Jawab soalan mengikut arahan yang diberikan dalam setiap bahagian. Questions should be answered according to the instructions given in each section.

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1 UNIVERSITI MALAYA UNIVERSITY OF MALAYA PEPERIKSAAN IJAZAH SARJANA MUDA SAINS EXAMINATION FOR THE DEGREE OF BACHELOR OF SCIENCE PEPERIKSAAN IJAZAH SARJANA MUDA SAINS DENGAN PENDIDIKAN EXAMINATION FOR THE DEGREE OF BACHELOR OF SCIENCE WITH EDUCATION SESI AKADEMIK 2013/2014 : SEMESTER 2 ACADEMIC SESSION 2013/2014 : SEMESTER 2 SCES2210 : KIMIA TAKORGANIK II INORGANIC CHEMISTRY II Jun 2014 June 2014 MASA : 2 jam TIME : 2 hours ARAHAN KEPADA CALON : INSTRUCTIONS TO CANDIDATES : Kertas soalan ini mengandungi Bahagian A, B dan C. This paper consists of Section A, B and C. Jawab soalan mengikut arahan yang diberikan dalam setiap bahagian. Questions should be answered according to the instructions given in each section. (Kertas soalan ini mengandungi 6 soalan dalam 6 halaman yang dicetak) (This question paper consists of 6 questions on 6 printed pages)

2 BAHAGIAN A (33 MARKAH) SECTION A (33 MARKS) Arahan: Jawab SEMUA soalan dalam bahagian ini. Instruction: Answer ALL questions in this section. 1. (a) Setiap unsur dalam Jadual Berkala mempunyai cas nucleus berkesan, Z eff, yang ditakrifkan oleh Aturan Slater. Each element in Periodic Table has its own effective nuclear charge, Z eff, as defined by Slater Rule. (i) Takrifkan Aturan Slater dan tuliskan persamaan yang mewakili aturan ini. Define Slater Rule and write the equation. (2 markah/marks) (ii) Apakah keadaan pengoksidaan yang paling lazim untuk 27 Co? Jelaskan jawapan anda dengan menggunakan pengiraan Aturan Slater. What is the most common oxidation state of 27 Co? Explain your answer by using the Slater Rule calculation. (3 markah/marks) Berikan dua contoh dari sifat anomali Li. Jelaskan jawapan anda. Give two examples of the anomalous behavior of Li. Explain your answer. (4 markah/marks) (c) Apakah cara terbaik dan terselamat untuk menjalankan tindak balas yang melibatkan logam K? Jelaskan jawapan anda. What is the proper and safe way to conduct a reaction involving K metal? Explain your answer. (3 markah/marks) 2. (a) Terangkan mengapa PbO membentuk kumpulan ruang tak bersimetri? Explain why PbO crystallizes in a non-centrosymmetric space group? (4 markah/marks) 2/6

3 Jelaskan mengapa NiO berwarna hijau. Explain why NiO is green. (c) Apakah jenis kemagnetan bagi CoO? Jelaskan jawapan anda. What type of magnetism would CoO have? Explain your answer. (d) Terangkan mengapa kereaktifan atom lantanida tak berbeza merentasi kala. Explain why the reactivity of the lanthanides is similar across the period. (3 markah/marks) (e) Jelaskan mengapa kereaktifan La 2 O 3 tidak sama dengan La pada suhu bilik. Explain why La 2 O 3 is not as reactive as La at room temperature. (4 markah/marks) BAHAGIAN B (33 MARKAH) SECTION B (33 MARKS) Arahan: Jawab SEMUA soalan dalam bahagian ini. Instruction: Answer ALL questions in this section. 3. (a) Senaraikan semua operasi simetri bagi ion cis-dibromodiklorokuprat(ii). List all the symmetry operations for cis-dibromodichlorocuprate(ii) ion. Nyatakan kumpulan titik bagi sebatian-sebatian yang berikut. Jelaskan jawapan anda. State the point group for the following compounds. Explain your answers. (i) trans-[fecl 2 (H 2 O) 4 ] (ii) CO 2 (8 markah/marks) 3/6

4 (c) Dengan menggunakan molekul NH 3 sebagai contoh, tunjukkan bahawa perwakilan tak terturunkan bagi orbital p z adalah A 1. Using NH 3 molecule as an example, show that the irreducible representation for its p z orbital is A Tentukan bilangan puncak yang dijangka dalam spektrum getaran bagi molekul CCl 4. Determine the number of peaks expected in the vibrational spectrum of a CCl 4 molecule. (15 markah/marks) Jawab SEMUA soalan dalam bahagian ini. Answer ALL questions in this section. BAHAGIAN C (34 MARKAH) SECTION C (34 MARKS) 5. (a) Satu ion kompleks oktahedral terbentuk daripada satu ion Fe 2+ dan enam molekul H 2 O. An octahedral complex ion is formed from one Fe 2+ ion and six H 2 O molecules. (i) (ii) (iii) Lukis formula struktur and tulis nama ion kompleks itu. Draw the structural formula and write the name of the complex ion. Guna teori medan hablur untuk menjelaskan pengikatan bagi ion kompleks itu. Use the crystal field theory to explain the bonding for the complex ion. Tentukan momen magnet bagi ion kompleks tersebut. Determine the magnetic moment of the complex ion. (15 markah/marks) 4/6

5 Deduksikan simbol ungkapan bagi ion Fe 2+ bebas pada keadaan asas. Deduce the term symbol for the free Fe 2+ ion in the ground state. 6. Spektrum elektronik bagi ion [Co(H 2 O) 6 ] 2+ menunjukkan tiga jalur pada 8,100 cm -1, 16,000 cm -1 dan 19,400 cm -1. Guna gambar rajah Tanabe-Sugano yang betul untuk mengenal pasti peralihan elektron bagi jalur-jalur ini, dan hitung tenaga penstabilan medan hablur (dalam unit cm -1 ) bagi ion kompleks ini. The electronic spectrum of [Co(H 2 O) 6 ] 2+ ion shows three bands at 8,100 cm -1, 16,000 cm -1 and 19,400 cm -1. Use the correct Tanabe-Sugano diagram to identify the electronic transitions for these bands, and calculate the crystal field stabilisation energy (in cm -1 ) for the complex ion. (14 markah/marks) 5/6

6 Lampiran Attachment TAMAT END 6/6

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