RE: 2005 Annual Report: AR (Boyd Point Facility)

Transcription

1 1520 S. OHIO ST.. PINE BLUFF, ARKANSAS PHONE: (870) FAX (870) March 23,2006 Mr. Allen Gilliam Pretreatment Coordinator AEQ PO Box 8913 Little Rock, AR RE: 2005 Annual Report: AR (Boyd Point Facility) ear Allen: Please see attached a copy of our annual pretreatment report in compliance with our NPES permit. As a report requirement, I have listed the following: 1. Analytical data 2. List of SIU's We have no SIU's meeting the definition of SNC this year; therefore a newspaper notification has not been attached. All SIU's are now issued a permit for a five (5) year period. If you should need additional information, please give us a call at (870) Sincerely, PdPES PERMll FILE NPES #. IR/;;) 333.3/~ 35-0b/V5 PerrnR PN Correspondence Cc: Vincent Miles, Environmental Compliance Supervisor Lorraine Steward, Enforcement Assistant Attachment Technical Backup 'V ate Scanned l?!mxmi We are committed to provide our customers with efficient, reliable service while protecting the public health and maintaining a clean environment.

2 MONITORING RESULTS (1) FOR THE ANNUAL PRETREATMENT REPORT REPORTING YEAR 7005 T O TREATMENT PLANT :Ci tv Of Pi no P&i@ES PERMIT #AR AVERAGE POTW FLOW: 11 MG (1) It is advised that the influent and effluent samples are collected considering flow detention time through each plant. Analytical MQLs should be used so that the data can also be used for Local Limits assessment and htes application purpose. (2) Indicate reported unit of measurement. (3) This value was calculated during development of TBLL and based on State Water Quality Standards and implementation procedures. (4) This can be reported in ppm (mg/l), ppb (ua) or ibslday. (5) Record the named of any pollutants [40 CFR 122, Appendix, Table 11 and/or Table V] detected any the quantity in which they were detected.

3 MONITORING RESULTS (1) FOR THE ANNUAL PRETREATMENT REPORT REPORTING YEAR TO- TREATMENT PLANTGitg nf pi -wes PERMIT #AR00=716 AVERAGE POTW FLOW: 11 MG % IUFLOW: 75 % (1) It is advised that the influent and effluent samples are collected considering flow detention time thmugh each plant. Analytical MQLs should be used so that the data can also be used for Local Limits assessment and htes application purpose. (2) Indicate reported unit of measurement. (3) This value was calculated during development of TBLL and based on State Water Quality Standards and implementation procedures. (4) lhis can be reported in ppm (mg/l), ppb (ug~l) or lbs/day. (5) Record the named of any pollutants [40 CFR 122, Appendix. Table I1 andlor Table V] detected any the quantity in which they were detected.

4 ATTACHMENT C PRETREATMENT PERFORMANCE SUMNARY (PPS) iote: ALL QUESTIONS REFER TO THE INUSTRIAL PRETREATMENT PROGRAM AS APPROVE BY THE EPA. 'HE PERMITTEE SHOUL NOT ANSWER THE QUESTIONS BASE ON CHANGES MAE TO THE APPROVE PROGRAX >IITHOUT EPARTMENT AUTHORIZATION. I. General ~nfomation Zontrol Authority Name ~;n,w... Ly :ontact Person Kpnneth.~nhnsnn Position -- 'ontact Telephone ~ NPES permit Nos. m a Reporting Period ; 0 2 / ~7nr-16 (Beginning Month and Year) Total Number of Categorical IUs 7 (Ending Month and Year) Total Number of Significant Noncategorical IUs Significant Industrial User Compliance SIGNIFICANT INUSTRIAL USERS categorical onc categorical 1) No. of SIUs Submitting BMRs/Total No. Required.... Ll-!kL 2) No. of SIUs Submitting 90-ay Compliance Reports/No. Required.... & 3) No. of SIUs Submitting Semiannual Reports/ Total No. Required..... u-2 N/r\ 4) No. of SIUs Meeting Compliance Schedule/ Total No. Required to Meet Schedule. 5) No. of SIUs in significant Noncompliance/ Total NO. of SIUS d.0- n_/o 6) Rate of Significant Noncompliance for all SIUs (categorical and noncategorical).

5 Page 2 of Attachment C 111. Compliance Monitoring Program SIGNIFICANT INUSTRIAL USERS Categorical NonCategorical 1) No. of Control ocuments Issued/TotalNo. Required /7 9/9 2) No. of Nonsampling Inspections Conducted.. 7 / 7 9/9 3) No. of Sampling Visits Conducted /3 4) No. of Facilities Inspected (nonsampling). 7 / 7 8-% 5) No. of Facilities Sampled... LL-L a - h IV. Enforcement Actions SIGNIFICANT INUSTRIAL USERS Categorical NonCategorical 1) No. of Compliance Schedules Issued/No.... of Schedules Required 0/0 do- 2) No. of Notices of Violations Issued to SIUs q h 3) No. of Administrative Orders Issued to SIUs n 4) No. of Civil Suits Filed..... n + 5) No. of Criminal Suits Filed.... n n 6) No. of Significant Violators (attach newspaper publication) & 7) Amount of penalties Collected (total... dollars/ius assessed) 6 81 Other Actions (sewer bans, etc.)..... n n The following certification must be signed in order for this form to be considered complete: I certify that the information contained herein is complete and accurate to the best of my knowledge.. ate Y.

6 ATTACHMENT A PRETREATMENT PROGRAICSTATUS REPORT UPATE SIGNIFICANT INUSTRIAL USERS LIST ocument ndustrial User

7

8 ATTACHMENT B SIGNIFICANT VIOLATIONS - ENFORCEMENT ACTIONS TAKEN Collected

9 Updated 6/6/05 SIGNIFICANT INUSTRIES PERMIT INUSTRY MFG. OPERATION CONTACT PERSON EXP.ATE amark Uniform Services - MC 592 tom.dikos@uniform.aramark.com 2300 Warrenville Rd. owners Grove, IL Industrial Laundry Tom ikos Envir. Eng FAX: Attn: Linda Petrush Central Moloney, Inc. - A Power /P.O. Box 6608 Transformers Pine Bluff, AR Paul Skuban Envir. & Safety Mgr Central Moloney, Inc. - B p.0. BOX 6608 Pine Bluff, AR & :?;R: garyr@alliedtube.com All' d Tube & Conduit-A Power Transformers Iron/Steel Paul Skuban Envir. & Safety Mgr FAX: Gary Reynolds FAX: /07 ATC #I 0A Metal Finishing Gary Reynolds Pine Bluff, AR garyraalliedtu be.com FAX: garyr@alliedtube.com Metal Finishing Gary Reynolds Fax: Je rson Re Medical Center A W. 42"'. Pine Bluff, AR trussellw@jrmc.org Hospital Wesley Trussel ir. Plant Operations FAX: bjackson@plantersoil.com Cotton Seed Processor Brad Jackson Superintendent FAX:

10 PERMIT INUSTRY MFG. OPERATION CONTACT PERSON EXP.ATE Rolling Pin, Mfg Industrial ' r 3. Pine Bluff, AR Bakery Craig Eastham Plant Manager Ext. 108 FAX: Hood Packaging Cor 7 Multiwall P.O. Box 7068 Paper Sacks Pine Bluff, AR avid uffe FAX Stant, Inc. Pine Bluff, AR cmichael@stantinc.com TrefilARBE tommy.tooke@tyson.com Electroplating Metal-Finishing Steel Wire Belts FAX: Cooked Poultry Cloyd Michael Evironmental Coord FAX: Mike Barrett Evironmental Mgr ext. 794 Tommy Tooke Env. Manager FAX: Wheeling Machin Electroplating Metal-Finishing clampkin@wheelingmachineproducts.com Union Pacific RR iesel Oil Papermill ' - d Ro a Pine Bluff, AR jwstewar@up.com or 1001 W. 4'h Street North Little Rock, AR Attn: John Stewart Charlie Lampkin FAX: John Stewart istrict Manager FAX: (B.W.) Fax: SPECIAL PURPOSE USERS: waste p t Landfill Leachate Gravel P' d Gravel Pit Rd. Pine Bluff, AR (Billing) 2859 paces Feny Rd. Suite 1600 (Billing Address) Allanla. GA Waste Manaaement Landfill Leachate Hugh Cockrell 8/30/ WM-SRL#7-01 FAX: Mark R. Snvder. P.E. 8/30/2007

11 Shannon Rd. Landfill 7700 Shannon Rd. Pine Bluff, AR Project Mgr. Closed Sites (770) FAX: (770) WM-SRL#8-02

12 CORPORATION ATTN: Mr. Vincent Miles Pine Bluff, AR Page 1 of 24 ear Mr. Vincent Miles: Project escription: Twelve (12) water sample(s) received on November 29, 2005 NOV P.O. No This report is the analytical results and supporting information for the samples submitted to American lnterplex Corporation (AIC) on November The following results are applicable only to the samples identified by the control number referenced above. Accurate assessment of the data requires access to the entire document. Each section of the report has been reviewed and approved by the appropriate laboratory director or a qualified designee. ata has been validated using standard quality control measures (blanks, laboratory control samples, spike and spike duplicates) performed on at least 10% of the samples analyzed. Quality Assurance, instrumentation, maintenance and calibration were performed in accordance with guidelines established by the cited methodology. CL)RPORATION Enclosure(s): Chains of Custody 8600 Kanis Road - Little Rock, AR FAX

13 CORPORATION Pine Bluff, AR CASE NARRATIVE Page 2 of 24 SAMPLE RECEIPT Received Temperature: 1 C Receipt Verification: Complete Chain of Custody Sample I on Sample Labels ate and Time on Sample Labels Proper Sample Containers Within Holding Times Adequate Sample Volume Sample Integrity Proper Temperature Proper Preservative QUALIFIERS AIC Sample No. Qualifiers efinition R n-nitrosodiphenylamine cannot be separated from diphenylamine Result is from a secondary dilution factor Result is from a secondary dilution factor R n-nitrosodiphenylamine cannot be separated from diphenylamine Result is from a secondary dilution factor Result is from a secondary dilution factor R n-nitrosodiphenylamine cannot be separated from diphenylamine Result is from a secondary dilution factor -1 R n-nitrosodiphenylamine cannot be separated from diphenylamine -4 Result is from a secondary dilution factor -5 Result is from a secondary dilution factor References: "Methods for Chemical Analysis of Water and Wastes", EPN (Mar 1983) with updates and supplements EPN (Jun 1991), EPA16001R (Aug 1992) and EPA1600lR (Aug 1993). "Test Methods for Evaluating Solid Waste PhysicallChemical Methods (SW846)", Third Edition. "Standard Methods for the Examination of Water and Wastewaters", 20th edition "American Society for Testing and Materials" (ASTM). "Association of Analytical Chemists" (AOAC) Kanis Road Little Rock, AR FAX

14 CORPORATION Pine Bluff, AR ANALYTICAL RESULTS Page 3 of 24 AIC NO Sample Identification: BP-EFF-1105-VOA 11/28/ HRS Analyte Method Volatile Oraanic - Comoounds Bv EPA 624 Acrolein Acrylonitrile Benzene Bromoform Carbon tetrachloride Chlorobenzene Chlorodibromomethane Chloroethane 2-Chloroethylvinyl ether Chloroform ichlorobromomethane I.I-ichloroethane 1,2-ichloroethane I,l-ichloroethylene trans-i.2-ichloroethylene 1,2-ichloropropane cis-i,3-ichloropropylene trans-i.3-ichloropropylene Ethylbenzene Methyl bromide(bromomethane) Methyl chioride(chloromethane) Methylene chloride 1,1,2,2-Tetrachloroethane Tetrachloroethylene Toluene 1,I,I-Trichloroethane 1,I,2-Trichloroethane Trichloroethylene Vinyl chloride Surrogate Recovery Bromofluorobenzene ibromofluoromethane Toluene-8 Result < 50 < 50 < 4.4 < 4.7 < 2.8 < 6 < 3.1 < 8.7 < 5.1 < 1.6 < 2.2 < 4.7 < 2.8 < 2.8 < 1.6 < 6 < 5 < 1.3 < < 7.8 < < 4.1 < 6 < 3.8 < 5 < 1.9 < Units % % % Batch Qualifier AIC NO Sample Identification: BP-EFF-SEMI-VOA HRS Analyte Method BaselNeutral and Acid Com~ounds Bv EPA 625 Acenaphthene Acenaphthylene Anthracene Benzidine Benzo(a)anthracene Benzo(a)pyrene Benzo(g,h,i)perylene Benzo(k)fluoranthene 3.4-Benzofluoranthene Result Units Batch Qualifier 8600 Kanis Road. Little Rock. AR FAX

15 /IP CORPORAllON Pine Bluff, AR ANALYTICAL RESULTS Page 4 of 24 AIC No (Continued) Sample Identification: BP-EFF-SEMI-VOA 11/28/ HRS Analyte Method BaselNeutral and Acid Compounds By EPA 625 (Continued) ~1~{2-eth~lhexyl)phihalate 4-Bromophenyl phenyl ether Butylbenzyl phthalate 2-Chloronaphthalene 2-Chlorophenol 4-Chlorophenyi phenyl ether Chlysene i-n-butyl phthalate i-n-octyl phthalate ibenzo(a, h)anthracene 1-2-ichlorobenzene 1.3-ichlorobenzene 1,4-ichlorobenzene 3.3'-ichlorobenzidine 2,4-ichlorophenol iethyl phthalate imethyi phthalate 2.4-imethylphenol 4,6-initro-o-cresol 2,4-initrophenol 2.4-initrotoluene 2.6-initrotoluene 1,2-iphenylhydrazine Fluoranthene Fluorene Hexachlorobenzene Hexachlorobutadiene Hexachlorocyclopentadiene Hexachloroethane Indeno(l.2.3-cd)pyrene lsophorone n-nitrosodi-n-propylamine n-nitrosodimethylamine n-nitrosodiphenylamine Naphthalene Nitrobenzene 2-Nitrophenol 4-Nitrophenol p-chloro-m-cresol Pentachlorophenol Phenanthrene Phenol Pyrene 1,2.4-Trichlorobenzene 2,4,6-Trichlorophenol Result < 5.3 < 5.7 < < 1.9 < 2.5 < 1.9 < 3.3 c 4.2 < 2.5 < 2.5 < 2.5 < 2.5 < 1.9 < 1.9 < 4.4 < 17 < 2.7 < 1.9 < 1.6 < 2.7 < 24 < 42 < 5.7 < 1.9 < 11 < 2.2 < 1.9 < 1.9 < 0.9 < 5 < 1.6 < 3.7 < 2.2 < 0.84 < 0.96 < 1.9 < 1.6 < 1.9 < 3.6 < 2.4 < 3 < 3.6 < 5.4 < 1.5 < 1.9 < 1.9 < 2.7 Units ug1l Batch B B Qualifier 8600 Kanis Road Little Rock. AR w.americaninterplex.com FAX

16 Page 5 of 24 Pine Bluff, AR ANALYTICAL RESULTS AIC No (Continued) Sample Identification: BP-EFF-SEMI-VOA HRS Analyte Method Result RL Units Batch Qualifier BaselNeutral and Acid Compounds By EPA 625 (Continued) Surrogate Recovery 2-Fluorobiphenyl 2-Fluorophenol Nitrobenzene-5 Phenol-5 Terphenyl-l4 2.4,6-Tribromophenol AIC NO Sample Identification: BP-EFF-SEMI-VOA-2 I HRS ~ote! Elevated reporting. limits for chlorinated pesticides are due to interference. Analyte Method Result RL Units Batch Qualifier Organochlorine Pesticides and PCBs By EPA 608 Aldrin < uall G5631 alpha-bhc alpha-endosulfan beta-bhc beta-endosulfan Chlordane 4,4'- 4,4'-E 4,4'-T delta-bhc ~eldrin Endosulfan sulfate Endrin Endrin aldehyde gamma-bhc (Lindane) He~tachlor ~e'~tachlor epoxide PCB 1016 PCB 1221 PCB 1232 PCB 1242 PCB 1248 PCB 1254 PCB 1260 Toxaphene Surrogate Recovery ecachlorobiphenyl Tetrachloro-m-xylene uall < 2 2 G5631 < G5631 < G5631 AIC NO Sample Identification: INF-A-1105-VOA 11/28/ HRS Analyte Method Result RL Units Batch Qualifier Volatlle Oraanic - Comoounds Bv EPA 624 Acrolein < Kanis Road Little Rock, AR FAX

17 CORPORATION Pine Bluff, AR ANALYTICAL RESULTS Page 6 of 24 AIC No (Continued) Sam~le Identification: INF-A-1105-VOA 11/28/ HRS Analyte Method Volatile Organic Compounds By EPA 624 (Continued) ~enzene Bromoform Carbon tetrachloride Chlorobenzene Chlorodibromomethane Chloroethane 2-Chloroethylvinyl ether Chloroform ichlorobromomethane I,I-ichloroethane 1,2-ichloroethane 1.1-ichloroethylene trans-i,2-ichloroethylene 1,2-ichloropropane cis-i,3-ichloropropylene trans-i.3-ichloropropylene Ethylbenzene Methyl bromide(bromomethane) Methyl chloride(chloromethane) Methylene chloride 1,I,2.2-Tetrachloroethane Tetrachloroethylene Toluene I,I,I-Trichloroethane 1,I,2-Trichloroethane Trichloroethylene Vinyl chloride Surrogate Recovery Bromofluorobenzene ibromofluoromethane Toluene-8 Result < 50 < 4.4 < 4.7 < 2.8 < 6 < 3.1 < < 1.6 < 2.2 < 4.7 < 2.8 < 2.8 < 1.6 < 6 < 5 < < 8.9 < 7.8 < 10 < < < 5 < 1.9 < 6.4 Units % % % Batch Qualifier AIC NO Sample Identification: INF-A-SEMI-VOA 11/28/ HRS Note: Elevated reporting limits for semi-volatiles are due to interference. Analyte Method Result BaseINeutral and Acid Compounds By EPA 625 Acenaphthene Acenaphthylene Anthracene Benzidine Benzo(a)anthracene Benzo(a)pyrene Benzo(g.h,i)perylene Benzo(k)fluoranthene 3.4-Benzofluoranthene 8600 Kanis Road Little Rock, AR Units Batch Qualifier B FAX

18 CORPORATION Pine Bluff, AR ANALYTICAL RESULTS Page 7 of 24 AIC No (Continued) Sample Identification: INF-A-SEMI-VOA 11/28/ HRS Analyte Method - BaseINeutral and Acid Compounds By EPA 625 (Continued) Bis(2-chloroethoxy)methane Bis(2-chloroethy1)ether Bis(2-chloroisopropyl)ether Bis(2-ethylhexy1)phthalate 4-Bromophenyl phenyl ether Butylbenzyl phthalate 2-Chloronaphthalene 2-Chlorophenol 4-Chlorophenyl phenyl ether Chrysene i-n-butyl phthalate i-n-octyl phthalate ibenzo(a,h)anthracene 1,2-ichlorobenzene 1,3-ichlorobenzene 1,4-ichlorobenzene 3,Y-ichlorobenzidine 2,4-ichlorophenol iethyl phthalate imethyl phthalate 2,4-imethylphenol 4,6-initro-o-cresol 2,4-initrophenol 2.4-initrotoluene 2,6-initrotoluene 1,2-iphenylhydrazine Fluoranthene Fluorene Hexachlorobenzene Hexachlorobutadiene Hexachlorocyclopentadiene Hexachloroethane Indeno(l,2,3-cd)pyrene lsophorone n-nitrosodi-n-propylamine n-nitrosodimethylamine n-nitrosodiphenylamine Naphthalene Nitrobenzene 2-Nitrophenol 4-Nitrophenol pghloro-m-cresol Pentachlorophenol Phenanthrene Phenol Pyrene 1.2,4-Trichlorobenzene 2,4,6=Trichlorophenol Result < 53 < 57 < < 19 < 25 < 19 < 33 < 42 < 25 < 25 < 25 < 25 < 19 < 19 < 44 < 170 < 27 < 19 < 16 < 27 < 240 c 420 < 57 < 19 < 110 < 22 < 19 < 19 < 9 < 50 < 16 < 37 < 22 < 8.4 < 9.6 < 19 < 16 < 19 < 36 < 24 < 30 < 36 ' 54 < 15 < 19 < 19 < 27 Units Batch Qualifier R 8600 Kanis Road. Little Rock. AR w.americaninterplex.com FAX

19 CORPORATION Pine Bluff. AR ANALYTICAL RESULTS Page 8 of 24 AIC No (Continued) Sample Identification: INF-A-SEMI-VOA 11/28/ HRS Analyte Method Result RL Units Batch Qualifier BaselNeutral and Acid Compounds By EPA 625 (Continued) Surrogate Recovery 2-Fluorobiphenyl 2-Fluorophenol Nitrobenzene-5 Phenol-5 Terphenyl-l4 2.4,6-Tribromophenol AIC NO Sample Identification: INF-A-SEMI-VOA-2 11/28/ HRS Note: Elevated reporting limits for chlorinated pesticides are due to interference. Analyte Method Result RL Organochlorine Pesticides and PCBs By EPA 608 Aldrin < alpha-bhc < alpha-endosulfan < beta-bhc < beta-endosulfan < Chlordane < '- < ,4'-E < ,4'-T < delta-bhc < ieldrin < Endosulfan sulfate < Endrin c Endrin aldehyde < gamma-bhc (Lindane) < Heptachlor < Heptachlor epoxide < PCB 1016 < PCB 1221 PCB 1232 PCB 1242 PCB 1248 PCB 1254 PCB 1260 Toxaphene Surrogate Recovery ecachlorobiphenyl Tetrachloro-m-xylene Units uqll Batch G5631 G5631 G5631 G5631 G5631 G5631 G5631 G5631 G5631 G5631 G5631 G5631 G5631 G5631 G5631 G5631 G5631 G5631 Qualifier < G5631 < G5631 < 3 3 G5631 < G5631 < G5631 < 3 3 G5631 < G5631 AIC NO Sample Identification: INF-C-1105-VOA 11/28/ HRS Analyte Method Result RL Units Batch Qualifier Volatile Organic Compounds By EPA 624 Acrolein < Kanis Road. Little Rock, AR FAX

20 Page 9 of 24 I Pine Bluff, AR ANALYTICAL RESULTS AIC No (Continued) Sam~le Identification: INF-C-1105-VOA HRS Analyte Method Volatile Oraanic Com~ounds Bv EPA 624 (Continued) ~crylonitxle Benzene Bromoform Carbon tetrachloride Chlorobenzene Chlorodibromomethane Chloroethane 2-Chloroethylvinyl ether Chloroform ichlorobromomethane I,l-ichloroethane 1,2-ichloroethane I,l-ichloroethylene trans-i,2-ichloroethylene 1,2-ichloropropane cis-1.3-ichloropropylene trans-i,3-ichloropropylene Ethylbenzene Methyl bromide(bromomethane) Methyl chloride(chloromethane) Methylene chloride 1,1,2,2-Tetrachloroethane Tetrachloroethylene Toluene 1,I,I-Trichloroethane 1,I,2-Trichloroethane Trichloroethylene Vinyl chloride Surrogate Recovery Bromofluorobenzene ibromofluoromethane Toluene-8 Result < 50 < 4.4 < 4.7 < 2.8 < 6 c 3.1 < 8.7 < 5.1 < 1.6 < 2.2 < 4.7 < 2.8 < 2.8 < 1.6 < 6 < 5 < 1.3 < 7.2 < 8.9 < 7.8 < 10 < 6.9 < 4.1 < 6 < 3.8 < 5 < 1.9 < Units % % % Batch Qualifier AIC NO Sample Identification: INF-C-SEMI-VOA 11/28/ HRS ~otei Elevated reporting limits for semi-volatiles are due to interference. Analyte Method Result BaselNeutral and Acid CO~OU~~S Bv EPA 625 Acenaphthene Acenaphthylene Anthracene Benzidine Benzo(a)anthracene Benzo(a)pyrene Units Batch Qualifier B3735 B Kanis Road. Little Rock, AR FAX

21 CORPORATION Pine Bluff. AR ANALYTICAL RESULTS Control No Page 10 of 24 AIC No (Continued) Sample Identification: INF-C-SEMI-VOA HRS Analyte Method Result BaseINeutral and Acid Compounds By EPA 625 (Continued) ~is[2-eth~lhex~l)ph~halate 4-Bromophenyl phenyl ether Butylbenzyl phthalate 2-Chloronaphthalene 2-Chlorophenol 4-Chlorophenyl phenyl ether Chlysene i-n-butyl phthalate i-n-octyl phthalate ibenzo(a, h)anthracene 1,2-ichlorobenzene I,3-ichlorobenzene 1-4-ichlorobenzene 3.3'-ichlorobenzidine 2,4-ichlorophenol iethyl phthalate imethyl phthalate 2,4-imethylphenol 4,6-initro-o-cresol 2,Cinitrophenol 2,4-initrotoluene 2.6-initrotoluene 1,Ziphenylhydrazine Fluoranthene Fluorene Hexachlorobenzene Hexachlorobutadiene Hexachlorocyclopentadiene Hexachloroethane Indeno(l.2,3-cd)pyrene lsophorone n-nitrosodi-n-propylamine n-nitrosodimethylamine n-nitrosodiphenylamine Naphthalene Nitrobenzene 2-Nitrophenol 4-Nitrophenol p-chloro-m-cresol Pentachlorophenol Phenanthrene Phenol Pyrene 1,2.4-Trichlorobenzene 2,4,6-Trichlorophenol Units Ugll Batch B3735 Qualifier R 8600 Kanis Road. Little Rock, AR FAX

22 /IP CORPORATION Pine Bluff, AR ANALYTICAL RESULTS Page 11 of 24 AIC No (Continued) Sample Identification: INF-C-SEMI-VOA 11/28/ HRS Analyte Method Result RL Units Batch Qualifier BaselNeutral and Acid Compounds By EPA 625 (Continued) Surrogate Recovery 2-Fluorobiphenyl 2-Fluorophenol Nitrobenzene-5 Phenol-5 Terphenyl-l4 2,4,6-Tribromophenol AIC NO Sample Identification: INF-C-SEMI-VOA-2 11/28/ HRS ~ote! Elevated reporting limits for chlorinated pesticides are due to interference Analyte Method Organochlorine Pesticides and PCBs By EPA 608 Aldrin alpha-bhc alpha-endosulfan beta-bhc beta-endosulfan Chlordane 4.4'- 4,4'-E 4.4'-T delta-bhc ieldrin Endosulfan sulfate Endrin Endrin aldehyde gamma-bhc (Lindane) Heptachlor Heotachlor eooxide PCB 1221 PCB 1232 PCB 1242 PCB 1248 PCB 1254 PCB 1260 Toxaphene Surrogate Recovery ecachlorobiphenyl Tetrachloro-m-xylene Result RL Units Batch Qualifier uall c G5631 c G5631 < G5631 c 3 3 uall G5631 < G5631 C G G5631 < G5631 AIC NO Sample Identification: BP-EFF-1105-Hg 11/28/ HRS Analyte Method Result RL Units Batch Qualifier Mercury EPA mgll S Kanis Road Little Rock. AR FAX

23 CORPORATlON Pine Bluff, AR ANALYTICAL RESULTS ecember Page 12 of 24 AIC NO Sam~le Identification: INF-C-1105-Ha - 11/28/ HRS Analyte Method Result RL Units Batch Qualifier Mercury EPA mgll S17130 AIC NO Sam~le Identification: INF-A-1105-Ha - 11/28/ HRS Analyte Method Result RL Units Batch Qualifier Mercury EPA mgll S Kanis Road. Little Rock, AR FAX

24 CORPORATION Pine Bluff. AR SAMPLE PREPARATION REPORT ecember Page 13 of 24 AIC No atemime atemime Analyte Prepared By Analyzed By ilution Batch Qualifier Volatile Organic Compounds 30NOV AIC No atemime atemime Analyte Prepared By Analyzed By ilution Batch Qualifier BaselNeutral and Acid Compounds 01EC EC R AIC No atflime atemime Analyte Prepared By Analyzed By ilution Batch Qualifier Organochlorine Pesticides and PCBs 29NOV EC G5631 AIC No atemime atemime Analyte Prepared By Analyzed By ilution Batch Qualifier Volatile Organic Compounds 30NOV AIC No aterrime ateitime Analyte Prepared By Analyzed By ilution Batch Qualifier BaseINeutral and Acid Compounds 01EC EC R AIC No atemime atemime Analyte Prepared By Analyzed By ilution Batch Qualifier Organochlorine Pesticides and PCBs 29NOV EC G5631 AIC No atemime atemime Analyte Prepared By Analyzed By ilution Batch Qualifier Volatile Organic Compounds 30NOV AIC No atemime atemime Analyte Prepared By Analyzed By ilution Batch Qualifier BaselNeutral and Acid Com~ounds 01 EC EC R AIC No atemime atemime Analyte Prepared By Analyzed By ilution Batch Qualifier Organochlorine Pesticides and PCBs 29NOV EC G5631 AIC No atemime atemime Analyte Prepared By Analyzed By ilution Batch Qualifier Mercury 30NOV NOV S17130 AIC No atemime atemime Analyte Prepared By Analyzed By ilution Batch Qualifier Mercury 30NOV NOV Kanis Road Little Rock, AR FAX

25 I Pine Bluff, AR SAMPLE PREPARATION REPORT Page 14 of 24 AIC No aterrime aterrime Analyte Prepared By Analyzed By ilution Batch Qualifier Mercury 30NOV NOV S Kanis Road. Little Rock. AR FAX

26 CORPORATION Pine Bluff, AR LABORATORY CONTROL SAMPLE RESULTS Page 15 of 24 Analyte Mercury BaseINeutral and Acid Compou Acenaphthene Acenaphthylene Anthracene Benzo(a)anthracene Benzo(a)pyrene Benzo(g,h,i)perylene Benzo(k)fluoranthene 3,4-Benzofluoranthene Bis(2-chloroethoxy)methane Bis(2-ch1oroethyl)ether Bis(2-chloroisopropyI)ether Bis(2-ethylhexy1)phthalate 4-Bromophenyl phenyl ether Butylbenzyl phthalate 2-Chloronaphthalene 2-Chlorophenol 4-Chlorophenyl phenyl ether Chrysene i-n-butyl phthalate i-n-octyl phthalate ibenzo(a, h)anthracene 1.2-ichlorobenzene 1-3-ichlorobenzene 1,4-ichlorobenzene 2,4-ichlorophenol iethyl phthalate imethyl phthalate 2,4-imethylphenol 4,6-initro-o-cresol 2,4-initrophenol 2,4-initrotoluene 2,6-initrotoluene 1,2-iphenylhydrazine Fluoranthene Fluorene Hexachlorobenzene Hexachlorobutadiene Hexachlorocyclopentadiene Hexachloroethane Indeno(l,2.3-cd)pyrene lsophorone n-nitrosodi-n-propylamine n-nitrosodimethylamine n-nitrosodiphenylamine Naphthalene Nitrobenzene nds Spike mount mgll Recovery Limits RP RP Limit Kanis Road. Little Rock. AR FAX

27 CORPORATION Pine Bluff, AR LABORATORY CONTROL SAMPLE RESULTS ecember Page 16 of 24 Spike Analyte Amount BaseINeutral and Acid Compounds (Continued) 2-Nitrophenol Nitrophenol 100 p-chloro-m-cresol 100 Pentachlorophenol 100 Phenanthrene 100 Phenol 100 Pyrene 100 1,2,4-Trichlorobenzene 100 2,4,6-Trichlorophenol 100 Surrogate Recovery 2-Fluorobiphenyl 50 2-Fluorophenol 100 Nitrobenzene-5 50 Phenol Terphenyl-l4 50 2,4,6-Tribromophenol 100 Volatile Organic Compounds Acrylonitrile 200 Benzene 20 Bromoform 20 Carbon tetrachloride 20 Chlorobenzene 20 Chlorodibromomethane 20 Chloroethane 20 Chloroform 20 ichlorobromomethane 20 I, l-ichloroethane 20 1,2-ichloroethane 20 I, l-ichloroethylene 20 trans-l,2-ichloroethylene 20 1,2-ichloropropane 20 cis-1,3-ichloropropylene 20 trans-i.3-ichloropropylene 20 Ethylbenzene 20 Methyl bromide(bromomethane) 20 Methyl chloride(chloromethane) 20 Methylene chloride 20 1,1.2,2-Tetrachloroethane 20 Tetrachloroethylene 20 Toluene 20 I.I,l-Trichloroethane 20 1,I,2-Trichloroethane 20 Trichloroethylene 20 Vinyl chloride 20 Surrogate Recovery Bromofluorobenzene 50 ibromofluoromethane 50 % Recovery % Recovely Limits RP RP Limit Batch Qualifier 8600 Kanis Road - Little Rock. AR FAX

28 CORPORATION Pine Bluff. AR LABORATORY CONTROL SAMPLE RESULTS Page 17 of 24 Spike Analyte Amount Volatile Organic Compounds (Continued) Surrogate Recovery Toluene-8 50 Organochlorine Pesticides and PCBs Aldrin 0.5 alpha-bhc 0.5 alpha-endosulfan 0.5 beta-bhc 0.5 beta-endosulfan ' '-E 0.5 4,4-T 0.5 delta-bhc 0.5 ieldrin 0.5 Endosulfan sulfate 0.5 Endrin 0.5 Endrin aldehyde 0.5 garnma-bhc (Lindane) 0.5 Heptachlor 0.5 Heptachlor epoxide 0.5 Surrogate Recovery ecachlorobiphenyl 1 Tetrachloro-m-xylene 1 % Recovery % Recovery Limits RP RP Limit Batch Qualifier 8600 Kanis Road Little Rock. AR FAX

29 CORPORATION Pine Bluff, AR MATRIX SPIKE SAMPLE RESULTS Page 18 of 24 Spike % %Recovery Analyte mount Recovery Limits Mercury mgll BaselNeutral and Acid Compounds Acenaphthene 100 Acenaphthylene 100 Anthracene 100 Benzo(a)anthracene 100 Benzo(a)pyrene 100 Benzo(g, h,i)perylene 100 8enzolk)fluoranthene 100 uall 3,4-~&n;ofluoranthene Bis(2-chloroethoxy)methane Bis(2-chloroethy1)ether Bis(2chloroisopropyl)ether Bis(2-ethylhexy1)phthalate 4-Bromophenyl phenyl ether Butylbenzyl phthalate 2-Chloronaphthalene 2-Chlorophenol 4-Chlorophenyl phenyl ether Chrysene i-n-butyi phthalate i-n-octyl phthalate ibenzo(a,h)anthracene 1,2-ichlorobenzene 1,3-ichlorobenzene I,4-ichlorobenzene 2,4-ichlorophenol iethyl phthalate imethyl phthalate 2.4-imethylphenol 4,6-initro-o-cresol 2,4-initrophenol 2,4-initrotoluene 2.6-initrotoluene 1,2-iphenylhydrazine Fluoranthene Fluorene Hexachlorobenzene Hexachlorobutadiene Hexachlorocyclopentadiene Hexachloroethane Indeno(l,2,3-cd)pyrene lsophorone n-nitrosodi-n-propylamine n-nitrosodimethylamine n-nitrosodiphenylamine Naphthalene Nitrobenzene 100 ug ug1l RP... - RP Limit Batch Qualifier S Kanis Road. Little Rock, AR w.americaninterplex.wm FAX

30 CORPORATION Pine Bluff, AR MATRIX SPIKE SAMPLE RESULTS Page 19 of 24 Spike % % Recovety Analyte Amount Recovery Limits BaselNeutral and Acid Compounds (Continued) 2-Nitrophenol Nitrophenol pghloro-m-cresol Pentachlorophenol Phenanthrene Phenol Pyrene Trichlorobenzene Trichlorophenol Surrogate Recovely 2-Fluorobiphenyl 2-Fluorophenol Nitrobenzene-5 Phenol-5 Terphenyl-l4 2,4,6-Tribromophenol Volatile Organic Compounds Acrylonitrile Benzene Bromoform Carbon tetrachloride Chlorobenzene Chlorodibromomethane Chloroethane Chloroform ichlorobromomethane I,I-ichloroethane 1,2-ichloroethane I,I-ichloroethylene trans-l,2-ichloroethylene 1,2-ichloropropane cis-i,3-ichloropropylene trans-i,3-ichloropropylene Ethylbenzene Methyl bromide(8romomethane) Methyl chloride(chloromethane) Methylene chloride 1,I,2,2-Tetrachloroethane Tetrachloroethylene Toluene 1.1,I-Trichloroethane 1.I.2-Trichloroethane Trichloroethylene Vinyl chloride Surrogate Recovery Bromofluorobenzene ibromofluoromethane RP RP Limit Batch Qualifier 8600 Kanis Road Little Rock, AR FAX

31 CORPORATION Pine Bluff, AR MATRIX SPIKE SAMPLE RESULTS Page 20 of 24 -,~ ~ Analyte Amount Volatile Organic CO~OU~~S (Continued) ~urro~at;! ~ecovery Toluene-8 Organochlorine Pesticides and PCBs Aldrin alpha-bhc alpha-endosulfan beta-bhc beta-endosulfan 4,4'- 4,4'-E 4,4'-T delta-bhc ieldrin Endosulfan sulfate Endrin Endrin aldehyde gamma-bhc (Lindane) Heptachlor Heptachlor epoxide Surrogate Recovery ecachlorobiphenyl Tetrachloro-m-xylene Recovery Limits RP RP Limit Batch Qualifier 8600 Kanis Road. Little Rock, AR FAX

32 CORPORATION Pine Bluff. AR LABORATORY BLANK RESULTS Page 21 of 24 Analyte Method Result Units RL Sample Qualifier Mercury EPA < mgll S BaselNeutral and Acid Compounds By EPA 625 Acena~hthene < 1.9 uall 1.9 B ~cenaphthylene Anthracene Benzidine Benzo(a)anthracene Benzo(a)pyrene Benzo(g,h,i)perylene Benzo(k)fluoranthene 3,4-Benzofluoranthene Bis(2-chloroethoxy)methane Bis(2-chloroethy1)ether Bis(2-chloroisopropyI)ether Bis(2-ethylhexy1)phthalate 4-Bromophenyl phenyl ether Butylbenzyl phthalate 2-Chloronaphthalene 2-Chlorophenol 4-Chlorophenyl phenyl ether Chrysene i-n-butyl phthalate i-n-octyl phthalate ibenzo(a, h)anthracene 1,2-ichlorobenzene 1,3-ichlorobenzene 1.4-ichlorobenzene 3,3'-ichlorobenzidine 2,4-ichlorophenol iethyl phthalate imethyl phthalate 2,4-imethylphenol 4,6-initro-o-cresol 2.4-initrophenol 2,4-initrotoluene 2,6-initrotoluene 1,Z-iphenylhydrazine Fluoranthene Fluorene Hexachlorobenzene Hexachlorobutadiene Hexachlorocyclopentadiene Hexachloroethane Indeno(l,2,3-cd)pyrene lsophorone n-nitrosodiphenylamine Naphthalene Nitrobenzene < 3.5 uill < 1.9 < 44 < 7.8 < 2.5 < 4.1 < 2.5 < 4.8 < 5.3 < 5.7 < 5.7 ~2.5 < 1.9 < 2.5 < 1.9 < 3.3 < 4.2 < 2.5 < 2.5 < 2.5 < 2.5 < 1.9 < 1.9 < 4.4 < 16.5 < 2.7 < 1.9 < 1.6 c 2.7 < 24 < 42 < 5.7 ug/l < 1.9 < 11 < 2.2 < 1.9 < 1.9 < 0.9 < 5 < 1.6 < 3.7 < 2.2 < 0.84 < 0.96 < 1.9 < 1.6 < Kanis Road. Little Rock, AR FAX

33 CORPORATION Pine Bluff, AR LABORATORY BLANK RESUl TS Control No Page 22 of 24 Analyte Method BaselNeutral and Acid Com~ounds Bv EPA Nitrophenol 4-Nitrophenol p-chloro-m-cresol Pentachlorophenol Phenanthrene Phenol Pyrene 1,2,4-Trichlorobenzene 2,4,6-Trichlorophenol Surrogate ~ecovery 2-Fluorobiphenyl 2-Fluorophenol Nitrobenzene-5 Phenol-5 Terphenyl-l4 2,4,6-Tribromophenol Volatile Organic Compounds By EPA 624 Acrolein Acrylonitrile Benzene Bromoform Carbon tetrachloride Chlorobenzene Chlorodibromomethane Chloroethane 2-Chloroethylvinyl ether Chloroform ichlorobromomethane I.I-ichloroethane 1.2-ichloroethane 1.1-ichloroethylene trans-i,2-ichloroethylene 1,2-ichloropropane cis-i,3-ichloropropylene trans-i,3-ichloropropylene Ethylbenzene Methyl bromide(bromomethane) Methyl chloride(chloromethane) Methylene chloride 1,1.2,2-Tetrachloroethane Tetrachloroethylene Toluene 1,I,I-Trichloroethane 1,I.2-Trichloroethane Trichloroethylene Vinyl chloride Surrogate Recovery Bromofluorobenzene ibromofluoromethane Result Units QC RL Sample Qualifier Kanis Road. Linle Rock. AR FAX

34 CORPORATION Pine Bluff, AR LABORATORY BLANK RESULTS Control No Page 23 of 24 Analyte Volatile Oraanic CO~OU~~S Bv EPA 624 Method Result Units QC RL Sample Qualifier ~oluene-~~ Organochlorine Pesticides and PCBs By EPA 608 ~ldrin alpha-bhc alpha-endosulfan beta-bhc beta-endosulfan Chlordane 4,4'- 4,4'-E 4,4-T delta-bhc ieldrin Endosulfan sulfate Endrin Endrin aldehyde garnma-bhc (Lindane) Heptachlor Heptachlor epoxide PCB 1016 PCB 1221 PCB 1232 PCB 1242 PCB 1248 PCB 1254 PCB 1260 Toxaphene Surrogate Recovery ecachlorobiphenyl Tetrachloro-rn-xylene 8600 Kanis Road. Little Rock. AR FAX

35 ~~ ~~~ ~ ~ ~ ~ ~~ ~~~ ~~~~ ~ ~ ~ -~ ~~ ~ CORPORATION Pine Bluff, AR QUALITY CONTROL PREPARATION REPORT Page 24 of 24 LABORATORY CONTROL SAMPLES ateitime atemime QC Analyte Prepared By Analyzed By ilution Sample Qualifier Mercury 30NOV NOV S Mercurv 30NOV NOV S ~asel~eutral and Ac~d Compounds 01 EC EC BaselNeutral and Acld Com~ounds 01 EC EC B Volatile Organic Compounds 30NOV Volatile organic compounds 30NOV Organochlorine Pesticides and PCBs 28NOV NOV G Organochlorine Pesticides and PCBs 29NOV EC G MATRIX SPIKE SAMPLES ateitime atemime QC Analyte Prepared By Analyzed By ilution Sample Qualifier Mercury 30NOV NOV S Mercury 30NOV NOV S BaselNeutral and Acid Compounds 01EC EC BaselNeutral and Acid CO~OU~~S 01 EC EC ~~, Volatile Oraanic CO~~OU~~S 30~0~ Volatile 0r;anic omb bounds 30NOV ~r~anochlor~ne ~est~c~des and PCBs 28NOV NOV G Organochlor~ne Pesticides and PCBs 28NOV NOV G LABORATORY BLANKS aterrime ateitime QC Analyte Prepared By Analyzed By ilution Sample Qualifier Mercurv 30NOV NOV S ~asel~eutral and Acid Compounds 01EC EC R Volatile Organic Compounds Organochlorine Pesticides and PCBs 30NOV NOV EC G Kanis Road. Little Rock, AR FAX

36 2005 SAMPLE CUSTOY REPORT PINE BLUFF WASTEWATER UTILITY 1520 SOUTH OHIO STREET PINE BLUFF, AR PBWWU LAB. TEL. (870) PBWWU LAB. FAX. NUMBER: (870) P.O. NUMBER: ANALYSIS PERFORME BY;. MTERPLEX CORPORATION SAMPLE TRANSPORT BY: - SAMPLE TRANSPORT ATE & TIME: f I.Z 4 - b 5- J ; (h) I,& kau 31. HAVE RECEIVE WASTEWATER SAMPLE(S) FROM PINE BLUFF WASTEWATER UTILITY AN O HEREBY FIN THESE SAMPLE(S) TO BE AEQUATE UPON RECEIPT AN THEREBY SUITABLE FOR LABORATORY ANALYSIS. PLEASE INCLUE A P.O. NUMBER WITH THE PWE BLUPF WASI'EWATER INVOICE ALL RECORS ARE TO BE RETAINE FOR A PERIO OF AT L M THREE YEARS SEN INVOICE TO : EBORAH BASS. CONTROLLER SEN ANALYTICAL RESULTS TO : VINCENT MILES, LABORATORY SUPERVISOR

37 2005 SAMPLE CUSTOY REPORT PINE BLUFF WASTEWATER UTILITY 1520 SOUTH OHIO S WET PINE BLUFF, AR P B W LAB. TEL. (870) PBWWU LAB. FAX. NUMBER: (870) P.O. NIJMBER: MONTH: ANALYSIS PERFORME B& WR1C.W JNTERPLEX CORPORATION SAMPLE TRANSPORT BY: /-&.L-$, SAMPLE TRANSPORT ATE & TIME: ( L? $- ; /;30 (hrs) I GX - - il r r- La y, HAVE RECE~ WASTEWATER SAMPLE(S) FROM PINE BLUFF WASTEWATER UTILITY AN O HEREBY FIN THESE SAMPLE(S) TO BE AEQUATE UPON RECEIIT AN THEREBY SUITABLE FOR LABORATORY ANALYSIS. PLEASE INCLUE A P.O. NUMBER WITH THE PME B L m WASTEWATER INVOICE ALL RECORS ARE TO BE RETAINE POR A PERIO OF AT LEAST THREE YEARS SEN INVOICE TO : EBORAH BASS, CONTROLLER SEM) ANALYTICAL RESULTS TO : VINCENT MILES. LABORATORY SUPERVISOR

38 2005 SAMPLE CUSTOY REPORT PINE BLUFF WASTEWATER UTILITY 1520 SOUTFI OHIO STREET PINE BLUFF, AR PBWWU LAB. TEL. (870) PBWWU LAB. FAX. NUMBER: (870) P.O. NUMBER: I PINE BLUFF WASTEWATER UTILITY AN O HEREBY FIN THESE SAMPLE(S) TO BE AEQUATE W ON RECEIPT AN THEREBY SUITABLE FOR LABORATORY ANALYSIS. PLEASE Ih'CLUE A P.O. NUMBER WlTR TRE PINE BLUPP WAfXEWATER INVOICE ALL RECORS ARE TO BE RETAINE FOR A PERIO OF AT LEAST THREE YEARS SEN INVOICE TO : EBORAH BASS, CONTROLLER SEN ANALYTICAL RESULTS TO : VINCENT MILES, LABORATORY SUPERVISOR

39 2005 SAMPLE CUSTOY REPORT PWE BLUFF WASTEWATER UTILITY 1520 SOUTH OHIO STREET PINE BLUFF, AR PBWWU LAB. TEL. (870) PBWWU LAB. FAX. NUMBER: (870) ANALYSIS PERFORME BY: WRIWN MTERPLEX CORPORATION SAMPLE TRANSPORT BY: :L I SAMPLE TRANSPORT AS & TU I : 5gi " ' P (%I IS) c. I f L 5 C. HAVE RECEIVE WASTEWATER SAMPLE(S) FROM PME BLUFF WASTEWATER UTILITY AN O HEREBY FIN THESE SAMPLE(S) TO BE AEQUATE UPON RECEIPT AN THEREBY SUITABLE FOR LABORATORY ANALYSIS. PLEASE INCLUE A P.O. NUMBER WlTA THE PJNE BLUFF WASTEWATER INVOICE ALL RECORS ARE TO BE RETAINE FOR A PERIO OF AT LEAST TAREE YEARS SEN INVOICE TO :EBORAH BASS, CONTROLLER SEN ANALYTICAL RESULTS TO : VINCENT MILES. LABORATORY SUPERVISOR

40 COE SHEET Annual Report Auditor's Name &, //, a A Permit Number AR Period Report Covers End ate Z/Z B/ (. PSE / Start ate 3/1/05 PSS PPETS WENB ATA ELEMENTS Significant IUs in Significant Noncompliance with Pretreatment Compliance Schedule 0 SSNC NOV's and A.O.'s Issued Against Significant IUs Civil andlor Criminal Judicial Actions Against Significant lus Significant IUs with Significant Violations published in Newspaper IUs fiom which penalties have been collected 0 nrpn COMMENTS: