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1 UNIVERSITI MALAYA UNIVERSITY OF MALAYA PEPERIKSAAN IJAZAH SARJANA MUDA SAINS EXAMINATION FOR THE DEGREE OF BACHELOR OF SCIENCE PEPERIKSAAN IJAZAH SARJANA MUDA SAINS DENGAN PENDIDIKAN EXAMINATION FOR THE DEGREE OF BACHELOR OF SCIENCE WITH EDUCATION SESI AKADEMIK 2015/2016 : SEMESTER 1 ACADEMIC SESSION 2015/2016 : SEMESTER 1 SCES1230 : KIMIA FIZIK I PHYSICAL CHEMISTRY I Dis 2015/Jan 2016 Dec 2015/Jan 2016 MASA : 2 jam TIME : 2 hours ARAHAN KEPADA CALON : INSTRUCTIONS TO CANDIDATES : Kertas soalan ini mengandungi Bahagian A dan B. This paper consists of Section A and B. Jawab soalan mengikut arahan yang diberikan dalam setiap bahagian. Questions should be answered according to the instructions given in each section. (Kertas soalan ini mengandungi 5 soalan dalam 7 halaman yang dicetak) (This question paper consists of 5 questions on 7 printed pages)

2 BAHAGIAN A (50 MARKAH) SECTION A (50 MARKS) Jawab semua soalan. Answer all questions. 1. (a) Kelaskan setiap entiti berikut kepada sifat-sifat ekstensif atau intensif. Classify each of the following entities according to extensive or intensive properties. (iii) (iv) (v) (vi) Ketumpatan Density Tekanan Pressure Isipadu Volume Suhu Temperature Jisim Mass Entropi Entropy (3 markah/marks) Lakarkan gambarajah P-V untuk proses-proses isotermal, adiabatik, isobarik, dan isokorik pada satu graf. Sketch the P-V diagrams for isothermal, adiabatic, isobaric, and isochoric processes into one single graph. 2/7

3 (c) Satu tindakbalas kimia berlaku di dalam bekas yang mempunyai omboh dengan luas keratan rentas 60 cm 2. Gas yang terhasil oleh tindakbalas itu telah menggerakkan omboh tersebut sebanyak 15 cm bertentangan tekanan luaran sebanyak 130 kpa. Kirakan kerja yang dilakukan oleh sistem terhadap persekitaran dalam unit kilojoule. (Nota: 1 Pa = 1 Nm -2 ; 1 J = 1 Nm). A chemical reaction took place in a container fixed with a piston with a crosssectional area of 60 cm 2. The gas produced in the reaction moved the piston by 15 cm against an external pressure of 130 kpa. Calculate the work done by the system in kilojoules. (Note: 1 Pa = 1 Nm -2 ; 1 J = 1 Nm). (3 markah/marks) (d) Apabila 185 J tenaga dibekalkan sebagai haba pada tekanan malar kepada 2.3 mol sesuatu gas, suhu gas tersebut meningkat sebanyak 3.1 K. Kirakan kapasiti haba molar pada tekanan malar dan isipadu malar untuk gas tersebut. (Nota: R = J K -1 mol -1 ) When 185 J of energy is supplied as heat at a constant pressure to 2.3 moles of a gas, the temperature of the gas increases by 3.1 K. Calculate the molar heat capacities at constant pressure and constant volume of the gas. (Note: R = J K -1 mol -1 ) (e) Dari data berikut, hitung entalpi pembentukan piawai, f H,untuk pembentukan diborana, B 2 H 6 (g) pada suhu 298 K: From the following data, calculate the standard enthalpy of formation, f H, for diborane, B 2 H 6 (g) at 298 K: B 2 H 6 (g) + 3O 2 (g) B 2 O 3 (s) + 3H 2 O (g) H 1 = 1941 kj/mol 2B (s) + 3 O 2 (g) B 2 O 3 (s) 2 H 2 = 2368 kj/mol (iii) H 2 (g) O 2 (g) H 2 O (g) H 3 = kj/mol (6 markah/marks) (f). Jelaskan mengapa haba kapasiti pada suatu tekanan, C p, adalah lebih besar daripada haba kapasiti pada suatu isipadu malar, C v Explain why the heat capacity at a constant pressure, C p, is larger than that at a constant volume, C v. 3/7

4 2. (a) Nyatakan dua situasi di mana perubahan pada tenaga dalaman, U, bersamaan dengan perubahan entalpi, H. State two situations in which the change in the internal energy, U, is the same as the change in the enthalpy, H. Nyatakan kesemua hukum-hukum Termodinamik. State all the laws of Thermodynamics. (c) 1.00 mol gas ideal monoatomik dengan kapasiti haba C V,m = 3 2 R dipanaskan pada suhu 70 C sehingga 150 C pada tekanan malar. Hitung perubahan entropi, S, untuk sistem tersebut. (Note: R = J K -1 mol -1 ; V is volume; m is molar) 1.00 mole of a monoatomic ideal gas with a heat capacity of C V,m = 3 R is heated 2 at 70 C to 150 C at a constant pressure. Calculate the change in entropy, S, for the system. (Note: R = J K -1 mol -1 ; V is volume; m is molar) (d) (e) (f) Nyatakan keempat-empat proses yang berlaku pada kitaran Carnot. State the four processes that take place in a Carnot cycle. (2 markah/marks) Mengapakah tenaga bebas Gibbs, G, lebih biasa digunakan di eksperimen makmal kimia daripada tenaga bebas Helmholtz, A? Apakah signifikan perubahan tenaga bebas Gibbs free energy, G, dalam sesuatu proses kimia? Why is the Gibbs free energy, G, more commonly used in a laboratory chemistry experiment than that of the Helmholtz free energy, A? What is the significance of the change in Gibbs free energy, G, in a chemical process? Jelaskan hubungan perubahan, tenaga bebas Helmholtz, A, dengan kerja. Describe the change in the Helmholtz free energy, A, with work. 4/7

5 BAHAGIAN B (50 MARKAH) SECTION B (50 MARKS) Jawab 2 soalan sahaja. Answer 2 questions only 3. (a) Terangkan kenapa untuk kepekatan yang besar, pengunaan aktiviti adalah lebih tepat daripada kepekatan. Why in large concentrations, it is more accurate to use activities instead of concentrations. Terangkan elektrolit manakah, sama ada NaCl atau MgCl 2, mempunyai nilai koeffisi aktiviti min yang lebih rendah. Explain which electrolyte, NaCl or MgCl 2, has the lower mean activity coefficient value. (iii) Terangkan kefahaman tentang kealiran molar pada keterlarutan infinit, Λ o / S m 2 mol -1. Explain the understanding of molar conductivity at infinite dilution, Λ o / S m 2 mol -1. (15 markah/marks) Dari notasi sel berikut, berikan tindakbalas anod dan katod. From the following cell notation, give the anodic and cathodic reactions. Al (p) Al(OH) - 4 (ak) KOH (ak) O 2 (g) Pt (p) Al (s) Al(OH) - 4 (aq) KOH (aq) O 2 (g) Pt (s) Hg 2 Cl 2 (p) Hg (c) HCl (ak) H 2 (g) Pt (p) Hg 2 Cl 2 (s) Hg (l) HCl (aq) H 2 (g) Pt (s) (10 markah/marks) 4. (a) Terangkan yang berikut: Explain the following: Dua kesan yang memperlahankan kekonduksian ion (k / S m -1 ) pada kepekatan besar. the two effects which slows the ionic conductivity (k / S m -1 ) at large concentrations. 5/7

6 Keupayaan litar terbuka. open circuit potential. (iii) Rintangan dalam. internal resistance. (15 markah/marks) Dari tindakbalas berikut, tuliskan katod dan anod. From the chemical equations below, write the cathodic and anodic reactions 2MnO - 4 (ak) + 6H + (ak) + 5H 2 O 2 (c) 2Mn 2+ (ak) + 5O 2 (g) + 8H 2 O (c) 2MnO - 4 (aq) + 6H + (aq) + 5H 2 O 2 (l) 2Mn 2+ (aq) + 5O 2 (g) + 8H 2 O (l) 2CuCl 2 (ak) + H 2 (g) 2H + (ak) + 2CuCl - 2 (ak) 2CuCl 2 (aq) + H 2 (g) 2H + (aq) + 2CuCl - 2 (aq) (10 markah/marks) 5. (a) Suatu tindakbalas mempunyai skema berikut, di mana langkah 2 adalah langkah yang paling lambat. A chemical reaction has the following reaction scheme, where step 2 is the slowest step. H 2 N-C 2 H 4 OH + HCl X 1 langkah 1 H 2 N-C 2 H 4 OH + HCl X 1 step 1 X 1 X 2 langkah 2 X 1 X 2 step 2 X 3 Cl-C 2 H 4 OH + NH 3 langkah 3 X 3 Cl-C 2 H 4 OH + NH 3 step 3 Langkah yang manakah yang merupakan langkah penentu kadar untuk tindakbalas keseluruhan? Which is the rate determining step of the whole reaction? Terangkan apakah tenaga pengaktifan. Explain what is activation energy. 6/7

7 (iii) Terangkan langkah yang manakah mempunyai tenaga pengaktifan yang terbesar. Explain which step has the largest activation energy. Di mana X 1, X 2 dan X 3 adalah bahan perantaraan untuk langkah 1, 2 dan 3 masing-masing. Where X 1, X 2 and X 3 are the intermediates for steps 1, 2 and 3 respectively. (15 markah/marks) Bagaimanakah untuk mengubah suatu tindakbalas tertib kedua kepada tindakbalas tertib pertama. How to change a second order reaction into a first order reaction. Tuliskan persamaan hukum kadar untuk tindakbalas di dalam 5(a). Write the rate law equation for the reaction in 3a). (10 markah/marks) TAMAT END 7/7

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