AMBIENT AIR MONITORING MONTHLY DATA REPORT

Transcription

1 MAXXAM ANALYTICS # Ave. NE, Calgary, AB T2E 6P7 maxxam.ca Toll Free Fax AMBIENT AIR MONITORING MONTHLY DATA REPORT PEACE RIVER AREA MONITORING PROGRAM COMMITTEE THREE CREEKS 986B STATION JOB #: C February 2017 Prepared for: PEACE RIVER AREA MONITORING PROGRAM COMMITTEE MIKE BISAGA C/O PRAMP COMMITTEE, ST NW CALGARY, ALBERTA T2N 2J1 Attention: KARLA REESOR DATE: March 29, 2017 Prepared by: Wunmi Adekanmbi, M.Sc., EPt. Project Manager, Customer Service, Air Services Reviewed by: Cheri Sinclair, B.Sc. Supervisor, Customer Service, Air Services

2 PEACE RIVER AREA MONITORING PROGRAM COMMITTEE Three Creeks 986b Station - February 2017 SUMMARY In February 2017, Maxxam Analytics was contracted to manage the ambient air quality monitoring and maintenance activities at the Three Creeks 986b Station, near Peace River Oil Sands Area 2, Alberta. The monitoring station provides continuous meteorological measurements and air quality data for compliance parameters, as requested by the PRAMP Committee. All data collected this month was compliant with the requirements outlined in the Air Monitoring Directive (Alberta Environment and Parks, 2016). The operational time for all continuous ambient air analyzers, meteorological systems and data acquisition systems were above the 90% requirement. A station audit was conducted by Maxxam on February 5. Audit report is included in the appendix section. TRS: The as-found high point value obtained from the calibration on February 4 was 8.1% off the reference value. This was within the tolerance limits of +/-10%. However, as a precaution, an as-found response check was completed on February 5, using an alternate calibrator. The result was 1.2% off reference value. Two hours of downtime were recorded due to this additional quality check. THC/CH 4 /NMHC: One hour of downtime was recorded on February 22, at hour 13:00, as the analyzer was recovering from a brief power outage. Wind System: The wind system was upgraded on February 15. The RM Young 05103VK (s/n: 43711) was removed following a successful shut-down calibration. Subsequently, an RM Young 05305VK (s/n: ) was installed and calibrated. The summary of results is presented on the following pages. Any deviations or modifications made to the sampling or analytical methods are outlined in Section 1.0, Discussion. On this basis, Maxxam Analytics is issuing this completed report to Peace River Area Monitoring Program Committee, Three Creeks 986b Station. Should you have any questions concerning the results or if we can be of further assistance, please contact us at or toll-free at JOB #: C Page 1 of 106

3 PEACE RIVER AREA MONITORING PROGRAM COMMITTEE Three Creeks 986b Station - February 2017 Monthly Continuous Data Summary Peace River Area Monitoring Program Committee Three Creeks 986b Station PARAMETER SO₂ (ppb) TRS (ppb) THC (ppm) CH₄ (ppm) NMHC (ppm) RELATIVE HUMIDITY (%) BAROMETRIC PRESSURE (millibar) AMBIENT TEMPERATURE ( C) STATION TEMPERATURE ( C) VECTOR WS (kph) VECTOR WD (sec) VAR-VARIOUS OBJECTIVES 1-hr 24-hr 1-hr 24-hr ENE EXCEEDANCES SSW WSW (WSW) DAY 12 OPERATIONAL TIME (%) SSE SSE SW 0.00 ALL VAR VAR VAR MONTHLY AVERAGE WNW VAR VAR VAR , 17 1-HOUR READING DAY HOUR MAXIMUM VALUES WIND SPEED (kph) 1, WIND DIRECTION (sector) SSE NW READING HOUR JOB #: C Page 2 of 106

4 PEACE RIVER AREA MONITORING PROGRAM COMMITTEE Three Creeks 986b Station - February 2017 SOUR GAS PROCESSING INDUSTRY MONTHLY REPORT SUMMARY Three Creeks 986b Station Plant Name / Location Peace River Area Monitoring Program Committee Company Report Date Licence Number YEAR MONTH N/A 2017 February CONTINUOUS AMBIENT MONITORING ONE - HOUR AVERAGE PARAMETER STN No. % TIME OPERATIONAL MAXIMUM VALUES NO. READINGS > REGULATION SO₂ ppm ppm 0 TRS ppm ppm - THC ppm ppm - CH₄ ppm ppm - NMHC ppm ppm - RH % - 96 % - BP mb mb - Ambient TPX C C - Station TPX C C - Wind Speed kph kph Wind Direction HOUR AVERAGE NO. READINGS > MAXIMUM VALUES REGULATION FOR ALBERTA ENVIRONMENT USE ONLY - - SIGNATURE OF COMPANY REPRESENTATIVE JOB #: C Page 3 of 106

5 PEACE RIVER AREA MONITORING PROGRAM COMMITTEE Three Creeks 986b Station - February 2017 Exceedance Summary Report SO 2 1-Hour Exceedances Measured concentrations of sulphur dioxide were below the 1-hour AAAQO of 172 ppb. SO 2 24-Hour Exceedances Measured concentrations of sulphur dioxide were below the 24-hour AAAQO of 48.0 ppb. In accordance with EPEA and the Substance Release Regulation. In accordance with A Guide to Release Reporting and the Alberta Ambient Air Quality Objectives and Guidelines Summary. JOB #: C Page 4 of 106

6 PEACE RIVER AREA MONITORING PROGRAM COMMITTEE Three Creeks 986b Station - February 2017 TABLE OF CONTENTS Title Page SUMMARY 1 MONTHLY CONTINUOUS DATA SUMMARY REPORT 2 SOUR GAS SUMMARY REPORT 3 EXCEEDANCE SUMMARY REPORT 4 TABLE OF CONTENTS Discussion Project Personnel Plant Monthly Required AMD Summary Calculations and Results Methods and Procedures 9 Appendix I Continuous Monitoring Data Results 12 Sulphur Dioxide 13 Total Reduced Sulphur 21 Total Hydrocarbon 29 Methane 37 Non-Methane Hydrocarbon 45 Wind Speed 53 Wind Direction 60 Relative Humidity 63 Barometric Pressure 66 Ambient Temperature 69 Station Temperature 72 Appendix II Equipment Calibration Results 75 Sulphur Dioxide 76 Total Reduced Sulphur 80 Total Hydrocarbon 85 Wind System 89 Calibrators 93 Calibration Gases 96 Appendix III Internal Audit Results 100 Appendix IV Report Certification Form 103 Appendix V Data Validation Certification Form 105 JOB #: C Page 5 of 106

7 PEACE RIVER AREA MONITORING PROGRAM COMMITTEE Three Creeks 986b Station - February Discussion This monthly report consists of continuous monitoring results for the following parameters: Sulphur Dioxide (SO₂), Total Reduced Sulphur (TRS), Total Hydrocarbon (THC), Methane (CH₄), Non-Methane Hydrocarbon (NMHC), Relative Humidity (RH), Barometric Pressure (BP), Ambient Temperature (AmbTPX), Station Temperature (StnTPX), Wind Speed (WS) and Wind Direction (WD). Sample filters for all continuous air monitors are changed before the calibration begins. The sample manifold is cleaned during the site visit each month. Control checks, consisting of a zero and span, are conducted daily on all continuous air monitors. In place of the air sample, zero air (from scrubbed air or gas cylinders) is used for zero checks, and a known concentration of the pollutant being analyzed is used for span checks. These checks are controlled by automatic timers and valves. The total zero span cycle is completed within an hour, the commencement of the zero span cycle is at the beginning of the hour. Multipoint calibrations are done a minimum of once a month for each continuous air monitor. An additional calibration is required under the following conditions: 1) within three days after the initial start-up and stabilization of a newly installed instrument, 2) prior to shut-down or moving of an instrument which has been working to specification, and 3) when major repair has been done on the instrument. Time during the first multi-point calibration is not considered downtime (Data is flagged as C). If more than one calibration is performed during the month, the time during the additional calibration is considered as downtime (Data is flagged as C1). Only one zero/span check is run per day. Time during the zero/span check is not considered as downtime (Data is flagged as S). If an extra zero/span check is performed, the time during the additional check is considered as downtime (Data is flagged as S1). The AMD requires each instrument and accompanying data recording system to be operational 90% of the time, at a minimum, for each monthly monitoring period. All sampling, analysis, and QA/QC for this project was performed by Maxxam Analytics and complies with the Alberta Air Monitoring Directive. Data contained in this monthly report has undergone the verification and validation based on the requirements of the AMD Chapter 6: Ambient Data Quality (August 3, 2016). The descriptions of the data verification and validation process can be found in Section 5 of this report. Instantaneous data, where applicable, is provided for reference purposes and has not undergone zero correction. Hourly/minute data have been reviewed based on daily zero/span results and multi-point calibration results. Data may be considered invalid if a zero-corrected span check in excess of +/- 10% of the span concentration (established by the previous multi-point calibration) is encountered and/or significant differences in the calibration factor occurs (greater than 10%). JOB #: C Page 6 of 106

8 PEACE RIVER AREA MONITORING PROGRAM COMMITTEE Three Creeks 986b Station - February 2017 SULPHUR DIOXIDE (SO₂) Following a successful shut-down calibration on February 4, the sample pump was rebuilt. A successful post-repair calibration was subsequently performed. There were no issues that impacted operational time this month. The instantaneous channel was impacted by station audit activities on February 5, causing the invalidation of two hours of maximum instantaneous data. Maximum instantaneous data collected on February 22 at hour 13:00 was invalidated due to a brief power outage. TOTAL REDUCED SULPHUR (TRS) The routine monthly calibration was performed on February 4. The as-found high point value obtained from the calibration was 8.1% off the reference value. This was within the tolerance limits of +/-10%. However, as a precaution, an as-found response check was completed on February 5, using an alternate calibrator. The result was 1.2% off reference value. No further action was taken. The instantaneous channel was impacted by station audit activities on February 5, causing the invalidation of two hours of maximum instantaneous data. Maximum instantaneous data collected on February 22 at hour 13:00 was invalidated due to a brief power outage. TOTAL HYDROCARBONS (THC), METHANE (CH₄) and NON-METHANE HYDROCARBONS (NMHC) The routine monthly calibration was performed on February 4. One hour of downtime was recorded on February 22, at hour 13:00, as the analyzer was recovering from a brief power outage. The canister sampler is programmed to draw in a whole air sample when the 5-minute average concentration of NMHC is above 0.30 ppm. A representative sample of ambient air is collected over a one-hour period when the canister event is triggered. One canister event was recorded on February 16 at 20:10, at a concentration of 0.31 ppm. WIND SPEED (WS) and WIND DIRECTION (WD) Wind data is reported as vector wind speed and vector wind direction. Wind direction is defined as the direction from which the wind is blowing from and is measured in degrees from true north. There were no issues that impacted operational time this month. The wind system was upgraded on February 15. The RM Young 05103VK (s/n: 43711) was removed following a successful shut-down calibration. Subsequently, an RM Young 05305VK (s/n: ) was installed and calibrated. Maximum instantaneous data collected on February 22 at hour 13:00 was invalidated due to a brief power outage. RELATIVE HUMIDITY (RH) There were no issues that impacted operational time this month. BAROMETRIC PRESSURE (BP) There were no issues that impacted operational time this month. The reporting unit for Barometric Pressure was changed from inhg to millibar, as per client request. AMBIENT TEMPERATURE (AmbTPX) There were no issues that impacted operational time this month. STATION TEMPERATURE (StnTPX) There were no issues that impacted operational time this month. JOB #: C Page 7 of 106

9 PEACE RIVER AREA MONITORING PROGRAM COMMITTEE Three Creeks 986b Station - February Project Personnel Karla Reesor was the contact for Peace River Area Monitoring Program Committee and the Maxxam field technicians were Limin Li and Christopher Wesson. 3.0 Plant Monthly Required AMD Summary All data collected this month was compliant with the requirements outlined in the Air Monitoring Directive (Alberta Environment and Parks, 2016). The operational time for all continuous ambient air analyzers, meteorological systems and data acquisition systems were above the 90% requirement. 4.0 Calculations and Results All calculations and reporting of results follow the methods described in the AMD, JOB #: C Page 8 of 106

10 PEACE RIVER AREA MONITORING PROGRAM COMMITTEE Three Creeks 986b Station - February Methods and Procedures The following methods and procedures were used to complete the monitoring program: Maxxam AIR SOP Methane, Non-Methane Hydrocarbon Analyzer Monitoring Maxxam AIR SOP-00208: RM Young Wind Monitor Calibration Maxxam AIR SOP-00209: Ambient Sulphur Monitoring There were no deviations from the prescribed methods. The following instruments were used to perform the test program: Sulphur Dioxide - Thermo 43C UV Flourescent Analyzer Total Reduced Sulphur - Thermo 43i UV Flourescent Analyzer Methane, Non-Methane Hydrocarbon - Thermo 55i FID Analyzer Wind System - RM Young Unit Relative Humidity - Campbell Scientific Unit Barometric Pressure - Met One Unit Ambient Temperature - Campbell Scientific Unit Datalogger - ESC 8832 JOB #: C Page 9 of 106

11 PEACE RIVER AREA MONITORING PROGRAM COMMITTEE Three Creeks 986b Station - February 2017 The following steps were used to complete the data verification and validation process: Level 0 Preliminary Verification Level 0 data are raw data obtained directly from the data acquisition system (DAS). Under the step of Level 0, these data undergo a certain amount of manual or automated screening and flagging. It included a) identification of periods of missing data; b) verification of time stamps against reference time; c) verification that instrument diagnostics/datalogger flags indicate normal operation; d) comparison of data to upper and lower limits; e) rate of change flagging indicating that data changed too rapidly or not at all; and f) verification that zero, span and multipoint performance checks are within specifications. This level of verification is performed on a daily basis. Level 1 Primary Validation Validation actions under the step of Level 1 include a) review of all screening flags assigned during preliminary verification; b) review of all supporting site information and documentation; c) review of operational acceptance limits for each parameter/analyzer; d) review of daily zero/span and monthly calibration results for all gaseous parameters; and e) application of any necessary adjustments to data (e.g. baseline adjustments, below zero adjustments). This level of validation is performed on a monthly basis. Level 2 Final Validation The purpose of Level 2 validation is to verify that there are no inconsistencies among related data, or among regional data measured at nearby sites. Level 3 Independent Data Review Level 3 validation is the last step of data review, and it is completed by an individual that is independent of both field operations and primary data validation. A final independent QA review and endorsement is performed during this step before data is submitted to Alberta Environment. Post-Final Validation The Post-Final Validation step serves to re-evaluate the data that errors or omissions are discovered and/or suspected after the initial submittal of data. Any data issues or patterns which were not clear on a monthly basis are highlighted during this step. This validation is performed on an annual basis. JOB #: C Page 10 of 106

12 PEACE RIVER AREA MONITORING PROGRAM COMMITTEE Three Creeks 986b Station - February 2017 Source: Air Monitoring Directive (Aug 3, 2016), Chapter 6, Ambient Data Quality; Figure 1 Data Collection and Management Process Flow Chart JOB #: C Page 11 of 106

13 APPENDIX I CONTINUOUS MONITORING DATA RESULTS JOB #: C Page 12 of 106

14 SULPHUR DIOXIDE JOB #: C Page 13 of 106

15 PEACE RIVER AREA MONITORING PROGRAM COMMITTEE Three Creeks 986b Station - February 2017 SULPHUR DIOXIDE Hourly Averages (SO₂ ppb) HR START (MST) 0:00 1:00 2:00 3:00 4:00 5:00 6:00 7:00 8:00 9:00 10:00 11:00 12:00 13:00 14:00 15:00 16:00 17:00 18:00 19:00 20:00 21:00 22:00 23:00 DAILY DAILY 24-HR HR END (MST) 0:59 1:59 2:59 3:59 4:59 5:59 6:59 7:59 8:59 9:59 10:59 11:59 12:59 13:59 14:59 15:59 16:59 17:59 18:59 19:59 20:59 21:59 22:59 23:59 MIN. MAX. AVG. RDGS. DAY S S S S C C C C C C S S S S S S S S S S S S S S S S S S S S S S S S S HOURLY MAX HOURLY AVG STATUS FLAG CODES C - MONTHLY CALIBRATION Q - QUALITY ASSURANCE OBJECTIVE LIMIT: ALBERTA ENVIRONMENT: 1-HR 172 ppb 24-HR 48 ppb C1 - REPEAT CALIBRATION R - RECOVERY Y - MAINTENANCE X - MACHINE MALFUNCTION S - DAILY ZERO/SPAN CHECK G - OUT FOR REPAIR MONTHLY SUMMARY S1 - REPEAT ZERO/SPAN CHECK P - POWER FAILURE NUMBER OF 1-HR EXCEEDANCES: 0 NUMBER OF 24-HR EXCEEDANCES: 0 24 HR AVERAGES February 2017 NUMBER OF NON-ZERO READINGS: 350 MINIMUM 1-HR AVERAGE 0.0 HOUR(S) VAR ON DAY(S) VAR MAXIMUM 1-HR AVERAGE: 4.4 HOUR(S) 16 ON DAY(S) 6 MAXIMUM 24-HR AVERAGE: 0.8 ppb ON DAY(S) VAR-VARIOUS IZS CALIBRATION TIME: 29 hrs OPERATIONAL TIME: 672 hrs MONTHLY CALIBRATION TIME: 6 hrs AMD OPERATION UPTIME: % STANDARD DEVIATION: 0.3 MONTHLY AVERAGE: 0.2 ppb JOB #: C Page 14 of 106

16 PEACE RIVER AREA MONITORING PROGRAM COMMITTEE Three Creeks 986b Station - February 2017 SULPHUR DIOXIDE Hourly Averages (SO₂ ppb) 8.0 SO₂ 1hrAve (ppb) AAAQO (172 ppb) SO₂ (ppb) AAAQO 1-Hr Averaging Period Day 0 JOB #: C Page 15 of 106

17 PEACE RIVER AREA MONITORING PROGRAM COMMITTEE Three Creeks 986b Station - February 2017 SULPHUR DIOXIDE Instantaneous Maximum (SO₂ ppb) HR START (MST) 0:00 1:00 2:00 3:00 4:00 5:00 6:00 7:00 8:00 9:00 10:00 11:00 12:00 13:00 14:00 15:00 16:00 17:00 18:00 19:00 20:00 21:00 22:00 23:00 DAILY DAILY 24-HR HR END (MST) 0:59 1:59 2:59 3:59 4:59 5:59 6:59 7:59 8:59 9:59 10:59 11:59 12:59 13:59 14:59 15:59 16:59 17:59 18:59 19:59 20:59 21:59 22:59 23:59 MIN. MAX. AVG. RDGS. DAY S S S S C C C C C C S X X S S S S S S S S S S S S S S S S S S P S S S S S S HOURLY MAX HOURLY AVG STATUS FLAG CODES C - MONTHLY CALIBRATION Q - QUALITY ASSURANCE MONTHLY SUMMARY C1 - REPEAT CALIBRATION R - RECOVERY Y - MAINTENANCE X - MACHINE MALFUNCTION NUMBER OF NON-ZERO READINGS: 634 S - DAILY ZERO/SPAN CHECK G - OUT FOR REPAIR S1 - REPEAT ZERO/SPAN CHECK P - POWER FAILURE MAXIMUM INSTANTANEOUS VALUE: 6.6 HOUR(S) 16 ON DAY(S) 6 VAR-VARIOUS IZS CALIBRATION TIME: 29 hrs OPERATIONAL TIME: 669 hrs MONTHLY CALIBRATION TIME: 6 hrs STANDARD DEVIATION: 0.5 JOB #: C Page 16 of 106

18 PEACE RIVER AREA MONITORING PROGRAM COMMITTEE Three Creeks 986b Station - February 2017 SULPHUR DIOXIDE Instantaneous Maximum (SO₂ ppb) 8.0 SO₂ InsMax (ppb) SO₂ max (ppb) Day JOB #: C Page 17 of 106

19 Wind: PRAMP_986 Poll.: PRAMP_986-SO2[ppb] Monthly: 02/2017 Type: PollutionRose Direction: Blowing From (Wind Frequency) Based On 1 Hr. Calm: 12.68% Valid Data: 93.90% Calm Avg: 0.21 [ppb] Direction >170.0 Total N NE E SE S SW W NW Summary JOB #: C Page 18 of 106

20 JOB #: C Page 19 of 106

21 JOB #: C Page 20 of 106

22 TOTAL REDUCED SULPHUR JOB #: C Page 21 of 106

23 PEACE RIVER AREA MONITORING PROGRAM COMMITTEE Three Creeks 986b Station - February 2017 TOTAL REDUCED SULPHUR Hourly Averages (TRS ppb) HR START (MST) 0:00 1:00 2:00 3:00 4:00 5:00 6:00 7:00 8:00 9:00 10:00 11:00 12:00 13:00 14:00 15:00 16:00 17:00 18:00 19:00 20:00 21:00 22:00 23:00 DAILY DAILY 24-HR HR END (MST) 0:59 1:59 2:59 3:59 4:59 5:59 6:59 7:59 8:59 9:59 10:59 11:59 12:59 13:59 14:59 15:59 16:59 17:59 18:59 19:59 20:59 21:59 22:59 23:59 MIN. MAX. AVG. RDGS. DAY S S S S C C C C C S C1 C S S S S S S S S S S S S S S S S S S S S S S S S HOURLY MAX HOURLY AVG STATUS FLAG CODES C - MONTHLY CALIBRATION Q - QUALITY ASSURANCE C1 - REPEAT CALIBRATION R - RECOVERY Y - MAINTENANCE X - MACHINE MALFUNCTION S - DAILY ZERO/SPAN CHECK G - OUT FOR REPAIR S1 - REPEAT ZERO/SPAN CHECK P - POWER FAILURE HR AVERAGES February MONTHLY SUMMARY NUMBER OF NON-ZERO READINGS: 636 MINIMUM 1-HR AVERAGE 0.1 HOUR(S) VAR ON DAY(S) VAR MAXIMUM 1-HR AVERAGE: 1.2 HOUR(S) 7 ON DAY(S) 10 MAXIMUM 24-HR AVERAGE: 0.5 ppb ON DAY(S) VAR-VARIOUS 16 IZS CALIBRATION TIME: 29 hrs OPERATIONAL TIME: 670 hrs MONTHLY CALIBRATION TIME: 5 hrs AMD OPERATION UPTIME: 99.7 % STANDARD DEVIATION: 0.1 MONTHLY AVERAGE: 0.3 ppb JOB #: C Page 22 of 106

24 PEACE RIVER AREA MONITORING PROGRAM COMMITTEE Three Creeks 986b Station - February 2017 TOTAL REDUCED SULPHUR Hourly Averages (TRS ppb) 3.0 TRS 1hrAve (ppb) TRS (ppb) Day JOB #: C Page 23 of 106

25 PEACE RIVER AREA MONITORING PROGRAM COMMITTEE Three Creeks 986b Station - February 2017 TOTAL REDUCED SULPHUR Instantaneous Maximum (TRS ppb) HR START (MST) 0:00 1:00 2:00 3:00 4:00 5:00 6:00 7:00 8:00 9:00 10:00 11:00 12:00 13:00 14:00 15:00 16:00 17:00 18:00 19:00 20:00 21:00 22:00 23:00 DAILY DAILY 24-HR HR END (MST) 0:59 1:59 2:59 3:59 4:59 5:59 6:59 7:59 8:59 9:59 10:59 11:59 12:59 13:59 14:59 15:59 16:59 17:59 18:59 19:59 20:59 21:59 22:59 23:59 MIN. MAX. AVG. RDGS. DAY S S S S C C C C C S C1 C1 X X S S S S S S S S S S S S S S S S S S P S S S S S S HOURLY MAX HOURLY AVG STATUS FLAG CODES C - MONTHLY CALIBRATION Q - QUALITY ASSURANCE MONTHLY SUMMARY C1 - REPEAT CALIBRATION R - RECOVERY Y - MAINTENANCE X - MACHINE MALFUNCTION NUMBER OF NON-ZERO READINGS: 633 S - DAILY ZERO/SPAN CHECK G - OUT FOR REPAIR S1 - REPEAT ZERO/SPAN CHECK P - POWER FAILURE MAXIMUM INSTANTANEOUS VALUE: 2.5 HOUR(S) 12 ON DAY(S) 16 VAR-VARIOUS IZS CALIBRATION TIME: 29 hrs OPERATIONAL TIME: 667 hrs MONTHLY CALIBRATION TIME: 5 hrs STANDARD DEVIATION: 0.2 JOB #: C Page 24 of 106

26 PEACE RIVER AREA MONITORING PROGRAM COMMITTEE Three Creeks 986b Station - February 2017 TOTAL REDUCED SULPHUR Instantaneous Maximum (TRS ppb) TRS InsMax (ppb) TRS max (ppb) Day JOB #: C Page 25 of 106

27 Wind: PRAMP_986 Poll.: PRAMP_986-TRS[ppb] Monthly: 02/2017 Type: PollutionRose Direction: Blowing From (Wind Frequency) Based On 1 Hr. Calm: 12.70% Valid Data: 93.75% Calm Avg: 0.38 [ppb] Direction >10.0 Total N NE E SE S SW W NW Summary JOB #: C Page 26 of 106

28 JOB #: C Page 27 of 106

29 JOB #: C Page 28 of 106

30 TOTAL HYDROCARBON JOB #: C Page 29 of 106

31 PEACE RIVER AREA MONITORING PROGRAM COMMITTEE Three Creeks 986b Station - February 2017 TOTAL HYDROCARBONS Hourly Averages (THC ppm) HR START (MST) 0:00 1:00 2:00 3:00 4:00 5:00 6:00 7:00 8:00 9:00 10:00 11:00 12:00 13:00 14:00 15:00 16:00 17:00 18:00 19:00 20:00 21:00 22:00 23:00 DAILY DAILY 24-HR HR END (MST) 0:59 1:59 2:59 3:59 4:59 5:59 6:59 7:59 8:59 9:59 10:59 11:59 12:59 13:59 14:59 15:59 16:59 17:59 18:59 19:59 20:59 21:59 22:59 23:59 MIN. MAX. AVG. RDGS. DAY S S S S S C C C C C S S S S S S S S S S S S S S S S S S R S S S S S S HOURLY MAX HOURLY AVG STATUS FLAG CODES C - MONTHLY CALIBRATION Q - QUALITY ASSURANCE C1 - REPEAT CALIBRATION R - RECOVERY Y - MAINTENANCE X - MACHINE MALFUNCTION S - DAILY ZERO/SPAN CHECK G - OUT FOR REPAIR S1 - REPEAT ZERO/SPAN CHECK P - POWER FAILURE 24 HR AVERAGES February MONTHLY SUMMARY NUMBER OF NON-ZERO READINGS: 637 MINIMUM 1-HR AVERAGE 1.81 HOUR(S) 19, 20 ON DAY(S) 15, 15 MAXIMUM 1-HR AVERAGE: 2.11 HOUR(S) 2 ON DAY(S) 2 MAXIMUM 24-HR AVERAGE: 2.07 ppm ON DAY(S) VAR-VARIOUS 2 IZS CALIBRATION TIME: 29 hrs OPERATIONAL TIME: 671 hrs MONTHLY CALIBRATION TIME: 5 hrs AMD OPERATION UPTIME: 99.9 % STANDARD DEVIATION: 0.06 MONTHLY AVERAGE: 1.91 ppm JOB #: C Page 30 of 106

32 PEACE RIVER AREA MONITORING PROGRAM COMMITTEE Three Creeks 986b Station - February 2017 TOTAL HYDROCARBONS Hourly Averages (THC ppm) 5.0 THC 1hrAve (ppm) THC (ppm) Day JOB #: C Page 31 of 106

33 PEACE RIVER AREA MONITORING PROGRAM COMMITTEE Three Creeks 986b Station - February 2017 TOTAL HYDROCARBONS Instantaneous Maximum (THC ppm) HR START (MST) 0:00 1:00 2:00 3:00 4:00 5:00 6:00 7:00 8:00 9:00 10:00 11:00 12:00 13:00 14:00 15:00 16:00 17:00 18:00 19:00 20:00 21:00 22:00 23:00 DAILY DAILY 24-HR HR END (MST) 0:59 1:59 2:59 3:59 4:59 5:59 6:59 7:59 8:59 9:59 10:59 11:59 12:59 13:59 14:59 15:59 16:59 17:59 18:59 19:59 20:59 21:59 22:59 23:59 MIN. MAX. AVG. RDGS. DAY S S S S S C C C C C S S S S S S S S S S S S S S S S S S R S S S S S S HOURLY MAX HOURLY AVG STATUS FLAG CODES C - MONTHLY CALIBRATION Q - QUALITY ASSURANCE MONTHLY SUMMARY C1 - REPEAT CALIBRATION R - RECOVERY Y - MAINTENANCE X - MACHINE MALFUNCTION NUMBER OF NON-ZERO READINGS: 637 S - DAILY ZERO/SPAN CHECK G - OUT FOR REPAIR S1 - REPEAT ZERO/SPAN CHECK P - POWER FAILURE MAXIMUM INSTANTANEOUS VALUE: 2.37 HOUR(S) 20 ON DAY(S) 16 VAR-VARIOUS IZS CALIBRATION TIME: 29 hrs OPERATIONAL TIME: 671 hrs MONTHLY CALIBRATION TIME: 5 hrs STANDARD DEVIATION: 0.07 JOB #: C Page 32 of 106

34 PEACE RIVER AREA MONITORING PROGRAM COMMITTEE Three Creeks 986b Station - February 2017 TOTAL HYDROCARBONS Instantaneous Maximum (THC ppm) 5.0 THC InsMax (ppm) 4.0 THC max (ppm) Day JOB #: C Page 33 of 106

35 Wind: PRAMP_986 Poll.: PRAMP_986-THC55[ppm] Monthly: 02/2017 Type: PollutionRose Direction: Blowing From (Wind Frequency) Based On 1 Hr. Calm: 12.62% Valid Data: 94.35% Calm Avg: 1.94 [ppm] Direction >10.0 Total N NE E SE S SW W NW Summary JOB #: C Page 34 of 106

36 JOB #: C Page 35 of 106

37 JOB #: C Page 36 of 106

38 METHANE JOB #: C Page 37 of 106

39 PEACE RIVER AREA MONITORING PROGRAM COMMITTEE Three Creeks 986b Station - February 2017 METHANE Hourly Averages (CH₄ ppm) HR START (MST) 0:00 1:00 2:00 3:00 4:00 5:00 6:00 7:00 8:00 9:00 10:00 11:00 12:00 13:00 14:00 15:00 16:00 17:00 18:00 19:00 20:00 21:00 22:00 23:00 DAILY DAILY 24-HR HR END (MST) 0:59 1:59 2:59 3:59 4:59 5:59 6:59 7:59 8:59 9:59 10:59 11:59 12:59 13:59 14:59 15:59 16:59 17:59 18:59 19:59 20:59 21:59 22:59 23:59 MIN. MAX. AVG. RDGS. DAY S S S S S C C C C C S S S S S S S S S S S S S S S S S S R S S S S S S HOURLY MAX HOURLY AVG STATUS FLAG CODES C - MONTHLY CALIBRATION Q - QUALITY ASSURANCE C1 - REPEAT CALIBRATION R - RECOVERY Y - MAINTENANCE X - MACHINE MALFUNCTION S - DAILY ZERO/SPAN CHECK G - OUT FOR REPAIR S1 - REPEAT ZERO/SPAN CHECK P - POWER FAILURE 24 HR AVERAGES February MONTHLY SUMMARY NUMBER OF NON-ZERO READINGS: 637 MINIMUM 1-HR AVERAGE 1.81 HOUR(S) 19, 20 ON DAY(S) 15, 15 MAXIMUM 1-HR AVERAGE: 2.11 HOUR(S) 2 ON DAY(S) 2 MAXIMUM 24-HR AVERAGE: 2.07 ppm ON DAY(S) VAR-VARIOUS 2 IZS CALIBRATION TIME: 29 hrs OPERATIONAL TIME: 671 hrs MONTHLY CALIBRATION TIME: 5 hrs AMD OPERATION UPTIME: 99.9 % STANDARD DEVIATION: 0.06 MONTHLY AVERAGE: 1.91 ppm JOB #: C Page 38 of 106

40 PEACE RIVER AREA MONITORING PROGRAM COMMITTEE Three Creeks 986b Station - February 2017 METHANE Hourly Averages (CH₄ ppm) 5.0 CH₄ 1hrAve (ppm) CH₄ (ppm) Day JOB #: C Page 39 of 106

41 PEACE RIVER AREA MONITORING PROGRAM COMMITTEE Three Creeks 986b Station - February 2017 METHANE MAX Instantaneous Maximum (CH₄ ppm) HR START (MST) 0:00 1:00 2:00 3:00 4:00 5:00 6:00 7:00 8:00 9:00 10:00 11:00 12:00 13:00 14:00 15:00 16:00 17:00 18:00 19:00 20:00 21:00 22:00 23:00 DAILY DAILY 24-HR HR END (MST) 0:59 1:59 2:59 3:59 4:59 5:59 6:59 7:59 8:59 9:59 10:59 11:59 12:59 13:59 14:59 15:59 16:59 17:59 18:59 19:59 20:59 21:59 22:59 23:59 MIN. MAX. AVG. RDGS. DAY S S S S S C C C C C S S S S S S S S S S S S S S S S S S R S S S S S S HOURLY MAX HOURLY AVG STATUS FLAG CODES C - MONTHLY CALIBRATION Q - QUALITY ASSURANCE MONTHLY SUMMARY C1 - REPEAT CALIBRATION R - RECOVERY Y - MAINTENANCE X - MACHINE MALFUNCTION NUMBER OF NON-ZERO READINGS: 637 S - DAILY ZERO/SPAN CHECK G - OUT FOR REPAIR S1 - REPEAT ZERO/SPAN CHECK P - POWER FAILURE MAXIMUM INSTANTANEOUS VALUE: 2.33 HOUR(S) 18 ON DAY(S) 18 VAR-VARIOUS IZS CALIBRATION TIME: 29 hrs OPERATIONAL TIME: 671 hrs MONTHLY CALIBRATION TIME: 5 hrs STANDARD DEVIATION: 0.07 JOB #: C Page 40 of 106

42 PEACE RIVER AREA MONITORING PROGRAM COMMITTEE Three Creeks 986b Station - February 2017 METHANE MAX Instantaneous Maximum (CH₄ ppm) 5.0 CH₄ InsMax (ppm) 4.0 CH₄ max (ppm) Day JOB #: C Page 41 of 106

43 Wind: PRAMP_986 Poll.: PRAMP_986-CH4[ppm] Monthly: 02/2017 Type: PollutionRose Direction: Blowing From (Wind Frequency) Based On 1 Hr. Calm: 12.62% Valid Data: 94.35% Calm Avg: 1.94 [ppm] Direction >10.0 Total N NE E SE S SW W NW Summary JOB #: C Page 42 of 106

44 JOB #: C Page 43 of 106

45 JOB #: C Page 44 of 106

46 NON-METHANE HYDROCARBON JOB #: C Page 45 of 106

47 PEACE RIVER AREA MONITORING PROGRAM COMMITTEE Three Creeks 986b Station - February 2017 NON-METHANE HYDROCARBONS Hourly Averages (NMHC ppm) HR START (MST) 0:00 1:00 2:00 3:00 4:00 5:00 6:00 7:00 8:00 9:00 10:00 11:00 12:00 13:00 14:00 15:00 16:00 17:00 18:00 19:00 20:00 21:00 22:00 23:00 DAILY DAILY 24-HR HR END (MST) 0:59 1:59 2:59 3:59 4:59 5:59 6:59 7:59 8:59 9:59 10:59 11:59 12:59 13:59 14:59 15:59 16:59 17:59 18:59 19:59 20:59 21:59 22:59 23:59 MIN. MAX. AVG. RDGS. DAY S S S S S C C C C C S S S S S S S S S S S S S S S S S S R S S S S S S HOURLY MAX HOURLY AVG STATUS FLAG CODES C - MONTHLY CALIBRATION Q - QUALITY ASSURANCE C1 - REPEAT CALIBRATION R - RECOVERY Y - MAINTENANCE X - MACHINE MALFUNCTION S - DAILY ZERO/SPAN CHECK G - OUT FOR REPAIR S1 - REPEAT ZERO/SPAN CHECK P - POWER FAILURE 24 HR AVERAGES February 2017 MONTHLY SUMMARY NUMBER OF NON-ZERO READINGS: 1 MINIMUM 1-HR AVERAGE 0.00 HOUR(S) VAR ON DAY(S) ALL MAXIMUM 1-HR AVERAGE: 0.08 HOUR(S) 20 ON DAY(S) 16 MAXIMUM 24-HR AVERAGE: 0.00 ppm ON DAY(S) VAR-VARIOUS ALL IZS CALIBRATION TIME: 29 hrs OPERATIONAL TIME: 671 hrs MONTHLY CALIBRATION TIME: 5 hrs AMD OPERATION UPTIME: 99.9 % STANDARD DEVIATION: 0.00 MONTHLY AVERAGE: 0.00 ppm JOB #: C Page 46 of 106

48 PEACE RIVER AREA MONITORING PROGRAM COMMITTEE Three Creeks 986b Station - February 2017 NON-METHANE HYDROCARBONS Hourly Averages (NMHC ppm) 1.0 NMHC 1hrAve (ppm) NMHC (ppm) Day JOB #: C Page 47 of 106

49 PEACE RIVER AREA MONITORING PROGRAM COMMITTEE Three Creeks 986b Station - February 2017 NON-METHANE HYDROCARBONS Instantaneous Maximum (NMHC ppm) HR START (MST) 0:00 1:00 2:00 3:00 4:00 5:00 6:00 7:00 8:00 9:00 10:00 11:00 12:00 13:00 14:00 15:00 16:00 17:00 18:00 19:00 20:00 21:00 22:00 23:00 DAILY DAILY 24-HR HR END (MST) 0:59 1:59 2:59 3:59 4:59 5:59 6:59 7:59 8:59 9:59 10:59 11:59 12:59 13:59 14:59 15:59 16:59 17:59 18:59 19:59 20:59 21:59 22:59 23:59 MIN. MAX. AVG. RDGS. DAY S S S S S C C C C C S S S S S S S S S S S S S S S S S S R S S S S S S HOURLY MAX HOURLY AVG STATUS FLAG CODES C - MONTHLY CALIBRATION Q - QUALITY ASSURANCE MONTHLY SUMMARY C1 - REPEAT CALIBRATION R - RECOVERY Y - MAINTENANCE X - MACHINE MALFUNCTION NUMBER OF NON-ZERO READINGS: 9 S - DAILY ZERO/SPAN CHECK G - OUT FOR REPAIR S1 - REPEAT ZERO/SPAN CHECK P - POWER FAILURE MAXIMUM INSTANTANEOUS VALUE: 0.51 HOUR(S) 20 ON DAY(S) 16 VAR-VARIOUS IZS CALIBRATION TIME: 29 hrs OPERATIONAL TIME: 671 hrs MONTHLY CALIBRATION TIME: 5 hrs STANDARD DEVIATION: 0.02 JOB #: C Page 48 of 106

50 PEACE RIVER AREA MONITORING PROGRAM COMMITTEE Three Creeks 986b Station - February 2017 NON-METHANE HYDROCARBONS Instantaneous Maximum (NMHC ppm) 1.0 NMHC InsMax (ppm) 0.8 NMHC max (ppm) Day JOB #: C Page 49 of 106

51 Wind: PRAMP_986 Poll.: PRAMP_986-NMHC[ppm] Monthly: 02/2017 Type: PollutionRose Direction: Blowing From (Wind Frequency) Based On 1 Hr. Calm: 12.62% Valid Data: 94.35% Calm Avg: 0.00 [ppm] Direction >2.0 Total N NE E SE S SW W NW Summary JOB #: C Page 50 of 106

52 JOB #: C Page 51 of 106

53 JOB #: C Page 52 of 106

54 WIND SPEED JOB #: C Page 53 of 106

55 PEACE RIVER AREA MONITORING PROGRAM COMMITTEE Three Creeks 986b Station - February 2017 WIND SPEED Hourly Averages (WS kph) HR START (MST) 0:00 1:00 2:00 3:00 4:00 5:00 6:00 7:00 8:00 9:00 10:00 11:00 12:00 13:00 14:00 15:00 16:00 17:00 18:00 19:00 20:00 21:00 22:00 23:00 DAILY DAILY 24-HR HR END (MST) 0:59 1:59 2:59 3:59 4:59 5:59 6:59 7:59 8:59 9:59 10:59 11:59 12:59 13:59 14:59 15:59 16:59 17:59 18:59 19:59 20:59 21:59 22:59 23:59 MIN. MAX. AVG. RDGS. DAY C C HOURLY MAX HOURLY AVG STATUS FLAG CODES C - MONTHLY CALIBRATION Q - QUALITY ASSURANCE LAST CALIBRATION: C1 - REPEAT CALIBRATION R - RECOVERY DECLINATION : Y - MAINTENANCE X - MACHINE MALFUNCTION S - DAILY ZERO/SPAN CHECK G - OUT FOR REPAIR S1 - REPEAT ZERO/SPAN CHECK P - POWER FAILURE HR AVERAGES February NUMBER OF NON-ZERO READINGS: 669 February 15, 2017 MAGNETIC DECLINATION 15 DEGREE EAST MONTHLY SUMMARY MINIMUM 1-HR AVERAGE 0.0 HOUR(S) 21 ON DAY(S) 3 MAXIMUM 1-HR AVERAGE: 20.1 HOUR(S) 11 ON DAY(S) 12 MAXIMUM 24-HR AVERAGE: 14.7 kph ON DAY(S) VAR-VARIOUS 12 OPERATIONAL TIME: 672 hrs MONTHLY CALIBRATION TIME: 2 hrs AMD OPERATION UPTIME: % STANDARD DEVIATION: 3.5 MONTHLY AVERAGE: 1.9 kph JOB #: C Page 54 of 106

56 PEACE RIVER AREA MONITORING PROGRAM COMMITTEE Three Creeks 986b Station - February 2017 WIND SPEED Hourly Averages (WS kph) 25 WS 1hrAve (kph) WS (kph) Day JOB #: C Page 55 of 106

57 PEACE RIVER AREA MONITORING PROGRAM COMMITTEE Three Creeks 986b Station - February 2017 WIND SPEED Instantaneous Maximum (WS kph) HR START (MST) 0:00 1:00 2:00 3:00 4:00 5:00 6:00 7:00 8:00 9:00 10:00 11:00 12:00 13:00 14:00 15:00 16:00 17:00 18:00 19:00 20:00 21:00 22:00 23:00 DAILY DAILY 24-HR HR END (MST) 0:59 1:59 2:59 3:59 4:59 5:59 6:59 7:59 8:59 9:59 10:59 11:59 12:59 13:59 14:59 15:59 16:59 17:59 18:59 19:59 20:59 21:59 22:59 23:59 MIN. MAX. AVG. RDGS. DAY C C C P HOURLY MAX HOURLY AVG STATUS FLAG CODES C - MONTHLY CALIBRATION Q - QUALITY ASSURANCE C1 - REPEAT CALIBRATION R - RECOVERY Y - MAINTENANCE X - MACHINE MALFUNCTION MONTHLY SUMMARY S - DAILY ZERO/SPAN CHECK G - OUT FOR REPAIR S1 - REPEAT ZERO/SPAN CHECK P - POWER FAILURE MAXIMUM INSTANTANEOUS VALUE: 65.3 HOUR(S) 10 ON DAY(S) 12 VAR-VARIOUS OPERATIONAL TIME: 671 hrs JOB #: C Page 56 of 106

58 PEACE RIVER AREA MONITORING PROGRAM COMMITTEE Three Creeks 986b Station - February 2017 WIND SPEED Instantaneous Maximum (WS kph) 70 WS InsMax (kph) WS max (kph) Day JOB #: C Page 57 of 106

59 Wind: PRAMP_986 Monitor: WSP [kph] Monthly: 02/2017 Type: WindRose Direction: Blowing From (Wind Frequency) Based On 1 Hr. Calm: 12.24% Valid Data: 99.70% Direction >39.0 Total N NE E SE S SW W NW Summary JOB #: C Page 58 of 106

60 JOB #: C Page 59 of 106

61 WIND DIRECTION JOB #: C Page 60 of 106

62 PEACE RIVER AREA MONITORING PROGRAM COMMITTEE Three Creeks 986b Station - February 2017 WIND DIRECTION Hourly Averages (WD) HR START (MST) 0:00 1:00 2:00 3:00 4:00 5:00 6:00 7:00 8:00 9:00 10:00 11:00 12:00 13:00 14:00 15:00 16:00 17:00 18:00 19:00 20:00 21:00 22:00 23:00 24-HOUR AVG 24-HR HR END (MST) 0:59 1:59 2:59 3:59 4:59 5:59 6:59 7:59 8:59 9:59 10:59 11:59 12:59 13:59 14:59 15:59 16:59 17:59 18:59 19:59 20:59 21:59 22:59 23:59 QUADRANT RDGS. DAY 1 W WNW WNW WNW WNW WNW WNW NNW SSE SE SSE WNW WNW WNW W S WSW SSW SSE ESE SE SE SSE SSE SW 24 2 SE SE SSE S S S S S SSW SSW SW WNW W W W W W W NNW SW SSE W NNW NNW SW 24 3 NNW NNW N N N N N N NNW NNW N NNW NNW NNW NNW NW NW SW SSW S S ENE NW WNW WSW 24 4 NW W WNW NW WNW W WNW W WSW WSW SW WSW SW SW SW SW SW SW WSW WSW NW NNW NNW N W 24 5 N N NNW N NNW NNW N N N SSW NNW NNE WNW NW WNW W SW SSW S S S SSE ESE SE WSW 24 6 SE SE SE SE ESE ESE ESE E E E ESE SE WNW WNW WNW WNW WNW NNW W W S WNW NW NW SSW 24 7 NNW WNW SSE S SSW SSW SSW SSW S SSW SSW SSW SSW SSW SSW SW SW SW SSW SSW WSW WSW S SW SW 24 8 SW SW SW SW SW SW SSW SSW SSW SSW SSW SSW SSW SSW SSW SSW SSW SSW SSW SSW SSW SSW SSE SSE SSW 24 9 S ESE SE SE SE SE SE SE SE ESE SE E WNW ENE NE N NNW NNW N NE ENE NNW N NNW SSE NW NNW SE N ESE ESE E ENE ENE NE NE ENE ESE W WNW WNW WSW SSW S S S SSE SSW SW SSE SW SW SSW SW SW SSW SSW SSW SSW SW WSW WSW WSW WSW W WSW W W WSW SSW SSW SW SW SW SW WSW WSW WSW WSW WSW SW SW WSW SW WSW WSW WSW WSW SW SW WSW WSW SW WSW WSW WSW WSW WSW W WSW W WSW SSW SSW S SSW SW SW SW SSW SW SW SW SW SW SW SSW SSW SSW SSW SSW S S SSE SSW S SSW S S SSW SSW S SSE SSE SSE S SSE SSW SSW S S S SSE S SSE S S SSE SSE S SSE SSE SSE SSE SE SE ESE E E NW NW W WSW SSW SW SW SSW S C C SSW SW SSW S S SSE SSE S SSE ESE SE ESE ESE E E ESE E NW W WNW W W SSW SE ENE SW W SW ESE S WNW WNW W WNW NW NW WNW WNW S SW SW WSW WSW WSW W WSW SW SW WSW WSW WNW NW WNW WNW W NNW S SSE SE SSE S N E ESE E E E ESE E ENE E ENE ENE ENE ENE ENE ENE ENE ENE ESE ENE NE NE ENE ENE ENE ENE NE NE NE NE NE NNE NNW NNW NW NW NW NW NW NW NW NW NNW S NW NNW NNW NNW NW NW NW NNW NNW NNW NNW NNW NNW WNW WNW WNW WNW W W WNW SSW SW SW W WNW WNW NW NW NNW NNW NNW NW NW NW NNW NNW NNW NW NW WNW NNW NNW N NE SE SSE S S WSW W W WNW NW W W W WNW NW NW NW NW NW WNW NW WNW WNW WNW NNW N SE S S SSE SW W ESE ESE SSE SSW SSW SSW SSW SSW SSW SW WSW SW SSW WSW WSW NW NW NW NW NNW N N NNW NNW WSW NNW N N NNW N N NNW N N N NW WNW W WNW W SSW SSW S SSE S SSW S S SSE WSW S SSE SSW SSW SSW SSW SSW SSW SSW SSW WNW WNW NW NW NW NW NW NW NW NW NNW NNW N NNW W NNW NNW NNW NNW NNW NW NW NW NW NNW NNW N WNW WSW SW SSW SSW S S SSW SSW SE S SSW W S S SSE SSE SE ESE E ENE E ENE ENE SE NNW NNW NNW NNW NNW N N ESE N NW NNW N SW NNE N N NNW N N NNW NNW NNW N E E E ESE E ENE ENE ENE ENE NE ENE NE NE NE SSE 24 STATUS FLAG CODES C - MONTHLY CALIBRATION Q - QUALITY ASSURANCE LAST CALIBRATION: February 15, 2017 C1 - REPEAT CALIBRATION R - RECOVERY DECLINATION : MAGNETIC DECLINATION 15 DEGREE EAST Y - MAINTENANCE X - MACHINE MALFUNCTION S - DAILY ZERO/SPAN CHECK G - OUT FOR REPAIR S1 - REPEAT ZERO/SPAN CHECK P - POWER FAILURE MONTHLY CALIBRATION TIME: 2 hrs OPERATIONAL TIME: 672 hrs STANDARD DEVIATION: 90 AMD OPERATION UPTIME: % MONTHLY AVERAGE: 254 (WSW) JOB #: C Page 61 of 106

63 PEACE RIVER AREA MONITORING PROGRAM COMMITTEE Three Creeks 986b Station - February 2017 WIND DIRECTION Hourly Averages (WD) 390 WD 1hrAve (deg) WD (deg) Day JOB #: C Page 62 of 106

64 RELATIVE HUMIDITY JOB #: C Page 63 of 106

65 PEACE RIVER AREA MONITORING PROGRAM COMMITTEE Three Creeks 986b Station - February 2017 RELATIVE HUMIDITY Hourly Averages (RH %) HR START (MST) 0:00 1:00 2:00 3:00 4:00 5:00 6:00 7:00 8:00 9:00 10:00 11:00 12:00 13:00 14:00 15:00 16:00 17:00 18:00 19:00 20:00 21:00 22:00 23:00 DAILY DAILY 24-HR HR END (MST) 0:59 1:59 2:59 3:59 4:59 5:59 6:59 7:59 8:59 9:59 10:59 11:59 12:59 13:59 14:59 15:59 16:59 17:59 18:59 19:59 20:59 21:59 22:59 23:59 MIN. MAX. AVG. RDGS. DAY HOURLY MAX HOURLY AVG STATUS FLAG CODES C - MONTHLY CALIBRATION Q - QUALITY ASSURANCE C1 - REPEAT CALIBRATION R - RECOVERY Y - MAINTENANCE X - MACHINE MALFUNCTION S - DAILY ZERO/SPAN CHECK G - OUT FOR REPAIR S1 - REPEAT ZERO/SPAN CHECK P - POWER FAILURE 24 HR AVERAGES February 2017 MONTHLY SUMMARY MINIMUM 1-HR AVERAGE: 37 HOUR(S) 14 ON DAY(S) 12 MAXIMUM 1-HR AVERAGE: 98 HOUR(S) VAR ON DAY(S) 17 MAXIMUM 24-HR AVERAGE: 96 % ON DAY(S) VAR-VARIOUS 17 OPERATIONAL TIME: 672 hrs AMD OPERATION UPTIME: % STANDARD DEVIATION: 13 MONTHLY AVERAGE: 73 % JOB #: C Page 64 of 106

66 PEACE RIVER AREA MONITORING PROGRAM COMMITTEE Three Creeks 986b Station - February 2017 RELATIVE HUMIDITY Hourly Averages (RH %) 100 RH 1hrAve (%) RH (%) Day JOB #: C Page 65 of 106

67 BAROMETRIC PRESSURE JOB #: C Page 66 of 106

68 PEACE RIVER AREA MONITORING PROGRAM COMMITTEE Three Creeks 986b Station - February 2017 BAROMETRIC PRESSURE Hourly Averages (BP mbar) HR START (MST) 0:00 1:00 2:00 3:00 4:00 5:00 6:00 7:00 8:00 9:00 10:00 11:00 12:00 13:00 14:00 15:00 16:00 17:00 18:00 19:00 20:00 21:00 22:00 23:00 DAILY DAILY 24-HR HR END (MST) 0:59 1:59 2:59 3:59 4:59 5:59 6:59 7:59 8:59 9:59 10:59 11:59 12:59 13:59 14:59 15:59 16:59 17:59 18:59 19:59 20:59 21:59 22:59 23:59 MIN. MAX. AVG. RDGS. DAY HOURLY MAX HOURLY AVG STATUS FLAG CODES C - MONTHLY CALIBRATION Q - QUALITY ASSURANCE C1 - REPEAT CALIBRATION R - RECOVERY Y - MAINTENANCE X - MACHINE MALFUNCTION S - DAILY ZERO/SPAN CHECK G - OUT FOR REPAIR S1 - REPEAT ZERO/SPAN CHECK P - POWER FAILURE 24 HR AVERAGES February 2017 MONTHLY SUMMARY MINIMUM 1-HR AVERAGE: 912 HOUR(S) VAR ON DAY(S) 16 MAXIMUM 1-HR AVERAGE: 961 HOUR(S) VAR ON DAY(S) 1 MAXIMUM 24-HR AVERAGE: 960 mbar ON DAY(S) VAR-VARIOUS 1 OPERATIONAL TIME: 672 hrs AMD OPERATION UPTIME: % STANDARD DEVIATION: 11 MONTHLY AVERAGE: 938 mbar JOB #: C Page 67 of 106

69 PEACE RIVER AREA MONITORING PROGRAM COMMITTEE Three Creeks 986b Station - February 2017 BAROMETRIC PRESSURE Hourly Averages (BP mbar) 970 BP 1hrAve (mbar) BP (mbar) Day JOB #: C Page 68 of 106

70 AMBIENT TEMPERATURE JOB #: C Page 69 of 106

71 PEACE RIVER AREA MONITORING PROGRAM COMMITTEE Three Creeks 986b Station - February 2017 AMBIENT TEMPERATURE Hourly Averages (AmbTPX C) HR START (MST) 0:00 1:00 2:00 3:00 4:00 5:00 6:00 7:00 8:00 9:00 10:00 11:00 12:00 13:00 14:00 15:00 16:00 17:00 18:00 19:00 20:00 21:00 22:00 23:00 DAILY DAILY 24-HR HR END (MST) 0:59 1:59 2:59 3:59 4:59 5:59 6:59 7:59 8:59 9:59 10:59 11:59 12:59 13:59 14:59 15:59 16:59 17:59 18:59 19:59 20:59 21:59 22:59 23:59 MIN. MAX. AVG. RDGS. DAY HOURLY MAX HOURLY AVG STATUS FLAG CODES C - MONTHLY CALIBRATION Q - QUALITY ASSURANCE C1 - REPEAT CALIBRATION R - RECOVERY Y - MAINTENANCE X - MACHINE MALFUNCTION S - DAILY ZERO/SPAN CHECK G - OUT FOR REPAIR S1 - REPEAT ZERO/SPAN CHECK P - POWER FAILURE 24 HR AVERAGES February 2017 MONTHLY SUMMARY MINIMUM 1-HR AVERAGE: HOUR(S) 8 ON DAY(S) 6 MAXIMUM 1-HR AVERAGE: 9.6 HOUR(S) 16 ON DAY(S) 15 MAXIMUM 24-HR AVERAGE: 5.1 C ON DAY(S) VAR-VARIOUS 14 OPERATIONAL TIME: 672 hrs AMD OPERATION UPTIME: % STANDARD DEVIATION: 9.3 MONTHLY AVERAGE: -9.2 C JOB #: C Page 70 of 106

72 PEACE RIVER AREA MONITORING PROGRAM COMMITTEE Three Creeks 986b Station - February 2017 AMBIENT TEMPERATURE Hourly Averages (AmbTPX C) 15 AmbTPX 1hrAve ( C) AmbTPX ( C) Day JOB #: C Page 71 of 106

73 STATION TEMPERATURE JOB #: C Page 72 of 106

74 PEACE RIVER AREA MONITORING PROGRAM COMMITTEE Three Creeks 986b Station - February 2017 STATION TEMPERATURE Hourly Averages (StnTPX C) HR START (MST) 0:00 1:00 2:00 3:00 4:00 5:00 6:00 7:00 8:00 9:00 10:00 11:00 12:00 13:00 14:00 15:00 16:00 17:00 18:00 19:00 20:00 21:00 22:00 23:00 DAILY DAILY 24-HR HR END (MST) 0:59 1:59 2:59 3:59 4:59 5:59 6:59 7:59 8:59 9:59 10:59 11:59 12:59 13:59 14:59 15:59 16:59 17:59 18:59 19:59 20:59 21:59 22:59 23:59 MIN. MAX. AVG. RDGS. DAY HOURLY MAX HOURLY AVG STATUS FLAG CODES C - MONTHLY CALIBRATION Q - QUALITY ASSURANCE C1 - REPEAT CALIBRATION R - RECOVERY Y - MAINTENANCE X - MACHINE MALFUNCTION S - DAILY ZERO/SPAN CHECK G - OUT FOR REPAIR S1 - REPEAT ZERO/SPAN CHECK P - POWER FAILURE 24 HR AVERAGES February 2017 MONTHLY SUMMARY MINIMUM 1-HR AVERAGE: 18.9 HOUR(S) 19 ON DAY(S) 15 MAXIMUM 1-HR AVERAGE: 23.0 HOUR(S) 1, 4 ON DAY(S) 16, 17 MAXIMUM 24-HR AVERAGE: 22.1 C ON DAY(S) VAR-VARIOUS 11 OPERATIONAL TIME: 672 hrs AMD OPERATION UPTIME: % STANDARD DEVIATION: 0.5 MONTHLY AVERAGE: 21.7 C JOB #: C Page 73 of 106

75 PEACE RIVER AREA MONITORING PROGRAM COMMITTEE Three Creeks 986b Station - February 2017 STATION TEMPERATURE Hourly Averages (StnTPX C) 50 StnTPX 1hrAve ( C) StnTPX ( C) Day JOB #: C Page 74 of 106

76 APPENDIX II EQUIPMENT CALIBRATION RESULTS JOB #: C Page 75 of 106

77 SULPHUR DIOXIDE JOB #: C Page 76 of 106

78 Thermo 43C Sulphur Dioxide Analyzer Calibration Date: Company/Airshed: Location/Station Name: Parameter: Start Time 24 hr. (mst): End Time 24 hr. (mst): Calibration Method: February 4, 2017 Barometric Pressure: inhg PRAMP Station Temperature o C: b Weather Conditions: Sunny Sulphur Dioxide Calibration Purpose: shut down 15:20 Performed By/Reviewer: Limin Li Trina Whitsitt 17:28 Cal Gas Expiry Date: December 25, 2018 Gas Dilution Converter Model & s/n (if applicable): n/a Analyzer: ID# or Serial Number: 43C Range ppb: 500 Last Calibration Date: January 10, 2017 As Found C.F.: Previous C.F.: New C.F.: n/a Calibrator: Standard Calibration Points for Ranges Flow Meter ID's: n/a Point ppb Make & Model: Sabio 2010 High 380 Serial #: Mid 180 Cal Gas Cylinder I.D. # : BLM002756T Low 90 Cal Gas Conc. (ppm): 49.9 ALL POINTS ARE 15 MINUTES OF STABILITY AS OF SEPTEMBER 23, 2015 Calibrator Flow Rates (cc/min) Calculated Concentration: Indicated Concentration: Correction Factors (C.F.): Point Diluent Cal Gas Total (ppb) (ppb) - as found zero n/a as found high mid low Average C.F.= Linear Regression/Calibration Results: LIMITS Correlation Coeffecient = > or = Slope = b (Intercept as % of full scale)= 0.08% ± 3% F.S. % change in C.F. from last cal= 2.21% ± 10% Thermo 43C Sulphur Dioxide Analyzer Calibration indicated ppb calculated ppb BKG: COEF: PMT: LAMP: BATTERY: INTERNAL: CHAMBER: PRESSURE: FLOW: INTENSITY: Expected Value: Comments: The analyzer sample inlet filter was changed. As found: As left: 66.3 BKG: n/a COEF: n/a -654 PMT: n/a 839 LAMP: n/a 3.3 BATTERY: n/a 29.7 INTERNAL: n/a 45.5 CHAMBER: n/a PRESSURE: n/a FLOW: n/a INTENSITY: n/a Expected Value: n/a The analyzer cooling fan filter(s) were cleaned. The pump was rebuilt after the shutdown calibration. JOB #: C Page 77 of 106

79 Thermo 43C Sulphur Dioxide Analyzer Calibration Date: Company/Airshed: Location/Station Name: Parameter: Start Time 24 hr. (mst): End Time 24 hr. (mst): Calibration Method: February 4, 2017 Barometric Pressure: inhg PRAMP Station Temperature o C: b Weather Conditions: Sunny Sulphur Dioxide Calibration Purpose: post repair 18:00 Performed By/Reviewer: Limin Li Trina Whitsitt 20:30 Cal Gas Expiry Date: December 25, 2018 Gas Dilution Converter Model & s/n (if applicable): n/a Analyzer: ID# or Serial Number: 43C Range ppb: 500 Last Calibration Date: n/a As Found C.F.: n/a Previous C.F.: n/a New C.F.: Calibrator: Standard Calibration Points for Ranges Flow Meter ID's: n/a Point ppb Make & Model: Sabio 2010 High 380 Serial #: Mid 180 Cal Gas Cylinder I.D. # : BLM002756T Low 90 Cal Gas Conc. (ppm): 49.9 ALL POINTS ARE 15 MINUTES OF STABILITY AS OF SEPTEMBER 23, 2015 Calibrator Flow Rates (cc/min) Calculated Concentration: Indicated Concentration: Correction Factors (C.F.): Point Diluent Cal Gas Total (ppb) (ppb) - adjusted zero n/a adjusted high mid low calibrator zero n/a Average C.F.= Linear Regression/Calibration Results: LIMITS Correlation Coeffecient = > or = Slope = b (Intercept as % of full scale)= 0.14% ± 3% F.S. % change in C.F. from last cal= n/a ± 10% Thermo 43C Sulphur Dioxide Analyzer Calibration indicated ppb calculated ppb BKG: COEF: PMT: LAMP: BATTERY: INTERNAL: CHAMBER: PRESSURE: FLOW: INTENSITY: Expected Value: Comments: The analyzer sample inlet filter was changed. As found: As left: n/a BKG: 72.1 n/a COEF: n/a PMT: -654 n/a LAMP: 838 n/a BATTERY: 3.3 n/a INTERNAL: 29.9 n/a CHAMBER: 45.4 n/a PRESSURE: n/a FLOW: n/a INTENSITY: n/a Expected Value: The analyzer cooling fan filter(s) were cleaned. The pump was rebuilt after the shutdown calibration. JOB #: C Page 78 of 106

80 JOB #: C Page 79 of 106

81 TOTAL REDUCED SULPHUR JOB #: C Page 80 of 106

82 Thermo 43i Total Reduced Sulphur Analyzer Calibration Date: Company/Airshed: Location/Station Name: Parameter: Start Time 24 hr. (mst): End Time 24 hr. (mst): Calibration Method: February 4, 2017 Barometric Pressure: inhg PRAMP Station Temperature o C: b Weather Conditions: Sunny Total Reduced Sulphur Calibration Purpose: routine monthly 15:20 Performed By/Reviewer: Limin Li Trina Whitsitt 19:35 Cal Gas Expiry Date: January 6, 2018 Gas Dilution Converter Model & s/n (if applicable): CD NOVA CDN 101 s/n 516 Analyzer: ID# or Serial Number: Range ppb: 100 Last Calibration Date: January 10, 2017 As Found C.F.: Previous C.F.: New C.F.: Calibrator: Standard Calibration Points for Ranges SO 2 Scrubber Check (10 mins.) Flow Meter ID's: n/a Point ppb Start/End Time 24 hr.: 16:30-16:40 Make & Model: Sabio 2010 High 78 Target Concentration (ppb): 780 Serial #: Mid 38 Result (ppb): 0 Cal Gas Cylinder I.D. # : BLM Low 19 Zero Corrected Result (ppb): 0 Cal Gas Conc. (ppm): 10.2 ALL POINTS ARE 15 MINUTES OF STABILITY AS OF SEPTEMBER 23, 2015 Calibrator Flow Rates (cc/min) Calculated Concentration: Indicated Concentration: Correction Factors (C.F.): Point Diluent Cal Gas Total (ppb) (ppb) - as found zero n/a as found high adjusted zero n/a adjusted high mid low calibrator zero n/a Average C.F.= Linear Regression/Calibration Results: LIMITS Correlation Coeffecient = > or = Slope = b (Intercept as % of full scale)= -0.01% ± 3% F.S. % change in C.F. from last cal= -8.13% ± 10% Thermo 43i Total Reduced Sulphur Analyzer Calibration indicated ppb calculated ppb BKG: COEF: PMT: FLASH: INTERNAL: CHAMBER: PERM OVEN GAS: PERM OVEN HEATER: PRESSURE: SAMPLE FLOW: LAMP INTENSITY: CONVERTER: CONVERTER SET: Expected Value: Comments: The analyzer sample inlet filter was changed. As found: As left: 11.0 BKG: COEF: PMT: FLASH: INTERNAL: CHAMBER: PERM OVEN GAS: PERM OVEN HEATER: PRESSURE: SAMPLE FLOW: LAMP INTENSITY: CONVERTER: CONVERTER SET: Expected Value: 46.7 The analyzer cooling fan filter(s) were cleaned. As-found restarted after regulator was repurged. JOB #: C Page 81 of 106

83 JOB #: C Page 82 of 106

84 Thermo 43i Total Reduced Sulphur Analyzer Calibration Date: Company/Airshed: Location/Station Name: Parameter: Start Time 24 hr. (mst): End Time 24 hr. (mst): Calibration Method: February 5, 2017 Barometric Pressure: inhg PRAMP Station Temperature o C: b Weather Conditions: Sunny Total Reduced Sulphur Calibration Purpose: as found 10:28 Performed By/Reviewer: Limin Li Trina Whitsitt 11:17 Cal Gas Expiry Date: January 6, 2018 Gas Dilution Converter Model & s/n (if applicable): CD NOVA CDN 101 s/n 516 Analyzer: ID# or Serial Number: Range ppb: 100 Last Calibration Date: January 10, 2017 As Found C.F.: Previous C.F.: New C.F.: n/a Calibrator: Standard Calibration Points for Ranges Flow Meter ID's: n/a Point ppb Make & Model: Sabio 2010 High 78 Serial #: Mid 38 Cal Gas Cylinder I.D. # : BLM Low 19 Cal Gas Conc. (ppm): 10.2 ALL POINTS ARE 15 MINUTES OF STABILITY AS OF SEPTEMBER 23, 2015 Calibrator Flow Rates (cc/min) Calculated Concentration: Indicated Concentration: Correction Factors (C.F.): Point Diluent Cal Gas Total (ppb) (ppb) - as found zero n/a as found high Average C.F.= n/a Linear Regression/Calibration Results: LIMITS Correlation Coeffecient = n/a > or = Slope = n/a b (Intercept as % of full scale)= n/a ± 3% F.S. % change in C.F. from last cal= 1.20% ± 10% BKG: COEF: PMT: FLASH: INTERNAL: CHAMBER: PERM OVEN GAS: PERM OVEN HEATER: PRESSURE: SAMPLE FLOW: LAMP INTENSITY: CONVERTER: CONVERTER SET: Expected Value: As found: As left: 12.1 BKG: COEF: PMT: FLASH: INTERNAL: CHAMBER: PERM OVEN GAS: PERM OVEN HEATER: PRESSURE: SAMPLE FLOW: LAMP INTENSITY: CONVERTER: CONVERTER SET: Expected Value: 46.7 Comments: As found done with Sabio sn: calibrator. Feb 4 as -found was 72.1/78.1, 8% drift with calibrator Sabio sn: JOB #: C Page 83 of 106

85 JOB #: C Page 84 of 106

86 TOTAL HYDROCARBON JOB #: C Page 85 of 106

87 Thermo 55i Methane/Non-Methane Analyzer Calibration remove Date: February 5, 2017 Barometric Pressure: inhg Company/Airshed: PRAMP Station Temperature o C: 21 Location/Station Name: 986b Weather Conditions: Sunny Parameter: CH 4 / NMHC / THC Calibration Purpose: routine monthly Start/End Time 24 hr. (mst): 11:22/14:30 Performed By/Reviewer: Limin Li Trina Whitsitt Calibration Method: Gas Dilution Cal Gas Expiry Date: July 7, 2022 Analyzer: ID# or Serial Number: Previous C.F.: Correction Factors: As Found C.F.: New C.F.: Measured Flow: 1062 sccm CH 4 = Last Calibration Date: January 10, 2017 NMHC = Range ppm: 20 CH4/20 NMHC/40 THC THC = Calibrator: Flow Meter ID's: n/a Standard Calibration Points for Analyzer Range of 20/20/40 ppm Make & Model: Sabio 2010 Point CH4 NMHC THC Serial #: High Cal Gas Cylinder I.D. # : LL83638 Mid CH4 Cylinder Conc.= =C 3H 8 Cylinder Conc. Low CH 4 as C 3H 8= =total CH 4 equivilant ALL POINTS ARE 15 MINUTES OF STABILITY AS OF SEPTEMBER 23, 2015 Calibrator Flow Rates (cc/min) Calculated Correction Factors: Calculated Calculated Indicated CH Indicated NMHC 4 Indicated Point Diluent Cal Gas Total Flow CH 4 (ppm) THC (ppm) (ppm) NMHC (ppm) THC (ppm) CH (ppm) 4 NMHC THC as found zero n/a n/a n/a as found high adjusted zero n/a n/a n/a adjusted high mid low calibrator zero n/a n/a n/a Linear Regression/Calibration Results: CH 4 NMHC THC LIMITS Average C.F.= Correlation Coeffecient = > or = Slope = b (Intercept as % of full scale)= 0.11% 0.03% 0.07% ± 3% F.S. % change in C.F. from last cal= 6.06% 5.23% 5.70% ± 10% As found: As left: Interface Board Voltages: Bias Supply: Calibration History cnt'd: NM Peak Area: Temperatures: Detector Oven: Crucial Settings: Methane Start: 8 Filter: Methane End: 16 Column Oven: 75.0 Backflush: 18 Internal: 33.8 NMHV Start: 30 Cylinder Pressures/reg.: Carrier: NMHC End: 56 Fuel: Run History>1: Date: 05FEB17 Span Gas: Time: 11:21 Zero Air Generator: 45 CH 4 PK HT: 2564 Internal Pressures: Carrier: 31.3 CH 4 RT: 12.4 Fuel: 40.5 CH 4 Baseline: 1573 Air: 32.4 CH 4 LOD: 22 FID Status: Status: LIT CH 4 SD: 7 Counts: CH 4 CONC: 2.02 Flame: NM PK HT: 0 Det Base: 175 NM Peak Area: 0 Flame and Power Stats: Last Power On: 05Jan2017@13:21 NM CONC: 0 Flameouts: 3 NM Base Start: 1587 Det Oven at Start: 32.8 NM Base End: 1579 Col Oven at Start: 29.9 NM LOD: 8 Calibration History: Time: 10JAN17 12:35 NM Start IDX: 4 Type: SPAN NM End IDX: 37 Status: GOOD NM Max Slope: 3.6e-01 Check/Adjust: ADJUST NM Min Slope: -4.7e-01 CH 4 Span Conc: NM PT Count: 0 CH 4 SP Ratio: Expected Values: Previous CH4: CH 4 RT: 12.6 Previous NMHC CH 4 PK IDX: 23 Previous THC: CH 4 PK HT: New CH4: 8.84 NM Span Conc: New NMHC NM SP Ratio: New THC: Comments: The analyzer sample inlet filter was changed. A new nitrogen cylinder was installed. No zero adjustment was required/made. As found zero values were copied to adjusted zero values for linearity calculation purposes. JOB #: C Page 86 of 106

88 Date: Company/Airshed: Location/Station Name: February 5, 2017 Start/End Time 24 hr. (mst): 11:22/14:30 PRAMP Calibration Purpose: routine monthly 986b Calibration Method: Gas Dilution CH 4 Calibration Graph indicated ppb calculated ppb 16 NMHC Calibration Graph indicated ppb calculated ppb 35 THC Calibration Graph indicated ppb calculated ppb JOB #: C Page 87 of 106

89 JOB #: C Page 88 of 106