Benetton Group Restricted Substances List (RSL) contains the complete list of banned or restricted chemical substances.
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1 TEST REPORT Facility: NANDE KNITTING & GARMENTS CO., LTD. YONG CHUN Country: China Address: Bangde Industrial Zong, Yongchun County, Quanzhou City, Fujian Province, China Date of report: Oct 15, 2015 INTRODUCTION Benetton Group has a relevant experience of environmentally responsible business practices and is putting significant resources and passion on its environmental program with the objective to minimize the impact of all its activities and preserve the natural resources for present and future generations. Benetton Group Restricted Substances List (RSL) contains the complete list of banned or restricted chemical substances. In line with the Company s commitment to zero discharges of hazardous substances by 2020, chemical investigations are regularly conducted by independent external auditors considering the following groups of hazardous chemical substances and using the lowest detection limits currently available with the best in class chemical laboratories around the world: PRIORITY CHEMICAL GROUPS 1. Alkylphenols 2. Phthalates 3. Brominated and chlorinated flame retardants 4. Azo dyes 5. Organotin compounds 6. Perfluorinated chemicals 7. Chlorobenzenes 8. Chlorinated solvents 9. Chlorophenols 10. Short chain chlorinated paraffins 11. Heavy metals such as cadmium, lead, mercury and chromium (VI). The findings are meant to highlight the current level of use (at times also unintentional) of the above chemical groups through a comparison of the incoming, UNTREATED wastewaters (i.e. samples are collected upstream of any wastewaters treatment plant) and treated wastewater (if there is. i.e. samples are collected downstream of self-owned Effluent Treatment Plant). The comparison is in fact a valuable tool to identify if and in which formulations, used by the Page 1 of 11
2 facility, the above chemical groups might be contained, helping to subsequently identify potential alternatives of assessed lower impact. For every specific situation an action plan is designed and a monitoring procedure is put in place to avoid non viable substitutions. Page 2 of 11
3 Facility details and analysis results Date: OCT 15,2015 Facility Name: NANDE KNITTING & GARMENTS CO., LTD. YONG CHUN Address: Bangde Industrial Zong, Yongchun County, Quanzhou City, Fujian Province, China Activity: Dyeing and Finishing Sample Description: Three (3) Samples: (1) Transparent Liquid, Incoming Water, Tap Water, Collected During Operating Hours on Sep. 17 th, 2015 (2) Light White Liquid with Turbidity, Untreated Discharge Water, Collected During Operating Hours on Sep. 17 th, 2015 (3) Light Yellow Liquid, Treated Discharge Water, Collected During Operating Hours on Sep. 17 th, 2015 The water samples were collected and tested by Intertek. SUMMARY Test Items Result Azodyes (Banned Aromatic Amines) - - Chlorinated Solvents - - Phthalates - - Brominated and Chlorinated Flame Retardants - - Organic Tin Compounds - - Chlorophenols - - Short-Chain Chlorinated Paraffins (C 10-C 13) - - Heavy Metals Alkylphenol ethoxylates/alkylphenols(apeos/aps) Perfluorinated Chemicals (PFCs) - - Chlorinated Benzenes - - Cyanide - - Note/ Key Detected Not Detected - Not Tested Page 3 of 11
4 Detection Of Amines Derived From Azocolourants And Azodyes With Reference To EN 14362:1&3, By Gas Chromatographic - Mass Spectrometric (GC-MS) And High Performance Liquid Chromatographic - Diode Array Detector(HPLC-DAD) Analysis. Compound(s) Cas No. Result (μg/l) 1,4-Phenylenediamine ND - 2,4,5-Trimethylaniline ND - 2,4-Diaminoanisole ND - 2,4-Diaminotoluene ND - 2,4-Xylidine ND - 2,6-Xylidine ND - 2-Chloroaniline ND - 2-Naphthylamine ND - 3,3'-Dichlorobenzidine ND - 3,3'-Dimethoxybenzidine ND - 3,3'-Dimethyl-4,4'-diaminodiphenylmethane ND - 3,3'-Dimethylbenzidine ND - 4,4'-Diaminodiphenylmethane ND - 4,4'-Methylene-bis(2-chloroaniline) ND - 4,4'-Oxydianiline ND - 4,4'-Thiodianiline ND - 4-Aminobiphenyl ND - 4-Chloroaniline ND - 4-Chloro-o-toluidine ND - 5-Nitro-o-anisidine ND - 5-Nitro-o-toluidine ND - 4-Aminoazobenzene ND - Aniline ND - Benzidine ND - m-toluidine ND - n,n-diethylanaline ND - n-ethylaniline ND - n-methylaniline ND - o-aminoazotoluene ND - o-anisidine ND - o-toluidine ND - p-cresidine ND - p-toluidine ND - Remark: ND= Not detected Detection limit = 0.1μg/L Page 4 of 11
5 Chlorinated Solvents By Headspace Gas Chromatography Mass Spectrometric (HS-GC/MS) Analysis. Compound(s) Cas No. Result (μg/l) Carbon tetrachloride ND - Pentachloroethane ND - 1,1,1-trichloroethane ND - 1,1,1,2-tetrachloroethane ND - 1,1,2,2-tetrachloroethane ND - Chloroform ND - 1,1,2-trichloroethane ND - 1,1-dichloroethylene ND - Trichloroethylene ND - Tetrachloroethylene ND - 1,2-dichloroethane ND - Dichloromethane ND - Remark: ND= Not detected Detection limit = 1μg/L Page 5 of 11
6 Phthalates Solvent Extraction And By Gas Chromatography-Mass Spectrometry (GC-MS) Analysis. Compound(s) Cas No. Result (μg/l) Di-iso-butyl-phthalate(DIBP) ND - Di-butyl-phthalate(DBP) ND - Benzyl-butyl-phthalate(BBP) ND - Di-(2-ethyl-hexyl)-phthalate(DEHP) ND - Di-n-octyl-phthalate(DNOP) ND - Di-iso-nonyl-phthalate(DINP) ND - Di-iso-decyl-phthalate(DIDP) ND - Di-methyl-phthalate(DMP) ND - Di-ethyl-phthalate(DEP) ND - Di-n-propyl-phthalate(DPrP / DPP) ND - Di-iso-pentyl-phthalate(DIPP) ND - Di-n-hexyl-phthalate(DNHP) ND - Di-cyclo-hexyl-phthalate(DCHP) ND - Di-iso-heptyl-phthalate(DIHP) ND - Di-iso-octyl-phthalate(DIOP) ND - Di-nonyl-phthalate(DNP) ND - Bis-(2-methoxy-ethyl)-phthalate(DMEP) ND - 1,2-Benzene-di-carboxylic acid di-pentylesters, branched and linear ND - N-iso-pentyl-iso-pentyl-phthalate(PIPP) ND - 1,2-Benzene-di-carboxylic acid, di-c 7, ND - branched and linear alkyl esters(dhnup) Remark: ND= Not detected Detection limit = 1μg/L Page 6 of 11
7 Brominated And Chlorinated Flame Retardants Solvent Extraction And By Liquid Chromatography - Mass Spectrometry (LC-MS) And Gas Chromatography - Mass Spectrometry (GC-MS) Analysis. Compound(s) Cas No. Result (μg/l) Detection Limit (µg/l) Polybrominated Biphenyles(PBBs) various Polybrominated Diphenyl ethers(pbdes) Bromo-biphenyl - - ND Di-bromo-biphenyl - - ND Tri-bromo-biphenyl - - ND Tetra-bromo-biphenyl - - ND Penta-bromo-biphenyl - - ND Hexa-bromo-biphenyl - - ND Hepta-bromo-biphenyl - - ND Octa-bromo-biphenyl - - ND Nona-bromo-biphenyl - - ND Deca-bromo-biphenyl ND various Bromo-diphenyl-ether - - ND Di-bromo-diphenyl-ether - - ND Tri-bromo-diphenyl-ether - - ND Tetra-bromo-diphenyl-ether - - ND Penta-bromo-diphenyl-ether - - ND Hexa-bromo-diphenyl-ether - - ND Hepta-bromo-diphenyl-ether - - ND Octa-bromo-diphenyl-ether - - ND Nona-bromo-diphenyl-ether - - ND Deca-bromo-diphenyl-ether ND Hexa-bromo-cyclo-dodecan(HBCDD) ND Tri-(2,3-di-bromo-propyl)-phosphate(TRIS) ND Tetra-bromo-bisphenol-A(TBBPA) ND ND Bis-(2,3-di-bromo-propyl)-phosphate ND Tris-(2-chloro-ethyl)-phosphate(TCEP) ND Tetra-bromo-bisphenol A bis-(d-ibromopropyl-ether)(tbbpa-bdpe) Tris-(1,3-di-chloro-iso-propyl)- phosphate(tdcpp) ND Tris-(2-chloroisopropyl)-phosphate(TCPP) ND Remark: ND= Not detected Page 7 of 11
8 Organic Tin Compounds Compound(s) With Reference To DIN EN 17353, By Gas Chromatography-Mass Spectrometry (GC-MS) Analysis. Result (µg/l) Monobutyltin (MBT) - ND - Dibutyltin (DBT) - ND - Tributyltin (TBT) - ND - Triphenyltin (TPhT) - ND - Dioctyltin (DOT) - ND - Monooctyltin (MOT) - ND - Tetrabutyltin (TeBT) - ND - Trioctyltin(TriOT) - ND - Tricyclohexyltin(TCyHT) - ND - Tripropyltin (TPT) - ND - Remark: ND= Not Detected Detection limit =0.01μg/L Chlorophenols Solvent Extraction And Acetylated By Acetic Anhydride, And Analyzed By Gas Chromatography-Mass Spectrometry (GC-MS). Compound(s) Cas No. Result (µg/l) Pentachlorophenol (PCP) ND - Tetrachlorophenols (TeCP) ND - Trichlorophenols (TriCP) Various - ND - Dichlorophenol (DiCP) Various - ND - Monochlorophenol Various - ND - Remark: ND = Not detected Detection limit = 0.5µg/L Page 8 of 11
9 Short-Chain Chlorinated Paraffins (C 10-C 13) Solvent Extraction And By Liquid Chromatography - Mass Spectrometry (LC-MS) Analysis. Compound(s) Cas No. Result (µg/l) Short-chain chlorinated paraffins (C 10-C 13) ND - Remark: ND = Not detected Detection limit = 0.4µg/L Heavy Metals By Inductively Coupled Argon Plasma-Mass Spectrometry(ICP-MS) Analysis And By Ion Chromatography- Inductively Coupled Argon Plasma-Mass Spectrometry(IC-ICP-MS) Analysis. Compound(s) CAS No. Result (µg/l) Detection Limit (µg/l) Total Cadmium(Cd) ND ND ND 0.1 Total Lead(Pb) ND 11 ND 1 Total Mercury(Hg) ND ND ND 0.5 Total Hexavalent Chromium(Cr-VI) ND ND ND 1 Total Arsenic (As) ND ND ND 1 Total Antimony (Sb) ND ND ND 1 Total Cobalt (Co) ND ND ND 1 Total Nickel (Ni) ND Total Copper (Cu) ND 16 ND 1 Total Zinc (Zn) ND 42 ND 1 Total Manganese (Mn) ND Total Chromium (Cr) ND Remark: ND = Not detected Alkylphenol ethoxylates/alkylphenols(apeos/aps) Solvent Extraction And By Gas Chromatography-Mass Spectrometry (GC-MS) And By Liquid Chromatography-Mass Spectrometry (LC-MS/MS) Analysis. Compound(s) Cas No. Result (µg/l) Detection Limit (µg/l) Nonylphenols ND 14 ND Octylphenols ND ND ND Nonylphenolethoxylates ND ND ND 2.5 Octylphenolethoxylates ND ND ND 2.5 Nonylphenolethoxylates ND ND ND 5 Octylphenolethoxylates ND ND ND 5 Remark: ND = Not detected Page 9 of 11
10 Perfluorinated Chemicals (PFCs) By Liquid Chromatography Mass Spectrometry (LC-MS/MS) Analysis. Compound(s) Cas No. Result (µg/l) Perfluorooctane sulphonates (PFOS) ND - Perfluoro-octane-sulfon- amide(pfosa) ND - N-Methyl-Perfluoro-octane-sulfon-amide(N-Me ND - FOSA) N-Ethyl-Perfluoro-octane-sulfon-amide(N-Et- FOSA) N-Methyl-Perfluoro-octane-sulfon-amidoethanol(N-Me-FOSE alcohol) N-Ethyl-Perfluoro-octane-sulfon-amidoethanol(N-Et-FOSE alcohol) ND ND ND - Perfluoro-octane acid ND - Perfluoro-butanoic acid ND - Perfluoro-pentanoic acid ND - Perfluoro-hexanoic acid ND - Perfluoro-heptanoic acid ND - Perfluoro-nonanoic acid ND - Perfluoro-decanoic acid ND - Perfluoro-undecanoic acid ND - Perfluoro-dodecanoic acid ND - Perfluoro-tridecanoic acid ND - Perfluoro-tetradecanoic acid ND - Perfluoro-butane-sulfonic acid ND - Perfluoro-hexane-sulfonic acid / ND - Perfluoro-heptane-sulfonic acid ND - Perfluor-decane-sulfonic acid ND - 1H,1H,2H,2H-Perfluoro-octane-sulphonic acid ND - 2H,2H,3H,3H-Perfluoro-undecanoic acid ND - Perfluoro-3-7-dimethyl octane carboxylate ND - 7H-Dodecafluoro heptane carboxylate ND - Remark: ND = Not detected Detection limit = 0.2µg/L Page 10 of 11
11 Chlorinated Benzenes Compound(s) Solvent Extraction And Followed By Gas Chromatography-Mass Spectrometry (GC-MS) Analysis. Cas No. Result(µg/L) Dichlorobenzene various - ND - Trichlorobenzenes various - ND - Tetrachlorobenzenes various - ND - Pentachlorobenzenes ND - Hexachlorobenes ND - Chlorobenzene ND - Remark: ND = Not detected Detection limit = 0.02µg/L Cyanide With Reference To HJ 484 By Spectrophotometer Analysis. Compound(s) Result(ug/L) Cyanide - ND - Remarks: Detection limit = 4 ug/l ND = Not detected Testing Period: Sep. 21, 2015 To Oct. 15, 2015 End of report Page 11 of 11
Benetton Group Restricted Substances List (RSL) contains the complete list of banned or restricted chemical substances.
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