NANOTUBES ON PAR WITH COPPER INTERCONNECTS IMPRESSIVE DISPLAY DEMONSTRATIONS IMPRESSIVE DISPLAY DEMONSTRATIONS (CONTINUED)...

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Job Manning
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1 CHAPTER ONE: OVERVIEW... 1 PROGRESS IN NANOTECHNOLOGY... 1 TABLE 1 NANOTECH INVESTMENTS REPORTED IN TABLE 2 NANOTECHNOLOGY DRIVEN PARTNERSHIPS, TABLE 2 (CONTINUED)... 3 TABLE 3 EMERGING NANOTECHNOLOGY MARKET ACTIVITIES, TABLE 4 CARBON NANOTUBE COMMERCIAL DEVELOPMENTS, TABLE 5 SELECTED NANOMATERIAL PRODUCTS COMMERCIALIZED, TABLE 5 (CONTINUED)... 6 MARKET ASSESSMENT OF NANOTECHNOLOGY... 6 REPORT HIGHLIGHTS... 7 FIGURE 1 GLOBAL NANOTECHNOLOGY MARKET, THROUGH QUANTUM DOTS: TECHNICAL STATUS AND MARKET PROSPECTS... 8 FIGURE 2 GLOBAL MARKET GROWTH FOR QUANTUM DOTS IN PROMISING COMMERCIAL MARKET SECTORS, ($ MILLIONS)... 9 NEW FUNDING FOR TELECOMMUNICATION QD LASER PRODUCTS FUNDING BOOSTS QUANTUM DOT SOLAR CELL PRODUCTS NEWER CARBON NANOTUBES AND QUANTUM DOT PRODUCTS NANOPARTICLE TARGETING CANCER CHAPTER TWO: PROCESSING AND CHARACTERIZATION NANO-LIMITS IN TRANSMISSION ELECTRON MICROSCOPY TRANSMISSION NANOSCALE IMAGING DYNAMICS IMAGES OF GRAPHENE FIGURE 3 TEAM IMAGE OF GRAPHENE Images of Graphene (Continued) FABRICATION METHOD FOR GRAPHENE NANOELECTONICS CARBON NANOTUBE-GRAPHENE COMPOSITE FIGURE 4 CNT-GRAPHENE COMPOSITE STRUCTURE GRAPHENE BASED NANOELECTRONIC DEVICES INSIGHTS INTO GRAPHENE S PROPERTIES FIGURE 5 GRAPHENE S UNIQUE LATENT PROPERTIES ELECTROWETTING IN NANOFLUIDS... 24

2 FIGURE 6 NANOPARTICLES MODIFY ELECTROWETTING COPPER NANORODS INCREASE BOILING EFFICIENCY NANOIMPRINT LITHOGRAPHY ATTRACTS GOVERNMENT SUPPORT HIGHER RESOLUTION IN ELECTRON MICROSCOPY D IMAGES OF COMMON VIRUS STRUCTURE FIGURE 7 CRYO-EM IMAGE OF A COMMON VIRUS D TRANSMISSION ELECTRON MICROSCOPY IMAGING S COMMERCIAL REALITY TRUE COLOR ADDED TO ELECTRON MICROSCOPY FIGURE 8 STEM/ELECTRON ENERGY LOSS SPECTROSCOPY NANOFIBERS AND 3D STRUCTURES MORE APPLICATIONS OF NANOEMULSIONS MEASURING NANOSCALE LIQUID VISCOSITY FIGURE 9 ATOMIC FORCE MICROSCOPY LIQUID RHEOMETER FIGURE 10 MICROWAVE SYNTHESIS OF QUANTUM DOTS SYNTHESIS OF NANOPARTICLE FOR BIOCHEMISTRY FIGURE 11 LAB-ON-A-CHIP MICROFLUIDICS NANOPARTICLE SYNTHESIS SELF-ASSEMBLY SINGLE WALLED NANOTUBES NANOPARTICLE COLLOIDAL STABILIZATION MAGNETIC SHAPE-MEMORY ALLOY FIGURE 12 SEM OF POLYCRYSTALINE SHAPE MEMORY ALLOY CONDUCTIVE NANONETS MAY IMPROVE WIRES PROGRESS IN INSTRUMENTATION HIGH-RESOLUTION TRANSMISSION MICROSCOPY CAPTURES FULLERENE GROWTH CHEMICAL FORCE MICROSCOPY MEASURES CARBON NANOTUBE INTERACTIONS PROCESS FOR NANOFIBER POLYMER COMPOSITES LIQUID REPELLANT COATINGS FOR INDUSTRIAL APPLICATIONS SUPER WATER REPELLENT COATING SUPER OIL REPELLENT COATING CHAPTER THREE: ELECTRONICS, OPTICS AND OPTOELECTRONICS HIGHER RESOLUION OPTICAL IMAGING FIGURE 13 SCHEMATIC OF NANOWIRE METAMATERIAL FIGURE 14 POROUS METAMATERIAL SINGLE WALLED CARBON NANOTUBE ELECTRONICS CARBON NANOTUBE TRANSISTOR COATING PROCESS GIANT NANOCAPACITOR MEMORY CARBON NANOTUBE LOGIC CIRCUITS NANOSCALE SWITCHABLE ELECTRICAL PROPERTIES ORGANIC ELECTRONICS ON POLYMER SHEETS... 57

3 NANOTUBES ON PAR WITH COPPER INTERCONNECTS IMPRESSIVE DISPLAY DEMONSTRATIONS IMPRESSIVE DISPLAY DEMONSTRATIONS (CONTINUED) EASE OF FABRICATION FOR SEMICONDUCTOR DEVICES EASIER SORTING BRINGS NANOELECTRONICS CLOSER TO REALITY FLEXIBLE ELECTRONICS CLOSER TO REALITY FIGURE 15 FLEXIBLE CIRCUITS CREATED USING CARBON NANOTUBES POLYMER-BASED LITHOGRAPHY IMPROVES DEVICE MINIATURIZATION THEORY SUGGESTS NEW GENERATION OF ELECTRONIC MATERIALS FIGURE 16 POSSIBLE NEW GENERATION OF ELECTRONIC MATERIALS PHOTONIC CRYSTAL CREATES LOW POWER OPTICAL MEMORY FIGURE 17 PHOTONIC CRYSTAL MEMORY: STRUCTURE OF NEW INGAASP PHOTONIC CRYSTAL DEVICE PARTICLE SELF-ASSEMBLY PROCESS AIDS OPTICAL MATERIALS FIGURE 18 FABRICATION OF A NEAR PERFECT 2D COLLOIDAL CRYSTAL MODEL TO UNDERSTANDING LASING WITHOUT INVERSION ADVANCES IN CONVENTIONAL MICROPROCESSOR TECHNOLOGY NANOSCALE DETAILS IN PHOTORESISTS Nanoscale Details (Continued) FIGURE 19 SCHEMATIC OF THE PHOTOLITHOGRAPHY PROCESS SINGLE WALLED NANOTUBES DIRECTED ASSEMBLY AT SEMICONDUCTOR SWNT-BASED TRANSISTOR EVALUATED SYNTHETIC DIAMOND DEVICE FABRICATION VERTICALLY ALIGNED CARBON NANOTUBES CREATE THE DARKEST MATERIAL SILICON TRANSISTORS BENEFIT FROM QUANTUM SIZE EFFECTS PRACTICAL DEVELOPMENTS IN METAMATERIALS NEGATIVE INDEX OF REFRACTION FIGURE 20 SCHEMATIC OF ARTIFICALLY STRUCTURED METAMATERIALS INDEX OF REFRACTION Negative Index (Continued) D GOLD PHOTONIC METAMATERIALS FIGURE 21 3D GOLD PHOTONIC METAMATERIALS NANOLASER PROMISES MEMORY CAPACITY BREAKTHROUGH FIGURE 22 NANOLASER-BASED MEMORY SCANNING... 84

4 PROCESS FOR FLEXIBLE SILICON ICS HERALDS NEW APPLICATIONS FIGURE 23 PROCESS FOR FLEXIBLE SILICONICS HERALDS NEW APPLICATIONS NANOWIRES KEY TO NEW GENERATION OF AMOLED DISPLAYS MANIPULATING BLOCK COPOLYMERS FIGURE 24 INDUCING ORDER IN POLYMER DISORDER SEMI-TRANSPARENT CONDUCTIVE CNTS DEMONSTRATE TUNABLE COLOR RISK ASSESSMENT OF MANUFACTURED CNTS SYNTHESIZING MAGNETIC NANOPARTICLES NATURALLY FIGURE 25 BACTERIA INDUCE ORDER IN MAGNETIC NPS MODEL PREDICTS DEFECT FREE NANOPARTICLE SELF- ASSEMBLY MODEL PREDICTS DEFECT FREE (CONTINUED) CHAPTER FOUR: ENERGY AND ENVIRONMENT TUNGSTEN OXIDE NANOTUBES AS INDOOR PHOTOCATALYSTS FIGURE 26 HIGH SURFACE AREA TUNGSTEN OXIDE NANOTUBES FIGURE 27 PHOTOCATALYTIC ACTIVITY UNDER VISIBLE LIGHT IRRADIATION NANOFIBER-NP FABRICS TARGET TOXIC CHEMICAL PROTECTION FIGURE 28 NYLON NANOFIBERS COATED WITH METAL NANOPARTICLES RESEARCHING LOWER COST COPPER-INDIUM-GALLIUM- SELENIDE SOLAR CELLS RESEARCHING LOWER (CONTINUED) NANOSOLAR ACHIEVES HIGH CIGS THROUGHPUT NANOMATERIALS PROMISE ENHANCED ENERGY HARVESTING NANOPARTICLES MAY AID LARGE COOLING SYSTEMS NANOPARTICLES MAY AID (CONTINUED) SURFACE TEXTURING IMPROVES SOLAR EFFICIENCY NANOROD SYNTHESIS PROMISES THERMOELECTRICS IMPROVEMENTS CNTS HYDROGEN STORAGE CAPACITY EXCEEDS DOE GOAL KONARKA DEMONSTRATES INKJET PRINTED SOLAR CELLS SAUDI S AND IBM CREATE NT SUSTAINABLE RESOURCES CENTER DIESEL EXHAUST PUTS NANOPARTICLES IN LUNGS CLIMATE CHANGE AND CARBON CAPTURE ENZYME-LADEN NANOPARTICLES SEQUESTER GREENHOUSE GASES

5 SYNTHETIC ZEOLITES OFFER CARBON DIOXIDE CAPTURE RUBBING SHOULDERS WITH NANO- WIRES YIELDS PORTABLE POWER CARBON AEROSOL NANOPARTICLES HELP IN CLIMATE FORECAST EFFICIENT THERMOELECTRIC MATERIALS THERMOELECTRIC PERFORMANCE OF ROUGH SILICON NANOWIRES FIGURE 29 THERMOELECTRIC MATERIAL COMPRISING ROUGH SILICON NANOWIRE ARRAYS ENERGY-EFFICIENT RECTANGULAR SILICON NANOWIRES NANOCATALYST AIDS HYDROGEN FUEL CELL EFFICIENCY FIGURE 30 SCHEMATIC STRUCTURE FORMED BY SURROUNDING RU NANOPARTICLES MESOPOROUS METAL OXIDES SYNTHESIS FIGURE 31 NOVEL MESOPOROUS METAL OXIDE SYNTHESIS WATER PROPERTIES DICTATE FATE OF NANOPARTICLES NANOWIRE-POLYMER MAY BOOST SOLAR CELL EFFICIENCY FIGURE 32 NOVEL NANOWIRE-POLYMER SOLAR CELL CANADA INVESTS IN FUEL CELL INDUSTRY RESEARCH ON HYDROGEN STORAGE IN NANOPARTICLES FIGURE 33 SCHEMATIC DEPICTION OF H2 (GREEN) STORAGE EFFICIENT SILICON NANOWIRE SOLAR CELL RIT S RENEWABLE ENERGY AND SUSTAINABILITY BOOSTED FLEXIBLE NANOANTENNAS AID SOLAR HARVESTING FLEXIBLE NANOANTENNAS PROMISE FIGURE 34 PLASTIC SHEET OF NANOANTENNA ARRAYS CNT X-RAY SOURCE TO UNDERGO AIRPORT EXPLOSIVES SCREENING ADVERSE EFFECTS OF NANOPARTICLE VEHICLE EMISSIONS FIGURE 35 IMPACT OF FREEWAY AIR POLLUTANT PARTICLES PAINT NANOPARTICLES SCAVENGE POWER PLANT MERCURY EMISSIONS HIGHER SURFACE AREA SHOULD BOOST SOLAR CELL EFFICIENCY FIGURE 36 DYE-SENSITIZED SOLAR CELLS CHAPTER FIVE: BIOTECHNOLOGY AND DRUG DELIVERY STRONG ANTIMICROBIAL COATINGS PROMISE WIDESPREAD USAGE FIGURE 37 COMPOSITE STRUCTURE NANO EMULSION VACCINES SHOW POTENTIAL FIGURE 38 DISPERSION OF OIL-IN-WATER EMULSION- CONTAINING VACCINES

6 NOVEL CELL IMAGING FOR CANCER/DRUGS QUANTUM DOTS IN FOOD CHAIN MAY NOT POSE HIGH RISK FIGURE 39 QUANTUM DOTS IN FOOD CHAIN AQUATIC ORGANISMS COLLOIDAL NANOPARTICLE SYSTEMS PROMISE ADVANCES IN NANOMEDICINE SMALLER MAGNETIC NPS IMPROVE CANCER DETECTION FIGURE 40 NEW SMALLER MAGNETIC NPS ENHANCE CANCER DETECTION NANOPARTICLES IMAGE, TARGET, AND TREAT TUMORS MASS-PRODUCTION OF TUNABLE MAGNETIC NANOPARTICLES DENDRIMER-FUNCTIONALIZED MAGNETIC NANOPARTICLES POLYMER MICELLES PAVE WAY FOR CANCER TREATMENT FIGURE 41 POLYMER MICELLE AIDS CANCER TREATMENT NANOSUSPENSION FOR DELIVERY OF NON-SOLUBLE DRUGS THE MICROFLUIDICS REACTION TECHNOLOGY PROCESS FIGURE 42 PRINCIPAL OF OPERATION OF MICROFLUIDICS REACTION TECHNOLOGY MRT EXPERIMENTAL RESULTS TABLE 6 CRYSTALLIZATION RESULTS USING MICROFLUIDICS REACTION TECHNOLOGY NANOSUSPENSIONS DEVELOPMENT ROADMAP MRT NANOSUSPENSION PROCESSING SUMMARY TELOMERASE AND ITS POTENTIAL CANCER ROLE IMAGING NANOPARTICLES REVEALS ADVERSE EFFECTS POLYMER PEN LITHOGRAPHY FIGURE 43 PRINTING VIA POLYMER PEN LITHOGRAPHY NANOMATERIALS MAY IMPACT TOXICITY AND BIOLOGICAL ACTIVITY QUANTUM DOTS AID GENE SILENCING IN LIVE HUMAN CELLS FIGURE 44 LIVE CELL FLUORESCENT IMAGES LIGHT ACTIVATED CNTS DESTROY ANTHRAX TOXIN FIGURE 45 TEM IMAGES OF CNTS CONJUGATED WITH ANTHRAX TOXIN TUMOR EMBEDDED CARBON NANOTUBES ENHANCE CANCER DESTRUCTION ENHANCING IN VIVO IMAGING QUANTUM RODS TRAVERSE THE BLOOD-BRAIN BARRIER TARGETED PROBES FOR EFFICIENT TRANSMIGRATION

7 ASSAY SCREENING FOR NANOPARTICLE CYTOTOXICITY DEVELOPMENTS IN BIONANOTECHNOLOGY COMMERCIALIZATION OF NANOPORE DNA SEQUENCING FIGURE 46 PROTEIN NANOPORE: SCHEMATIC PROGRAMMABLE-SIZED DNA TUBES MAY AID NANOSCALE MANUFACTURING DEVELOPMENTS IN LAYER-BY-LAYER TECHNOLOGY DEVELOPMENTS IN LAYER- (CONTINUED) TWO-PHOTON POROUS SILICON NPS ENHANCE CELL DETECTION FIGURE 47 MONOLAYER- FUNCTIONALIZED POROUS NPS CHAPTER SIX: CARBON NANOSTRUCTURES BUCKYPAPER COMPOSITES ENABLED BY TUNABLE MECHANICS MODEL FIGURE 48 ATOMIC FORCE MICROGRAPH FIGURE 49 SCHEMATIC OF MODEL CARBON NANOTUBE SYNTHESIS USING THEMOSET RESINS NOVEL NANOPOWER STORAGE AIMS TO TAP NEW MARKET BUCKYPAPER SUPERCAPACITOR SHOWS SIGNIFICANT STORAGE POTENTIAL FIGURE 50 BUCKYPAPER-BASED (SWNT) POLYMER COMPOSITE ELECTROWETTING KEEPS BATTERY GOING THIN-FILM RECHARGEABLE LITHIUM BATTERIES CARBON DIOXIDE -TO-FUEL PROTOTYPE FIGURE 51 INEXPENSIVE BIOCATALYTIC CO2-TO-FUEL PROCESS EUROPE COMMITS TO MAJOR FUEL CELL/H2 INITIATIVE CARBON NANOTUBES-RUBBER COULD BE USED IN ROBOTIC SKINS AND E-DISPLAYS FIGURE 52 RESEARCHER HOLDING A HIGHLY CONDUCTIVE ELASTIC SHEET BIOGENIC AS-S NANOTUBES PROMISE GREEN ELECTRONICS DENSE ARRAYS OF LONG CNTS CARBON NANOTUBES FIGURE 53 GROWTH OF STRAIGHT, LONG, DENSE SINGLE WALLED NANOTUBES CENTRIFUGATION PROCESS SORTS CARBON NANOTUBES FIGURE 54 SORTING CNTS BY LENGTH GRAPHENE ENHANCES POLYMER NANOCOMPOSITES GRAPHENE ENHANCES POLYMER (CONTINUED) MICROELECTRODE PROCESS AIDS USE IN SENSORS AND FUEL CELLS Microelectrode Process Aids (Continued) CHAPTER SEVEN: ADMINISTRATIVE WATCH REGULATORY STAGE FOR NEXT ADMINISTRATION

8 BUDGET REQUEST REFLECTS STEADY GROWTH CANADIAN NANOPRODUCTS STUDY NNI UPDATES STRATEGIC PLAN ENERGY RESEARCH CENTERS AND NT-BASED FUNDING DIRECT CONVERSION OF SOLAR ENERGY TO ELECTRICITY AND CHEMICAL FUELS UNDERSTANDING OF HOW BIOLOGICAL FEEDSTOCKS ARE CONVERTED INTO PORTABLE FUELS ADDRESSING FUNDAMENTAL KNOWLEDGE GAPS IN ENERGY STORAGE TRANSFORMING ENERGY UTILIZATION AND TRANSMISSION SCIENCE-BASED GEOLOGICAL CARBON SEQUESTRATION KOREAN GOVERNMENT SUPPORTS U.S. NANOCOMPOSITES RESEARCH REPORT CHALLENGES COMMERCIAL PROLIFERATION OF NANOSILVER NANO FORMS OF CARBON RAISE EU SAFETY CONCERNS CNT MANUFACTURER RECEIVES EPA APPROVAL CNT MANUFACTURER RECEIVES (CONTINUED) CHAPTER EIGHT: INDUSTRY NEWS NANOPARTICLES MANUFACTURER MEETS NIOSH GUIDELINES CONSORTIUM TARGETS OPTIMIZED NP DISPERSION PROCESS OXONICA S WOES DEEPEN FURTHER NANOSAFE S SAFE TESTED PRODUCT REGISTRY FIGURE 55 NANOSAFE TESTED MARK EU-FUNDED PROJECT TARGETS NTS PROS AND CONS UC DAVIS LICENSES SOLAR KNOW-HOW TO Q1 NANOSYSTEMS UNIDYM RAMPS UP CNT PRODUCTION TO MEET DEMAND CHIP CHARACTERIZATION NANOGRAPHENE PLATELET PRODUCTION SCALES UP STRATEGIC ALLIANCE STRENGTHENS LIGHTWEIGHT PRODUCT PERFORMANCE E-BEAM ON-A-CHIP MOVES TO PILOT COMMERCIAL PRODUCTION GLOBAL ALLIANCE PROMISES IMPARTIALITY CNT-BASED COMPOSITE FLIES HIGH IN FIRST AERIAL TESTS FIRST COMMERCIAL BIOMEDICAL DENDRIMER PRODUCTS LAUNCHED GRAPHITE NANOPLATELETS POTENTIAL MICHIGAN STATE SCIENTISTS GET AWARD METHOD FOR LARGE-SCALE GRAPHENE SHEETS

9 FIGURE 56 LARGE SCALE GRAPHENE SHEET DIAMONDOIDS LAUNCHED FOR COATING APPLICATIONS CONVENTIONAL TOP DOWN PUSHED TO NEXT LIMIT CHAPTER NINE: BRIEFLY NOTED APPLIED MATERIALS EXPANDS MANUFACTURING NANOCOMP AWARDEDBODY ARMOR CONTRACT FEI S STRONG REVENUE GROWTH CONTINUES IBM EARMARKS $1.5 BILLION NT INVESTMENT MICROFLUIDICS APPOINTS NEW CTO FEI LAUNCH EXTREME HIGH RESOLUTION SEM HITACHI SHOWCASES STATE-OF-THE-ART SEM

TABLE OF CONTENTS 1 RESEARCH SCOPE AND METHODOLOGY Report scope Market definition Categorization...

TABLE OF CONTENTS 1 RESEARCH SCOPE AND METHODOLOGY... 15 1.1 Report scope... 15 1.2 Market definition... 15 1.2.1 Categorization.... 16 1.3 Research methodology... 17 1.4 Assumptions and limitations...