H&M Chemical Restrictions Manufacuring Restricted Substance List (MRSL) Global Substainaiblity Department May 2016 Valid for all brands in H&M Group

Transcription

1 s Manufacuring Restricted Substance List (MRSL) Global Substainaiblity Department May 2016 Valid for all brands in H&M Group

2 Table of Contents General... 2 Commitment... 2 Definitions... 3 Abbreviations... 3 Approach... 4 Requirement... 4 APPENDIX A Test Methods and Detection Limits for chemicals and wastewater Version Date Changes made Page or Chapter 1.0 January 2016 Original May 2016 Included information about the clean factory approach Updated the list of restricted substances Added Appendix A Page 4-19 May (20)

3 General H&M has with concern for the health of customers as well as for the environment and working conditions, established H&M Chemical Restrictions for all products. H&M Chemical Restrictions consist of several parts with regard to product types. All products must fulfill their corresponding parts in Chemical restriction and its production processing must also fulfill H&M Manufacturing Restricted Substance List (MRSL). This H&M Manufacturing Restricted Substance List (MRSL) is applied for the whole production site, not only limited to H&M production lines. The official and valid version of this document is in English. Any translation of the document is prepared for reference only. H&M accepts no liability for any mistakes done in the translation. Commitment By accepting H&M Standard Purchase Conditions, the Supplier commits to comply with H&M Chemical Restrictions. It is the Supplier s responsibility to assure compliance with H&M Chemical Restrictions and to inform all their downstream suppliers and subcontractors about the content of H&M Chemical Restrictions. By accepting H&M Standard Purchase Conditions, each Supplier acknowledges that H&M reserves the right to: Inspect and test any product, any part of production and/or packaging, by any listed or appropriate method, at any time or at any stage of production. Cancel the Order, or, if the products are already delivered, return the products to the Supplier if the product, production and/or packaging do not correspond to the H&M Chemical Restrictions. Hold the Supplier responsible for any damage caused by the ordered product if the product, production and/or packaging do not correspond to the H&M Chemical Restrictions. Receive the Safety Data Sheets (SDS) for all substances and preparations (dyes, colorants, solvents, chemicals etc.) used in the production of a specific Order. In the case of contradictory test results, H&M test result will prevail. May (20)

4 Definitions Usage ban The substance must not be used in production and it must not be added to the product 1. Homogeneous Not Detected Reporting Limit Self-declaration Substances defined as hazardous due to intrinsic properties. Uniform composition throughout, i.e. a material that cannot be mechanically disjointed into different materials. The substance must not be present in the tested sample at concentrations above the analytical reporting limits. Describes the level of detection times a safety factor selected by the laboratory that ensures repeatability and reproducibility. All chemicals used should have Safety Data Sheets, SDS, showing that no restricted substance is included. Upon request supplier must be able to present the SDS for the chemicals used in the production of the requested product. Other supporting documents such as certificates from subcontractors etc. can also be considered as a part of the SD. Persistent, bio accumulative and toxic (PBT), very persistent and very bio accumulative (vpvb), carcinogenic, mutagenic and toxic for reproduction (CMR), endocrine disruptors (ED) or equivalent concern Abbreviations CAS no CI no MRSL ppm Percentage REACH SVHC Chemical Abstracts Service number, an identification number for chemicals in this database. Color Index number Manufacturing Restricted Substances List Parts per million, which is the same as mg/kg. Percentage is weight by weight, % w/w Registration, Evaluation, Authorisation and Restriction of Chemicals Substances of Very High Concern 1 Impurities at low concentrations of these substances may be accepted only if technically unavoidable due to e.g. raw materials, formation in the manufacturing process, storage or packaging. May (20)

5 Approach Reaching zero discharge in all supply chains means restricted substances should not be used in manufacturing processes and found in products. There is no absolute zero and the best available detection limit should always be used whenever there is a need to verify the presence of restricted substances. Test methods and best available detection limits could be found in appendix A. In line with our ambition to work towards a clean factory approach in our supply chain by 2020, we will guide and support our facilities to phase out restricted chemicals used in production by setting up specific timelines. The phase out time plan will be included in the next version of our MRSL to be published in Requirement The consists of hazardous substances potentially used in manufacturing. These substances may be especially harmful for workers and/or the environment if not handled properly. To protect workers health and minimize environmental impact, restricted chemicals are not allowed to be intentionally used in the production. Restricted substances are classified into two groups as listed below: Group 1: Substances are not allowed to be found in whole production sites and used in H&M production lines. We continuously monitor to secure complete phase out in whole production site Group 2: Substances are not allowed to be used in H&M production lines. These substances shall be phased out in the whole production site latest by 2020, and hence work towards a clean factory approach. GROUP Production Sites Restricted Level H&M Production Lines 1 USAGE BAN USAGE BAN 2 TO BE PHASED OUT IN THE WHOLE PRODUCTION SITE BY THE LATEST USAGE BAN 2 Specific time lines for these substances will be published in a stepwise approach starting May (20)

6 GROUP 1 Alkylphenol Ethoxylates / Alkylphenols (APEOs/APs) Nonylphenol Ethoxylates (NPE) Various Nonylphenolethoxylates (NP1EO) Octylphenol Ethoxylates (OPE) Various Octylphenolethoxylates (OP1EO) Nonylphenol (NP) Various 2-(2H-Bensotriazol-2-yl)-4,6-bis(1,1- dimetylpropyl)phenol Chlorinated Aromatic Hydrocarbons Octylphenol (OP) Various Chlorobenzenes Various Chloronaphthalenes Various Chlorortoluenes Various Chloroxylenes Various Chlorinated Bleaching Agents Finishing treatments with chlorinated bleaching agents can only be used in denim production. Chlorinated Organic Solvents 1,2-Dichloroethane ,1-Dichloroethane ,1-Dichloroethylene Methylene Chloride cis-1,2-dichloroethylene trans-1,2-dichloroethylene chloroform ,1,1-Trichloroethane Carbon Tetrachloride Trichloroethylene ,1,2-trichloroethane ,1,1,2-tetrachloroethane May (20)

7 Brominated Organic Solvent Dimethylformamide (DMF) Organic Solvents 1,1,2,2-Tetrachloroethane Tetrachloroethylene ,2,3-trichloropropane bromopropane (n-propyl bromide) bromopropane Dimethylformamide (DMF) Usage ban except during PU production. Please see below for more info about PU production. Benzene (Benzol) ,4-Butanediol Dimethylacetamide (DMAC) Ethylene glycol monoethyl ether n-hexane ,4 -Methylene-bis-(2-chloroaniline) (MOCA) Phenol Toluene (Toluol) Xylene , , , o-cresol p-cresol m-cresol Cyclododecane hexamethylphosphoramide (HEMPA) N-methylformamide Furan N-methyl-2-pyrrolidone ,4-Butanediol, xylene, o-cresol, p-cresol, m-cresol are exempted in cosmetic products. May (20)

8 GROUP 2 Chloroparaffins Chlorophenols Short chained (SCCPs) C10-C Pentachlorophenol (PCP) and its salts and esters Tetrachlorophenol (TeCP) and its salts and esters , Dyes Azo releasing following amines Mono, di- and tri-chlorophenol 4 Various 4-Aminodiphenyl Amino-4-nitrotoluene Benzidine Chloro-o-toluidine ,4-Diaminoanisole ,3 -Dichlorobenzidine ,3 -Dimethoxybenzidine (o-dianisidine) ,3 -Dimethyl-4,4 -diaminodiphenylmethane ,3 -Dimethylbenzidine (o-tolidine) ,4 -Diaminodiphenylmethane ,4 -Methylene-bis-(2-chloroaniline) (MOCA) Naphtylamine o-aminoazotoluene o-anisidine o-toluidine m-toluidine p-toluidine ,4 -Oxydianiline p-chlorophenol with CAS is exempted in cosmetic products. May (20)

9 4,4 -Thiodianiline ,4-Toluenediamine ,4,5-Trimethylaniline p-aminoazobenzene p-chloroaniline Chloroaniline p-cresidine ,4-Xylidine ,6-Xylidine Diaminobenzidine (biphenyl-3,3',4,4'-tetrayltetraamine) diaminotoluene N,N'-Diacetylbenzidine toluene-2,4-diammonium sulphate ethyl-2-methyl-2-(3-methylbutyl)-1,3-oxazolidine Diazene-1,2-dicarboxamide (C,C`-azodi(formamide), ADCA) Other dyes/ CI no 5-Nitro-o-anisidine N,N-Diethylaniline N-Ethylaniline N-Methylaniline C.I. Direct Black C.I. Direct Blue C.I. Acid Red C.I. Basic Red C.I. Direct Red C.I. Basic Violet C.I. Disperse Blue C.I. Disperse Blue C.I. Basic Blue 26 (with Michler s Ketone > 0.1%) C.I. Basic Green 4 (Malachite green chloride) May (20)

10 Disperse (Sensitizing) C.I. Basic Green 4 (Malachite green oxalate) C.I. Basic Green 4 (Malachite green) C.I. Basic Violet C.I. Pigment Black C.I. Pigment Yellow Disperse Orange Disperse Yellow Disperse Blue Disperse Blue Disperse Yellow Disperse Orange 37/59/ Disperse Brown Disperse Orange Disperse Yellow Disperse Red Disperse Red Disperse Red Disperse Blue Disperse Blue Disperse Yellow Disperse Blue Disperse Blue Disperse Yellow Disperse Orange Disperse Blue Disperse Red 17 is exempted in cosmetic products. May (20)

11 Navy Blue Colorant Anilines Flame retardants Glycols Disperse Orange Component 1: C39H23ClCrN7O12S 2Na Component 2: C46H30CrN10O20S2 3Na Not Allocated Aniline Tris(2,3-dibromopropyl)phosphate (TRIS) Bis(2,3-dibromopropyl)phosphate Tris-(aziridinyl)-phosphineoxide (TEPA) Polybrominated Diphenyl Ethers (PBDE) Various Tetrabromobisphenol A (TBBP A) Polybrominated Biphenyls (PBB) Various Tri-o-cresyl phosphate Tris(2-chloroethyl)phosphate (TCEP) Hexabromocyclododecane ,2-Bis(bromomethyl)-1,3-propanediol Tris(1,3-dichloroisopropyl)phosphate (TDCP) Triphenyl phosphate (TPhP) Tetrabromobisphenol A bis(2,3-dibromopropyl ether) (TBBPA-DBPE) Tri(1-chloro-2-propyl) phosphate (TCPP) Bis(2-methoxyethyl)-ether Ethoxyethyl acetate Ethylene glycol dimethyl ether Methoxyethanol Methoxyethylacetate Triphenyl phosphate (TPhP) is exempted in cosmetic products. May (20)

12 Heavy metals 7 Arsenic (As) H&M Chemical Restriction 2-Methoxypropylacetate Triethylene glycol dimethyl ether ,2-diethoxyethane methoxypropanol methoxyacetic acid Organotin Compounds Cadmium (Cd) Chromium VI (Cr VI) Lead (Pb) Mercury (Hg) Beryllium and beryllium oxide , cobalt and cobalt compounds Various nickel and nickel compounds Various Antimony and antimony compounds Various Dibutyltin (DBT) Dimethyltin (DMT) Various Dioctyltin (DOT) Diphenyltin (DPhT) Various Monobutyltin (MBT) Various Monoctyltin (MOT) Various Tetrabutyltin (TebT) Various Tetraethyltin (TeET) Tributyltin (TBT) Tricyclohexyltin (TCyHT) Trioctyltin (TOT) Lead is allowed in a few applications due top regulatory exceptions in REACH Annex XVII, RoHS-directive 2011/65/EU and US regulation 16 CFR 1303 May (20)

13 Perfluorinated Compounds (PFCs) 8 Triphenyltin (TPhT) Tripropyltin (TPT) Other tri-substituted organotins Various Tributyltin oxide (TBTO) Dibutyltin dichloride (DBTC) Dibutyltin hydrogen borate (DBB) Perfluorobutane Sulfonate (PFBS) Perfluorohexane Sulfonate (PFHxS) Perfluoroheptane Sulfonate (PFHpS) Perfluorooctane Sulfonate (PFOS) Perfluorodecane Sulfonate (PFDS) Perfluorooctane Sulfonamide (PFOSA) 1H,1H,2H,2H H4PFOS; 6: Perfluorobutane Acid (PFBA) Perfluoropentane Acid (PFPA) Perfluorohexane Acid (PFHxA) Perfluoroheptane Acid (PFHpA) Perfluorooctanoic Acid (PFOA) Perfluorononane Acid (PFNA) Perfluorodecane Acid (PFDA) Perfluoroundecanoic Acid (PFUnA) Perfluorododecanoic Acid (PFDoA) Perfluorotridecanoic Acid (PFTrA) Perfluorotetradecanoic Acid (PFTeA) Perfluo-3,7-dimethyloctanoic Acid (PF-3,7-DMOA) H-Dodecanefluoroheptane Acid (HPFHpA) Perfluorinated Compounds (PFC) is restricted for all product types except cosmetic products. May (20)

14 2H,2H-perfluorodecane Acid (H2PFDA) - 2H,2H,3H,3H-Perfluoroundecanoic Acid (H4PFUnA) H,1H,2H,2H-Perfluorooctylacrylate (6:2 FTA) H,1H,2H,2H-Perfluorodecylacrylate (8:2 FTA) H,1H,2H,2H-Perfluorododecylacrylate (10:2 FTA) H,1H,2H,2H-Perfluoro-1-hexanol (4:2 FTOH) H,1H,2H,2H-Perfluoro-1-oktanol (6:2 FTOH) H,1H,2H,2H-Perfluoro-1-decanol (8:2 FTOH) H,1H,2H,2H-Perfluoro-1-dodecanol (10:2 FTOH) (N-methylperfluoro-FASE 1 octanesulfonamido)-ethanol (MeFOSE) (N-ethylperfluoro-1-octanesulfonamido)-ethanol (EtFOSE) N-methylperfluoro-1-octanesulfonamide (MeFOSA) N-ethylperfluoro-1-octanesulfonamide (EtFOSA) H,1H,2H,2H-Perfluorooctanesulphonic acid (H4PFOS 6-2) All other Perfluorinated or Polyfluorinated compounds (fully or partially luorinated compounds) Phthalates Various Butyl benzyl phthalate (BBP) Dibutyl phthalate (DBP) Diethyl phthalate (DEP) Di-(2-ethylhexyl) phthalate (DEHP) Diisobutyl phthalate (DIBP) Diisodecyl phthalate (DIDP) Diisononyl phthalate (DINP) Di-n-hexyl phthalate (DnHP) Di-n-octyl phthalate (DnOP) Diethyl phthalate (DEP) is exempted in cosmetic products. May (20)

15 Phenols Butyl octyl phthalate (BOP) Diundecyl phthalate (DUP) Bis(2-ethoxyethyl) phthalate (BEEP) All other phthalates /all other esters of o-phthalic acid) Various Polychlorinated Compounds Polycyclic Aromatic hydrocarbons (PAHs) o-phenylphenol (OPP) Polychlorinated Biphenyls (PCB) Polychlorinated Triphenyls (PCT) Acenaphthene Acenaphthylene Anthracene Benzo[a]anthracene Benzo[a]pyrene (BaP) Benzo[b]fluoranthene Benzo[e]pyrene Benzo[ghi]perylene Benzo[j]fluoranthene Benzo[k]fluoranthene Chrysene Coal tar pitch Anthracene oil Other Anthracene oil compounds , , , Dibenz[a,h]anthracene Fluoranthene Fluorene May (20)

16 Indeno[1,2,3-cd]pyrene Naphthalene Phenanthrene Pyrene Polyvinylchloride (PVC) and similar chlorinated polymers, e.g. Polyvinylidenchloride and Polychloroprene (neoprene) N-nitroso compounds Polyvinylchloride (PVC) Polyvinylidenchloride Polychloroprene N-Nitrosodi-n-propylamine N-Nitrosodimethylamine N-Nitrosodiethanolamine Petroleum distillate , , , , , , , , , , , , Biocide Solvent based Glues Metam sodium Safrole (5-allyl-1,3-benzodioxole] Cycloheximide Organic solvent based systems shall be exchanged to water based systems. 11 Solvent based Polyurethane, PU Shall be exchanged to water based systems in cases where it is technically possible. 10 Petroleum distillate with CAS , , , , , , are exempted in cosmetic products. 11 Supplier must always get an approval from H&M Global Sustainability Department before using any non-water based systems May (20)

17 APPENDIX A Test Methods and Detection Limits for chemicals and wastewater This Appendix specifies the test methods that could be used as reference when testing for the restricted substances. The test methods and limits will be reviewed at least annually so as to reflect the best available detection limit. Chemical Groups Chemicals Wastewater Test Method Detection Limit (ppm) Test Method DetectionLimit (ppm) APEOs/ APs Chlorinated Aromatic Hydrocarbons Solvent extraction and analysis by Gas Chromatography Mass Spectrometry (GC-MS) and Liquid Chromatograph Mass Spectrometer (LC-MS) Chlorobenzenes Solvent extraction and analysis by Gas Chromatography Mass Spectrometry (GC-MS) Each: 10 Each: 0.1 With reference to ASTM International Standard ASTM D7065 With reference to U. S. EPA 8260B and U. S. EPA 8270D Each: Each: Chloronaphthalenes Under development Under development Under development Under development Chlorortoluenes Solvent extraction and analysis by Gas Each: 0.1 With reference to U. S. EPA 8260B Each: Chromatography Mass Spectrometry (GC-MS) and U. S. EPA 8270D Chloroxylenes Under development Under development Under development Under development Chlorinated Organic Solvents Brominated Organic Solvents Direct analysis by Headspace Gas Chromatography with Mass Spectrometer (HSGC-MS) Head-space or Solvent extraction and analysis by Gas Chromatography Mass Spectrometry (GC-MS) 1,2,3-trichloropropane: 10 Each(Others): 5 With reference to U. S. EPA 8260B Each: 0.02 Each: 5 With reference to U. S. EPA 8260C Each: 0.01 Dimethylformamide (DMF) Solvent extraction and analysis by Gas Chromatography Mass Spectrometry (GC-MS) 5 With reference to U. S. EPA 8260B 0.02 Organic Solvents Direct analysis by Headspace Gas Chromatography with Mass Spectrometer (HSGC-MS) Each: 5 With reference to U. S. EPA 8260B Each: 0.01 May (20)

18 Chemical Groups Chemicals Wastewater Test Method Detection Limit (ppm) Test Method Detection Limit (ppm) Chloroparaffins (SCCPs) Chlorophenols Aromatic Amines in Azo Colorants Other dyes/ CI no Disperse (Sensitizing) Solvent extraction and analysis by Gas Chromatograph Mass Spectrometer in Negative Chemical Ionization mode (GC- MS-NCI) Solvent extraction, derivatization and analysis by Gas Chromatography Mass Spectrometry (GC-MS) With reference to EN : 2013, analysis by Gas Chromatography Mass Spectrometry (GC-MS) and confirmation by Liquid Chromatography cope with Diode Array Detector (LC-DAD) Solvent extraction and analysis by Liquid Chromatography cope with Diode Array Detector and Mass Spectrometer (LC- DAD-MS) Solvent extraction and analysis by Liquid Chromatography cope with Diode Array Detector and Mass Spectrometer (LC- DAD-MS) 30 With reference to International Standard ISO PCP : TeCP : Each(Mono/ di-/ Tri-chlorophenol): Each: 10 With reference to U. S. EPA 8270D With reference to German Standard DIN / With reference to European Standard EN incorporating Corrigendum and European Standard EN Each: Each(5-Nitro-o-anisidine& N-Ethylaniline&N- Methylaniline) : Each(Others) : Each: 1 Direct analysis by LC-MS Each: 1 Direct analysis by LC-MS Aniline Solvent extraction and analysis by Gas Chromatography Mass Spectrometry (GC-MS) 10 With reference to German Standard DIN / With reference to European Standard EN incorporating Corrigendum and European Standard EN May (20)

19 Chemical Groups Chemicals Wastewater Test Method Detection Limit (ppm) Test Method Detection Limit (ppm) Flame retardants Solvent extraction and analysis by Gas Chromatography Mass Spectrometry (GC-MS), and Liquid Chromatograph Mass Spectrometer (LC-MS) Each: 5 With reference to U. S. EPA 527 and with reference to U. S. EPA 8321B Each(TRIS& TBBPA& Bis(2,3- dibromopropyl) phosphate& HBCDD& BBMP& TBBPA-DBPE& TDCPP& TEPA& Tri-o-cresylphosphate) : Glycols Heavy metals Solvent extraction and analysis by Gas Chromatography Mass Spectrometry (GC-MS) Acid digestion and analysis by Inductively Coupled Argon Plasma Mass Spectrometer (ICP-MS) Each(Others) : Each: 30 Under development Under development Mercury : 0.1 Each(As&Cd&Cr&Pb) : 1 Each(Others): 10 With reference to U. S. EPA 3015A and U. S. EPA 6020A Cd : Hg : Each(Others) : Organotin Compounds Perfluorinated Compounds (PFCs) Solvent extraction, derivatization and analysis by Gas Chromatography Mass Spectrometry (GC-MS) Solvent extraction and analysis by Gas Chromatography Mass Spectrometry (GC-MS) and Liquid Chromatography with Tandem Mass Spectrometry (LC-MS/MS) Each: Each(PFOS&PFOA) : 0.1 Each(4:2 FTOH& 6:2 FTOH& 8:2 FTOH& 10:2 FTOH) : 1 Each(Others) : 0.5 Cr(VI): With reference to U. S. EPA 7196A With reference to European Standard EN ISO Solvent extraction and analysis by LC-MS and GC-MS Each: Each(PFOS&PFOA) : Each(Others) : May (20)

20 Chemical Groups Chemicals Wastewater Test Method Detection Limit (ppm) Test Method Detection Limit (ppm) Phthalates Phenols (OPP) Polychlorinated Compounds Polycyclic Aromatic hydrocarbons (PAHs) N-nitroso compounds Petroleum distillate Solvent extraction and analysis by Gas Chromatography Mass Spectrometry (GC-MS) and Liquid Chromatograph Mass Spectrometer (LC-MS) Solvent extraction, derivatization and analysis by Gas Chromatography Mass Spectrometry (GC-MS) Solvent extraction and analysis by Gas Chromatography Mass Spectrometry (GC-MS) Solvent extraction and analysis by Gas Chromatography Mass Spectrometry (GC-MS) Solvent extraction and analysis by Gas Chromatography Mass Spectrometry (GC-MS) Solvent extraction and analysis by Gas Chromatography Mass Spectrometry (GC-MS) Each: 50 With reference to U. S. EPA 8270D With reference to U. S. EPA 8270D Each: Under development Under development Under development Each: 0.1 Each: 0.1 Each: 1 Solvent extraction and analysis by Gas Chromatography Mass Spectrometry (GC-MS) With reference to USEPA 8270D With reference to USEPA 8270D Each(Coal tar pitch& Anthracene oil compounds): 0.01 Each(Others): Each: Each: 0.01 Biocide Under development Under development Under development Under development May (20)