelahan 235 U, banyak nuklid ringan akan dihasilkan. Plotkan satu graf untuk menunjukkan perubahan peratusan hasil nuklid-nuklid melawan nombor jisim sekiranya: i. high energy neutrons are used neutron bertenaga tinggi digunakan. ii. low energy neutrons are used neutron bertenaga rendah digunakan (c) (d) 137 Ba and 94 Sr are formed as the final stable products in the neutron initiated fission of 238 Pu. What are the primary nuclides formed at the beginning of the fission? 137 Ba dan 94 Sr dihasilkan sebagai produk akhir yang stabil dalam tindak balas pembelahan 238 Pu yang dimulakan oleh neutron. Apakah nuklidnuklid primer yang dihasilkan pada permulaan tindak balas pembelahan? In the combustion of helium, 8 Be isotope will be formed. The formation of 8 Be is one of the important process in the formation of elements that are heavier than helium. Please explain the statement. Dalam pembakaran helium, isotop 8 Be akan dihasilkan. Pembentukan 8 Be merupakan salah satu proses yang penting dalam penghasilan unsurunsur yang lebih berat daripada helium. Terangkan kenyataan ini. (25 marks/markah)

7 SCES2313/ SCEP2313/07 5. (a) Discuss the following topics: Bincangkan topik-topik berikut: i. The monitoring of radiation doses used in the context of health and safety of workers. Pemonitoran dos sinaran yang digunakan dalam konteks kesihatan dan keselamatan pekerja. ii. Detectors for radioactive particles. Alat-alat pengesan untuk zarah radioaktif. A beam of gamma radiation with energy 135 MeV is focused on an absorber that consists of a mixture of 30% Ca 3 (PO 4 ) 2 and 70% Na 2 CO 3 with thickness 40 mm. Given the electronic absorption coefficient e μ is barn. The density for Ca 3 (PO 4 ) 2 and Na 2 CO 3 is 3.14 g cm -3 and 2.53 g cm -3, respectively. Satu bim sinar gama dengan tenaga 135 MeV telah dipancarkan ke atas satu penyerap yang mengandungi campuran 30% Ca 3 (PO 4 ) 2 dan 70% Na 2 CO 3 dengan ketebalan 40 mm. Diberi koefisyen penyerapan elektronik eμ ialah barn. Ketumpatan untuk Ca 3 (PO 4 ) 2 dan Na 2 CO 3 ialah 3.14 g cm -3 dan 2.53 g cm -3, masing-masing. i. Calculate the reduction in the gamma energy after passing through the absorber. Hitungkan pengurangan tenaga gama selepas melalui penyerap tersebut. ii. Assuming that the loss in gamma energy is due to only absorption and scattering, what is the loss in energy due to absorption? Given the absorption coefficient due to the scattering, μ s is 0.10 cm -1. Dengan menganggap kehilangan tenaga gama adalah disebabkan oleh penyerapan dan penyerakan, apakah kehilangan tenaga yang disebabkan oleh penyerapan? Diberi koefisyen penyerapan disebabkan oleh penyerakan, μ s ialah 0.10 cm -1. (25 marks/markah) END TAMAT

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