Toxics Release Inventory (TRI) Basis of OSHA Carcinogens
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1 February 2005, Technical Update Toxics Release Inventory (TRI) Basis of OSHA Carcinogens Under the TRI Program, a chemical does not have to be counted towards threshold determinations and release and other waste management calculations if it is present in a mixture below a certain concentration. This is known as the de minimus concentration in mixture. When the rule was developed that implemented the reporting requirements of Section 313 of the Emergency Planning and Community Right-to-Know Act (EPCRA), EPA adopted the de minimus percentages from the Occupational Safety and Health Administration s (OSHA) Hazard Communication Standards (29 CFR ) because much of the initial information that industry would have relating to chemicals in mixtures would most likely be from the material safety data sheet (MSDS) on that mixture. The OSHA de minimus limitation is 0.1 percent if the chemical is a known or suspect carcinogen by virtue of appearing in one of three sources: 1. National Toxicology Program (NTP), "Annual Report on Carcinogens" (Latest Editions); 2. International Agency for Research on Cancer (IARC) "Monographs" (Latest Editions); CFR 1910, Subpart Z, Toxic and Hazardous Substances, Occupational Safety and Health Administration. The de minimus limitation is 1.0 percent for chemicals that do not meet the above OSHA carcinogen criteria. The carcinogen designation in the list of chemicals relates to any chemical that the Agency determined met the above OSHA criteria for the 0.1 percent de minimus limitation. Certain metal compound categories have two de minimus limitations. For example, hexavalent chromium compounds and inorganic arsenic compounds meet the OSHA carcinogen criteria, while trivalent chromium compounds and organic arsenic do not meet the OSHA criteria. In addition, there are no de minimus levels for persistent bioaccumulative toxic (PBT) chemicals, except for supplier notification purposes. The following table shows the specific bases for which chemicals have been designated as a known or suspect carcinogens. This list is based on a review of the most current NTP, IARC, and OSHA sources as of February 2005.
2 Basis of OSHA Carcinogen Listing for TRI Chemicals Chemical Name IARC NTP OSHA Z Acetaldehyde 2B P Acetamide 2B 2-Acetylaminofluorene P Z Acrylamide 2A P Acrylonitrile 2B P Z 2-Aminoanthraquinone P 4-Aminoazobenzene 2B 4-Aminobiphenyl 1 K Z 1-Amino-2-methylanthraquinone P Amitrole P o-anisidine 2B o-anisidine hydrochloride P Arsenic and inorganic arsenic compounds 1 K* Z Asbestos (friable) 1 K Z Benzene 1 K Z Benzidine 1 K Z Benzoic trichloride 2B P Beryllium and beryllium compounds 1 P* Bis(chloromethyl)ether 1 K Z 1,3-Butadiene 2A K 1,2-Butylene oxide 2B Cadmium and cadmium compounds 1 K* Carbon tetrachloride 2B P Catechol 2B Chlordane 2B Chlorendic acid 2B P p-chloroaniline 2B Chloroform 2B P Chloromethyl methyl ether 1 K Z 3-Chloro-2-methyl-1-propene P Chlorophenols 2B Chloroprene 2B P Chlorothalonil 2B p-chloro-o-toluidine 2A P Chromium (VI) compounds 1 K C.I. Acid Red 114 2B C.I. Direct Black 38 2A K C.I. Direct Blue 6 2A K C.I. Direct Brown 95 2A C.I. Food Red 5 2B C.I. Solvent Yellow 3 (o-aminoazotoluene) 2B P C.I. Solvent Yellow 34 (Auramine) 2B Cobalt and cobalt compounds 2B P*
3 Creosote 2A K p-cresidine 2B P Cupferron P 2,4-D** 2B 2,4-D butoxyethyl ester** 2B 2,4-D butyl ester** 2B 2,4-D chlorocrotyl ester** 2B 2,4-D 2-ethylhexyl ester** 2B 2,4-D 2-ethyl-4-methylpentyl ester** 2B 2,4-Diaminoanisole 2B 2,4-Diaminoanisole sulfate P 4,4'-Diaminodiphenyl ether 2B 2,4-Diaminotoluene 2B P Diaminotoluene (mixed isomers) 2B P 1,2-Dibromo-3-chloropropane 2B P Z 1,2-Dibromoethane 2A P 1,4-Dichlorobenzene 2B P Dichlorobenzene (mixed isomers) 2B P 3,3'-Dichlorobenzidine 2B P Z 3,3'-Dichlorobenzidine dihydrochloride 2B P 3,3'-Dichlorobenzidine sulfate 2B P Dichlorobromomethane 2B P 1,2-Dichloroethane 2B P Dichloromethane 2B P trans-1,3-dichloropropene 2B 1,3-Dichloropropylene 2B P Dichlorvos 2B Diepoxybutane 2B P Di-(2-ethylhexyl)phthalate P Diethyl sulfate 2A P Diglycidyl resorcinol ether 2B P Dihydrosafrole 2B 3,3'-Dimethoxybenzidine 2B P 3,3'-Dimethoxybenzidine dihydrochloride 2B P 3,3'-Dimethoxybenzidine hydrochloride 2B P 4-Dimethylaminoazobenzene 2B P Z 3,3'-Dimethylbenzidine 2B P 3,3'-Dimethylbenzidine dihydrochloride 2B P 3,3'-Dimethylbenzidine dihydrofluoride 2B P Dimethylcarbamyl chloride 2A P 1,1-Dimethylhydrazine 2B P Dimethyl sulfate 2A P 2,4-Dinitrotoluene 2B 2,6-Dinitrotoluene 2B 1,4-Dioxane 2B P 1,2-Diphenylhydrazine P
4 2,4-D isopropyl ester** 2B 2,4-DP** 2B 2,4-D propylene glycol butyl ether ester** 2B 2,4-D sodium salt** 2B Epichlorohydrin 2A P Ethyl acrylate 2B Ethyl benzene 2B Ethyleneimine Z Ethylene oxide 1 K Z Ethylene thiourea P Formaldehyde 2A P Z Heptachlor 2B Hexachlorobenzene 2B P alpha-hexachlorocyclohexane 2B P Hexachloroethane 2B P Hexamethylphosphoramide 2B P Hydrazine 2B P Hydrazine sulfate P Lead and inorganic lead compounds 2B P Z Lindane 2B P Mecoprop** 2B Methoxone** 2B Methoxone sodium salt** 2B 4,4-Methylenebis (2-chloroaniline) 2A P 4,4'-Methylenebis (N,N-dimethyl) benzeneamine 2B P 4,4'-Methylenedianiline 2B P Z Michler's ketone P Mustard gas 1 K Naphthalene 2B P alpha-naphthylamine Z beta-naphthylamine 1 K Z Nickel 2B P Nickel compounds 1 P* Nitrilotriacetic acid P Nitrobenzene 2B P 4-Nitrobiphenyl Z Nitrofen 2B P Nitrogen mustard 2A 2-Nitropropane 2B P N-Nitrosodi-n-butylamine 2B P N-Nitrosodiethylamine 2A P N-Nitrosodimethylamine 2A P Z N-Nitrosodi-n-propylamine 2B P N-Nitroso-N-ethylurea 2A P N-Nitroso-N-methylurea 2A P N-Nitrosomethylvinylamine 2B P
5 N-Nitrosomorpholine 2B P N-Nitrosonornicotine 2B P N-Nitrosopiperidine 2B P Pentachlorophenol 2B Phenytoin 2B P Polybrominated biphenyls (PBBs) 2B P Polychlorinated alkanes (C 12, 60% chlorinated) P Polychlorinated biphenyls (PCBs) 2A P Polycyclic aromatic compounds (PACs): Benz(a)anthracene 2A P Benzo(b)fluoranthene 2B P Benzo(j)fluoranthene 2B P Benzo(k)fluoranthene 2B P Benzo(rst)pentaphene 2B Benzo(a)pyrene 2A P Dibenz(a,h)acridine 2A P Dibenz(a,j)acridine 2B P Dibenzo(a,h)anthracene 2B P 7H Dibenzo(c,g)carbazole 2B P Dibenzo(a,e)pyrene 2B P Dibenzo(a,h)pyrene 2B P Dibenzo(a,l)pyrene 2B P 7,12 Dimethylbenz(a)anthracene 2B Indeno[1,2,3 cd]pyrene 2B P 5 Methylchrysene 2B P 1 Nitropyrene 2B P Potassium bromate 2B Propane sultone 2B P beta-propiolactone 2B P Z Propyleneimine 2B P Propylene oxide 2B P Safrole 2B P Sodium o-phenylphenoxide 2B Styrene 2B Styrene oxide 2A Tetrachloroethylene 2B P 2,3,7,8-Tetrachlorodibenzo-p-dioxin 1 K Thioacetamide 2B P 4,4'-Thiodianiline 2B P Thiourea P Toluene-2,4-diisocyanate 2B P Toluene-2,6-diisocyanate 2B P Toluene diisocyanate (mixed isomers) 2B P o-toluidine 2A P o-toluidine hydrochloride P Toxaphene 2B P
6 Trichloroethylene 2A P 2,4,6-Trichlorophenol 2B P 1,2,3-Trichloropropane 2A P Tris(2,3-dibromopropyl)phosphate 2A P Trypan blue 2B Urethane 2B P Vinyl acetate 2B Vinyl bromide 2A Vinyl chloride 1 K Z 2,6-Xylidine 2B Note: The list of TRI chemicals meeting the OSHA carcinogen standard and, therefore, not reported when in a mixture at a concentration level below the de minimus level of 0.1% has been updated, and this list reflects the update. IARC: 1 The chemical is carcinogenic to humans; 2A The chemical is probably carcinogenic to humans; 2B The chemical is possibly carcinogenic to humans. NTP: K The chemical is known to be a human carcinogen; P The chemical is reasonably anticipated to be a human carcinogen. OSHA: Z The chemical appears at 29 CFR part 1910 Subpart Z. * Certain compounds. ** Chlorophenoxy herbicides (IARC 2B).
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