Benetton Group Restricted Substances List (RSL) contains the complete list of banned or restricted chemical substances.
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1 TEST REPORT Facility: SHI SHI ZHANYAO TEXTILE TECHONOLOGY CO., LTD Country: China Address: Dabao Industrial Zone, Shishi City, Fujian, China Date of report: Feb 03, 2016 INTRODUCTION Benetton Group has a relevant experience of environmentally responsible business practices and is putting significant resources and passion on its environmental program with the objective to minimize the impact of all its activities and preserve the natural resources for present and future generations. Benetton Group Restricted Substances List (RSL) contains the complete list of banned or restricted chemical substances. In line with the Company s commitment to zero discharges of hazardous substances by 2020, chemical investigations are regularly conducted by independent external auditors considering the following groups of hazardous chemical substances and using the lowest detection limits currently available with the best in class chemical laboratories around the world: PRIORITY CHEMICAL GROUPS 1. Alkylphenols 2. Phthalates 3. Brominated and chlorinated flame retardants 4. Azo dyes 5. Organotin compounds 6. Perfluorinated chemicals 7. Chlorobenzenes 8. Chlorinated solvents 9. Chlorophenols 10. Short chain chlorinated paraffins 11. Heavy metals such as cadmium, lead, mercury and chromium (VI). The findings are meant to highlight the current level of use (at times also unintentional) of the above chemical groups through a comparison of the incoming, UNTREATED wastewaters (i.e. samples are collected upstream of any wastewaters treatment plant) and treated wastewater (if there is. i.e. samples are collected downstream of self-owned Effluent Treatment Plant). The comparison is in fact a valuable tool to identify if and in which formulations, used by the Page 1 of 9
2 facility, the above chemical groups might be contained, helping to subsequently identify potential alternatives of assessed lower impact. For every specific situation an action plan is designed and a monitoring procedure is put in place to avoid non viable substitutions. Page 2 of 9
3 Facility details and analysis results Date: FEB 03, 2016 Facility Name: SHI SHI ZHANYAO TEXTILE TECHONOLOGY CO., LTD Address: Dabao Industrial Zone, Shishi City, Fujian, China Activity: Sample Description: Two (2) Samples: (1) Transparent Liquid, Incoming Water, Tap Water, Collected During Operating Hours on Jan. 14 th, 2016 (2) Dark Blue Liquid with Turbidity, Untreated Discharge Water, Collected During Operating Hours on Jan. 14 th, 2016 The water samples were collected and tested by Intertek. SUMMARY Test Items Result Azodyes (Banned Aromatic Amines) - Chlorinated Solvents Phthalates - Brominated and Chlorinated Flame - Retardants Organic Tin Compounds - Chlorophenols - Short-Chain Chlorinated Paraffins (C C 13) Heavy Metals Alkylphenol ethoxylates/alkylphenols(apeos/aps) Perfluorinated Chemicals (PFCs) - Chlorinated Benzenes Cyanide Note/ Key Detected Not Detected - Not Tested Page 3 of 9
4 Detection of Amines Derived from Azocolourants and Azodyes With Reference to EN 14362:1&3, by Gas Chromatographic - Mass Spectrometric (GC-MS) and High Performance Liquid Chromatographic - Diode Array Detector(HPLC-DAD) Analysis. 1,4-Phenylenediamine ND 2,4,5-Trimethylaniline ND 2,4-Diaminoanisole ND 2,4-Diaminotoluene ND 2,4-Xylidine ND 2,6-Xylidine ND 2-Chloroaniline ND 2-Naphthylamine ND 3,3'-Dichlorobenzidine ND 3,3'-Dimethoxybenzidine ND 3,3'-Dimethyl-4,4' ND diaminodiphenylmethane 3,3'-Dimethylbenzidine ND 4,4'-Diaminodiphenylmethane ND 4,4'-Methylene-bis(2-chloroaniline) ND 4,4'-Oxydianiline ND 4,4'-Thiodianiline ND 4-Aminobiphenyl ND 4-Chloroaniline ND 4-Chloro-o-toluidine ND 5-Nitro-o-anisidine ND 5-Nitro-o-toluidine ND 4-Aminoazobenzene ND Aniline ND Benzidine ND m-toluidine ND n,n-diethylanaline ND n-ethylaniline ND n-methylaniline ND o-aminoazotoluene ND o-anisidine ND o-toluidine ND p-cresidine ND p-toluidine ND Remark: ND= Not detected Detection limit = 0.1µg/L - = Not Tested Page 4 of 9
5 Chlorinated Solvents By Headspace Gas Chromatography Mass Spectrometric (HS-GC/MS) Analysis. Carbon tetrachloride ND ND Pentachloroethane ND ND 1,1,1-trichloroethane ND ND 1,1,1,2-tetrachloroethane ND ND 1,1,2,2-tetrachloroethane ND ND Chloroform ND 9 1,1,2-trichloroethane ND ND 1,1-dichloroethylene ND ND Trichloroethylene ND ND Tetrachloroethylene ND ND 1,2-dichloroethane ND ND Dichloromethane ND ND Remark: ND= Not detected Detection limit = 1µg/L Phthalates Solvent Extraction and by Gas Chromatography-Mass Spectrometry (GC-MS) Analysis. Di-iso-butyl-phthalate(DIBP) ND Di-butyl-phthalate(DBP) ND Benzyl-butyl-phthalate(BBP) ND Di-(2-ethyl-hexyl)-phthalate(DEHP) ND Di-n-octyl-phthalate(DNOP) ND Di-iso-nonyl-phthalate(DINP) ND Di-iso-decyl-phthalate(DIDP) ND Di-methyl-phthalate(DMP) ND Di-ethyl-phthalate(DEP) ND Di-n-propyl-phthalate(DPrP / DPP) ND Di-iso-pentyl-phthalate(DIPP) ND Di-n-hexyl-phthalate(DNHP) ND Di-cyclo-hexyl-phthalate(DCHP) ND Di-iso-heptyl-phthalate(DIHP) ND Di-iso-octyl-phthalate(DIOP) ND Di-nonyl-phthalate(DNP) ND Bis-(2-methoxy-ethyl)-phthalate(DMEP) ND 1,2-Benzene-di-carboxylic acid di-pentyl-esters, ND branched and linear N-iso-pentyl-iso-pentyl-phthalate(PIPP) ND 1,2-Benzene-di-carboxylic acid, di-c 7, 11-branched and ND linear alkyl esters(dhnup) Remark: ND= Not detected Detection limit = 1µg/L - = Not Tested Page 5 of 9
6 Brominated and Chlorinated Flame Retardants Solvent Extraction and by Liquid Chromatography - Mass Spectrometry (LC-MS) and Gas Chromatography - Mass Spectrometry (GC-MS) Analysis. Detection Limit (µg/l) Polybrominated Biphenyles(PBBs) various Bromo-biphenyl - -- ND 0.05 Di-bromo-biphenyl - -- ND 0.05 Tri-bromo-biphenyl - -- ND 0.05 Tetra-bromo-biphenyl - -- ND 0.05 Penta-bromo-biphenyl - -- ND 0.05 Hexa-bromo-biphenyl - -- ND 0.05 Hepta-bromo-biphenyl - -- ND 0.05 Octa-bromo-biphenyl - -- ND 0.05 Nona-bromo-biphenyl - -- ND 0.05 Deca-bromo-biphenyl ND 0.05 Polybrominated Diphenyl ethers(pbdes) various Bromo-diphenyl-ether - -- ND 0.05 Di-bromo-diphenyl-ether - -- ND 0.05 Tri-bromo-diphenyl-ether - -- ND 0.05 Tetra-bromo-diphenyl-ether - -- ND 0.05 Penta-bromo-diphenyl-ether - -- ND 0.05 Hexa-bromo-diphenyl-ether - -- ND 0.05 Hepta-bromo-diphenyl-ether - -- ND 0.05 Octa-bromo-diphenyl-ether - -- ND 0.05 Nona-bromo-diphenyl-ether - -- ND 0.05 Deca-bromo-diphenyl-ether ND 0.05 Hexa-bromo-cyclo-dodecan(HBCDD) ND 0.5 Tri-(2,3-di-bromo-propyl)-phosphate(TRIS) ND 0.5 Tetra-bromo-bisphenol-A(TBBPA) ND 0.5 Tetra-bromo-bisphenol A bis-(d-ibromopropyl-ether)(tbbpa-bdpe) ND 0.5 Bis-(2,3-di-bromo-propyl)-phosphate ND 0.5 Tris-(2-chloro-ethyl)-phosphate(TCEP) ND 0.05 Tris-(1,3-di-chloro-iso-propyl)- phosphate(tdcpp) ND 0.05 Tris-(2-chloroisopropyl)-phosphate(TCPP) ND 0.5 ***************************************************************************************************************************************************** Page 6 of 9
7 Organic Tin Compounds With Reference to DIN EN 17353, by Gas Chromatography-Mass Spectrometry (GC-MS) Analysis. Compound(s) Result (µg/l) Monobutyltin (MBT) -- ND Dibutyltin (DBT) -- ND Tributyltin (TBT) -- ND Triphenyltin (TPhT) -- ND Dioctyltin (DOT) -- ND Monooctyltin (MOT) -- ND Tetrabutyltin (TeBT) -- ND Trioctyltin(TriOT) -- ND Tricyclohexyltin(TCyHT) -- ND Tripropyltin (TPT) -- ND Remark: ND= Not detected Detection limit =0.01µg/L Chlorophenols Solvent Extraction and Acetylated by Acetic Anhydride, and Analyzed by Gas Chromatography-Mass Spectrometry (GC-MS). Pentachlorophenol (PCP) ND Tetrachlorophenols (TeCP) ND Trichlorophenols (TriCP) Various -- ND Dichlorophenol (DiCP) Various -- ND Monochlorophenol Various -- ND Detection limit = 0.5µg/L Short-Chain Chlorinated Paraffins (C 10-C 13) Solvent Extraction and by Liquid Chromatography - Mass Spectrometry (LC-MS) Analysis. Short-chain chlorinated paraffins (C 10-C 13) ND Detection limit = 0.4µg/L Page 7 of 9
8 Heavy Metals By Inductively Coupled Argon Plasma-Mass Spectrometry(ICP-MS) Analysis and by Ion Chromatography- Inductively Coupled Argon Plasma-Mass Spectrometry(IC-ICP-MS) Analysis. Compound(s) CAS No. Result (µg/l) Detection Limit (µg/l) Total Cadmium(Cd) ND ND 0.1 Total Lead(Pb) ND ND 1 Total Mercury(Hg) ND ND 0.5 Total Hexavalent ND ND 1 Chromium(Cr-VI) Total Arsenic (As) ND ND 1 Total Antimony (Sb) ND ND 1 Total Cobalt (Co) ND ND 1 Total Nickel (Ni) ND 5 1 Total Copper (Cu) ND Total Zinc (Zn) ND 39 1 Total Manganese (Mn) ND 33 1 Total Chromium (Cr) ND 6 1 Alkylphenol ethoxylates/alkylphenols(apeos/aps) Solvent Extraction and by Gas Chromatography-Mass Spectrometry (GC-MS) and by Liquid Chromatography-Mass Spectrometry (LC-MS/MS) Analysis. Detection Limit (µg/l) Nonylphenols ND Octylphenols ND ND Nonylphenolethoxylates ND ND 2.5 Octylphenolethoxylates ND ND 2.5 Nonylphenolethoxylates ND ND 5 Octylphenolethoxylates ND ND 5 Page 8 of 9
9 Perfluorinated Chemicals (PFCs) By Liquid Chromatography Mass Spectrometry (LC-MS/MS) Analysis. Perfluorooctane sulphonates (PFOS) ND Perfluoro-octane-sulfon- amide(pfosa) ND N-Methyl-Perfluoro-octane-sulfon-amide(N-Me- FOSA) ND N-Ethyl-Perfluoro-octane-sulfon-amide(N-Et- FOSA) ND N-Methyl-Perfluoro-octane-sulfon-amidoethanol(N-Me-FOSE alcohol) ND N-Ethyl-Perfluoro-octane-sulfon-amido-ethanol(N ND Et-FOSE alcohol) Perfluoro-octane acid ND Perfluoro-butanoic acid ND Perfluoro-pentanoic acid ND Perfluoro-hexanoic acid ND Perfluoro-heptanoic acid ND Perfluoro-nonanoic acid ND Perfluoro-decanoic acid ND Perfluoro-undecanoic acid ND Perfluoro-dodecanoic acid ND Perfluoro-tridecanoic acid ND Perfluoro-tetradecanoic acid ND Perfluoro-butane-sulfonic acid ND / Perfluoro-hexane-sulfonic acid -- ND Perfluoro-heptane-sulfonic acid ND Perfluor-decane-sulfonic acid ND 1H,1H,2H,2H-Perfluoro-octane-sulphonic acid ND 2H,2H,3H,3H-Perfluoro-undecanoic acid ND Perfluoro-3-7-dimethyl octane carboxylate ND 7H-Dodecafluoro heptane carboxylate ND Detection limit = 0.2µg/L Page 9 of 9
10 Chlorinated Benzenes Solvent Extraction and Followed by Gas Chromatography-Mass Spectrometry (GC-MS) Analysis. Compound(s) Cas No. Result(µg/L) Dichlorobenzene various ND 0.45 Trichlorobenzenes various ND ND Tetrachlorobenzenes various ND ND Pentachlorobenzenes ND ND Hexachlorobenes ND ND Chlorobenzene ND ND Detection limit = 0.02µg/L Cyanide With Reference to HJ 484 by Spectrophotometer Analysis. Compound(s) Result(ug/L) Cyanide ND 21 Remarks: Detection limit = 4 ug/l ND = Not detected Testing Period: Jan. 15, 2016 To Feb. 02, 2016 End of report This report is made solely on the basis of your instructions and/or information and materials supplied by you. It is not intended to be a recommendation for any particular course of action. Intertek does not accept a duty of care or any other responsibility to any person other than the Client in respect of this report and only accepts liability to the Client insofar as is expressly contained in the terms and conditions governing Intertek's provision of services to you. Intertek makes no warranties or representations either express or implied with respect to this report save as provided for in those terms and conditions. We have aimed to conduct the Review on a diligent and careful basis and we do not accept any liability to you for any loss arising out of or in connection with this report, in contract, tort, by statute or otherwise, except in the event of our gross negligence or wilful misconduct. Page 10 of 9
Benetton Group Restricted Substances List (RSL) contains the complete list of banned or restricted chemical substances.
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