SCES1200/ SIX1009 : PRINSIP-PRINSIP KIMIA/ KIMIA AM PRINCIPLES OF CHEMISTRY/ GENERAL CHEMISTRY

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1 UNIVERSITI MALAYA UNIVERSITY OF MALAYA PEPERIKSAAN IJAZAH SARJANA MUDA SAINS EXAMINATION FOR THE DEGREE OF BACHELOR OF SCIENCE PEPERIKSAAN IJAZAH SARJANA MUDA SAINS DENGAN PENDIDIKAN EXAMINATION FOR THE DEGREE OF BACHELOR OF SCIENCE WITH EDUCATION SESI AKADEMIK 2016/2017 : SEMESTER I ACADEMIC SESSION 2016/2017 : SEMESTER I SCES1200/ SIX1009 : PRINSIP-PRINSIP KIMIA/ KIMIA AM PRINCIPLES OF CHEMISTRY/ GENERAL CHEMISTRY Dis 2016/Jan 2017 Dec 2016/Jan 2017 Masa: 2 jam Time: 2 hours ARAHAN KEPADA CALON INSTRUCTIONS TO CANDIDATES : Kertas soalan ini mengandungi Bahagian A, B, C dan D. This paper consists of Section A, B, C and D. Jawab soalan mengikut arahan yang diberikan dalam setiap bahagian. Questions should be answered according to the instructions given in each section. (Kertas soalan ini mengandungi 6 soalan dalam 8 halaman yang dicetak) (This question paper consists of 6 questions on 8 printed pages)

2 BAHAGIAN A (25 MARKAH) SECTION A (25 MARKS) Jawab SEMUA soalan. Answer ALL questions. 1. (a) Jelaskan model atom Bohr, nyatakan dua kelemahan dan bagaimana ini diperbaiki dalam model atom Schrödinger? Describe Bohr atomic model, state two of its limitations and how it can be modified in the Schrödinger atomic model? (10 markah/marks) Kira panjang gelombang, λ radiasi yang dipancarkan akibat peralihan tahap tenaga daripada n = 2 kepada n = 1 bagi hidrogen atom. [Pemalar Planck, h = x Js, kelajuan cahaya, c = x 10 8 ms -1, Tenaga Rydberg bagi hidrogen, R H = x J] Calculate the wavelength, λ of the radiation emitted from to the transition of energy level from n=2 to n=1 of hydrogen atom. [Planck constant, h = x Js, velocity of light, c = x 10 8 ms -1, Rydberg energy for hydrogen, R H = x J] (c) Beri konfigurasi elektronbagi atom-atom berikut: Give the electronic configurations of the following atoms: 15 P, 25 Mn, 28 Ni, 31 Ga, dan/and 74 W (d) Lengkapkan nilai untuk empat nombor kuantum berikut. Apakah orbital yang bersamaan dengan nombor-nombor kuantum ini? Complete the values of the four quantum numbers. What are the orbitals corresponding to these quantum numbers? (i) n =?, l = 1, m l = 0, m s =? (ii) n = 3, l =?, m l = 1, m s = -½ (iii) n = 5, l =?, m l = 2, m s =? 2/8

3 BAHAGIAN B (25 MARKAH) SECTION B (25 MARKS) Jawab SEMUA soalan. Answer ALL questions. 2. Sebuah bekas 22.4 dm 3 mengandungi 1.5 mol H 2 dan2.5 mol N 2 pada K. Kirakan, A vessel of 22.4 dm 3 contains 1.5 mol H 2 and 2.5 mol N 2 at K. Calculate, (a) (c) Pecahan mol setiap komponen. The mole fractions of each component. Jumlah tekanan. Total pressure. Tekanan separa mereka. Their partial pressure. Diberi bahawa pemalar gas Given that gas constant R = dm 3 atm mol 1 K 1 (10 markah/marks) 3. Pemerhatian eksperimen sifat makroskopik gas dapat dijelaskan dengan teori molekul kinetik gas. The experimental observation of macroscopic properties of gasses can be explained with kinetic molecular theory of gases. (a) Terangkan pastulat teori molekul kinetik gas. Describe the postulate of the kinetic molecular theory of gases. Berdasarkan ungkapan berikut, terbit bahawa purata tenaga kinetik translasi molekul gas adalah berkadar terus dengan suhu mutlak. Based on the following expression, derive that the average translational kinetic energy of a gas molecule is directly proportional to the absolute temperature. PV = 1 3 Nmc2 3/8

4 di mana P ialah tekanan gas, V ialah isipadu gas, N ialah bilangan molekul, m ialah jisim setiap molekul, dan c adalah kelajuan punca kuasa dua molekul tersebut. where P is the gas pressure,v is the volume,nis the number of molecules, m is the molecular mass, and c is the root mean square speed of the molecules. (15 markah/marks) 4/8

5 BAHAGIAN C (25 MARKAH) SECTION C (25 MARKS) Jawab SEMUA soalan. Answer ALL questions. 4. (a) Takrifkan tenaga pengionan pertama. Define first ionization energy. (2 markah/marks) Tenaga pengionan pertama bagi setiap unsur dalam kala 3 adalah rendah berbanding unsur dalam kala 2. Sebagai contoh, tenaga pengionan pertama magnesium dalam kala 2 adalah 736 kjmol -1 manakala bagi berilium, yang berada di atas magnesium dalam kumpulan yang sama, mempunyai tenaga pengionan pertama sebanyak 900 kjmol -1. Dengan menggunakan magnesium dan berilium sebagai contoh, jelaskan mengapa tenaga pengionan pertama unsur di kala 3 lebih rendah daripada unsur di kala 2. The first ionization energy of each element in Period 3 is less than that for the corresponding element in Period 2. For example, magnesium in Group 2 has the first ionization energy of 736 kjmol -1, whereas beryllium, above it in the same group, has the first ionization energy of 900 kj mol -1. Using magnesium and beryllium as an example, explain why first ionization energies in Period 3 are smaller than the corresponding ones in Period 2. (c) Salah satu faktor yang menyumbang kepada tenaga pengionan pertama adalah cas nuklear. Litium mempunyai 1 proton lebih daripada helium (oleh itu cas nuclear lebih tinggi), tetapi tenaga pengionan pertama yang lebih rendah (519 kjmol -1 ). Jelaskan sebabnya. (Nombor atom: Li=3, He=2) One of the factors which affect first ionization energy is the nuclear charge. Lithium has 1 proton more than helium (and so a greater nuclear charge), and yet its first ionization energy is much lower (519 kjmol -1 ). Explain why. (Atomic number: Li=3, He=2) (6 markah/marks) 5. (a) Takrifkan isoelektronik. Define isoelectronic. (2 markah/marks) 5/8

6 Gas dwiatom manakah yang bersifat isoelektronik dengan ion karbid, C 2 2? (Nombor atom: H=1, C=6, N=7, O=8, F=9) Which two well-known diatomic gases are iso-electronic with the carbide ion, C 2 2? (Atomic number: H=1, C=6, N=7, O=8, F=9) (3 markah/marks) (c) Dengan menggunakan teori penghibridan orbital, tunjukkan bagaimana ikatan kovalen dalam molekul etena terbentuk. (Nombor atom: C=6, H=1) By using the orbital hybridization theory, show how covalent bonds are formed in an ethene molecule. (Atomic number: C=6, H=1) 6/8

7 BAHAGIAN D (25 MARKAH) SECTION D (25 MARKS) Jawab SEMUA soalan. Answer ALL questions. 6. (a) Imbangkan tindak balas kimia berikut: Balance the following chemical reactions: (i) CH 3 NH 2 + O 2 CO 2 + H 2 O + N 2 (ii) Cr(OH) 3 + HClO 4 Cr(ClO 4 ) 3 + H 2 O (4 markah/marks) Komponen utama kaca ialah silika (SiO 2 ). Ia boleh dilarutkan oleh asid hidroflourik, HF, dan mengikut tindak balas berikut yang menghasilkan silicon tetraflourida, SiF 4, sejenis gas pada suhu bilik. The main component of glass is silica (SiO 2 ). It can be dissolved by hydrofluoric acid, HF, and according to the following reaction that produces silicon tetrafluoride, SiF 4, a gas at room temperature. SiO 2 + 4HF SiF 4 + 2H 2 O Berapakah bilangan gram dan berapakah bilangan mol SiF 4 yang boleh dihasilkan daripada 63.4 g HF? How many grams and how many moles of SiF 4 can be produced from 63.4 g of HF? (6 markah/marks) (c) Jika 11.2 g Na bertindak balas dengan 9.00 g H 2 O dan 0.40 g H 2 terbentuk, apakah peratusan hasil tindak balas? If 11.2 g of Na reacts with 9.00 g of H 2 O and 0.40 g of H 2 is formed, what is the percent yield of the reaction? (d) Satu sampel garam tidak tulen (NaCl) dengan berat 6.5 g, telah dirawat dengan larutan perak nitrat berlebihan, g perak klorida (AgCl). Kirakan peratusan ketulenan garam. An impure sample of salt (NaCl) which weighed 6.5 g, gave on treatment with excess silver nitrate solution, g of silver chloride (AgCl). Calculate the percentage of purity of table salt. 7/8

8 (e) Satu hidrokarbon tertentu memerlukan 5 kali isipadu oksigen untuk pembakaran lengkap dan campuran gas yang dihasilkan telah digoncang dengan larutan kalium kaustik yang menunjukkan pengurangan bersamaan dengan tiga kali jumlah hidrokarbon yang diambil. Cari formula hidrokarbon. (Semua isipadu telah diukur pada suhu dan tekanan yang sama) A certain hydrocarbon required 5 times its volume of oxygen for complete combustion and the resultant gas mixture on being shaken with caustic potash solution showed a reduction equal to thrice the volume of the hydrocarbon taken. Find the formula of hydrocarbon. (All volumes have been measured at same temperature and pressure) [Jisim atom / atomic mass: H=1.0, C=12.0, N=14.0, O=16.0, F=19.0, Na=23.0, Si=28.1, Cl=35.5, K=39.1, Ag=107.9] TAMAT END 8/8

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