October 26, Dear Mr. White:

Transcription

1 ExxonMobil Environmental Services Company 38 Varick Street Brooklyn, New York October 26, 2011 New York State Department of Environmental Conservation Division of Environmental Remediation Remedial Bureau D 625 Broadway 12th Floor Albany, New York Attention: Mr. A. Joseph White Re: Discharge Monitoring Report September 2011 SPDES Permit No. NY ExxonMobil Greenpoint Petroleum Remediation Project Greenpoint, Brooklyn, New York Dear Mr. White: ExxonMobil Oil Corporation is submitting this Discharge Monitoring Report (DMR) for the On-Site Free-Product Recovery System (RCS) and the Off-Site Free-Product Recovery System (ORS) for the month of September The RCS was sampled on September 12, 2011 for the monthly DMR (Outfalls 001 and 01A), with the RCS operating at a flow rate of approximately 391 gallons per minute (gpm). The average operational flow rate for the period of September 1, 2011 through September 30, 2011 was approximately 405 gpm. The total amount of flow treated and discharged by the RCS during this reporting period was approximately 16,809,648 gallons, of which, approximately 2,606,159 gallons were conveyed from the BP remedial system and approximately 10,737,994 gallons were conveyed from the OU-7 recovery wells (formerly known as the Off-Site wells). The RCS sample results indicate no exceedances of either the discharge quality or flow limits for the parameters specified in the monthly DMR (Outfalls 001 and 01A). A summary of the RCS DMR analytical results is provided in Tables 1 and 2. A summary of the analytical results for additional parameters detected is provided in Table 3. The RCS laboratory analytical data are provided in Attachment 1. RCS photographs of the discharge point and receiving water taken in September 2011 are enclosed in Attachment 2. Based on visual inspections of the discharge location performed by RCS operations personnel on a periodic basis, the RCS discharge is in compliance with the narrative water quality standard for turbidity (NYCRR Title 6, Chapter X, Part 703.2). The DMR forms for Outfalls 001 and 01A are provided in Attachment 3. The ORS was sampled on September 8, 2011 for the monthly DMR (Outfall 002), with the ORS operating at a flow rate of approximately 389 gpm. The average operational flow rate for the period of September 1, 2011 through September 30, 2011 was approximately 397 gpm. The total MC Y /ML

2 Mr. A. Joseph White October 26, 2011 Page 2 amount of flow treated and discharged by the ORS during this reporting period was approximately 16,145,130 gallons. The ORS sample results indicate no exceedances of either the discharge quality or flow limits for the parameters specified in the monthly DMR (Outfalls 002). A summary of the ORS DMR analytical results is provided in Table 4. A summary of the analytical results of additional parameters detected is provided in Table 5. The laboratory analytical data are provided in Attachment 1. Photographs of the discharge point and receiving water taken in September 2011 are enclosed in Attachment 2. Based on visual inspections of the discharge location performed by ORS operations personnel at the time of the sample collection, the ORS discharge is in compliance with the narrative water quality standard for turbidity (NYCRR Title 6, Chapter X, Part 703.2). The DMR forms for Outfall 002 are provided in Attachment 3. Should there be any questions or comments on this submission, please do not hesitate to contact me at Sincerely, Attachments Steve P. Trifiletti Project Manager cc: Regional Water Engineer (NYSDEC Region 2) Long Island City, NY NYSDEC (Division of Water, Bureau of Water Compliance Programs) Albany, NY [Attachment 3 Only] Justin Kennedy, Roux Associates, Inc. MC Y /ML

3 Table 1. September 2011 Outfall 01A Discharge Monitoring Results Summary, Former ExxonMobil Brooklyn Terminal ExxonMobil Greenpoint Petroleum Remediation Project, Greenpoint, Brooklyn, New York Outfall 01A Discharge Limitations Results Discharge Loading (lbs / Day) Estimated Parameter Daily Max Units Type RCS - Influent RCS - BP Influent RCS - Effluent RCS - AS Effluent Percent Removal Flow MGD DL NA -- ph S.U. DL NA -- Oil & Grease 15 mg/l DL 7.5 <5.2 <5.1 < Total Suspended Solids 40 mg/l DL % Settleable Solids 0.1 ml/l DL <0.10 <0.10 <0.10 < ,1-Dichloroethane 10 µg/l DL <1.0 < >37.5% 1,2-Dichloroethane 10 µg/l DL <1.0 <1.0 <1.0 < Benzene 10 µg/l DL % Copper 95 µg/l DL <10 <10 <10 < Ethylbenzene 5 µg/l DL < >93.4% Mercury Monitor µg/l -- <0.20 <0.20 <0.20 < Methyl-tert-butyl ether 50 µg/l AL-I % Naphthalene 20 µg/l AL-I < >29.2% Phenols Monitor µg/l -- <200 <200 <200 < Tetrachloroethylene 10 µg/l DL % Toluene 5 µg/l DL % Trichloroethylene 10 µg/l DL % Vinyl chloride 10 µg/l DL <1.0 < >81.5% Xylenes (Total) 10 µg/l DL % Notes: 1. mg/l - milligrams per Liter, µg/l - micrograms per Liter, ml/l - milliliters per Liter, MGD - million gallons per Day 2. NTU - Nephelometric Turbidity Unit 3. NA - Not Applicable 4. NM - Not Measured 5. S.U. - Standard Unit 6. NS - Not Sampled 7. The ph was measured in the field at the time of sampling 8. "RCS - Influent" includes the untreated process water from the ExxonMobil recovery wells and BPAmoco's treatment system 9. "RCS - BP Influent" includes the untreated process water from the BPAmoco treatment system 10. "RCS - Effluent" includes the process water that has been treated and discharged by the air strippers 11. DL - Discharge Limit 12. AL-1 - Action Limit Type I 13. "RCS - Effluent" concentrations (highlighted column) are those that are used for comparison with the effluent discharge limits and action limits. 14. The maximum daily flow is reported as the flow at the time of sampling. 15. Outfall 01A was sampled on September 12, SPDES Number: NY Laboratory Analytical Method Summary Constituent Method VOCs (BTEX, TCE, etc.): EPA Method 624 MTBE EPA Method 8260 SVOCs (Naphthalene): EPA Method 625 Oil & Grease EPA Method 1664A Metals (Copper, Iron, etc.): EPA Method Mercury EPA Method *Copies of all laboratory chain of custody reports are maintained in files at the Roux Associates, Inc. office, located at 209 Shafter Street, Islandia, New York ROUX ASSOCIATES, INC. 1 of 1 MC Y /WKB

4 Table 2. September 2011 Outfall 001 Discharge Monitoring Results Summary, Former ExxonMobil Brooklyn Terminal ExxonMobil Greenpoint Petroleum Remediation Project, Greenpoint, Brooklyn, New York Outfall 001 Discharge Limitations Parameter Daily Max Units Type Results RCS-Inground OWS Effluent Discharge Loading (lbs / Day) RCS-Inground OWS Effluent Flow Monitor MGD NA ph S.U. DL 7.25 NA Oil & Grease 15 mg/l DL <5.3 < Total Suspended Solids 40 mg/l DL <4.0 < System Turbidity 7 (Influent / Discharge Pipe) Turbidity 7 (Receiving Water Background) Monitor NTU NA Monitor NTU NA Notes: 1. mg/l - milligrams per Liter, µg/l - micrograms per Liter, ml/l - milliliters per Liter, MGD - million gallons per Day 2. NTU - Nephelometric Turbidity Unit 3. NA - Not Applicable 4. NM - Not Measured 5. S.U. - Standard Unit 6. NS - Not Sampled 7. ph and Turbidity were measured in the field. 8. "RCS-Inground OWS Effluent" includes the treated effluent to be discharged at Outfall DL - Discharge Limit 10. AL-1 - Action Limit Type I 11. The maximum daily flow is reported as the flow at the time of sampling. 12. Outfall 001 was sampled on September 12, SPDES Number: NY Laboratory Analytical Method Summary Constituent Method Oil & Grease EPA Method 1664A * Copies of all laboratory chain of custody reports are maintained in files at the Roux Associates, Inc. office, located at 209 Shafter Street, Islandia, New York ROUX ASSOCIATES, INC. 1 of 1 MC Y /WKB

5 Table 3. September 2011 Outfall 01A Summary of Additional Detections, Former ExxonMobil Brooklyn Terminal ExxonMobil Greenpoint Petroleum Remediation Project, Greenpoint, Brooklyn, New York Outfall 01A Results Discharge Loading (lbs / Day) Estimated Parameter Units RCS - Influent RCS - BP Influent RCS - Effluent RCS - AS Effluent Percent Removal Flow MGD NA -- 1,2-Dichloroethene µg/l % Acenaphthene µg/l Anthracene µg/l 1.1 < Benzo(a)anthracene µg/l 0.84 < Benzo(a)pyrene µg/l <1.0 < Benzo(g.h.i)perylene µg/l <1.0 < Chrysene µg/l 0.81 < Fluoranthene µg/l 0.53 < Fluorene µg/l Phenanthrene µg/l Pyrene µg/l 1.2 < Notes: 1. mg/l - milligrams per Liter, µg/l - micrograms per Liter, ml/l - milliliters per Liter, MGD - million gallons per Day 2. NTU - Nephelometric Turbidity Unit 3. NA - Not Applicable 4. NM - Not Measured 5. S.U. - Standard Unit 6. NS - Sample not analyzed for this parameter; analysis not required by permit 7. "RCS - Influent" includes the untreated process water from the ExxonMobil recovery wells and BPAmoco's treatment system 8. "RCS - BP Influent" includes the untreated process water from the BPAmoco treatment system 9. "RCS Effluent" includes the process water that has been treated and discharged by the air strippers 10. "RCS-BP Influent" was not measured due to inaccessibility at the time of sampling. 11. DL - Discharge Limit 12. AL-1 - Action Limit Type I 13. "RCS - Effluent" concentrations (highlighted column) are those that are used for comparison with the effluent discharge limits and action limits. 14. The maximum daily flow is reported as the flow at the time of sampling. 15. Outfall 01A was sampled on September 12, SPDES Number: NY Laboratory Analytical Method Summary Constituent Method VOCs (BTEX, TCE, ect.): EPA Method 624 SVOCs: EPA Method 625 *Copies of all laboratory chain of custody reports are maintained in files at the Roux Associates, Inc. office, located at 209 Shafter Street, Islandia, New York ROUX ASSOCIATES, INC. 1 of 1 MC Y /WKB

6 Table 4. September 2011 Outfall 002 Discharge Monitoring Results Summary, Off-Site Free-Product Recovery System ExxonMobil Greenpoint Petroleum Remediation Project, Greenpoint, Brooklyn, New York Outfall 002 Discharge Limitations Results Discharge Loading (lbs / Day) Estimated Parameter Daily Max Units Type OSS - Influent OSS - Effluent Effluent Percent Removal Flow 0.62 MGD DL NA -- ph S.U. DL NA -- Oil & Grease 15 mg/l DL <5.1 <5.1 < Total Suspended Solids 40 mg/l DL % System Turbidity (Influent / Discharge Pipe) Monitor NTU NA -- Turbidity (Receiving Water) Monitor NTU NA -- Settleable Solids 0.1 ml/l DL <0.10 <0.10 < ,1-Dichloroethane 10 µg/l DL 10.4 <1.0 < >90.4% 1,2-Dichloroethane 10 µg/l DL <5.0 <1.0 < Benzene 40 µg/l DL 771 <1.0 < >99.9% Copper 95 µg/l DL <10 <10 < Ethylbenzene 5 µg/l DL 51.4 <1.0 < >98.1% Mercury Monitor µg/l -- <0.20 <0.20 < Methyl-tert-butyl ether 90 µg/l AL-I % Naphthalene 40 µg/l AL-I 20.2 <1.0 < >95.0% Phenols Monitor µg/l -- <200 <200 < Tetrachloroethylene 10 µg/l DL % Toluene 10 µg/l DL 55.1 <1.0 < >98.2% Trichloroethylene 20 µg/l DL % Vinyl chloride 10 µg/l DL 39.9 <1.0 < >97.5% Xylenes 20 µg/l DL % Notes: 1. mg/l - milligrams per Liter, µg/l - micrograms per Liter, ml/l - milliliters per Liter, MGD - million gallons per Day 2. NTU - Nephelometric Turbidity Unit 3. NA - Not Applicable 4. NM - Not Measured 5. S.U. - Standard Unit 6. NS - Not Sampled 7. ph and Turbidity were measured in the field at the time of sampling. 8. "OSS - Effluent" includes the treated Off-Site System effluent to be discharged at Outfall "OSS - Influent" includes the untreated process water from the recovery wells to be treated by the Off-Site System. 10. DL-Discharge Limit 11. AL-1 - Action Limit Type I 12. Effluent concentrations (highlighted column) are those that are used for comparison with the effluent discharge limits and action limits. 13. The maximum daily flow is reported as the flow at the time of sampling. 14. Outfall 002 was sampled on September 8, SPDES Number: NY Laboratory Analytical Method Summary Constituent Method VOCs (BTEX, TCE, etc.): EPA Method 624 MTBE EPA Method 8260 SVOCs (Naphthalene): EPA Method 625 Oil & Grease EPA Method 1664A Metals (Copper, Iron, etc.): EPA Method Mercury EPA Method *Copies of all laboratory chain of custody reports are maintained in files at the Roux Associates, Inc. office, located at 209 Shafter Street, Islandia, New York ROUX ASSOCIATES, INC. 1 of 1 MC Y /WKB

7 Table 5. September 2011 Outfall 002 Summary of Additional Detections, Off-Site Free-Product Recovery System ExxonMobil Greenpoint Petroleum Remediation Project, Greenpoint, Brooklyn, New York Outfall 002 Results Discharge Loading (lbs / Day) Estimated Parameter Units OSS - Influent OSS - Effluent Effluent Percent Removal Flow MGD NA -- 1,2-Dichloroethene µg/l % Notes: 1. mg/l - milligrams per Liter, µg/l - micrograms per Liter, ml/l - milliliters per Liter, MGD - million gallons per Day 2. NTU - Nephelometric Turbidity Unit 3. NA - Not Applicable 4. NM - Not Measured 5. S.U. - Standard Unit 6. NS - Not Sampled 7. "OSS - Effluent" includes the treated Off-Site System effluent to be discharged at Outfall "OSS - Influent" includes the untreated process water from the recovery wells to be treated by the Off-Site System. 9. AL-1 - Action Limit Type I 10. Effluent concentrations (highlighted column) are those that are used for comparison with the effluent discharge limits and action limits. 11. The maximum daily flow is reported as the flow at the time of sampling. 12. Outfall 002 was sampled on September 8, SPDES Number: NY Laboratory Analytical Method Summary Constituent Method VOCs (BTEX, TCE, etc.): EPA Method 624 SVOCs: EPA Method 625 ROUX ASSOCIATES, INC. 1 of 1 MC Y /WKB

8 ATTACHMENT 1 Laboratory Analytical Data ROUX ASSOCIATES, INC. MC Y /AT-CV

9 e-hardcopy 2.0 Automated Report New Jersey 09/27/11 09/27/11 Technical Report for Roux Associates ExxonMobil Brooklyn Terminal, 400 Kingsland Avenue, Greenpoint, Brooklyn, NY PO# WBS#08 Accutest Job Number: JA85914 Sampling Date: 09/12/11 Report to: Roux Associates ATTN: Ritu Patel Total number of pages in report: 35 Test results contained within this data package meet the requirements of the National Environmental Laboratory Accreditation Conference and/or state specific certification programs as applicable. David N. Speis VP, Laboratory Director Client Service contact: Matt Cordova Certifications: NJ(12129), NY(10983), CA, CT, DE, FL, IL, IN, KS, KY, LA, MA, MD, MI, MT, NC, PA, RI, SC, TN, VA, WV This report shall not be reproduced, except in its entirety, without the written approval of Accutest Laboratories. Test results relate only to samples analyzed. New Jersey 2235 Route 130 Dayton, NJ tel: fax: Accutest Laboratories is the sole authority for authorizing edits or modifications to this document. Unauthorized modification of this report is strictly prohibited. JA of 35

10 Table of Contents Section 1: Sample Summary... 3 Section 2: Sample Results : JA : RCS-INFLUENT : JA A: RCS-INFLUENT : JA : RCS-BP INFLUENT : JA A: RCS-BP INFLUENT : JA : RCS-INGROUND OWS EFFLUENT : JA : QAQC_TB : JA : RCS-EFFLUENT : JA : QAQC TRIP BLANK Section 3: Misc. Forms : Chain of Custody Sections: of 35 JA85914

11 1 Accutest 13:57 27-Sep-2011 Sample Summary Roux Associates Job No: ExxonMobil Brooklyn Terminal, 400 Kingsland Avenue, Greenpoint, Brooklyn, NY Project No: PO# WBS#08 JA85914 Sample Collected Matrix Client Number Date Time By Received Code Type Sample ID JA /12/11 10:15 MS 09/12/11 AQ Influent RCS-INFLUENT JA A 09/12/11 10:15 MS 09/12/11 AQ Influent RCS-INFLUENT JA /12/11 11:15 MS 09/12/11 AQ Influent RCS-BP INFLUENT JA A 09/12/11 11:15 MS 09/12/11 AQ Influent RCS-BP INFLUENT JA /12/11 10:50 MS 09/12/11 AQ Effluent RCS-INGROUND OWS EFFLUENT JA /12/11 11:15 MS 09/12/11 AQ Trip Blank Water QAQC_TB JA /12/11 10:00 MS 09/13/11 AQ Ground Water RCS-EFFLUENT JA /12/11 10:00 MS 09/13/11 AQ Trip Blank Water QAQC TRIP BLANK 3 of 35 JA85914

12 2 Section 2 New Jersey Accutest LabLink@ :57 27-Sep-2011 Sample Results Report of Analysis 4 of 35 JA85914

13 Accutest 13:57 27-Sep-2011 Report of Analysis Page 1 of Client Sample ID: RCS-INFLUENT Lab Sample ID: JA Date Sampled: 09/12/11 Matrix: AQ - Influent Date Received: 09/12/11 Method: EPA 624 Percent Solids: n/a Project: ExxonMobil Brooklyn Terminal, 400 Kingsland Avenue, Greenpoint, Brooklyn, NY File ID DF Analyzed By Prep Date Prep Batch Analytical Batch Run #1 2E69198.D 1 09/16/11 MAH n/a n/a V2E3102 Run #2 2E69213.D 5 09/16/11 MAH n/a n/a V2E3103 Run #1 Run #2 Purge Volume 5.0 ml 5.0 ml VOA PPL List CAS No. Compound Result RL MDL Units Q Acrolein ND ug/l Acrylonitrile ND ug/l Benzene 215 a ug/l Bromodichloromethane ND ug/l Bromoform ND ug/l Bromomethane ND ug/l Carbon tetrachloride ND ug/l Chlorobenzene ug/l J Chloroethane ug/l J Chloroethyl vinyl ether ND ug/l Chloroform ND ug/l Chloromethane ND ug/l Dibromochloromethane ND ug/l ,2-Dichlorobenzene ND ug/l ,3-Dichlorobenzene ND ug/l ,4-Dichlorobenzene ND ug/l Dichlorodifluoromethane ND ug/l ,1-Dichloroethane ug/l ,2-Dichloroethane ND ug/l ,1-Dichloroethene ug/l cis-1,2-dichloroethene ug/l trans-1,2-dichloroethene ug/l ,2-Dichloropropane ND ug/l cis-1,3-dichloropropene ND ug/l trans-1,3-dichloropropene ND ug/l Ethylbenzene ug/l Methylene chloride ND ug/l ,1,2,2-Tetrachloroethane ND ug/l Tetrachloroethene ug/l Toluene ug/l ,1,1-Trichloroethane ug/l J ,1,2-Trichloroethane ND ug/l ND = Not detected MDL - Method Detection Limit J = Indicates an estimated value RL = Reporting Limit B = Indicates analyte found in associated method blank E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound 5 of 35 JA85914

14 Accutest 13:57 27-Sep-2011 Report of Analysis Page 2 of Client Sample ID: RCS-INFLUENT Lab Sample ID: JA Date Sampled: 09/12/11 Matrix: AQ - Influent Date Received: 09/12/11 Method: EPA 624 Percent Solids: n/a Project: ExxonMobil Brooklyn Terminal, 400 Kingsland Avenue, Greenpoint, Brooklyn, NY VOA PPL List CAS No. Compound Result RL MDL Units Q Trichloroethene ug/l Trichlorofluoromethane ND ug/l Vinyl chloride ug/l Xylenes (total) ug/l CAS No. Surrogate Recoveries Run# 1 Run# 2 Limits ,2-Dichloroethane-D4 (SUR) 105% 93% % Toluene-D8 (SUR) 101% 101% % Bromofluorobenzene (SUR) 97% 102% % Dibromofluoromethane (S) 95% 97% % (a) Result is from Run# 2 ND = Not detected MDL - Method Detection Limit J = Indicates an estimated value RL = Reporting Limit B = Indicates analyte found in associated method blank E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound 6 of 35 JA85914

15 Accutest 13:57 27-Sep-2011 Report of Analysis Page 1 of Client Sample ID: RCS-INFLUENT Lab Sample ID: JA Date Sampled: 09/12/11 Matrix: AQ - Influent Date Received: 09/12/11 Method: EPA 625 EPA 625 Percent Solids: n/a Project: ExxonMobil Brooklyn Terminal, 400 Kingsland Avenue, Greenpoint, Brooklyn, NY File ID DF Analyzed By Prep Date Prep Batch Analytical Batch Run #1 R89972.D 1 09/21/11 LP 09/13/11 OP51844 ER3461 Run #2 Initial Volume Final Volume Run #1 955 ml 1.0 ml Run #2 ABN PPL List CAS No. Compound Result RL MDL Units Q Chlorophenol ND ug/l Chloro-3-methyl phenol ND ug/l ,4-Dichlorophenol ND ug/l ,4-Dimethylphenol ND ug/l ,4-Dinitrophenol ND ug/l ,6-Dinitro-o-cresol ND ug/l Nitrophenol ND ug/l Nitrophenol ND ug/l Pentachlorophenol ND ug/l Phenol ND ug/l ,4,6-Trichlorophenol ND ug/l Acenaphthene ug/l Acenaphthylene ND ug/l Anthracene ug/l Benzidine ND ug/l Benzo(a)anthracene ug/l J Benzo(a)pyrene ND ug/l Benzo(b)fluoranthene ND ug/l Benzo(g,h,i)perylene ND ug/l Benzo(k)fluoranthene ND ug/l Bromophenyl phenyl ether ND ug/l Butyl benzyl phthalate ND ug/l Chloronaphthalene ND ug/l Chloroaniline ND ug/l Chrysene ug/l J bis(2-chloroethoxy)methane ND ug/l bis(2-chloroethyl)ether ND ug/l bis(2-chloroisopropyl)ether ND ug/l Chlorophenyl phenyl ether ND ug/l ,2-Dichlorobenzene ND ug/l ,2-Diphenylhydrazine ND ug/l ,3-Dichlorobenzene ND ug/l ND = Not detected MDL - Method Detection Limit J = Indicates an estimated value RL = Reporting Limit B = Indicates analyte found in associated method blank E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound 7 of 35 JA85914

16 Accutest 13:57 27-Sep-2011 Report of Analysis Page 2 of Client Sample ID: RCS-INFLUENT Lab Sample ID: JA Date Sampled: 09/12/11 Matrix: AQ - Influent Date Received: 09/12/11 Method: EPA 625 EPA 625 Percent Solids: n/a Project: ExxonMobil Brooklyn Terminal, 400 Kingsland Avenue, Greenpoint, Brooklyn, NY ABN PPL List CAS No. Compound Result RL MDL Units Q ,4-Dichlorobenzene ND ug/l ,4-Dinitrotoluene ND ug/l ,6-Dinitrotoluene ND ug/l ,3'-Dichlorobenzidine ND ug/l Dibenzo(a,h)anthracene ND ug/l Di-n-butyl phthalate ND ug/l Di-n-octyl phthalate ND ug/l Diethyl phthalate ND ug/l Dimethyl phthalate ND ug/l bis(2-ethylhexyl)phthalate ND ug/l Fluoranthene ug/l J Fluorene ug/l Hexachlorobenzene ND ug/l Hexachlorobutadiene ND ug/l Hexachlorocyclopentadiene ND ug/l Hexachloroethane ND ug/l Indeno(1,2,3-cd)pyrene ND ug/l Isophorone ND ug/l Naphthalene ug/l Nitrobenzene ND ug/l n-nitrosodimethylamine ND ug/l N-Nitroso-di-n-propylamine ND ug/l N-Nitrosodiphenylamine ND ug/l Phenanthrene ug/l Pyrene ug/l ,2,4-Trichlorobenzene ND ug/l CAS No. Surrogate Recoveries Run# 1 Run# 2 Limits Fluorophenol 33% % Phenol-d5 22% % ,4,6-Tribromophenol 92% % Nitrobenzene-d5 93% % Fluorobiphenyl 90% % Terphenyl-d14 92% % ND = Not detected MDL - Method Detection Limit J = Indicates an estimated value RL = Reporting Limit B = Indicates analyte found in associated method blank E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound 8 of 35 JA85914

17 Accutest 13:57 27-Sep-2011 Report of Analysis Page 1 of Client Sample ID: RCS-INFLUENT Lab Sample ID: JA Date Sampled: 09/12/11 Matrix: AQ - Influent Date Received: 09/12/11 Percent Solids: n/a Project: ExxonMobil Brooklyn Terminal, 400 Kingsland Avenue, Greenpoint, Brooklyn, NY Total Metals Analysis Analyte Result RL Units DF Prep Analyzed By Method Prep Method Calcium ug/l 1 09/21/11 09/22/11 BL EPA EPA Copper <10 10 ug/l 1 09/21/11 09/22/11 BL EPA EPA Iron ug/l 1 09/21/11 09/22/11 BL EPA EPA Manganese ug/l 1 09/21/11 09/22/11 BL EPA EPA Mercury < ug/l 1 09/21/11 09/21/11 JW EPA EPA (1) Instrument QC Batch: MA27130 (2) Instrument QC Batch: MA27135 (3) Prep QC Batch: MP60326 (4) Prep QC Batch: MP60330 RL = Reporting Limit 9 of 35 JA85914

18 Accutest 13:57 27-Sep-2011 Report of Analysis Page 1 of Client Sample ID: RCS-INFLUENT Lab Sample ID: JA Date Sampled: 09/12/11 Matrix: AQ - Influent Date Received: 09/12/11 Percent Solids: n/a Project: ExxonMobil Brooklyn Terminal, 400 Kingsland Avenue, Greenpoint, Brooklyn, NY General Chemistry Analyte Result RL Units DF Analyzed By Method Chloride mg/l 10 09/22/11 05:18 AE EPA 300/SW A HEM Oil and Grease mg/l 1 09/23/11 MP EPA 1664A Phenols < mg/l 1 09/20/11 10:37 MG EPA 420.4/LACHAT Solids, Settleable < ml/l 1 09/12/11 21:30 ML SM F Solids, Total Suspended mg/l 1 09/15/11 JF SM D Turbidity NTU 5 09/12/11 23:23 LS EPA ph a 6.72 su 1 09/12/11 17:05 SUB SM H B (a) Sample received out of holding time for ph analysis. RL = Reporting Limit JA of 35

19 Accutest 13:57 27-Sep-2011 Report of Analysis Page 1 of Client Sample ID: RCS-INFLUENT Lab Sample ID: JA A Date Sampled: 09/12/11 Matrix: AQ - Influent Date Received: 09/12/11 Method: SW B Percent Solids: n/a Project: ExxonMobil Brooklyn Terminal, 400 Kingsland Avenue, Greenpoint, Brooklyn, NY File ID DF Analyzed By Prep Date Prep Batch Analytical Batch Run #1 U D 1 09/22/11 SS n/a n/a VU6075 Run #2 Run #1 Run #2 Purge Volume 5.0 ml CAS No. Compound Result RL MDL Units Q Ethanol ND ug/l Methyl Tert Butyl Ether ug/l CAS No. Surrogate Recoveries Run# 1 Run# 2 Limits Dibromofluoromethane 94% % ,2-Dichloroethane-D4 105% % Toluene-D8 95% % Bromofluorobenzene 87% % ND = Not detected MDL - Method Detection Limit J = Indicates an estimated value RL = Reporting Limit B = Indicates analyte found in associated method blank E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound JA of 35

20 Accutest 13:57 27-Sep-2011 Report of Analysis Page 1 of Client Sample ID: RCS-BP INFLUENT Lab Sample ID: JA Date Sampled: 09/12/11 Matrix: AQ - Influent Date Received: 09/12/11 Method: EPA 624 Percent Solids: n/a Project: ExxonMobil Brooklyn Terminal, 400 Kingsland Avenue, Greenpoint, Brooklyn, NY File ID DF Analyzed By Prep Date Prep Batch Analytical Batch Run #1 2E69199.D 1 09/16/11 MAH n/a n/a V2E3102 Run #2 Run #1 Run #2 Purge Volume 5.0 ml VOA PPL List CAS No. Compound Result RL MDL Units Q Acrolein ND ug/l Acrylonitrile ND ug/l Benzene ug/l Bromodichloromethane ND ug/l Bromoform ND ug/l Bromomethane ND ug/l Carbon tetrachloride ND ug/l Chlorobenzene ND ug/l Chloroethane ND ug/l Chloroethyl vinyl ether ND ug/l Chloroform ND ug/l Chloromethane ND ug/l Dibromochloromethane ND ug/l ,2-Dichlorobenzene ND ug/l ,3-Dichlorobenzene ND ug/l ,4-Dichlorobenzene ND ug/l Dichlorodifluoromethane ND ug/l ,1-Dichloroethane ug/l J ,2-Dichloroethane ND ug/l ,1-Dichloroethene ND ug/l cis-1,2-dichloroethene ug/l trans-1,2-dichloroethene ug/l J ,2-Dichloropropane ND ug/l cis-1,3-dichloropropene ND ug/l trans-1,3-dichloropropene ND ug/l Ethylbenzene ug/l Methylene chloride ND ug/l ,1,2,2-Tetrachloroethane ND ug/l Tetrachloroethene ug/l J Toluene ug/l ,1,1-Trichloroethane ND ug/l ,1,2-Trichloroethane ND ug/l ND = Not detected MDL - Method Detection Limit J = Indicates an estimated value RL = Reporting Limit B = Indicates analyte found in associated method blank E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound JA of 35

21 Accutest 13:57 27-Sep-2011 Report of Analysis Page 2 of Client Sample ID: RCS-BP INFLUENT Lab Sample ID: JA Date Sampled: 09/12/11 Matrix: AQ - Influent Date Received: 09/12/11 Method: EPA 624 Percent Solids: n/a Project: ExxonMobil Brooklyn Terminal, 400 Kingsland Avenue, Greenpoint, Brooklyn, NY VOA PPL List CAS No. Compound Result RL MDL Units Q Trichloroethene ug/l Trichlorofluoromethane ND ug/l Vinyl chloride ug/l J Xylenes (total) ug/l CAS No. Surrogate Recoveries Run# 1 Run# 2 Limits ,2-Dichloroethane-D4 (SUR) 92% % Toluene-D8 (SUR) 100% % Bromofluorobenzene (SUR) 102% % Dibromofluoromethane (S) 95% % ND = Not detected MDL - Method Detection Limit J = Indicates an estimated value RL = Reporting Limit B = Indicates analyte found in associated method blank E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound 13 of 35 JA85914

22 Accutest 13:57 27-Sep-2011 Report of Analysis Page 1 of Client Sample ID: RCS-BP INFLUENT Lab Sample ID: JA Date Sampled: 09/12/11 Matrix: AQ - Influent Date Received: 09/12/11 Method: EPA 625 EPA 625 Percent Solids: n/a Project: ExxonMobil Brooklyn Terminal, 400 Kingsland Avenue, Greenpoint, Brooklyn, NY File ID DF Analyzed By Prep Date Prep Batch Analytical Batch Run #1 R90010.D 1 09/22/11 LP 09/13/11 OP51844 ER3463 Run #2 Initial Volume Final Volume Run #1 930 ml 1.0 ml Run #2 ABN PPL List CAS No. Compound Result RL MDL Units Q Chlorophenol ND ug/l Chloro-3-methyl phenol ND ug/l ,4-Dichlorophenol ND ug/l ,4-Dimethylphenol ug/l J ,4-Dinitrophenol ND ug/l ,6-Dinitro-o-cresol ND ug/l Nitrophenol ND ug/l Nitrophenol ND ug/l Pentachlorophenol ND ug/l Phenol ug/l J ,4,6-Trichlorophenol ND ug/l Acenaphthene ug/l J Acenaphthylene ND ug/l Anthracene ND ug/l Benzidine ND ug/l Benzo(a)anthracene ND ug/l Benzo(a)pyrene ND ug/l Benzo(b)fluoranthene ND ug/l Benzo(g,h,i)perylene ND ug/l Benzo(k)fluoranthene ND ug/l Bromophenyl phenyl ether ND ug/l Butyl benzyl phthalate ND ug/l Chloronaphthalene ND ug/l Chloroaniline ND ug/l Chrysene ND ug/l bis(2-chloroethoxy)methane ND ug/l bis(2-chloroethyl)ether ND ug/l bis(2-chloroisopropyl)ether ND ug/l Chlorophenyl phenyl ether ND ug/l ,2-Dichlorobenzene ND ug/l ,2-Diphenylhydrazine ND ug/l ,3-Dichlorobenzene ND ug/l ND = Not detected MDL - Method Detection Limit J = Indicates an estimated value RL = Reporting Limit B = Indicates analyte found in associated method blank E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound JA of 35

23 Accutest 13:57 27-Sep-2011 Report of Analysis Page 2 of Client Sample ID: RCS-BP INFLUENT Lab Sample ID: JA Date Sampled: 09/12/11 Matrix: AQ - Influent Date Received: 09/12/11 Method: EPA 625 EPA 625 Percent Solids: n/a Project: ExxonMobil Brooklyn Terminal, 400 Kingsland Avenue, Greenpoint, Brooklyn, NY ABN PPL List CAS No. Compound Result RL MDL Units Q ,4-Dichlorobenzene ND ug/l ,4-Dinitrotoluene ND ug/l ,6-Dinitrotoluene ND ug/l ,3'-Dichlorobenzidine ND ug/l Dibenzo(a,h)anthracene ND ug/l Di-n-butyl phthalate ND ug/l Di-n-octyl phthalate ND ug/l Diethyl phthalate ND ug/l Dimethyl phthalate ND ug/l bis(2-ethylhexyl)phthalate ND ug/l Fluoranthene ND ug/l Fluorene ug/l J Hexachlorobenzene ND ug/l Hexachlorobutadiene ND ug/l Hexachlorocyclopentadiene ND ug/l Hexachloroethane ND ug/l Indeno(1,2,3-cd)pyrene ND ug/l Isophorone ND ug/l Naphthalene ug/l Nitrobenzene ND ug/l n-nitrosodimethylamine ND ug/l N-Nitroso-di-n-propylamine ND ug/l N-Nitrosodiphenylamine ND ug/l Phenanthrene ug/l Pyrene ND ug/l ,2,4-Trichlorobenzene ND ug/l CAS No. Surrogate Recoveries Run# 1 Run# 2 Limits Fluorophenol 34% % Phenol-d5 25% % ,4,6-Tribromophenol 88% % Nitrobenzene-d5 105% % Fluorobiphenyl 96% % Terphenyl-d14 95% % ND = Not detected MDL - Method Detection Limit J = Indicates an estimated value RL = Reporting Limit B = Indicates analyte found in associated method blank E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound 15 of 35 JA85914

24 Accutest 13:57 27-Sep-2011 Report of Analysis Page 1 of Client Sample ID: RCS-BP INFLUENT Lab Sample ID: JA Date Sampled: 09/12/11 Matrix: AQ - Influent Date Received: 09/12/11 Percent Solids: n/a Project: ExxonMobil Brooklyn Terminal, 400 Kingsland Avenue, Greenpoint, Brooklyn, NY Total Metals Analysis Analyte Result RL Units DF Prep Analyzed By Method Prep Method Calcium ug/l 1 09/21/11 09/22/11 BL EPA EPA Copper <10 10 ug/l 1 09/21/11 09/22/11 BL EPA EPA Iron ug/l 1 09/21/11 09/22/11 BL EPA EPA Manganese ug/l 1 09/21/11 09/22/11 BL EPA EPA Mercury < ug/l 1 09/21/11 09/21/11 JW EPA EPA (1) Instrument QC Batch: MA27130 (2) Instrument QC Batch: MA27135 (3) Prep QC Batch: MP60326 (4) Prep QC Batch: MP60330 RL = Reporting Limit 16 of 35 JA85914

25 Accutest 13:57 27-Sep-2011 Report of Analysis Page 1 of Client Sample ID: RCS-BP INFLUENT Lab Sample ID: JA Date Sampled: 09/12/11 Matrix: AQ - Influent Date Received: 09/12/11 Percent Solids: n/a Project: ExxonMobil Brooklyn Terminal, 400 Kingsland Avenue, Greenpoint, Brooklyn, NY General Chemistry Analyte Result RL Units DF Analyzed By Method Chloride mg/l 10 09/22/11 05:42 AE EPA 300/SW A HEM Oil and Grease < mg/l 1 09/21/11 JOO EPA 1664A Phenols < mg/l 1 09/20/11 10:38 MG EPA 420.4/LACHAT Solids, Settleable < ml/l 1 09/12/11 21:30 ML SM F Solids, Total Suspended mg/l 1 09/15/11 JF SM D Turbidity NTU 10 09/12/11 23:23 LS EPA ph a 6.75 su 1 09/12/11 17:10 SUB SM H B (a) Sample received out of holding time for ph analysis. RL = Reporting Limit JA of 35

26 Accutest 13:57 27-Sep-2011 Report of Analysis Page 1 of Client Sample ID: RCS-BP INFLUENT Lab Sample ID: JA A Date Sampled: 09/12/11 Matrix: AQ - Influent Date Received: 09/12/11 Method: SW B Percent Solids: n/a Project: ExxonMobil Brooklyn Terminal, 400 Kingsland Avenue, Greenpoint, Brooklyn, NY File ID DF Analyzed By Prep Date Prep Batch Analytical Batch Run #1 U D 1 09/17/11 SS n/a n/a VU6067 Run #2 Run #1 Run #2 Purge Volume 5.0 ml CAS No. Compound Result RL MDL Units Q Ethanol ND ug/l Methyl Tert Butyl Ether ug/l CAS No. Surrogate Recoveries Run# 1 Run# 2 Limits Dibromofluoromethane 91% % ,2-Dichloroethane-D4 98% % Toluene-D8 93% % Bromofluorobenzene 88% % ND = Not detected MDL - Method Detection Limit J = Indicates an estimated value RL = Reporting Limit B = Indicates analyte found in associated method blank E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound JA of 35

27 Accutest 13:57 27-Sep-2011 Report of Analysis Page 1 of Client Sample ID: RCS-INGROUND OWS EFFLUENT Lab Sample ID: JA Date Sampled: 09/12/11 Matrix: AQ - Effluent Date Received: 09/12/11 Percent Solids: n/a Project: ExxonMobil Brooklyn Terminal, 400 Kingsland Avenue, Greenpoint, Brooklyn, NY General Chemistry Analyte Result RL Units DF Analyzed By Method Chloride mg/l 10 09/22/11 06:06 AE EPA 300/SW A HEM Oil and Grease < mg/l 1 09/23/11 MP EPA 1664A Solids, Total Suspended < mg/l 1 09/15/11 JF SM D Turbidity NTU 1 09/12/11 23:23 LS EPA ph a 7.65 su 1 09/12/11 17:14 SUB SM H B (a) Sample received out of holding time for ph analysis. RL = Reporting Limit JA of 35

28 Accutest 13:57 27-Sep-2011 Report of Analysis Page 1 of Client Sample ID: QAQC_TB Lab Sample ID: JA Date Sampled: 09/12/11 Matrix: AQ - Trip Blank Water Date Received: 09/12/11 Method: EPA 624 Percent Solids: n/a Project: ExxonMobil Brooklyn Terminal, 400 Kingsland Avenue, Greenpoint, Brooklyn, NY File ID DF Analyzed By Prep Date Prep Batch Analytical Batch Run #1 2E69202.D 1 09/16/11 MAH n/a n/a V2E3102 Run #2 Run #1 Run #2 Purge Volume 5.0 ml VOA PPL List CAS No. Compound Result RL MDL Units Q Acrolein ND ug/l Acrylonitrile ND ug/l Benzene ND ug/l Bromodichloromethane ND ug/l Bromoform ND ug/l Bromomethane ND ug/l Carbon tetrachloride ND ug/l Chlorobenzene ND ug/l Chloroethane ND ug/l Chloroethyl vinyl ether ND ug/l Chloroform ND ug/l Chloromethane ND ug/l Dibromochloromethane ND ug/l ,2-Dichlorobenzene ND ug/l ,3-Dichlorobenzene ND ug/l ,4-Dichlorobenzene ND ug/l Dichlorodifluoromethane ND ug/l ,1-Dichloroethane ND ug/l ,2-Dichloroethane ND ug/l ,1-Dichloroethene ND ug/l cis-1,2-dichloroethene ND ug/l trans-1,2-dichloroethene ND ug/l ,2-Dichloropropane ND ug/l cis-1,3-dichloropropene ND ug/l trans-1,3-dichloropropene ND ug/l Ethylbenzene ND ug/l Methylene chloride ND ug/l ,1,2,2-Tetrachloroethane ND ug/l Tetrachloroethene ND ug/l Toluene ND ug/l ,1,1-Trichloroethane ND ug/l ,1,2-Trichloroethane ND ug/l ND = Not detected MDL - Method Detection Limit J = Indicates an estimated value RL = Reporting Limit B = Indicates analyte found in associated method blank E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound JA of 35

29 Accutest 13:57 27-Sep-2011 Report of Analysis Page 2 of Client Sample ID: QAQC_TB Lab Sample ID: JA Date Sampled: 09/12/11 Matrix: AQ - Trip Blank Water Date Received: 09/12/11 Method: EPA 624 Percent Solids: n/a Project: ExxonMobil Brooklyn Terminal, 400 Kingsland Avenue, Greenpoint, Brooklyn, NY VOA PPL List CAS No. Compound Result RL MDL Units Q Trichloroethene ND ug/l Trichlorofluoromethane ND ug/l Vinyl chloride ND ug/l Xylenes (total) ND ug/l CAS No. Surrogate Recoveries Run# 1 Run# 2 Limits ,2-Dichloroethane-D4 (SUR) 94% % Toluene-D8 (SUR) 98% % Bromofluorobenzene (SUR) 100% % Dibromofluoromethane (S) 99% % ND = Not detected MDL - Method Detection Limit J = Indicates an estimated value RL = Reporting Limit B = Indicates analyte found in associated method blank E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound 21 of 35 JA85914

30 Accutest 13:57 27-Sep-2011 Report of Analysis Page 1 of Client Sample ID: RCS-EFFLUENT Lab Sample ID: JA Date Sampled: 09/12/11 Matrix: AQ - Ground Water Date Received: 09/13/11 Method: EPA 624 Percent Solids: n/a Project: ExxonMobil Brooklyn Terminal, 400 Kingsland Avenue, Greenpoint, Brooklyn, NY File ID DF Analyzed By Prep Date Prep Batch Analytical Batch Run #1 2E69214.D 1 09/16/11 MAH n/a n/a V2E3103 Run #2 Run #1 Run #2 Purge Volume 5.0 ml VOA PPL List CAS No. Compound Result RL MDL Units Q Acrolein ND ug/l Acrylonitrile ND ug/l Benzene ug/l Bromodichloromethane ND ug/l Bromoform ND ug/l Bromomethane ND ug/l Carbon tetrachloride ND ug/l Chlorobenzene ND ug/l Chloroethane ND ug/l Chloroethyl vinyl ether ND ug/l Chloroform ND ug/l Chloromethane ND ug/l Dibromochloromethane ND ug/l ,2-Dichlorobenzene ND ug/l ,3-Dichlorobenzene ND ug/l ,4-Dichlorobenzene ND ug/l Dichlorodifluoromethane ND ug/l ,1-Dichloroethane ND ug/l ,2-Dichloroethane ND ug/l ,1-Dichloroethene ND ug/l cis-1,2-dichloroethene ug/l trans-1,2-dichloroethene ND ug/l ,2-Dichloropropane ND ug/l cis-1,3-dichloropropene ND ug/l trans-1,3-dichloropropene ND ug/l Ethylbenzene ug/l J Methylene chloride ND ug/l ,1,2,2-Tetrachloroethane ND ug/l Tetrachloroethene ug/l Toluene ug/l J ,1,1-Trichloroethane ND ug/l ,1,2-Trichloroethane ND ug/l ND = Not detected MDL - Method Detection Limit J = Indicates an estimated value RL = Reporting Limit B = Indicates analyte found in associated method blank E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound JA of 35

31 Accutest 13:57 27-Sep-2011 Report of Analysis Page 2 of Client Sample ID: RCS-EFFLUENT Lab Sample ID: JA Date Sampled: 09/12/11 Matrix: AQ - Ground Water Date Received: 09/13/11 Method: EPA 624 Percent Solids: n/a Project: ExxonMobil Brooklyn Terminal, 400 Kingsland Avenue, Greenpoint, Brooklyn, NY VOA PPL List CAS No. Compound Result RL MDL Units Q Trichloroethene ug/l Trichlorofluoromethane ND ug/l Vinyl chloride ND ug/l Xylenes (total) ug/l CAS No. Surrogate Recoveries Run# 1 Run# 2 Limits ,2-Dichloroethane-D4 (SUR) 94% % Toluene-D8 (SUR) 101% % Bromofluorobenzene (SUR) 97% % Dibromofluoromethane (S) 94% % ND = Not detected MDL - Method Detection Limit J = Indicates an estimated value RL = Reporting Limit B = Indicates analyte found in associated method blank E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound 23 of 35 JA85914

32 Accutest 13:57 27-Sep-2011 Report of Analysis Page 1 of Client Sample ID: RCS-EFFLUENT Lab Sample ID: JA Date Sampled: 09/12/11 Matrix: AQ - Ground Water Date Received: 09/13/11 Method: SW B Percent Solids: n/a Project: ExxonMobil Brooklyn Terminal, 400 Kingsland Avenue, Greenpoint, Brooklyn, NY File ID DF Analyzed By Prep Date Prep Batch Analytical Batch Run #1 U D 1 09/22/11 SS n/a n/a VU6075 Run #2 Run #1 Run #2 Purge Volume 5.0 ml CAS No. Compound Result RL MDL Units Q Methyl Tert Butyl Ether ug/l CAS No. Surrogate Recoveries Run# 1 Run# 2 Limits Dibromofluoromethane 93% % ,2-Dichloroethane-D4 99% % Toluene-D8 89% % Bromofluorobenzene 85% % ND = Not detected MDL - Method Detection Limit J = Indicates an estimated value RL = Reporting Limit B = Indicates analyte found in associated method blank E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound JA of 35

33 Accutest 13:57 27-Sep-2011 Report of Analysis Page 1 of Client Sample ID: RCS-EFFLUENT Lab Sample ID: JA Date Sampled: 09/12/11 Matrix: AQ - Ground Water Date Received: 09/13/11 Method: EPA 625 EPA 625 Percent Solids: n/a Project: ExxonMobil Brooklyn Terminal, 400 Kingsland Avenue, Greenpoint, Brooklyn, NY File ID DF Analyzed By Prep Date Prep Batch Analytical Batch Run #1 R90008.D 1 09/22/11 LP 09/13/11 OP51844 ER3463 Run #2 Initial Volume Final Volume Run # ml 1.0 ml Run #2 ABN PPL List CAS No. Compound Result RL MDL Units Q Chlorophenol ND ug/l Chloro-3-methyl phenol ND ug/l ,4-Dichlorophenol ND ug/l ,4-Dimethylphenol ND ug/l ,4-Dinitrophenol ND ug/l ,6-Dinitro-o-cresol ND ug/l Nitrophenol ND ug/l Nitrophenol ND ug/l Pentachlorophenol ND ug/l Phenol ND ug/l ,4,6-Trichlorophenol ND ug/l Acenaphthene ug/l Acenaphthylene ND ug/l Anthracene ug/l Benzidine ND ug/l Benzo(a)anthracene ug/l Benzo(a)pyrene ug/l J Benzo(b)fluoranthene ND ug/l Benzo(g,h,i)perylene ug/l J Benzo(k)fluoranthene ND ug/l Bromophenyl phenyl ether ND ug/l Butyl benzyl phthalate ND ug/l Chloronaphthalene ND ug/l Chloroaniline ND ug/l Chrysene ug/l bis(2-chloroethoxy)methane ND ug/l bis(2-chloroethyl)ether ND ug/l bis(2-chloroisopropyl)ether ND ug/l Chlorophenyl phenyl ether ND ug/l ,2-Dichlorobenzene ND ug/l ,2-Diphenylhydrazine ND ug/l ,3-Dichlorobenzene ND ug/l ND = Not detected MDL - Method Detection Limit J = Indicates an estimated value RL = Reporting Limit B = Indicates analyte found in associated method blank E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound JA of 35

34 Accutest 13:57 27-Sep-2011 Report of Analysis Page 2 of Client Sample ID: RCS-EFFLUENT Lab Sample ID: JA Date Sampled: 09/12/11 Matrix: AQ - Ground Water Date Received: 09/13/11 Method: EPA 625 EPA 625 Percent Solids: n/a Project: ExxonMobil Brooklyn Terminal, 400 Kingsland Avenue, Greenpoint, Brooklyn, NY ABN PPL List CAS No. Compound Result RL MDL Units Q ,4-Dichlorobenzene ND ug/l ,4-Dinitrotoluene ND ug/l ,6-Dinitrotoluene ND ug/l ,3'-Dichlorobenzidine ND ug/l Dibenzo(a,h)anthracene ND ug/l Di-n-butyl phthalate ND ug/l Di-n-octyl phthalate ND ug/l Diethyl phthalate ND ug/l Dimethyl phthalate ND ug/l bis(2-ethylhexyl)phthalate ND ug/l Fluoranthene ug/l J Fluorene ug/l Hexachlorobenzene ND ug/l Hexachlorobutadiene ND ug/l Hexachlorocyclopentadiene ND ug/l Hexachloroethane ND ug/l Indeno(1,2,3-cd)pyrene ND ug/l Isophorone ND ug/l Naphthalene ug/l Nitrobenzene ND ug/l n-nitrosodimethylamine ND ug/l N-Nitroso-di-n-propylamine ND ug/l N-Nitrosodiphenylamine ND ug/l Phenanthrene ug/l Pyrene ug/l ,2,4-Trichlorobenzene ND ug/l CAS No. Surrogate Recoveries Run# 1 Run# 2 Limits Fluorophenol 25% % Phenol-d5 22% % ,4,6-Tribromophenol 52% % Nitrobenzene-d5 106% % Fluorobiphenyl 94% % Terphenyl-d14 104% % ND = Not detected MDL - Method Detection Limit J = Indicates an estimated value RL = Reporting Limit B = Indicates analyte found in associated method blank E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound 26 of 35 JA85914

35 Accutest 13:57 27-Sep-2011 Report of Analysis Page 1 of Client Sample ID: RCS-EFFLUENT Lab Sample ID: JA Date Sampled: 09/12/11 Matrix: AQ - Ground Water Date Received: 09/13/11 Percent Solids: n/a Project: ExxonMobil Brooklyn Terminal, 400 Kingsland Avenue, Greenpoint, Brooklyn, NY Total Metals Analysis Analyte Result RL Units DF Prep Analyzed By Method Prep Method Calcium ug/l 1 09/21/11 09/22/11 BL EPA EPA Copper <10 10 ug/l 1 09/21/11 09/22/11 BL EPA EPA Iron ug/l 1 09/21/11 09/22/11 BL EPA EPA Manganese ug/l 1 09/21/11 09/22/11 BL EPA EPA Mercury < ug/l 1 09/21/11 09/21/11 JW EPA EPA (1) Instrument QC Batch: MA27130 (2) Instrument QC Batch: MA27135 (3) Prep QC Batch: MP60326 (4) Prep QC Batch: MP60330 RL = Reporting Limit 27 of 35 JA85914

36 Accutest 13:57 27-Sep-2011 Report of Analysis Page 1 of Client Sample ID: RCS-EFFLUENT Lab Sample ID: JA Date Sampled: 09/12/11 Matrix: AQ - Ground Water Date Received: 09/13/11 Percent Solids: n/a Project: ExxonMobil Brooklyn Terminal, 400 Kingsland Avenue, Greenpoint, Brooklyn, NY General Chemistry Analyte Result RL Units DF Analyzed By Method Chloride mg/l 10 09/22/11 04:54 AE EPA 300/SW A HEM Oil and Grease < mg/l 1 09/23/11 MP EPA 1664A Phenols < mg/l 1 09/20/11 10:39 MG EPA 420.4/LACHAT Solids, Settleable < ml/l 1 09/13/11 17:00 CW SM F Solids, Total Suspended mg/l 1 09/15/11 JF SM D Turbidity NTU 1 09/13/11 21:23 LS EPA ph a 7.69 su 1 09/13/11 13:43 SUB SM H B (a) Sample received out of holding time for ph analysis. RL = Reporting Limit JA of 35

37 Accutest 13:57 27-Sep-2011 Report of Analysis Page 1 of Client Sample ID: QAQC TRIP BLANK Lab Sample ID: JA Date Sampled: 09/12/11 Matrix: AQ - Trip Blank Water Date Received: 09/13/11 Method: EPA 624 Percent Solids: n/a Project: ExxonMobil Brooklyn Terminal, 400 Kingsland Avenue, Greenpoint, Brooklyn, NY File ID DF Analyzed By Prep Date Prep Batch Analytical Batch Run #1 2E69203.D 1 09/16/11 MAH n/a n/a V2E3102 Run #2 Run #1 Run #2 Purge Volume 5.0 ml VOA PPL List CAS No. Compound Result RL MDL Units Q Acrolein ND ug/l Acrylonitrile ND ug/l Benzene ND ug/l Bromodichloromethane ND ug/l Bromoform ND ug/l Bromomethane ND ug/l Carbon tetrachloride ND ug/l Chlorobenzene ND ug/l Chloroethane ND ug/l Chloroethyl vinyl ether ND ug/l Chloroform ND ug/l Chloromethane ND ug/l Dibromochloromethane ND ug/l ,2-Dichlorobenzene ND ug/l ,3-Dichlorobenzene ND ug/l ,4-Dichlorobenzene ND ug/l Dichlorodifluoromethane ND ug/l ,1-Dichloroethane ND ug/l ,2-Dichloroethane ND ug/l ,1-Dichloroethene ND ug/l cis-1,2-dichloroethene ND ug/l trans-1,2-dichloroethene ND ug/l ,2-Dichloropropane ND ug/l cis-1,3-dichloropropene ND ug/l trans-1,3-dichloropropene ND ug/l Ethylbenzene ND ug/l Methylene chloride ND ug/l ,1,2,2-Tetrachloroethane ND ug/l Tetrachloroethene ND ug/l Toluene ND ug/l ,1,1-Trichloroethane ND ug/l ,1,2-Trichloroethane ND ug/l ND = Not detected MDL - Method Detection Limit J = Indicates an estimated value RL = Reporting Limit B = Indicates analyte found in associated method blank E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound JA of 35

38 Accutest 13:57 27-Sep-2011 Report of Analysis Page 2 of Client Sample ID: QAQC TRIP BLANK Lab Sample ID: JA Date Sampled: 09/12/11 Matrix: AQ - Trip Blank Water Date Received: 09/13/11 Method: EPA 624 Percent Solids: n/a Project: ExxonMobil Brooklyn Terminal, 400 Kingsland Avenue, Greenpoint, Brooklyn, NY VOA PPL List CAS No. Compound Result RL MDL Units Q Trichloroethene ND ug/l Trichlorofluoromethane ND ug/l Vinyl chloride ND ug/l Xylenes (total) ND ug/l CAS No. Surrogate Recoveries Run# 1 Run# 2 Limits ,2-Dichloroethane-D4 (SUR) 94% % Toluene-D8 (SUR) 100% % Bromofluorobenzene (SUR) 100% % Dibromofluoromethane (S) 99% % ND = Not detected MDL - Method Detection Limit J = Indicates an estimated value RL = Reporting Limit B = Indicates analyte found in associated method blank E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound 30 of 35 JA85914

39 3 Section 3 New Jersey Accutest LabLink@ :57 27-Sep-2011 Misc. Forms Custody Documents and Other Forms Includes the following where applicable: Chain of Custody 31 of 35 JA85914

40 3 3.1 JA85914: Chain of Custody Page 1 of 4 32 of 35 JA85914

41 3 3.1 JA85914: Chain of Custody Page 2 of 4 33 of 35 JA85914

42 Accutest Laboratories Sample Receipt Summary Accutest Job Number: JA85914 Date / Time Received: 9/12/ :50 Client: ROUX Project: GREENPOINT, BK 3.1 No. Coolers: 1 Airbill #'s: Delivery Method: PRIORITY 3 Cooler Security Y or N 1. Custody Seals Present: 2. Custody Seals Intact: 3. COC Present: 4. Smpl Dates/Time OK Cooler Temperature Y or N 1. Temp criteria achieved: 2. Cooler temp verification: 3. Cooler media: IR Gun Ice (Bag) Quality Control Preservatio Y or N N/A 1. Trip Blank present / cooler: 2. Trip Blank listed on COC: 3. Samples preserved properly: 4. VOCs headspace free: Y or N Sample Integrity - Documentation Y or N 1. Sample labels present on bottles: 2. Container labeling complete: 3. Sample container label / COC agree: Sample Integrity - Condition Y or N 1. Sample recvd within HT: 2. All containers accounted for: 3. Condition of sample: Intact Sample Integrity - Instructions 1. Analysis requested is clear: 2. Bottles received for unspecified tests 3. Sufficient volume recvd for analysis: 4. Compositing instructions clear: 5. Filtering instructions clear: Y or N N/A Comments DID NOT RECEIVE "RCS-EFFLUENT" DID NOT RECEIVE "QAQC-TB" Accutest Laboratories V: US Highway 130 F: Dayton, NJ www/accutest.com JA85914: Chain of Custody Page 3 of 4 34 of 35 JA85914

43 Problem Resolution Page 2 of 2 Accutest Job Number: JA85914 CSR: Response Date 3.1 Response: 3 JA85914: Chain of Custody Page 4 of 4 JA of 35

44 e-hardcopy 2.0 Automated Report New Jersey 09/23/11 09/23/11 Technical Report for Roux Associates ExxonMobil Brooklyn Terminal, 400 Kingsland Avenue, Greenpoint, Brooklyn, NY PO# WBS#08 Accutest Job Number: JA85910 Sampling Date: 09/12/11 Report to: Roux Associates ATTN: Ritu Patel Total number of pages in report: 15 Test results contained within this data package meet the requirements of the National Environmental Laboratory Accreditation Conference and/or state specific certification programs as applicable. David N. Speis VP, Laboratory Director Client Service contact: Matt Cordova Certifications: NJ(12129), NY(10983), CA, CT, DE, FL, IL, IN, KS, KY, LA, MA, MD, MI, MT, NC, PA, RI, SC, TN, VA, WV This report shall not be reproduced, except in its entirety, without the written approval of Accutest Laboratories. Test results relate only to samples analyzed. New Jersey 2235 Route 130 Dayton, NJ tel: fax: Accutest Laboratories is the sole authority for authorizing edits or modifications to this document. Unauthorized modification of this report is strictly prohibited. JA of 15

45 Table of Contents Section 1: Sample Summary... 3 Section 2: Sample Results : JA : RCS-BEFORE CARBON : JA : RCS-LEAD-1 CARBON EFFLUENT : JA : RCS-LAG-1 CARBON EFFLUENT Section 3: Misc. Forms : Chain of Custody : Summa Canister and Flow Controller Log Sections: of 15 JA85910

46 1 Accutest 14:08 23-Sep-2011 Sample Summary Roux Associates Job No: ExxonMobil Brooklyn Terminal, 400 Kingsland Avenue, Greenpoint, Brooklyn, NY Project No: PO# WBS#08 JA85910 Sample Collected Matrix Client Number Date Time By Received Code Type Sample ID JA /12/11 10:35 MS 09/12/11 AIR Air RCS-BEFORE CARBON JA /12/11 10:38 MS 09/12/11 AIR Air RCS-LEAD-1 CARBON EFFLUENT JA /12/11 10:40 MS 09/12/11 AIR Air RCS-LAG-1 CARBON EFFLUENT 3 of 15 JA85910

47 2 Section 2 New Jersey Accutest LabLink@ :08 23-Sep-2011 Sample Results Report of Analysis 4 of 15 JA85910

48 Accutest 14:08 23-Sep-2011 Report of Analysis Page 1 of Client Sample ID: RCS-BEFORE CARBON Lab Sample ID: JA Date Sampled: 09/12/11 Matrix: AIR - Air Summa ID: A634,A599 Date Received: 09/12/11 Method: TO-15 Percent Solids: n/a Project: ExxonMobil Brooklyn Terminal, 400 Kingsland Avenue, Greenpoint, Brooklyn, NY File ID DF Analyzed By Prep Date Prep Batch Analytical Batch Run #1 3W23961.D 25 09/13/11 YXC n/a n/a V3W948 Run #2 Run #1 Run #2 Initial Volume 200 ml CAS No. MW Compound Result RL MDL Units Q Result RL Units Acetone ND ppbv ND 24 ug/m ,3-Butadiene ND ppbv ND 22 ug/m Benzene ppbv ug/m Bromodichloromethane ND ppbv ND 67 ug/m Bromoform ND ppbv ND 100 ug/m Bromomethane ND ppbv ND 39 ug/m Bromoethene ND ppbv ND 44 ug/m Benzyl Chloride ND ppbv ND 52 ug/m Carbon disulfide ND ppbv ND 31 ug/m Chlorobenzene ND ppbv ND 46 ug/m Chloroethane ND ppbv ND 26 ug/m Chloroform ND ppbv ND 49 ug/m Chloromethane ND ppbv ND 21 ug/m Chloropropene ND ppbv ND 31 ug/m Chlorotoluene ND ppbv ND 52 ug/m Carbon tetrachloride ND ppbv ND 63 ug/m Cyclohexane ppbv ug/m ,1-Dichloroethane ppbv ug/m ,1-Dichloroethylene ppbv ug/m ,2-Dibromoethane ND ppbv ND 77 ug/m ,2-Dichloroethane ND ppbv ND 40 ug/m ,2-Dichloropropane ND ppbv ND 46 ug/m ,4-Dioxane ND ppbv ND 36 ug/m Dichlorodifluoromethane ND ppbv ND 49 ug/m Dibromochloromethane ND ppbv ND 85 ug/m trans-1,2-dichloroethylene ppbv ug/m cis-1,2-dichloroethylene ppbv ug/m cis-1,3-dichloropropene ND ppbv ND 45 ug/m m-dichlorobenzene ND ppbv ND 60 ug/m o-dichlorobenzene ND ppbv ND 60 ug/m p-dichlorobenzene ND ppbv ND 60 ug/m trans-1,3-dichloropropene ND ppbv ND 45 ug/m3 ND = Not detected MDL - Method Detection Limit J = Indicates an estimated value RL = Reporting Limit B = Indicates analyte found in associated method blank E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound JA of 15

49 Accutest 14:08 23-Sep-2011 Report of Analysis Page 2 of Client Sample ID: RCS-BEFORE CARBON Lab Sample ID: JA Date Sampled: 09/12/11 Matrix: AIR - Air Summa ID: A634,A599 Date Received: 09/12/11 Method: TO-15 Percent Solids: n/a Project: ExxonMobil Brooklyn Terminal, 400 Kingsland Avenue, Greenpoint, Brooklyn, NY CAS No. MW Compound Result RL MDL Units Q Result RL Units Ethanol ppbv J ug/m Ethylbenzene ppbv ug/m Ethyl Acetate ND ppbv ND 36 ug/m Ethyltoluene ppbv ug/m Freon 113 ND ppbv ND 77 ug/m Freon 114 ND ppbv ND 70 ug/m Heptane ppbv ug/m Hexachlorobutadiene ND ppbv ND 110 ug/m Hexane ppbv ug/m Hexanone ND ppbv ND 41 ug/m Isopropyl Alcohol ND ppbv ND 25 ug/m Methylene chloride ND ppbv ND 35 ug/m Methyl ethyl ketone ND ppbv ND 29 ug/m Methyl Isobutyl Ketone ND ppbv ND 41 ug/m Methyl Tert Butyl Ether ppbv ug/m Methylmethacrylate ND ppbv ND 41 ug/m Propylene ND ppbv ND 43 ug/m Styrene ND ppbv ND 43 ug/m ,1,1-Trichloroethane ND ppbv ND 55 ug/m ,1,2,2-Tetrachloroethane ND ppbv ND 69 ug/m ,1,2-Trichloroethane ND ppbv ND 55 ug/m ,2,4-Trichlorobenzene ND ppbv ND 74 ug/m ,2,4-Trimethylbenzene ppbv ug/m ,3,5-Trimethylbenzene ppbv ug/m ,2,4-Trimethylpentane ppbv ug/m Tertiary Butyl Alcohol ppbv J ug/m Tetrachloroethylene ppbv ug/m Tetrahydrofuran ND ppbv ND 29 ug/m Toluene ppbv ug/m Trichloroethylene ppbv ug/m Trichlorofluoromethane ND ppbv ND 56 ug/m Vinyl chloride ppbv ug/m Vinyl Acetate ND ppbv ND 35 ug/m m,p-xylene ppbv ug/m o-xylene ppbv ug/m Xylenes (total) ppbv ug/m3 CAS No. Surrogate Recoveries Run# 1 Run# 2 Limits Bromofluorobenzene 93% % ND = Not detected MDL - Method Detection Limit J = Indicates an estimated value RL = Reporting Limit B = Indicates analyte found in associated method blank E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound JA of 15

50 Accutest 14:08 23-Sep-2011 Report of Analysis Page 1 of Client Sample ID: RCS-LEAD-1 CARBON EFFLUENT Lab Sample ID: JA Date Sampled: 09/12/11 Matrix: AIR - Air Summa ID: A758 Date Received: 09/12/11 Method: TO-15 Percent Solids: n/a Project: ExxonMobil Brooklyn Terminal, 400 Kingsland Avenue, Greenpoint, Brooklyn, NY File ID DF Analyzed By Prep Date Prep Batch Analytical Batch Run #1 3W23962.D 1 09/13/11 YXC n/a n/a V3W948 Run #2 3W23979.D 1 09/14/11 YXC n/a n/a V3W949 Run #1 Run #2 Initial Volume 400 ml 100 ml CAS No. MW Compound Result RL MDL Units Q Result RL Units Acetone ND ppbv ND 0.48 ug/m ,3-Butadiene ND ppbv ND 0.44 ug/m Benzene 41.5 a ppbv 133 a 2.6 ug/m Bromodichloromethane ND ppbv ND 1.3 ug/m Bromoform ND ppbv ND 2.1 ug/m Bromomethane ND ppbv ND 0.78 ug/m Bromoethene ND ppbv ND 0.87 ug/m Benzyl Chloride ND ppbv ND 1.0 ug/m Carbon disulfide ND ppbv ND 0.62 ug/m Chlorobenzene ND ppbv ND 0.92 ug/m Chloroethane ppbv ug/m Chloroform ppbv J ug/m Chloromethane ppbv ug/m Chloropropene ND ppbv ND 0.63 ug/m Chlorotoluene ND ppbv ND 1.0 ug/m Carbon tetrachloride ND ppbv ND 1.3 ug/m Cyclohexane 38.6 a ppbv 133 a 2.8 ug/m ,1-Dichloroethane ppbv ug/m ,1-Dichloroethylene ppbv ug/m ,2-Dibromoethane ND ppbv ND 1.5 ug/m ,2-Dichloroethane ppbv ug/m ,2-Dichloropropane ND ppbv ND 0.92 ug/m ,4-Dioxane ND ppbv ND 0.72 ug/m Dichlorodifluoromethane ppbv ug/m Dibromochloromethane ND ppbv ND 1.7 ug/m trans-1,2-dichloroethylene ppbv ug/m cis-1,2-dichloroethylene 117 a ppbv 464 a 3.2 ug/m cis-1,3-dichloropropene ND ppbv ND 0.91 ug/m m-dichlorobenzene ND ppbv ND 1.2 ug/m o-dichlorobenzene ND ppbv ND 1.2 ug/m p-dichlorobenzene ND ppbv ND 1.2 ug/m trans-1,3-dichloropropene ND ppbv ND 0.91 ug/m3 ND = Not detected MDL - Method Detection Limit J = Indicates an estimated value RL = Reporting Limit B = Indicates analyte found in associated method blank E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound JA of 15

51 Accutest 14:08 23-Sep-2011 Report of Analysis Page 2 of Client Sample ID: RCS-LEAD-1 CARBON EFFLUENT Lab Sample ID: JA Date Sampled: 09/12/11 Matrix: AIR - Air Summa ID: A758 Date Received: 09/12/11 Method: TO-15 Percent Solids: n/a Project: ExxonMobil Brooklyn Terminal, 400 Kingsland Avenue, Greenpoint, Brooklyn, NY CAS No. MW Compound Result RL MDL Units Q Result RL Units Ethanol ppbv ug/m Ethylbenzene ND ppbv ND 0.87 ug/m Ethyl Acetate ND ppbv ND 0.72 ug/m Ethyltoluene ND ppbv ND 0.98 ug/m Freon 113 ND ppbv ND 1.5 ug/m Freon 114 ND ppbv ND 1.4 ug/m Heptane ppbv J ug/m Hexachlorobutadiene ND ppbv ND 2.1 ug/m Hexane ppbv ug/m Hexanone ppbv ug/m Isopropyl Alcohol ppbv ug/m Methylene chloride ppbv ug/m Methyl ethyl ketone ppbv ug/m Methyl Isobutyl Ketone ND ppbv ND 0.82 ug/m Methyl Tert Butyl Ether ND ppbv ND 0.72 ug/m Methylmethacrylate ND ppbv ND 0.82 ug/m Propylene ND ppbv ND 0.86 ug/m Styrene ND ppbv ND 0.85 ug/m ,1,1-Trichloroethane ppbv ug/m ,1,2,2-Tetrachloroethane ND ppbv ND 1.4 ug/m ,1,2-Trichloroethane ND ppbv ND 1.1 ug/m ,2,4-Trichlorobenzene ND ppbv ND 1.5 ug/m ,2,4-Trimethylbenzene ppbv J ug/m ,3,5-Trimethylbenzene ND ppbv ND 0.98 ug/m ,2,4-Trimethylpentane ppbv ug/m Tertiary Butyl Alcohol ppbv ug/m Tetrachloroethylene ppbv ug/m Tetrahydrofuran ppbv ug/m Toluene ppbv J ug/m Trichloroethylene ppbv ug/m Trichlorofluoromethane ppbv ug/m Vinyl chloride ppbv ug/m Vinyl Acetate ND ppbv ND 0.70 ug/m m,p-xylene ppbv J ug/m o-xylene ND ppbv ND 0.87 ug/m Xylenes (total) ppbv J ug/m3 CAS No. Surrogate Recoveries Run# 1 Run# 2 Limits Bromofluorobenzene 89% 92% % ND = Not detected MDL - Method Detection Limit J = Indicates an estimated value RL = Reporting Limit B = Indicates analyte found in associated method blank E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound JA of 15

52 Accutest 14:08 23-Sep-2011 Report of Analysis Page 3 of Client Sample ID: RCS-LEAD-1 CARBON EFFLUENT Lab Sample ID: JA Date Sampled: 09/12/11 Matrix: AIR - Air Summa ID: A758 Date Received: 09/12/11 Method: TO-15 Percent Solids: n/a Project: ExxonMobil Brooklyn Terminal, 400 Kingsland Avenue, Greenpoint, Brooklyn, NY CAS No. MW Compound Result RL MDL Units Q Result RL Units (a) Result is from Run# 2 ND = Not detected MDL - Method Detection Limit J = Indicates an estimated value RL = Reporting Limit B = Indicates analyte found in associated method blank E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound 9 of 15 JA85910

53 Accutest 14:08 23-Sep-2011 Report of Analysis Page 1 of Client Sample ID: RCS-LAG-1 CARBON EFFLUENT Lab Sample ID: JA Date Sampled: 09/12/11 Matrix: AIR - Air Summa ID: A308 Date Received: 09/12/11 Method: TO-15 Percent Solids: n/a Project: ExxonMobil Brooklyn Terminal, 400 Kingsland Avenue, Greenpoint, Brooklyn, NY File ID DF Analyzed By Prep Date Prep Batch Analytical Batch Run #1 3W23964.D 1 09/13/11 YXC n/a n/a V3W948 Run #2 Run #1 Run #2 Initial Volume 400 ml CAS No. MW Compound Result RL MDL Units Q Result RL Units Acetone ND ppbv ND 0.48 ug/m ,3-Butadiene ND ppbv ND 0.44 ug/m Benzene ppbv ug/m Bromodichloromethane ND ppbv ND 1.3 ug/m Bromoform ND ppbv ND 2.1 ug/m Bromomethane ND ppbv ND 0.78 ug/m Bromoethene ND ppbv ND 0.87 ug/m Benzyl Chloride ND ppbv ND 1.0 ug/m Carbon disulfide ND ppbv ND 0.62 ug/m Chlorobenzene ND ppbv ND 0.92 ug/m Chloroethane ppbv ug/m Chloroform ND ppbv ND 0.98 ug/m Chloromethane ppbv ug/m Chloropropene ND ppbv ND 0.63 ug/m Chlorotoluene ND ppbv ND 1.0 ug/m Carbon tetrachloride ND ppbv ND 1.3 ug/m Cyclohexane ppbv ug/m ,1-Dichloroethane ppbv ug/m ,1-Dichloroethylene ppbv ug/m ,2-Dibromoethane ND ppbv ND 1.5 ug/m ,2-Dichloroethane ND ppbv ND 0.81 ug/m ,2-Dichloropropane ND ppbv ND 0.92 ug/m ,4-Dioxane ND ppbv ND 0.72 ug/m Dichlorodifluoromethane ppbv ug/m Dibromochloromethane ND ppbv ND 1.7 ug/m trans-1,2-dichloroethylene ppbv ug/m cis-1,2-dichloroethylene ppbv ug/m cis-1,3-dichloropropene ND ppbv ND 0.91 ug/m m-dichlorobenzene ND ppbv ND 1.2 ug/m o-dichlorobenzene ND ppbv ND 1.2 ug/m p-dichlorobenzene ND ppbv ND 1.2 ug/m trans-1,3-dichloropropene ND ppbv ND 0.91 ug/m3 ND = Not detected MDL - Method Detection Limit J = Indicates an estimated value RL = Reporting Limit B = Indicates analyte found in associated method blank E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound JA of 15

54 Accutest 14:08 23-Sep-2011 Report of Analysis Page 2 of Client Sample ID: RCS-LAG-1 CARBON EFFLUENT Lab Sample ID: JA Date Sampled: 09/12/11 Matrix: AIR - Air Summa ID: A308 Date Received: 09/12/11 Method: TO-15 Percent Solids: n/a Project: ExxonMobil Brooklyn Terminal, 400 Kingsland Avenue, Greenpoint, Brooklyn, NY CAS No. MW Compound Result RL MDL Units Q Result RL Units Ethanol ppbv ug/m Ethylbenzene ND ppbv ND 0.87 ug/m Ethyl Acetate ND ppbv ND 0.72 ug/m Ethyltoluene ND ppbv ND 0.98 ug/m Freon 113 ND ppbv ND 1.5 ug/m Freon 114 ND ppbv ND 1.4 ug/m Heptane ppbv J ug/m Hexachlorobutadiene ND ppbv ND 2.1 ug/m Hexane ppbv ug/m Hexanone ND ppbv ND 0.82 ug/m Isopropyl Alcohol ppbv ug/m Methylene chloride ppbv ug/m Methyl ethyl ketone ppbv ug/m Methyl Isobutyl Ketone ND ppbv ND 0.82 ug/m Methyl Tert Butyl Ether ND ppbv ND 0.72 ug/m Methylmethacrylate ND ppbv ND 0.82 ug/m Propylene ND ppbv ND 0.86 ug/m Styrene ND ppbv ND 0.85 ug/m ,1,1-Trichloroethane ND ppbv ND 1.1 ug/m ,1,2,2-Tetrachloroethane ND ppbv ND 1.4 ug/m ,1,2-Trichloroethane ND ppbv ND 1.1 ug/m ,2,4-Trichlorobenzene ND ppbv ND 1.5 ug/m ,2,4-Trimethylbenzene ND ppbv ND 0.98 ug/m ,3,5-Trimethylbenzene ND ppbv ND 0.98 ug/m ,2,4-Trimethylpentane ppbv ug/m Tertiary Butyl Alcohol ND ppbv ND 0.61 ug/m Tetrachloroethylene ppbv ug/m Tetrahydrofuran ND ppbv ND 0.59 ug/m Toluene ppbv ug/m Trichloroethylene ND ppbv ND 0.21 ug/m Trichlorofluoromethane ppbv ug/m Vinyl chloride ppbv ug/m Vinyl Acetate ND ppbv ND 0.70 ug/m m,p-xylene ppbv J ug/m o-xylene ND ppbv ND 0.87 ug/m Xylenes (total) ppbv J ug/m3 CAS No. Surrogate Recoveries Run# 1 Run# 2 Limits Bromofluorobenzene 89% % ND = Not detected MDL - Method Detection Limit J = Indicates an estimated value RL = Reporting Limit B = Indicates analyte found in associated method blank E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound JA of 15

55 3 Section 3 New Jersey Accutest LabLink@ :08 23-Sep-2011 Misc. Forms Custody Documents and Other Forms Includes the following where applicable: Chain of Custody Summa Canister and Flow Controller Log 12 of 15 JA85910

56 3 3.1 JA85910: Chain of Custody Page 1 of 2 13 of 15 JA85910

57 Accutest Laboratories Sample Receipt Summary Accutest Job Number JA85910 Client: Date / Time Received: 9/12/2011 No. Coolers: 0 Airbill #'s: Project: Delivery Method: 3.1 Cooler Security 1. Custody Seals Present: 2. Custody Seals Intact: Y or N 3. COC Present: 4. Smpl Dates/Time OK Y or N Sample Integrity - Documentation Y or N 1. Sample labels present on bottles: 2. Container labeling complete: 3 Cooler Temperature Y or N 3. Sample container label / COC agree: 1. Temp criteria achieved: 2. Cooler temp verification: 3. Cooler media: Quality Control Preservatio Y or N N/A Sample Integrity - Condition Y or N 1. Sample recvd within HT: 2. All containers accounted for: 3. Condition of sample: Intact 1. Trip Blank present / cooler: 2. Trip Blank listed on COC: Sample Integrity - Instructions 1. Analysis requested is clear: Y or N N/A 3. Samples preserved properly: 2. Bottles received for unspecified tests 4. VOCs headspace free: 3. Sufficient volume recvd for analysis: 4. Compositing instructions clear: 5. Filtering instructions clear: Comments Accutest Laboratories V: US Highway 130 F: Dayton, New Jersey www/accutest.com JA85910: Chain of Custody Page 2 of 2 14 of 15 JA85910

58 Summa Canister and Flow Controller Log Page 1 of 1 Job Number: JA85910 Account: ROUXNYI Roux Associates Project: ExxonMobil Brooklyn Terminal, 400 Kingsland Avenue, Greenpoint, Brooklyn, NY Received: 09/12/ SUMMA CANISTERS Shipping Receiving Summa Vac Date SCC SCC Sample Date Vac Pres Final Dil ID L " Hg Out By Batch FileID Number In By " Hg psig psig Fact A /02/11 FZ CP4971 JA /13/11 FZ 4 1 A /02/11 FZ CP4971 JA /13/11 FZ 0 1 A /02/11 FZ CP4971 JA /13/11 FZ 1 1 Accutest Bottle Order(s): KM-12/29/ Prep Date Room Temp(F) Bar Pres "Hg 09/02/ JA of 15

59 e-hardcopy 2.0 Automated Report New Jersey 09/27/11 09/27/11 Technical Report for Roux Associates ExxonMobil Off-Site 31097, Brooklyn, NY PO# WBS#08 Accutest Job Number: JA85694A Sampling Date: 09/08/11 Report to: Roux Associates ATTN: Ritu Patel Total number of pages in report: 24 Test results contained within this data package meet the requirements of the National Environmental Laboratory Accreditation Conference and/or state specific certification programs as applicable. David N. Speis VP, Laboratory Director Client Service contact: Matt Cordova Certifications: NJ(12129), NY(10983), CA, CT, DE, FL, IL, IN, KS, KY, LA, MA, MD, MI, MT, NC, PA, RI, SC, TN, VA, WV This report shall not be reproduced, except in its entirety, without the written approval of Accutest Laboratories. Test results relate only to samples analyzed. New Jersey 2235 Route 130 Dayton, NJ tel: fax: Accutest Laboratories is the sole authority for authorizing edits or modifications to this document. Unauthorized modification of this report is strictly prohibited. JA85694A 1 of 24

60 Table of Contents Section 1: Sample Summary... 3 Section 2: Sample Results : JA : OSS-INFLUENT : JA : OSS-EFFLUENT Section 3: Misc. Forms : Chain of Custody Sections: of 24 JA85694A

61 1 Accutest 13:59 27-Sep-2011 Roux Associates ExxonMobil Off-Site 31097, Brooklyn, NY Project No: PO# WBS#08 Sample Summary Job No: JA85694A Sample Collected Matrix Client Number Date Time By Received Code Type Sample ID JA /08/11 11:15 BC 09/09/11 AQ Influent OSS-INFLUENT JA /08/11 13:10 BC 09/09/11 AQ Effluent OSS-EFFLUENT 3 of 24 JA85694A

62 2 Section 2 New Jersey Accutest LabLink@ :59 27-Sep-2011 Sample Results Report of Analysis 4 of 24 JA85694A

63 Accutest 13:59 27-Sep-2011 Report of Analysis Page 1 of Client Sample ID: OSS-INFLUENT Lab Sample ID: JA Date Sampled: 09/08/11 Matrix: AQ - Influent Date Received: 09/09/11 Method: EPA 624 Percent Solids: n/a Project: ExxonMobil Off-Site 31097, Brooklyn, NY File ID DF Analyzed By Prep Date Prep Batch Analytical Batch Run #1 2E69139.D 5 09/15/11 MAH n/a n/a V2E3099 Run #2 Run #1 Run #2 Purge Volume 5.0 ml VOA PPL List CAS No. Compound Result RL MDL Units Q Acrolein ND ug/l Acrylonitrile ND ug/l Benzene ug/l Bromodichloromethane ND ug/l Bromoform ND ug/l Bromomethane ND ug/l Carbon tetrachloride ND ug/l Chlorobenzene ND ug/l Chloroethane ug/l Chloroethyl vinyl ether ND ug/l Chloroform ND ug/l Chloromethane ND ug/l Dibromochloromethane ND ug/l ,2-Dichlorobenzene ND ug/l ,3-Dichlorobenzene ND ug/l ,4-Dichlorobenzene ND ug/l Dichlorodifluoromethane ND ug/l ,1-Dichloroethane ug/l ,2-Dichloroethane ND ug/l ,1-Dichloroethene ug/l J cis-1,2-dichloroethene ug/l trans-1,2-dichloroethene ug/l ,2-Dichloropropane ND ug/l cis-1,3-dichloropropene ND ug/l trans-1,3-dichloropropene ND ug/l Ethylbenzene ug/l Methylene chloride ND ug/l ,1,2,2-Tetrachloroethane ND ug/l Tetrachloroethene ug/l Toluene ug/l ,1,1-Trichloroethane ND ug/l ,1,2-Trichloroethane ND ug/l ND = Not detected MDL - Method Detection Limit J = Indicates an estimated value RL = Reporting Limit B = Indicates analyte found in associated method blank E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound 5 of 24 JA85694A

64 Accutest 13:59 27-Sep-2011 Report of Analysis Page 2 of Client Sample ID: OSS-INFLUENT Lab Sample ID: JA Date Sampled: 09/08/11 Matrix: AQ - Influent Date Received: 09/09/11 Method: EPA 624 Percent Solids: n/a Project: ExxonMobil Off-Site 31097, Brooklyn, NY VOA PPL List CAS No. Compound Result RL MDL Units Q Trichloroethene ug/l Trichlorofluoromethane ND ug/l Vinyl chloride ug/l Xylenes (total) ug/l CAS No. Surrogate Recoveries Run# 1 Run# 2 Limits ,2-Dichloroethane-D4 (SUR) 90% % Toluene-D8 (SUR) 101% % Bromofluorobenzene (SUR) 100% % Dibromofluoromethane (S) 94% % ND = Not detected MDL - Method Detection Limit J = Indicates an estimated value RL = Reporting Limit B = Indicates analyte found in associated method blank E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound 6 of 24 JA85694A

65 Accutest 13:59 27-Sep-2011 Report of Analysis Page 1 of Client Sample ID: OSS-INFLUENT Lab Sample ID: JA Date Sampled: 09/08/11 Matrix: AQ - Influent Date Received: 09/09/11 Method: SW B Percent Solids: n/a Project: ExxonMobil Off-Site 31097, Brooklyn, NY File ID DF Analyzed By Prep Date Prep Batch Analytical Batch Run #1 4B09930.D 1 09/12/11 TDN n/a n/a V4B433 Run #2 Run #1 Run #2 Purge Volume 5.0 ml CAS No. Compound Result RL MDL Units Q Methyl Tert Butyl Ether ug/l CAS No. Surrogate Recoveries Run# 1 Run# 2 Limits Dibromofluoromethane 101% % ,2-Dichloroethane-D4 105% % Toluene-D8 93% % Bromofluorobenzene 95% % ND = Not detected MDL - Method Detection Limit J = Indicates an estimated value RL = Reporting Limit B = Indicates analyte found in associated method blank E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound 7 of 24 JA85694A

66 Accutest 13:59 27-Sep-2011 Report of Analysis Page 1 of Client Sample ID: OSS-INFLUENT Lab Sample ID: JA Date Sampled: 09/08/11 Matrix: AQ - Influent Date Received: 09/09/11 Method: EPA 625 EPA 625 Percent Solids: n/a Project: ExxonMobil Off-Site 31097, Brooklyn, NY File ID DF Analyzed By Prep Date Prep Batch Analytical Batch Run #1 R89939.D 1 09/20/11 LP 09/10/11 OP51792 ER3460 Run #2 Initial Volume Final Volume Run #1 940 ml 1.0 ml Run #2 ABN PPL List CAS No. Compound Result RL MDL Units Q Chlorophenol ND ug/l Chloro-3-methyl phenol ND ug/l ,4-Dichlorophenol ND ug/l ,4-Dimethylphenol ND ug/l ,4-Dinitrophenol ND ug/l ,6-Dinitro-o-cresol ND ug/l Nitrophenol ND ug/l Nitrophenol ND ug/l Pentachlorophenol ND ug/l Phenol ug/l ,4,6-Trichlorophenol ND ug/l Acenaphthene ug/l Acenaphthylene ND ug/l Anthracene ND ug/l Benzidine ND ug/l Benzo(a)anthracene ND ug/l Benzo(a)pyrene ND ug/l Benzo(b)fluoranthene ND ug/l Benzo(g,h,i)perylene ND ug/l Benzo(k)fluoranthene ND ug/l Bromophenyl phenyl ether ND ug/l Butyl benzyl phthalate ND ug/l Chloronaphthalene ND ug/l Chloroaniline ND ug/l Chrysene ND ug/l bis(2-chloroethoxy)methane ND ug/l bis(2-chloroethyl)ether ND ug/l bis(2-chloroisopropyl)ether ND ug/l Chlorophenyl phenyl ether ND ug/l ,2-Dichlorobenzene ND ug/l ,2-Diphenylhydrazine ND ug/l ,3-Dichlorobenzene ND ug/l ND = Not detected MDL - Method Detection Limit J = Indicates an estimated value RL = Reporting Limit B = Indicates analyte found in associated method blank E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound 8 of 24 JA85694A

67 Accutest 13:59 27-Sep-2011 Report of Analysis Page 2 of Client Sample ID: OSS-INFLUENT Lab Sample ID: JA Date Sampled: 09/08/11 Matrix: AQ - Influent Date Received: 09/09/11 Method: EPA 625 EPA 625 Percent Solids: n/a Project: ExxonMobil Off-Site 31097, Brooklyn, NY ABN PPL List CAS No. Compound Result RL MDL Units Q ,4-Dichlorobenzene ND ug/l ,4-Dinitrotoluene ND ug/l ,6-Dinitrotoluene ND ug/l ,3'-Dichlorobenzidine ND ug/l Dibenzo(a,h)anthracene ND ug/l Di-n-butyl phthalate ND ug/l Di-n-octyl phthalate ND ug/l Diethyl phthalate ND ug/l Dimethyl phthalate ND ug/l bis(2-ethylhexyl)phthalate ND ug/l Fluoranthene ND ug/l Fluorene ND ug/l Hexachlorobenzene ND ug/l Hexachlorobutadiene ND ug/l Hexachlorocyclopentadiene ND ug/l Hexachloroethane ND ug/l Indeno(1,2,3-cd)pyrene ND ug/l Isophorone ND ug/l Naphthalene ug/l Nitrobenzene ND ug/l n-nitrosodimethylamine ND ug/l N-Nitroso-di-n-propylamine ND ug/l N-Nitrosodiphenylamine ND ug/l Phenanthrene ND ug/l Pyrene ND ug/l ,2,4-Trichlorobenzene ND ug/l CAS No. Surrogate Recoveries Run# 1 Run# 2 Limits Fluorophenol 37% % Phenol-d5 24% % ,4,6-Tribromophenol 104% % Nitrobenzene-d5 102% % Fluorobiphenyl 98% % Terphenyl-d14 109% % ND = Not detected MDL - Method Detection Limit J = Indicates an estimated value RL = Reporting Limit B = Indicates analyte found in associated method blank E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound 9 of 24 JA85694A

68 Accutest 13:59 27-Sep-2011 Report of Analysis Page 1 of Client Sample ID: OSS-INFLUENT Lab Sample ID: JA Date Sampled: 09/08/11 Matrix: AQ - Influent Date Received: 09/09/11 Percent Solids: n/a Project: ExxonMobil Off-Site 31097, Brooklyn, NY Total Metals Analysis Analyte Result RL Units DF Prep Analyzed By Method Prep Method Calcium ug/l 1 09/19/11 09/21/11 ND EPA EPA Copper <10 10 ug/l 1 09/19/11 09/20/11 VC EPA EPA Iron ug/l 1 09/19/11 09/21/11 ND EPA EPA Manganese ug/l 1 09/19/11 09/20/11 VC EPA EPA Mercury < ug/l 1 09/21/11 09/21/11 JW EPA EPA (1) Instrument QC Batch: MA27108 (2) Instrument QC Batch: MA27116 (3) Instrument QC Batch: MA27124 (4) Prep QC Batch: MP60266 (5) Prep QC Batch: MP60270 RL = Reporting Limit 10 of 24 JA85694A

69 Accutest 13:59 27-Sep-2011 Report of Analysis Page 1 of Client Sample ID: OSS-INFLUENT Lab Sample ID: JA Date Sampled: 09/08/11 Matrix: AQ - Influent Date Received: 09/09/11 Percent Solids: n/a Project: ExxonMobil Off-Site 31097, Brooklyn, NY General Chemistry Analyte Result RL Units DF Analyzed By Method Chloride mg/l 10 09/16/11 16:36 AE EPA 300/SW A HEM Oil and Grease < mg/l 1 09/21/11 JOO EPA 1664A Phenols < mg/l 1 09/14/11 13:00 JA EPA 420.4/LACHAT Solids, Settleable < ml/l 1 09/09/11 14:00 CW SM F Solids, Total Suspended mg/l 1 09/13/11 RI SM D Turbidity NTU 10 09/09/11 19:50 LS EPA ph a 6.95 su 1 09/09/11 11:12 SUB SM H B (a) Sample received out of holding time for ph analysis. RL = Reporting Limit JA85694A 11 of 24

70 Accutest 13:59 27-Sep-2011 Report of Analysis Page 1 of Client Sample ID: OSS-EFFLUENT Lab Sample ID: JA Date Sampled: 09/08/11 Matrix: AQ - Effluent Date Received: 09/09/11 Method: EPA 624 Percent Solids: n/a Project: ExxonMobil Off-Site 31097, Brooklyn, NY File ID DF Analyzed By Prep Date Prep Batch Analytical Batch Run #1 2E69138.D 1 09/15/11 MAH n/a n/a V2E3099 Run #2 Run #1 Run #2 Purge Volume 5.0 ml VOA PPL List CAS No. Compound Result RL MDL Units Q Acrolein ND ug/l Acrylonitrile ND ug/l Benzene ND ug/l Bromodichloromethane ND ug/l Bromoform ND ug/l Bromomethane ND ug/l Carbon tetrachloride ND ug/l Chlorobenzene ND ug/l Chloroethane ND ug/l Chloroethyl vinyl ether ND ug/l Chloroform ND ug/l Chloromethane ND ug/l Dibromochloromethane ND ug/l ,2-Dichlorobenzene ND ug/l ,3-Dichlorobenzene ND ug/l ,4-Dichlorobenzene ND ug/l Dichlorodifluoromethane ND ug/l ,1-Dichloroethane ND ug/l ,2-Dichloroethane ND ug/l ,1-Dichloroethene ND ug/l cis-1,2-dichloroethene ug/l trans-1,2-dichloroethene ND ug/l ,2-Dichloropropane ND ug/l cis-1,3-dichloropropene ND ug/l trans-1,3-dichloropropene ND ug/l Ethylbenzene ND ug/l Methylene chloride ND ug/l ,1,2,2-Tetrachloroethane ND ug/l Tetrachloroethene ug/l J Toluene ND ug/l ,1,1-Trichloroethane ND ug/l ,1,2-Trichloroethane ND ug/l ND = Not detected MDL - Method Detection Limit J = Indicates an estimated value RL = Reporting Limit B = Indicates analyte found in associated method blank E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound JA85694A 12 of 24

71 Accutest 13:59 27-Sep-2011 Report of Analysis Page 2 of Client Sample ID: OSS-EFFLUENT Lab Sample ID: JA Date Sampled: 09/08/11 Matrix: AQ - Effluent Date Received: 09/09/11 Method: EPA 624 Percent Solids: n/a Project: ExxonMobil Off-Site 31097, Brooklyn, NY VOA PPL List CAS No. Compound Result RL MDL Units Q Trichloroethene ug/l J Trichlorofluoromethane ND ug/l Vinyl chloride ND ug/l Xylenes (total) ug/l J CAS No. Surrogate Recoveries Run# 1 Run# 2 Limits ,2-Dichloroethane-D4 (SUR) 90% % Toluene-D8 (SUR) 100% % Bromofluorobenzene (SUR) 100% % Dibromofluoromethane (S) 98% % ND = Not detected MDL - Method Detection Limit J = Indicates an estimated value RL = Reporting Limit B = Indicates analyte found in associated method blank E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound 13 of 24 JA85694A

72 Accutest 13:59 27-Sep-2011 Report of Analysis Page 1 of Client Sample ID: OSS-EFFLUENT Lab Sample ID: JA Date Sampled: 09/08/11 Matrix: AQ - Effluent Date Received: 09/09/11 Method: SW B Percent Solids: n/a Project: ExxonMobil Off-Site 31097, Brooklyn, NY File ID DF Analyzed By Prep Date Prep Batch Analytical Batch Run #1 4B09927.D 1 09/12/11 TDN n/a n/a V4B433 Run #2 Run #1 Run #2 Purge Volume 5.0 ml CAS No. Compound Result RL MDL Units Q Methyl Tert Butyl Ether ug/l CAS No. Surrogate Recoveries Run# 1 Run# 2 Limits Dibromofluoromethane 104% % ,2-Dichloroethane-D4 107% % Toluene-D8 96% % Bromofluorobenzene 93% % ND = Not detected MDL - Method Detection Limit J = Indicates an estimated value RL = Reporting Limit B = Indicates analyte found in associated method blank E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound JA85694A 14 of 24

73 Accutest 13:59 27-Sep-2011 Report of Analysis Page 1 of Client Sample ID: OSS-EFFLUENT Lab Sample ID: JA Date Sampled: 09/08/11 Matrix: AQ - Effluent Date Received: 09/09/11 Method: EPA 625 EPA 625 Percent Solids: n/a Project: ExxonMobil Off-Site 31097, Brooklyn, NY File ID DF Analyzed By Prep Date Prep Batch Analytical Batch Run #1 R89808.D 1 09/14/11 LP 09/10/11 OP51792 ER3452 Run #2 Initial Volume Final Volume Run # ml 1.0 ml Run #2 ABN PPL List CAS No. Compound Result RL MDL Units Q Chlorophenol ND ug/l Chloro-3-methyl phenol ND ug/l ,4-Dichlorophenol ND ug/l ,4-Dimethylphenol ND ug/l ,4-Dinitrophenol ND ug/l ,6-Dinitro-o-cresol ND ug/l Nitrophenol ND ug/l Nitrophenol ND ug/l Pentachlorophenol ND ug/l Phenol ND ug/l ,4,6-Trichlorophenol ND ug/l Acenaphthene ND ug/l Acenaphthylene ND ug/l Anthracene ND ug/l Benzidine ND ug/l Benzo(a)anthracene ND ug/l Benzo(a)pyrene ND ug/l Benzo(b)fluoranthene ND ug/l Benzo(g,h,i)perylene ND ug/l Benzo(k)fluoranthene ND ug/l Bromophenyl phenyl ether ND ug/l Butyl benzyl phthalate ND ug/l Chloronaphthalene ND ug/l Chloroaniline ND ug/l Chrysene ND ug/l bis(2-chloroethoxy)methane ND ug/l bis(2-chloroethyl)ether ND ug/l bis(2-chloroisopropyl)ether ND ug/l Chlorophenyl phenyl ether ND ug/l ,2-Dichlorobenzene ND ug/l ,2-Diphenylhydrazine ND ug/l ,3-Dichlorobenzene ND ug/l ND = Not detected MDL - Method Detection Limit J = Indicates an estimated value RL = Reporting Limit B = Indicates analyte found in associated method blank E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound JA85694A 15 of 24

74 Accutest 13:59 27-Sep-2011 Report of Analysis Page 2 of Client Sample ID: OSS-EFFLUENT Lab Sample ID: JA Date Sampled: 09/08/11 Matrix: AQ - Effluent Date Received: 09/09/11 Method: EPA 625 EPA 625 Percent Solids: n/a Project: ExxonMobil Off-Site 31097, Brooklyn, NY ABN PPL List CAS No. Compound Result RL MDL Units Q ,4-Dichlorobenzene ND ug/l ,4-Dinitrotoluene ND ug/l ,6-Dinitrotoluene ND ug/l ,3'-Dichlorobenzidine ND ug/l Dibenzo(a,h)anthracene ND ug/l Di-n-butyl phthalate ND ug/l Di-n-octyl phthalate ND ug/l Diethyl phthalate ND ug/l Dimethyl phthalate ND ug/l bis(2-ethylhexyl)phthalate ND ug/l Fluoranthene ND ug/l Fluorene ND ug/l Hexachlorobenzene ND ug/l Hexachlorobutadiene ND ug/l Hexachlorocyclopentadiene ND ug/l Hexachloroethane ND ug/l Indeno(1,2,3-cd)pyrene ND ug/l Isophorone ND ug/l Naphthalene ND ug/l Nitrobenzene ND ug/l n-nitrosodimethylamine ND ug/l N-Nitroso-di-n-propylamine ND ug/l N-Nitrosodiphenylamine ND ug/l Phenanthrene ND ug/l Pyrene ND ug/l ,2,4-Trichlorobenzene ND ug/l CAS No. Surrogate Recoveries Run# 1 Run# 2 Limits Fluorophenol 41% % Phenol-d5 25% % ,4,6-Tribromophenol 118% % Nitrobenzene-d5 92% % Fluorobiphenyl 101% % Terphenyl-d14 129% % ND = Not detected MDL - Method Detection Limit J = Indicates an estimated value RL = Reporting Limit B = Indicates analyte found in associated method blank E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound 16 of 24 JA85694A

75 Accutest 13:59 27-Sep-2011 Report of Analysis Page 1 of Client Sample ID: OSS-EFFLUENT Lab Sample ID: JA Date Sampled: 09/08/11 Matrix: AQ - Effluent Date Received: 09/09/11 Percent Solids: n/a Project: ExxonMobil Off-Site 31097, Brooklyn, NY Total Metals Analysis Analyte Result RL Units DF Prep Analyzed By Method Prep Method Calcium ug/l 1 09/19/11 09/21/11 ND EPA EPA Copper <10 10 ug/l 1 09/19/11 09/20/11 VC EPA EPA Iron ug/l 1 09/19/11 09/21/11 ND EPA EPA Manganese ug/l 1 09/19/11 09/20/11 VC EPA EPA Mercury < ug/l 1 09/21/11 09/21/11 JW EPA EPA (1) Instrument QC Batch: MA27108 (2) Instrument QC Batch: MA27116 (3) Instrument QC Batch: MA27124 (4) Prep QC Batch: MP60266 (5) Prep QC Batch: MP60270 RL = Reporting Limit 17 of 24 JA85694A

76 Accutest 13:59 27-Sep-2011 Report of Analysis Page 1 of Client Sample ID: OSS-EFFLUENT Lab Sample ID: JA Date Sampled: 09/08/11 Matrix: AQ - Effluent Date Received: 09/09/11 Percent Solids: n/a Project: ExxonMobil Off-Site 31097, Brooklyn, NY General Chemistry Analyte Result RL Units DF Analyzed By Method Chloride mg/l 8 09/16/11 17:00 AE EPA 300/SW A HEM Oil and Grease < mg/l 1 09/21/11 JOO EPA 1664A Phenols < mg/l 1 09/14/11 13:03 JA EPA 420.4/LACHAT Solids, Settleable < ml/l 1 09/09/11 14:00 CW SM F Solids, Total Suspended mg/l 1 09/13/11 RI SM D Turbidity NTU 1 09/09/11 19:50 LS EPA ph a 7.97 su 1 09/09/11 11:15 SUB SM H B (a) Sample received out of holding time for ph analysis. RL = Reporting Limit JA85694A 18 of 24

77 3 Section 3 New Jersey Accutest LabLink@ :59 27-Sep-2011 Misc. Forms Custody Documents and Other Forms Includes the following where applicable: Chain of Custody 19 of 24 JA85694A

78 3 3.1 JA85694A: Chain of Custody Page 1 of 5 20 of 24 JA85694A

79 3 3.1 JA85694A: Chain of Custody Page 2 of 5 21 of 24 JA85694A

80 3 3.1 JA85694A: Chain of Custody Page 3 of 5 22 of 24 JA85694A

81 Accutest Laboratories Sample Receipt Summary Accutest Job Number: JA85694 Client: ROUX Immediate Client Services Action Required: Date / Time Received: 9/9/ :15 Delivery Method: FedEx Client Service Action Required at Login: Project: GREENPOINT No. Coolers: Airbill #'s: Yes No 3.1 Cooler Security 1. Custody Seals Present: 2. Custody Seals Intact: Y or N 3. COC Present: 4. Smpl Dates/Time OK Y or N Sample Integrity - Documentation Y or N 1. Sample labels present on bottles: 2. Container labeling complete: 3 Cooler Temperature Y or N 3. Sample container label / COC agree: 1. Temp criteria achieved: 2. Cooler temp verification: IR Gun 3. Cooler media: Ice (bag) Quality Control Preservation Y N N/A Sample Integrity - Condition Y or N 1. Sample recvd within HT: 2. All containers accounted for: 3. Condition of sample: Broken / Leaking 1. Trip Blank present / cooler: 2. Trip Blank listed on COC: Sample Integrity - Instructions 1. Analysis requested is clear: Y N N/A 3. Samples preserved properly: 2. Bottles received for unspecified tests 4. VOCs headspace free: 3. Sufficient volume recvd for analysis: 4. Compositing instructions clear: Comments 5. Filtering instructions clear: -6 "RW-H" PHENOL VOLUME REC'D BROKEN Accutest Laboratories V: US Highway 130 F: Dayton, New Jersey www/accutest.com JA85694A: Chain of Custody Page 4 of 5 23 of 24 JA85694A

82 Sample Receipt Summary - Problem Resolution Accutest Job Number: JA85694 CSR: Michelle Response Date 9/9/ Response: Please preserve a N/P volume w/h2so4 and analyze for PN per Chris Proce 3 Accutest Laboratories V: US Highway 130 F: Dayton, New Jersey www/accutest.com JA85694A: Chain of Custody Page 5 of 5 24 of 24 JA85694A

83 e-hardcopy 2.0 Automated Report New Jersey 09/23/11 09/23/11 Technical Report for Roux Associates ExxonMobil Off-Site 31097, Brooklyn, NY PO# WBS#08 Accutest Job Number: JA85709 Sampling Date: 09/08/11 Report to: Roux Associates ATTN: Ritu Patel Total number of pages in report: 13 Test results contained within this data package meet the requirements of the National Environmental Laboratory Accreditation Conference and/or state specific certification programs as applicable. David N. Speis VP, Laboratory Director Client Service contact: Matt Cordova Certifications: NJ(12129), NY(10983), CA, CT, DE, FL, IL, IN, KS, KY, LA, MA, MD, MI, MT, NC, PA, RI, SC, TN, VA, WV This report shall not be reproduced, except in its entirety, without the written approval of Accutest Laboratories. Test results relate only to samples analyzed. New Jersey 2235 Route 130 Dayton, NJ tel: fax: Accutest Laboratories is the sole authority for authorizing edits or modifications to this document. Unauthorized modification of this report is strictly prohibited. JA of 13

84 Table of Contents Section 1: Sample Summary... 3 Section 2: Sample Results : JA : OSS-CAT-OX INFLUENT : JA : OSS-CAT-OX EFFLUENT... 7 Section 3: Misc. Forms : Chain of Custody : Summa Canister and Flow Controller Log Sections: of 13 JA85709

85 1 Accutest 14:06 23-Sep-2011 Roux Associates ExxonMobil Off-Site 31097, Brooklyn, NY Project No: PO# WBS#08 Sample Summary Job No: JA85709 Sample Collected Matrix Client Number Date Time By Received Code Type Sample ID JA /08/11 13:00 BC 09/09/11 AIR Air OSS-CAT-OX INFLUENT JA /08/11 13:10 BC 09/09/11 AIR Air OSS-CAT-OX EFFLUENT 3 of 13 JA85709

86 2 Section 2 New Jersey Accutest LabLink@ :06 23-Sep-2011 Sample Results Report of Analysis 4 of 13 JA85709

87 Accutest 14:06 23-Sep-2011 Report of Analysis Page 1 of Client Sample ID: OSS-CAT-OX INFLUENT Lab Sample ID: JA Date Sampled: 09/08/11 Matrix: AIR - Air Summa ID: A816,A610 Date Received: 09/09/11 Method: TO-15 Percent Solids: n/a Project: ExxonMobil Off-Site 31097, Brooklyn, NY File ID DF Analyzed By Prep Date Prep Batch Analytical Batch Run #1 2W32479.D /13/11 YMH n/a n/a V2W1369 Run #2 Run #1 Run #2 Initial Volume 200 ml CAS No. MW Compound Result RL MDL Units Q Result RL Units Acetone ND ppbv ND 43 ug/m ,3-Butadiene ND ppbv ND 40 ug/m Benzene ppbv ug/m Bromodichloromethane ND ppbv ND 120 ug/m Bromoform ND ppbv ND 190 ug/m Bromomethane ND ppbv ND 70 ug/m Bromoethene ND ppbv ND 79 ug/m Benzyl Chloride ND ppbv ND 93 ug/m Carbon disulfide ND ppbv ND 56 ug/m Chlorobenzene ND ppbv ND 83 ug/m Chloroethane ppbv ug/m Chloroform ND ppbv ND 88 ug/m Chloromethane ND ppbv ND 37 ug/m Chloropropene ND ppbv ND 56 ug/m Chlorotoluene ND ppbv ND 93 ug/m Carbon tetrachloride ND ppbv ND 110 ug/m Cyclohexane ppbv ug/m ,1-Dichloroethane ppbv ug/m ,1-Dichloroethylene ppbv J ug/m ,2-Dibromoethane ND ppbv ND 140 ug/m ,2-Dichloroethane ND ppbv ND 73 ug/m ,2-Dichloropropane ND ppbv ND 83 ug/m ,4-Dioxane ND ppbv ND 65 ug/m Dichlorodifluoromethane ND ppbv ND 89 ug/m Dibromochloromethane ND ppbv ND 150 ug/m trans-1,2-dichloroethylene ppbv ug/m cis-1,2-dichloroethylene ppbv ug/m cis-1,3-dichloropropene ND ppbv ND 82 ug/m m-dichlorobenzene ND ppbv ND 110 ug/m o-dichlorobenzene ND ppbv ND 110 ug/m p-dichlorobenzene ND ppbv ND 110 ug/m trans-1,3-dichloropropene ND ppbv ND 82 ug/m3 ND = Not detected MDL - Method Detection Limit J = Indicates an estimated value RL = Reporting Limit B = Indicates analyte found in associated method blank E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound JA of 13

88 Accutest 14:06 23-Sep-2011 Report of Analysis Page 2 of Client Sample ID: OSS-CAT-OX INFLUENT Lab Sample ID: JA Date Sampled: 09/08/11 Matrix: AIR - Air Summa ID: A816,A610 Date Received: 09/09/11 Method: TO-15 Percent Solids: n/a Project: ExxonMobil Off-Site 31097, Brooklyn, NY CAS No. MW Compound Result RL MDL Units Q Result RL Units Ethanol ND ppbv ND 85 ug/m Ethylbenzene ppbv ug/m Ethyl Acetate ND ppbv ND 65 ug/m Ethyltoluene ppbv J ug/m Freon 113 ND ppbv ND 140 ug/m Freon 114 ND ppbv ND 130 ug/m Heptane ppbv J ug/m Hexachlorobutadiene ND ppbv ND 190 ug/m Hexane ppbv ug/m Hexanone ND ppbv ND 74 ug/m Isopropyl Alcohol ND ppbv ND 44 ug/m Methylene chloride ND ppbv ND 63 ug/m Methyl ethyl ketone ND ppbv ND 53 ug/m Methyl Isobutyl Ketone ND ppbv ND 74 ug/m Methyl Tert Butyl Ether ppbv ug/m Methylmethacrylate ND ppbv ND 74 ug/m Propylene ND ppbv ND 77 ug/m Styrene ND ppbv ND 77 ug/m ,1,1-Trichloroethane ND ppbv ND 98 ug/m ,1,2,2-Tetrachloroethane ND ppbv ND 120 ug/m ,1,2-Trichloroethane ND ppbv ND 98 ug/m ,2,4-Trichlorobenzene ND ppbv ND 130 ug/m ,2,4-Trimethylbenzene ppbv J ug/m ,3,5-Trimethylbenzene ppbv J ug/m ,2,4-Trimethylpentane ND ppbv ND 84 ug/m Tertiary Butyl Alcohol ND ppbv ND 55 ug/m Tetrachloroethylene ppbv ug/m Tetrahydrofuran ND ppbv ND 53 ug/m Toluene ppbv ug/m Trichloroethylene ppbv ug/m Trichlorofluoromethane ppbv J ug/m Vinyl chloride ppbv ug/m Vinyl Acetate ND ppbv ND 63 ug/m m,p-xylene ppbv ug/m o-xylene ppbv ug/m Xylenes (total) ppbv ug/m3 CAS No. Surrogate Recoveries Run# 1 Run# 2 Limits Bromofluorobenzene 91% % ND = Not detected MDL - Method Detection Limit J = Indicates an estimated value RL = Reporting Limit B = Indicates analyte found in associated method blank E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound JA of 13

89 Accutest 14:06 23-Sep-2011 Report of Analysis Page 1 of Client Sample ID: OSS-CAT-OX EFFLUENT Lab Sample ID: JA Date Sampled: 09/08/11 Matrix: AIR - Air Summa ID: A896,A568 Date Received: 09/09/11 Method: TO-15 Percent Solids: n/a Project: ExxonMobil Off-Site 31097, Brooklyn, NY File ID DF Analyzed By Prep Date Prep Batch Analytical Batch Run #1 2W32501.D /14/11 YMH n/a n/a V2W1369 Run #2 2W32480.D /13/11 YMH n/a n/a V2W1369 Run #1 Run #2 Initial Volume 50.0 ml 200 ml CAS No. MW Compound Result RL MDL Units Q Result RL Units Acetone ND ppbv ND 4.3 ug/m ,3-Butadiene ND ppbv ND 4.0 ug/m Benzene ppbv ug/m Bromodichloromethane ND ppbv ND 12 ug/m Bromoform ND ppbv ND 19 ug/m Bromomethane ND ppbv ND 7.0 ug/m Bromoethene ND ppbv ND 7.9 ug/m Benzyl Chloride ND ppbv ND 9.3 ug/m Carbon disulfide ND ppbv ND 5.6 ug/m Chlorobenzene ppbv ug/m Chloroethane ppbv ug/m Chloroform ppbv ug/m Chloromethane ppbv ug/m Chloropropene ND ppbv ND 5.6 ug/m Chlorotoluene ND ppbv ND 9.3 ug/m Carbon tetrachloride ND ppbv ND 11 ug/m Cyclohexane ppbv ug/m ,1-Dichloroethane ppbv ug/m ,1-Dichloroethylene ppbv ug/m ,2-Dibromoethane ND ppbv ND 14 ug/m ,2-Dichloroethane ppbv ug/m ,2-Dichloropropane ND ppbv ND 8.3 ug/m ,4-Dioxane ND ppbv ND 6.5 ug/m Dichlorodifluoromethane ND ppbv ND 8.9 ug/m Dibromochloromethane ND ppbv ND 15 ug/m trans-1,2-dichloroethylene ppbv ug/m cis-1,2-dichloroethylene 382 a ppbv 1510 a 36 ug/m cis-1,3-dichloropropene ND ppbv ND 8.2 ug/m m-dichlorobenzene ND ppbv ND 11 ug/m o-dichlorobenzene ND ppbv ND 11 ug/m p-dichlorobenzene ppbv J ug/m trans-1,3-dichloropropene ND ppbv ND 8.2 ug/m3 ND = Not detected MDL - Method Detection Limit J = Indicates an estimated value RL = Reporting Limit B = Indicates analyte found in associated method blank E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound JA of 13

90 Accutest 14:06 23-Sep-2011 Report of Analysis Page 2 of Client Sample ID: OSS-CAT-OX EFFLUENT Lab Sample ID: JA Date Sampled: 09/08/11 Matrix: AIR - Air Summa ID: A896,A568 Date Received: 09/09/11 Method: TO-15 Percent Solids: n/a Project: ExxonMobil Off-Site 31097, Brooklyn, NY CAS No. MW Compound Result RL MDL Units Q Result RL Units Ethanol ppbv ug/m Ethylbenzene ppbv ug/m Ethyl Acetate ND ppbv ND 6.5 ug/m Ethyltoluene ppbv ug/m Freon 113 ND ppbv ND 14 ug/m Freon 114 ND ppbv ND 13 ug/m Heptane ppbv ug/m Hexachlorobutadiene ND ppbv ND 19 ug/m Hexane ppbv ug/m Hexanone ND ppbv ND 7.4 ug/m Isopropyl Alcohol ND ppbv ND 4.4 ug/m Methylene chloride ND ppbv ND 6.3 ug/m Methyl ethyl ketone ppbv ug/m Methyl Isobutyl Ketone ND ppbv ND 7.4 ug/m Methyl Tert Butyl Ether ppbv ug/m Methylmethacrylate ND ppbv ND 7.4 ug/m Propylene ND ppbv ND 7.7 ug/m Styrene ND ppbv ND 7.7 ug/m ,1,1-Trichloroethane ND ppbv ND 9.8 ug/m ,1,2,2-Tetrachloroethane ND ppbv ND 12 ug/m ,1,2-Trichloroethane ND ppbv ND 9.8 ug/m ,2,4-Trichlorobenzene ND ppbv ND 13 ug/m ,2,4-Trimethylbenzene ppbv ug/m ,3,5-Trimethylbenzene ppbv ug/m ,2,4-Trimethylpentane ND ppbv ND 8.4 ug/m Tertiary Butyl Alcohol ND ppbv ND 5.5 ug/m Tetrachloroethylene 571 a ppbv 3870 a 12 ug/m Tetrahydrofuran ND ppbv ND 5.3 ug/m Toluene ppbv ug/m Trichloroethylene ppbv ug/m Trichlorofluoromethane ND ppbv ND 10 ug/m Vinyl chloride ppbv ug/m Vinyl Acetate ND ppbv ND 6.3 ug/m m,p-xylene ppbv ug/m o-xylene ppbv ug/m Xylenes (total) ppbv ug/m3 CAS No. Surrogate Recoveries Run# 1 Run# 2 Limits Bromofluorobenzene 95% 89% % ND = Not detected MDL - Method Detection Limit J = Indicates an estimated value RL = Reporting Limit B = Indicates analyte found in associated method blank E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound JA of 13

91 Accutest 14:06 23-Sep-2011 Report of Analysis Page 3 of Client Sample ID: OSS-CAT-OX EFFLUENT Lab Sample ID: JA Date Sampled: 09/08/11 Matrix: AIR - Air Summa ID: A896,A568 Date Received: 09/09/11 Method: TO-15 Percent Solids: n/a Project: ExxonMobil Off-Site 31097, Brooklyn, NY CAS No. MW Compound Result RL MDL Units Q Result RL Units (a) Result is from Run# 2 ND = Not detected MDL - Method Detection Limit J = Indicates an estimated value RL = Reporting Limit B = Indicates analyte found in associated method blank E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound 9 of 13 JA85709

92 3 Section 3 New Jersey Accutest LabLink@ :06 23-Sep-2011 Misc. Forms Custody Documents and Other Forms Includes the following where applicable: Chain of Custody Summa Canister and Flow Controller Log 10 of 13 JA85709

93 3 3.1 JA85709: Chain of Custody Page 1 of 2 11 of 13 JA85709

94 Accutest Laboratories Sample Receipt Summary Accutest Job Number: JA85709 Client: Date / Time Received: 9/9/2011 No. Coolers: 0 Airbill #'s: Project: Delivery Method: 3.1 Cooler Security 1. Custody Seals Present: 2. Custody Seals Intact: Y or N 3. COC Present: 4. Smpl Dates/Time OK Y or N Sample Integrity - Documentation Y or N 1. Sample labels present on bottles: 2. Container labeling complete: 3 Cooler Temperature Y or N 3. Sample container label / COC agree: 1. Temp criteria achieved: 2. Cooler temp verification: 3. Cooler media: Quality Control Preservatio Y or N N/A Sample Integrity - Condition Y or N 1. Sample recvd within HT: 2. All containers accounted for: 3. Condition of sample: Intact 1. Trip Blank present / cooler: 2. Trip Blank listed on COC: Sample Integrity - Instructions 1. Analysis requested is clear: Y or N N/A 3. Samples preserved properly: 2. Bottles received for unspecified tests 4. VOCs headspace free: 3. Sufficient volume recvd for analysis: 4. Compositing instructions clear: 5. Filtering instructions clear: Comments Accutest Laboratories V: US Highway 130 F: Dayton, New Jersey www/accutest.com JA85709: Chain of Custody Page 2 of 2 12 of 13 JA85709

95 Summa Canister and Flow Controller Log Page 1 of 1 Job Number: JA85709 Account: ROUXNYI Roux Associates Project: ExxonMobil Off-Site 31097, Brooklyn, NY Received: 09/09/ SUMMA CANISTERS Shipping Receiving Summa Vac Date SCC SCC Sample Date Vac Pres Final Dil ID L " Hg Out By Batch FileID Number In By " Hg psig psig Fact A /02/11 FZ CP4971 JA /09/11 FZ 0 1 A /02/11 FZ CP4971 JA /09/11 FZ 1 1 Accutest Bottle Order(s): KM-12/29/ Prep Date Room Temp(F) Bar Pres "Hg 09/02/ JA of 13

96 ATTACHMENT 2 Photographs of Discharge Points and Receiving Water ROUX ASSOCIATES, INC. MC Y /AT-CV

97 Photos = 4.25 x 5.67 Photograph 1: Former Brooklyn Terminal RCS outfall and receiving water in September 2011 (SPDES Permit No. NY , Outfall Number 001) 1 Photograph 2: Former Brooklyn Terminal RCS outfall and receiving water in September 2011 (SPDES Permit No. NY , Outfall Number 001) ROUX ASSOCIATES, INC. 1 MC Y /AT2

98 Photograph 3: Off-Site System outfall and receiving water in September 2011 (SPDES Permit No. NY , Outfall Number 002) 2 Photograph 4: Off-Site System outfall and receiving water in September 2011 (SPDES Permit No. NY , Outfall Number 002) ROUX ASSOCIATES, INC. 2 MC Y /AT2

99 ATTACHMENT 3 Discharge Monitoring Report Forms ROUX ASSOCIATES, INC. MC Y /AT-CV

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