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1 UNIVERSITI MALAYA UNIVERSITY OF MALAYA PEPERIKSAAN IJAZAH SARJANA MUDA SAINS EXAMINATION FOR THE DEGREE OF BACHELOR OF SCIENCE SESI AKADEMIK 2013/2014 : SEMESTER 2 ACADEMIC SESSION 2013/2014 : SEMESTER 2 SCES2313 : KIMIA NUKLEAR NUCLEAR CHEMISTRY Jun 2014 June 2014 MASA : 2 jam TIME : 2 hours ARAHAN KEPADA CALON : INSTRUCTIONS TO CANDIDATES : Kertas soalan ini mengandungi Bahagian A dan B. This paper consists of Section A and B. Jawab soalan mengikut arahan yang diberikan dalam setiap bahagian. Questions should be answered according to the instructions given in each section. (Kertas soalan ini mengandungi 6 soalan dalam 6 halaman yang dicetak) (This question paper consists of 6 questions on 6 printed pages)

2 BAHAGIAN A (50 MARKAH) SECTION A (50 MARKS) Jawab SEMUA soalan. Answer ALL questions. 1. (a) Lengkapkan skema pereputan dan tindak balas nuklear berikut: Complete the nuclear reaction and radioactive decays below: (i) (ii) (iii) (iv) (v) (vi) (vii) 222 Rn α U 234 Th + 27 Al + α 30 P + 51 V + n β + 13 N + + n + α 14 N + (10 markah/marks) Sebuah rakit daripada kerajaan silam Angkor memberikan bacaan 6.8 penyepaian 14 C seminit segram karbon. Anggarkan umur rakit tersebut. Karbon daripada bahan bernyawa adalah 15.3 penyepaian 14 C seminit segram karbon. Setengah-hayat untuk karbon-14 adalah x 10 3 tahun. Apakah anggapan yang perlu dibuat ketika menentukan umur rakit tersebut? A raft from the ancient kingdom of Angkor gave 6.8 disintegrations of 14 C per minute per gram of carbon. Estimate the age of this raft. Carbon from living material gives 15.3 disintegrations of 14 C per minute per gram of carbon. The half-life of carbon-14 is x 10 3 years. What assumption must be made in estimating your answer? (5 markah/marks) 2. (a) Tentukan jenis keseimbangan untuk pereputan bersiri berikut. Lukiskan gambarajah untuk keseimbangan fana, sekular dan tiada-keseimbangan. Labelkan gambarajah berikut dengan unsur yang betul. Determine the type of equilibria for the following decay series. Draw all the diagrams for transient, secular and non-equilibria. Label the diagram with the correct elements. 2/6

3 12.8 day 40.2 h Ba > La > Ce min 27 min Po > Pb > Bi-214 eq(1) eq(2) 4.51 x 10 9 years 24.1 day U > Th > Pa-234 eq(3) (12 markah/marks) Dalam keadaan keseimbangan yang dinyatakan dalam 2(a), tentukan: Under the equilibrium stated in 2(a) above, determine: (i) (ii) bilangan atom thorium untuk setiap 1 x 10 6 atom uranium. the number of thorium for every 1 x 10 6 uranium atoms. bilangan atom barium untuk setiap 3 x 10 6 atom lanthanum. the number of barium for every 3 x 10 6 lanthanum atoms. (6 markah/marks) 3. (a) Bincangkan kegunaan dan kepentingan persamaan Einstein, E = mc 2. Discuss the uses and importance of the Einstein equation, E = mc 2. (6 markah/marks) Perihalkan tiga kaedah untuk menghasilkan neutron. Sokong jawapan anda dengan persamaan nuklear Describe three methods for producing neutrons. Support your answers with nuclear equations. (11 markah/marks) Useful constants: Avogadro s number (N A ) = x mol -1 mass of proton = amu mass of neutron = amu speed of light (c) = 3.0 x 10 8 ms x amu = 1g 1 J = 1 kgm 2 s- 2 1 ev = x J 1 Mev = 10 6 ev 3/6

4 BAHAGIAN B (50 MARKAH) SECTION B (50 MARKS) Jawab SEMUA soalan. Answer ALL questions. 4. (a) Dalam tindak balas pembelahan neutron teraruh 238 Pu, banyak nuklid ringan akan dihasilkan. Lakarkan satu graf untuk menunjukkan perubahan peratusan hasil nuklid melawan nombor jisim sekiranya: In the neutron-induced fission of 238 Pu, many light nuclides will be formed. Sketch a graph showing the percentage difference in yield of the nuclides against the mass number if: (i) (ii) neutron bertenaga tinggi digunakan. high energy neutrons are used. neutron bertenaga rendah digunakan. low energy neutrons are used. (c) Bincangkan beberapa masalah yang berkaitan dengan penggunaan tindak balas pelakuran untuk menjana tenaga elektrik. Discuss some of the problems associated with using fusion to generate electricity. Bincangkan beberapa jenis interaksi sinaran gama dengan jirim. Discuss the various interactions of gamma-radiation with matter. (17 markah/marks) 5. (a) Satu 6.5 kg arnab telah terdedah kepada 35.4 rad radiasi. Kirakan berapa banyak tenaga yang diserap oleh badan arnab. A 6.5 kg rabbit was exposed to 35.4 rad of radiation. Calculate how much energy was absorbed by the rabbit s body. (c) Apakah risiko terhadap radiasi? Bincangkan cara untuk mengurangkan risiko pendedahan radiasi. What is radiation risk? Discuss ways to minimize radiation risks. Terangkan dengan bantuan gambarajah bagaimana kaunter Geiger- Müller digunakan untuk mengesan sinaran. Describe with the aid of a diagram on how Geiger-Müller counter is used to detect radiation. (17 markah/marks) 4/6

5 6. (a) Apabila sulfur radioaktif ditambah kepada larutan natrium sulfit beralkali, ion tiosulfat radioaktif akan terbentuk. Dengan penambahan Sr 2+, mendakan daripada SrS 2 O 3 diperolehi. Mendakan ini ditapis, dikeringkan dan kemudiannya dirawat dengan asid untuk menghasilkan pepejal sulfur, sulfur dioksida dan air. Sulfur dioksida didapati tidak radioaktif. Tuliskan persamaan bagi turutan tindak balas untuk menerangkan pemerhatian ini. Berikan ulasan mengenai struktur ion tiosulfat sebagai yang dijelaskan oleh eksperimen ini. When radioactive sulfur was added to an alkaline sodium sulfite solution, radioactive thiosulfate ion was formed. Upon the addition of Sr 2+, a precipitate of SrS 2 O 3 was obtained. The precipitate was filtered, dried and was then treated with acid to produce solid sulfur, sulfur dioxide and water. Sulfur dioxide was found to be not radioactive. Write the equations for the sequence of the reactions to explain the observation. Comment on the structure of the thiosulfate ion as elucidated by this experiment. (c) Satu meteor mengandungi 0.60 g Pb-206 untuk setiap 1.00 g U-238. Andaikan bahawa meteor itu tidak mengandungi sebarang Pb-206 pada masa pembentukannya, tentukan umur meteor tersebut. [Nota: Pereputan uranium-238 kepada plumbum-206 dengan separuh hayat 4.5 bilion tahun]. A meteor contained 0.60 g of Pb-206 for every 1.00 g of U-238. Assuming that the meteor did not contain any Pb-206 at the time of its formation, determine the age of the meteor. [Note: Uranium-238 decays to lead-206 with a half-life of 4.5 billion years] Penyinaran digunakan untuk mensterilkan beberapa makanan, bagi melanjutkan tempoh hayat penggunaan dengan membunuh pencemar mikrob. Proses ini melibatkan pendedahkan makanan kepada sinar gama, kebiasaan adalah dari sumber Co-60 atau Cs-137. Adakah makanan yang diradiasi ini radioaktif? Terangkan. Irradiation is used to sterilize some food to extend their usable lifetime by killing microbial contaminants. This process entails exposing the food to gamma rays, often from a Co-60 or Cs-137 source. Is the irradiated food radioactive? Explain. (16 markah/marks) 5/6

6 TAMAT END 6/6

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