INSTALLATION OF PORTABLE O3 MONITORING STATION NATIONAL PARK SERVICE AMBIENT AIR QUALITY AND METEOROLOGY MONITORING NETWORK

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1 INSTALLATION OF PORTABLE O3 MONITORING STATION TIOL PARK SERVICE AMBIENT AIR QUALITY AND METEOROLOGY MONITORING NETWORK ASSATEAGUE ISLAND TIOL SEASHORE APRIL 24, 2006 prepared for John Ray TIOL PARK SERVICE Research and Monitoring Branch Air Resources Division P.O. Box Denver, Colorado NPS Contract No. C prepared by AIR RESOURCE SPECIALISTS, INC Sharp Point Drive Suite E Fort Collins, Colorado 80525

2 1.0 CALIBRATION SUMMARY In accordance with NPS Gaseous Pollutant Monitoring Program (GPMP) guidelines, ARS performed a maintenance and calibration visit at the following air quality station: Park or Monument: Assateague Island National Seashore Air quality site: Maintenance Yard Subject: Re-Installation Visit Service date: April 24, 2006 Service technician: Michael Slate A summary of pre- and post-maintenance calibration results is presented in Table 1-1. Pre Maintenance Calibration Summary: All sensors passed the pre-maintenance checks except rainfall, which was found to be 10 percent low. Maintenance Action Summary: Ozone: The 2B Technologies O3 monitor (SN 173) was calibrated at ARS prior to this installation trip. No on-site calibration was required. The 2B instrument installed has the Nafion desiccant and the memory card. During the installation, the analyzer responded as expected. Meteorological: The wind speed/direction sensor was rebuilt, aligned, and passed all checks. The relative humidity/ambient temperature sensor was replaced with a recent calibrated unit and checked against a reference sensor onsite with good results. The solar radiation sensor was compared to a reference sensor with good results. The rainfall sensor failed the first tipping test. The tipping points were adjusted, and the test was performed again with excellent results. Post Maintenance Calibration Summary: All systems were within specifications.

3 STATION OPERATOR 2.0 ADDITIOL NOTES AND OBSERVATIONS Eric Sherry is the station operator and was refreshed to perform the weekly checks on the air quality station. Eric also assisted in the installation of the system. MONITORING EQUIPMENT This station operated at this location last season. The tripod and solar system were not moved. There is substantial evidence that birds like to perch on the equipment, especially the solar radiation sensor. The operator may try using an owl or snake decoy to keep the birds away. The Campbell Scientific Data Logger, Model 23X has serial number The ORBCOMM Satellite Modem, Model Q2000 manufactured by Quake, has serial number Campbell Scientific Relay Driver has serial number SITE LOCATION The following coordinates of the site location were determined by a hand held GPS unit: N 38 o W 75 o Elevation: 7 feet 3.0 CALIBRATION FORMS All calibration forms are attached. These forms present the details of pre- and postmaintenance calibrations.

4 Calibration Summary Network: NPS Location: Assateague Island Site: ASIS-MA Date: 04/24/06 Last Site Visit: 06/16/05 Field Specialist: Slate, Mike Parameter Criteria Accuracy Goal Precipitation max error <= ± 5.0 Pre-Maintenance Mfg, & Value Texas Electronics 525M FAIL Calibration Results Post Maintenance Mfg, & Value Texas Electronics 525M PASS Relative Humidity PRE Sensor ID# Z max error <= ± 5.0 Vaisala HMP45C Z PASS Vaisala HMP45C Z PASS Solar Radiation average error <= ± 5 LiCor Pyranometer PY PASS LiCor Pyranometer PY PASS Temperature max error Climatronics <= ± 0.2º C; RM Young <= ± 0.5º C; Rotronics <= ± 1.0º C Vaisala HMP45C Z º PASS Vaisala HMP45C Z º PASS Wind Direction Alignment max error <= ± 5º 2º PASS 2º PASS Linearity max error <= ± 3º Climatronics º PASS Climatronics º PASS Starting Threshold max error Climatronics <= 6 g-cm; RM Young AQ <= 9 g-cm; RM Young MA <= 30 g-cm, RM Young RE <= 7 g-cm Wind Speed max Wind Speed <5 max error <= ± 0.2 m/s N/A N/A N/A N/A max Wind Speed >= 5 max error <= ± 5 RM Young AQ 4.3 PASS RM Young AQ 4.3 PASS Starting Threshold max error Climatronics <= 0.2 g-cm; RM Young AQ <= 0.3 g-cm; RM Young MA <= 2.9 g-cm, RM Young RE <= 0.3 g-cm

5 Calibration Standards Field Specialist: Operator: Network: Location: Site: Date: Last Site Visit: Slate, Mike Eric Sherry NPS Assateague Island ASIS-MA 4/24/2006 6/16/2005 Parameter Device Manufacturer Model S/N Calibration Date Voltage Fluke 87 III /9/2006 Voltage Source Calib. Inc. DVC-350A Ozone Transfer Standard TECO 49PS Gas Dilution Mass flow ERT Gas Dil Barometric Pressure Barometer/Altimeter AIR AIR-HB-1A 3F2502 5/21/2004 High Flow Dry cal BIOS DC2 Low Flow Dry cal BIOS DC2 Precipitation PPT Calibrator Novalynx /8/2002 Volume (ml): 936 Relative Humidity RH Sensor Rotronics MP101A /17/2005 Solar Radiation Thermopile LiCor Pyranometer PY /11/2003 Multiplier Temperature Digital Thermometer Eutechinics /7/2006 Torque Gauge RM Young Wind Direction Linearity Jig RM Young Compass Brunton 5006LM Wind Speed Torque Disk RM Young Anemometer Drive RM Young CA /2/2002 Volumetric Flow Comments:

6 WETNESS, PRECIPITATION AND BAROMETRIC PRESSURE CALIBRATION FORM Network: NPS Location: Assateague Island Site: ASIS-MA Date: 04/24/06 Date of Last Site Visit: 06/16/05 Field Specialist: Slate, Mike Barometric Pressure Reference S/N: 3F2502 Calibration Date: 05/21/04 Precipitation Reference S/N: Calibration Volume: 936 ml Calibration Date: 10/08/02 WETNESS Pre-Maintenance Post Maintenance DRY WET PRE-MAINTENCE SENSOR RESPONSE LED (ON/OFF) off on DRY WET POST MAINTENCE SENSOR RESPONSE LED (ON/OFF) off on Pre-Maint Wetness Comments: Post Maint Wetness Comments: PRECIPITATION Reference Pre-Maintenance Post Maintenance Calibration Inlet Volume Diameter mm mm/tip Texas Electronics Texas Electronics M 525M cc Inlet Novalynx 9.66" 9.66" Diameter RM Young PRE-MAINTENCE POST MAINTENCE Cal Volume Designated Cal Volume Designated mm mm (ml) value in mm (ml) value in mm FAIL PASS 936 CC Novalynx RM Young Pre-Maint Precipitation Comments: Adjusted tipping points to 4.73 ml. Post Maint Precipitation Comments: BAROMETRIC PRESSURE PRE-MAINTENCE POST MAINTENCE SENSOR RESPONSE PRE-MAINTENCE POST MAINTENCE Reference (Volts) (mm Hg) Reference (Volts) (mm Hg) Maximum: Maximum: Pre-Maint Barometric Pressure Comments: Post Maint Barometric Pressure Comments:

7 SOLAR RADIATION CALIBRATION FORM Network: NPS Location: Assateague Island Site: ASIS-MA Date: 04/24/06 Date of Last Site Visit: 06/16/05 Field Specialist: Slate, Mike Solar Radiation Reference S/N: PY12080 Reference Factor: 95.64(W/m2) Calibration Date: 04/11/03 High Flow Standard Reference S/N: N/A Calibration Date: SOLAR RADIATION PRE-MAINTENCE LiCor Pyranometer POST MAINTENCE LiCor Pyranometer PY PY Translator TRANSLATOR CARD PRE-MAINTENCE POST MAINTENCE SETTING (W/m2) (W/m2) Zero Span SENSOR RESPONSE PRE-MAINTENCE POST MAINTENCE HOUR (W/m2) T.STD HOUR (W/m2) T.STD 09: : : : :00 13: :00 14:00 13:00 15:00 14:00 16:00 Average : -4 Average : 0 : PASS : PASS Pre-Maint Solar Radiation Comments: Post Maint Solar Radiation Comments:

8 TEMPERATURE, DELTA TEMPERATURE AND RELATIVE HUMIDITY CALIBRATION FORM Network: NPS Location: Assateague Island Site: ASIS-MA Date: 04/24/06 Date of Last Site Visit: 06/16/05 Field Specialist: Slate, Mike Reference Thermometer S/N: Calibration Date: 03/07/06 Relative Humidity Reference S/N: Calibration Date: 11/17/05 TEMPERATURE / DELTA TEMPERATURE Temperature Delta Temp. Translator Pre-Maintenance Vaisala HMP45C Z Post Maintenance Vaisala HMP45C Z PRE-MAINTENCE SENSOR RESPONSE PRE- TRANSLATOR CARD RESPONSE BATH TEMP TEMPERATURE Δ TEMPERATURE SETTING TEMPERATURE Δ TEMPERATURE PASS Zero PASS Span Maximum : 1.0 PASS Maximum : POST MAINTENCE SENSOR RESPONSE POST TRANSLATOR CARD RESPONSE BATH TEMP TEMPERATURE Δ TEMPERATURE SETTING TEMPERATURE Δ TEMPERATURE PASS Zero PASS Span PASS Maximum : 1.0 PASS Maximum : Pre-Maint Temperature Comments: AT/RH replaced at 9:30 EDT on 4/24/06. Post Maint Temperature Comments: RELATIVE HUMIDITY Pre-Maintenance Vaisala HMP45C Z Post Maintenance Vaisala HMP45C Z PRE-MAINTENCE SENSOR RESPONSE POST MAINTENCE SENSOR RESPONSE HOUR T.STD HOUR T.STD 9: PASS 11: PASS

9 WIND DIRECTION CALIBRATION FORM Network: NPS Location: Assateague Island Site: ASIS-MA Date: 04/24/06 Date of Last Site Visit: 06/16/05 Field Specialist: Slate, Mike To Landmark #1: 326 Degrees True From Landmark #1: 146 LM Description: To Landmark #2: 61 Degrees True From Landmark #2: 241 LM Description: Declination: Degrees Wind Direction Reference S/N: Calibration Date: Tower Tall Tree WIND DIRECTION WIND DIRECTION ALIGNMENT PRE-MAINTENCE POST MAINTENCE PRE-MAINTENCE POST MAINTENCE Land Mark Reference Degrees Degrees Climatronics Climatronics (degrees) (degrees) To PASS PASS From PASS PASS Translator To PASS 61 0 PASS From PASS PASS WIND DIRECTION TRANSLATOR CARD Average : 2 PASS Average : 1 PASS Card Setting Zero PRE POST Maximum : 2 PASS Maximum : 2 PASS WIND DIRECTION LINEARITY Span Check PRE-MAINTENCE POST MAINTENCE Point 360 Oscillator Frequency (Hz) = Data Logger Should Read (degrees) Degrees (degrees) Degrees PASS 0 0 PASS PASS 42-3 PASS WIND DIRECTION STARTING THRESHOLD PASS 86-1 PASS PRE POST PASS PASS Torque gm-cm Torque gm-cm PASS PASS PASS PASS Wind direction starting threshold accuracy goal: Climatronics <= 6 g-cm PASS PASS PASS PASS Average : 1 PASS Average : 1 PASS Maximum : 2 PASS Maximum : 3 PASS Pre-Maint Wind Direction Comments: Installed rebuilt WD sensor. Post Maint Wind Direction Comments:

10 WIND SPEED CALIBRATION FORM Network: NPS Location: Assateague Island Site: ASIS-MA Date: 04/24/06 Date of Last Site Visit: 06/16/05 Field Specialist: Slate, Mike Wind Speed Reference S/N: CA Calibration Date: 08/02/02 WIND SPEED WIND SPEED TRANSLATOR CARD PRE-MAINTENCE POST MAINTENCE Card PRE POST Setting RM Young AQ RM Young AQ Zero Span Translator Oscillator Frequency (Hz) = Data Logger Should Read WIND SPEED STARTING THRESHOLD PRE POST Torque gm-cm Torque gm-cm Wind speed starting threshold accuracy goal: RM Young AQ <= 0.3 g-cm Motor Speed (rpm) Climatronics RM Young WIND SPEED PRE-MAINTENCE WIND SPEED POST MAINTENCE PASS PASS PASS PASS PASS PASS PASS PASS PASS PASS 4000 N/A PASS PASS 7000 N/A PASS PASS Maximum ABS (use if Wind Speed <5): Maximum ABS (use if Wind Speed >=5): 4.3 PASS 4.3 PASS Pre-Maint Wind Speed Comments: Post Maint Wind Speed Comments:

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