Jawab soalan mengikut arahan yang diberikan dalam setiap bahagian. Questions should be answered according to the instructions given in each section.

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1 UNIVERSITI MALAYA UNIVERSITY OF MALAYA PEPERIKSAAN IJAZAH SARJANA MUDA SAINS EXAMINATION FOR THE DEGREE OF BACHELOR OF SCIENCE PEPERIKSAAN IJAZAH SARJANA MUDA SAINS DENGAN PENDIDIKAN EXAMINATION FOR THE DEGREE OF BACHELOR OF SCIENCE WITH EDUCATION SESI AKADEMIK 2009/2010 : SEMESTER 1 ACADEMIC SESSION 2009/2010 : SEMESTER 1 SCES1200/SCEP1200 : PRINSIP-PRINSIP KIMIA PRINCIPLES OF CHEMISTRY November 2009 November 2009 MASA : 2 jam TIME : 2 hours ARAHAN KEPADA CALON : INSTRUCTIONS TO CANDIDATES : Kertas soalan ini mengandungi Bahagian A dan B. This paper consists of Section A and B. Jawab soalan mengikut arahan yang diberikan dalam setiap bahagian. Questions should be answered according to the instructions given in each section. (Kertas soalan ini mengandungi 7 soalan dalam 6 halaman yang dicetak) (This question paper consists of 7 questions on 6 printed pages)

2 SCES1200/SCEP1200/02 Pilih MANA-MANA (2) dari yang berikut. Choose ANY (2) from the following. BAHAGIAN A (50 MARKAH) SECTION A (50 MARKS) 1. (a) Jelaskan model atom Bohr, nyatakan dua daripada kelemahannya dan bagaimana ini diperbaiki dalam model atom Schrodinger? Describe Bohr atomic model, state two of its limitations and how are these modified in the Schodinger atomic model? (12 markah/ marks) (b) Satu elektron memenuhi satu orbital dengan nombor kuantum utama n=4 dan l = 2. An electron occupies an orbital with the principal quantum number n = 4 and l = 2. i. Apakah nilai-nilai munasabah bagi nombor kuantum m dan s bagi elektron ini? What are the possible values for quantum numbers m and s for this electron? ii. Lakar bentuk orbital atom yang diduduki elektron ini. Draw the shape of the atomic orbital occupied by this electron. (5 markah/ marks) (c) Nyatakan prinsip aufbau, prinsip pengecualian Pauli dan aturan Hund. Illustrasikan ini mengguna contoh berikut: State the aufbau principle, Pauli s exclusion principle and Hund s rule. Illustrate these using examples below: i. atom titanium (Z = 22) a titanium atom (Z = 22) ii. atom yang mempunyai nombor proton 24 an atom with proton number 24 (8 markah/ marks)

3 SCES1200/SCEP1200/03 2. (a) Nyatakan andaian dalam model yang diguna untuk menerbitkan taburan Maxwell. Lakar gambar rajah taburan Maxwell ini bagi halaju gas CO pada 300 K dan 200 K. Terangkan faktor yang mempengaruhi taburan ini bagi gas CO. State the assumptions in the model used to derive the Maxwell distribution. Sketch the Maxwell distribution diagram for the velocity of CO gas at 300 K and at 200 K. Explain the factors influencing this distribution for CO gas. (b) Hitung purata halaju punca kuasa dua bagi gas CO pada 300 K. [R = kg m 2 s -2 K -1 mol -1 ; jisim atom relatif: C = 12.0; O = 16.0]. Calculate the root mean square velocity of CO gas at 300 K. [R = kg m 2 s -2 K -1 mol -1 ; relative atomic mass: C = 12.0; O = 16.0]. (5 markah/marks) (c) Berikan persamaan van der Waals, dan guna ia untuk mengira tekanan 1 mol gas ammonia dalam bekas 1.0-L pada 25 o C [R = J K -1 mol -1 ; a = 4.2 atm L 2 mol -2 ; b = 0.04 L mol -1, 1atm= Pa]. Terangkan mengapa persamaan van der Waals ini tidak sah pada tekanan tinggi. Give the van der Waals equation and use this to calculate the pressure of 1.0 mole of ammonia gas in a 1.0-L container at 25 o C [R = J K -1 mol -1 ; a = 4.2 atm L 2 mol -2 ; b = 0.04 L mol -1, 1atm= Pa]. Explain why van der Waals equation is invalid at high pressures. 3. (a) Terbitkan hubungan de Broglie ( =h/p). Guna hubungan ini untuk mendapatkan jarak gelombang sebiji bola tenis berjisim 56 g dan bergerak dengan halaju 73 ms -1, yang juga merupakan halaju bola tenis terpantas yang di pukul oleh Bill Tilden pada tahun Kira juga juga halaju bagi elektron yang mempunyai jarak gelombang 500 nm sekiranya jisim (pada keadaan rehat) ialah 9.1x10-31 kg. Bincang kedua-dua keputusan ini. Derive the de Broglie relationship ( =p/h). Use this relationship to determine the wavelength of a tennis ball mass, 56 g and travelling at the speed of 73 ms -1 which is the speed of the fastest tennis ball served by Bill Tilden in Calculate also the velocity of an electron whose wavelength is 500 nm given the mass (at rest) is 9.1x10-31 kg. Discuss the two results. (15 markah/marks)

4 SCES1200/SCEP1200/04 (b) Berikan faktor ketermampatan dan bagaimana ini diguna untuk menerangkan sifat gas tidak unggul. Give the compressibility factor and how is this used to describe real gasses. (5 markah/ marks) (c) Semasa parti dalam sebuah bilik yang dingin pada 25 o C, ayah meniup belon sehingga isipadunya naik ke 3 L. Belon ini kemudiannya di bawa ke luar rumah yang suhunya 35 o C. Andainya tekanan dalam rumah dan luar rumah tidak berubah, hitung isipadu belon bila ia berada di luar. During a party inside a cooled room at 25 o C, father blew up a balloon to a volume of 3 L. The balloon was brought outside the house where the temperature was 35 o C. By assuming the pressures inside and outside the house were the same, calculate the volume of the balloon when it was outside the house. (5 markah/marks) BAHAGIAN B (50 MARKAH) SECTION B (50 MARKS) Jawab SEMUA soalan. Answer ALL questions. 4. Fosforus triklorida bertindak balas dengan oksigen menghasilkan POCl 3. Dalam satu eksperimen di makmal 11.0 g PCl 3 dan 1.34 g O 2 dicampurkan, dan sebanyak 11.2 g POCl 3 terasing. (a) Apakah peratus hasilan? (b) Tentukan bahan berlebihan, dan kirakan jisimnya pada penghujung tindak balas. [Jisim atom relatif: P = 31; O = 16; Cl = 35.5] Phosphorus trichloride reacts with oxygen to yield POCl 3. In an experiment performed in the laboratory, 11.0 g of PCl 3 and 1.34 g of O 2 are mixed, and 11.2 g of POCl 3 are isolated. (a) What is the percent yield? (b) Identify the excess reactant, and calculate the mass of its mass at the end of the reaction. [Relative atomic mass: P = 31; O = 16; Cl = 35.5] (20 markah/ marks)

5 SCES1200/SCEP1200/05 5. Kirakan jisim AgCl yang terbentuk dari tindak balas 500 ml 1.30 M CaCl 2 dengan AgNO 3 berlebihan. [Jisim atom relatif: Ag = 108; Cl = 35.5; Ca = 40; N = 14; O = 16] Calculate the mass of AgCl formed by the reaction of 500 ml of 1.30 M CaCl 2 with excess AgNO 3. [Relative atomic mass: Ag = 108; Cl = 35.5; Ca = 40; N = 14; O = 16] 6. Peratus ion kuprum dalam satu sampel boleh ditentukan melalui tindak balas dengan logam zink untuk menghasilkan logam kuprum. Cu 2+ (ak) + Zn(p) Cu(p) + Zn 2+ (ak) Kuprum yang terhasil dikumpul dan ditimbang. Jika 15.5 g sampel yang mengandungi ion kuprum menghasilkan 4.33 g logam kuprum apabila ia bertindak balas dengan zink, kirakan peratusan kuprum dalam sampel yang tak diketahui. [Jisim atom relatif: Cu = 63.54; Zn = 65.39] The percentage of copper ion in a sample can be determined by reaction with zinc metal to produce copper metal. Cu 2+ (aq) + Zn(s) Cu(s) + Zn 2+ (aq) The copper produced is collected and weighed. If a 15.5 g sample containing copper ions produces 4.33 g of copper metal when it reacts with zinc, calculate the percentage of copper in the unknown. [Relative atomic mass Cu = 63.54; Zn = 65.39] 7. (a) Eksperimen menunjukkan tenaga pengionan pertama litium kurang daripada berilium, tetapi tenaga pengionan kedua berilium kurang daripada litium. Jelaskan pemerhatian ini. [Nombor atom relatif Li:3; Be:4] Experiment shows that the first ionization energy of lithium is less than that of beryllium, but the second ionization energy of beryllium is less than that of lithium. Explain these observations. [Realtive atomic number Li : 3; Be : 4]

6 SCES1200/SCEP1200/06 (b) Terangkan penyataan yang berikut: Explain the following statements: i. Afiniti elektron kedua satu atom biasanya endotermik. The second electron affinity of an atom is always endothermic. ii. Cas nukleur berkesan yang di rasai oleh elekton luar meningkat dari kiri kekanan merentasi kala dalam jadual berkala. The effective nuclear charge felt by the outer electrons increases from left to right across a period in the periodic table. TAMAT END

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