sludge mg/kg Finished Articles / Textiles mg/kg DIN EN ISO followed by Liquid followed by Liquid Chromatography Mass

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1 Nonylphenol ethoxylated 1. Alkylphenol (AP) and Alkylphenol Ethoxylates (APEOs) 4-(1,1,3,3 Tetramethylbutyl) phenol Oxtylphenol Pctylphenol Nonylphenol (branched) Nonylphenol Nonylphenol (mixed isomers) Nonylphenol Ethoxylates NPEO (1-2) various Nonylphenol Ethoxylates NPEO (3-18) various , , , , DIN EN ISO DIN EN ISO followed by Liquid followed by Liquid 1 (for each) Chromatography Mass 1 (for each) Chromatography Spectrometry (LC-MS) Analysis NPEO (1+2) : GC- MS Mass Spectrometry (LC-MS) Analysis NPEO (1+2) : GC-MS // GC-MS (Aps) LC-MS (APEOs) 4-Nonylphenol, ethoxylated Octylphenol Ethoxylates OPEO (1-2) various Octylphenol Ethoxylates OPEO (3-18) various 4-tert-Octyplphenolethoxylate , Chlorobenzene and Chlorotoluens Dichlorobenzene 1,2-Dichlorobenzene ,3-Dichlorobenzene ,4-Dichlorobenzene Trichlorobenzene 1,2,3-Trichlorobenzene ,2,4-Trichlorobenzene ,3,5-Trichlorobenzene Tetrachlorobenzene ,2,3,4-Tetrachlorbenzene ,2,3,5-Tetrachlorbenzene ,2,4,5-Tetrachlorbenzene Pentachlorbenzene Xexachlorbenzene Chlorinated Solvents Dichloromethane Chloroform Tetrachlormethane ,1,2-Trichloroethane Chlorobenzenes: 0.02 / Chlorotoluenes: 1 for some substances Chlorobenzenes: 0.5 Liquid Extraction GC-MS / Chlorotoluenes: 1 for some substances 0,5 (each) Liquid Extraction GC-MS Chlorobenzenes: 1 / Chlorotoluenes: 1 Sum all < 5 mg/kg Chlorobenzenes: 1 / Chlorotoluenes: 1 Sum all < 5 mg/kg DIN or //GC-MS

2 1,1-Dichloroethane ,2-Dichloroethane Trichloroethylene (each) HS-GC/MS Analysis Perchloroethane ,1,1-Trichloroethane ,1,1,2-Tetrachloroethane ,1,2,2-Tetrachloroethane Pentachlorbenzene ,1-Dichloroethylene Chlorophenols Pentachlorophenols (PCP) Tetrachlorophenol (TeCP) ,3,4,5-Tetrachlorophenol ,3,4,6-Tetrachlorophenol ,3,5,6-Tetrachlorophenol Trichlorophenol (TriCP) ,4,6-Trichlorophenol ,3,4-Trichlorophenol ,3,5-Trichlorophenol ,3,6-Trichlorophenol ,4,5-Trichlorophenol ,4,5-Trichlorophenol Dichlorophenols (DiCP) ,3-Dichlorophenol ,4-Dichlorophenol ,5-Dichlorophenol ,4-Dichlorophenol ,5-Dichlorophenol Mono Chlorophenol various 5. SCCP ,5 (sum) 6. Amines (associated with Azo dyes) 4-Aminodiphenyl Benzidine Chloro-o-Toluidine Naphthylamine o-aminoazotoluene Amino-4-Nitrotoluene p-chloroaniline ,4-Diaminoanisole ,4 -Diaminodiphenylmethane ,3 -Dichlorobenzine ,3 -Dimethoxybenzidine ,3 -Dimethylbenzidine ,3 -Dimethyl-4,4 - Diaminodiphenylmethane (each) 1 Liquid Extraction / derivation // GC-MS Extraction with Toluene // GC-MS resp. LC/MS With reference to EN 14362:1+3 // GC-MS and HPLC 0,5 (each) 0.05 (each) 1 (sum) HS-GC/MS Analysis Liquid Extraction / derivation // GC- MS Extraction with Toluene // GC-MS resp. LC/MS usage ban traces sum 0.1 With reference to 1 EN 14362:1+3 // GCtraces < 30 MS and HPLC usage ban sum 0.5 traces < 30 // GC-MS BVL :2001 Leather: ISO 17070:2012 (Draft) With reference to EN 14362:1+3 // GC- MS and HPLC Leather: EN ISO

3 p-cresidine ,4 Methylene-Bis(2- Chloroaniline) ,4 -Oxydianiline ,4 -Thiodianiline o-toluidine ,4-Toluylenediamine ,4,5-Trimetylaniline o-anisidine p-aminoazobenzene ,4-Xylidine ,6-Xylidine and HPLC MS and HPLC Leather: EN ISO 17234: 1+2 Subgroup: Dyes Carcinogenic C.I. Acid Red C.I. Basic Red C.I. Basic Violet C.I. Direct Blue C.I. Direct red C.I. Direct Black C.I. Disperse Blue C.I. Disperse Yellow C.I. Disperse Orange C.I. Disperse Xellow C.I. Disperse Orange C.I. Solvent Yellow C.I. Solvent Yellow C.I. Solvent Yellow ,3 C.I. Solvent Yellow C.I. Basis Blue C.I. Basic Violet C.I. Direct Brown C.I. Direct Blue C.I. Direct Blue C.I. Acid red C.I. Acid Violet Subgroup: Dyes Disperse 1 5 Traces:20 Traces:20 DIN C.I. Disperse Blue C.I. Disperse Blue C.I. Disperse Blue C.I. Disperse Blue ,7 C.I. Disperse Blue C.I. Disperse Blue C.I. Disperse Blue C.I. Disperse Blue C.I. Disperse Brown C.I. Disperse Orange C.I. Disperse Orange C.I. Disperse Orange 37/ : for each of C.I. Disperse Yellow 3 and C.I. Disperse Blue 1 5 t DIN 54231

4 C.I. Disperse Red C.I. Disperse red C.I. Disperse red C.I. Disperse Yellow C.I. Disperse Yellow C.I. Disperse Yellow C.I. Disperse Yellow C.I. Disperse Yellow Brominated and Chlorinated Flame Retardants Polybrominated biphenyls (PBBs) various Monobromo biphenyls (MonoBB) - Dobromo biphenyls (DiBB) - Tribromo biphenyls (TriBB) - Tetrabromo biphenyls (TetraBB) - Pentabromo biphyls (PentaBB) - Hexabromo biphenyls (HexaBB) - Heptabromo biphenyls (HeptaBB) - Octabromo biphenyls (OctaBB) - Nonabromo biphenyls (NonaBB) - Decabromo biphenyls (decabb) Polybrominateds diphenyl ethers (PBDEs) Monobromo diphenylethers (MonoDBE) various - Dibromo diphenylethers (DiDBE) - Trinbromo diphenylethers (TriDBE) Tetrabromo diphenylethers (tetradbe) Pentaobromo diphenylethers (PentaDBE) Hexabromo diphenylethers (HexaoDBE) Heptabromo diphenylethers (heptadbe) Octabromo diphenylethers (OctaDBE) ,0 GC- 5 for each 5 for each MS/LC-MS GC-MS/LC-MS usage Ban DL: 5 usage Ban DL: 5 GC-MS/LC-MS

5 Nonabromo diphenylethers (NonaDBE) Decabromo diphenylethers (DecaDBE) Tris(2,3-Dibromopropyl)- Phosphate Tris(2-Chloroethyl)Phosphate (TCEP) Hexabromocyclododecane (HBCDD) 8. Glycols , , , , Tetrabromo-bisphenol A (TBBPA) Subgroup: other flame retardants TEPA TRIS , Sodium tetraborate 4, , Boron trioxide for each Boric acid , Antimony trioxide Tri-o-cresyl phosphate Tris(1,3-dichloro-2- propyl)phosphate (TDCPP) , , , , , , , , Solvents Benzene ,2 Dichloroethane Dichloromethane N,N-Dimethylacetamide (DMAc) for each except for 2- methoxypropylacetate: 5 GC- MS/LC-MS 5 for each 10 for each except for 2- methoxypropylaceta te 1 GC-MS/LC-MS usage Ban DL: 5 Both: 1000 Usage ban usage Ban DL: 5 2- ethoxyethylacetate: 500 Bis-(2- methoxyethyl) ether: 1000 Usage ban Usage ban 50 for Usage ban 50 for N,N-Dimethylformamide (DMF) be solvent coated solvent coated fixed until mid articles articles N-Ethyl-2-pyrrolidone (NEP) N-Methylpyrrolidone (NMP) Tetrachloroethylene usage ban usage ban (Perchloroethylene) Toluene Trichloroethylene usage ban usage ban GC-MS/LC-MS GC-MS partly Usage Ba

6 Xylene, all isomers usage bam usage ban 10. Organotin Compounds MBT DBT TBT TPHT DOT MOT DphT TeBT TCyT - TPT - TeET TBTO DBTC TPT DBB Polycyclic Aromatic Hydrocarbons (PAHs) Benzo- [a]-pyrene (BaP) (each) or best current DIN EN // GC-MS 1 (each) or best current range from 0.5 to 2 DIN EN // GC- (MBT 1, MOT 2, MS DOT 1) range from 0.5 to 2 (MBT 1, MOT 2, DOT 1) // GC-MS or LC-MS or Multiple Headspace GC-MS Benzo- [e]-pyrene (BeP) Benzo- [a]-anthracene (BaA) Chrysene (CHR) Benzo- [b]-fluoranthene (BbFA) Benzo- [j]-fluoranthene (BjFA) (each), Naphthalene: (each), Naphthalene: 1 range Naphthalene: 50 sum all 10 Naphthalene: 500 /GC-MS Benzo- [k]-fluoranthene (BkFA) Dibenzo-[a,h]-anthracene (DBAhA) 12. Perfluorinated and Polyfluorinated Chemicals (PFCs) PFOA PFNA PFBS or PFOS :2 FTOH :2 FTOH :2 FTOH :2 FTOH POSF PFHxS PFHxA PFOSA PFHpA PFDA between 0.01, FTOH 0.1 each CEN/TS 15968:2010 LC/MS between 0.01, FTOH 0.1 each EN/TS 15968:2010 Wi 18 collection apparell, tents, shoes, Wi 18 collection apparell, tents, shoes, EN/TS 15968:2010 Wi 18 collection apparell, tents, shoes,

7 PFUnA PFDoA PFTrA PfteA PFHpS PFDS :2 FTA :2 FTA :2 FTA PF-3,7-DMOA HPFHpA HPFHUnA H, 1H, 2H, 2H-PFOS Phthalates Di-Butyl Phthalate (DPB) Di(2-Ethylhexyl) Phthalate (DEHP) Benzylbutyl Phthalate (BBP) , Di-Iso-Nonyl Phthalate (DINP) 48-0 Di-N-Octyl Phthalate (DNOP) , Di-Isodecyl Phthalate (DIDP) 49-1 Di-Isobutyl Phthalate (DIBP) Di-N-Hexyl Phthalate (DNHP) Di-(2-methoxyethyl) Phthalate (DMEP) 1,2-Benzenedicarboxylicacid, di C7-11-branched and linear alkyl 1,2-Benzenedicarboxylicacid, die C6-8 branched alkyl esters, C7 Dipentylphthalate (DPP) Diisopentylphthalate N-pentyl-Isopentyl Phthalate Heavy Metals 0.1 each LC/MS FTOH 0.1 each 1 (each) 10 (each) Total Cadmium (Cd) (extractable) 0.2 (extractable) Extraction DIN EN ISO 105-E04:2009 // ICP Total Lead (Pb) (total) 100 (total) Total digestion // ICP Total Mercury (Hg) Digestion ICP 0.02 (extractable) 0.02 (extractable) Digestion ICP analysis analysis Total Nickel (Ni) (total) 90 (total) Total Chrom VI (Cr-VI) leather: leather: 3 Total Arsenic (As) (extractable) 0.2 (extractable) Total Chrom (Cr) (extractable) 3 (extractable) Total Antimony (Sb) (extractable) 5 (extractable) 15. Isocyanates Diphenylmethane-4,4- diisocyanate (MDI) //LC-MS Toluene Extraction // GC_MS resp. LC/MS backpacks 2020 latest usage ban / traces 50 per single substance backpacks 2020 latest sum: 1000 //LC-MS Toluene Extraction // GC_MS resp. LC/MS Extraction DIN EN ISO 105-E04:2009 // ICP tents, shoes, backpacks 2020 latest

8 Hexamethylene didisocyanate (HMDI) Isophorone diidocyanate (IPDI) be fixed until mid summ of all 1.0 summ of all 1.0 Tetramethylxylene diisocyanate Toluene-2,4-diisocyanate (2,4- TDI) Toluene-2,6-diisocyanate (2,6- TDI) Volatile Organic Compounds (VOCs) Xylene o-cresol 10 p-cresol 10 m-cresol others Cyanide be be fixed until mis Formaldehyde fixed until mis EN :2001 (plastics) Extraction // Derivation//LC ISO Leather ISO MRSL Review Process: The process will be clearly framed with the intention to derive a (shared or individual) MRSL with a broad list of chemicals based on the hazard based screening methodology an principles outlined in the VAUDE Detox commitment. The MRSL covers incoming water, waste water, sludge and finished articles to support disclosure and inform the "clean factory" approach. Any collaborative work should have a clear understanding of progressively lowering contaminations in input through leverage and engagement (see VAUDE Detox commitment).

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