MIGROS REQUIREMENTS FOR TEXTILE

Transcription

1 MIGROS REQUIREMENTS FOR TEXTILE RSL Restricted Substance List ISSUE 3 February 2017

2 Restricted Harmful Substance List Introduction Objective/purpose Migros has set the goal of producing all of its store brand textiles according to eco regulations by the end of Within the framework of this goal, the requirements on hazardous substances for all textile suppliers will be integrated into Migros' regulations. The list of regulated substances has been revised and expanded according to the current level of understanding on the subject. In addition, the relevant legal requirements of Switzerland and the EU as well as the regulations and general terms and conditions of Migros apply. With the emergence of new scientific understanding, the list will be adjusted and published following internal approval; the current list represents the level of knowledge as of August Validity This document (Migros RSL Issue 3) comes into effect for all orders and eco registration made from February 15 th Basic Requirements The requirements are applicable to all textile suppliers and must be communicated by them throughout the supply chain. In addition, the requirements of the Migros inspection plan for textiles apply for products being received or sold. For ecological and toxicological reasons are the below mentioned substances, which are used in conventional textile processing, not to be used by Migros textile suppliers throughout the entire production process and replaced by alternative ecological variations. This also applies on auxiliary, which contain the below mentioned substances. APEO s (Substances Group # 6 and Appendix A (A11)) Chlorophenols (Substances Group # 8 and Appendix A (A10)) Flame retardants (Substances Group # 13 and Appendix A (A5)) Fluorinated hydrocarbons (e.g. PFC) Solvents (Substances Group # 30 and Appendix A (A16)) Phthalates (Substances Group # 25 and Appendix A (A6)) PVC (Appendix A (A15)) Owner: ET QS 2 of 17 Issue: 3

3 2.1. Detailed Information APEO s The use of Textile auxiliaries and dyestuffs, which contain APEOs, are banned. If the concentration exceeds the limited value, the source of contamination has to be specified and the quality management has to be informed. Flame retardants Flame retardants are in general banned. In exceptional cases, if the product requires the use of flame retardants, there can be defined as exceptions. But the Migros quality management has to give their approval. Fluorinated hydrocarbons (PFCs) Generally, Migros is banning all products, which have a PFC finish. In cases, where a ban is still not possible, is to be clarified if alternative finishing are available. During this evaluation Migros will permit to use PFC finishing, but only short chain PFCs ( C6). Biocide Biocides or antimicrobial treatments are forbidden for use in textiles. Biocides, which are approved by bluesign are also allowed at Migros. Ecological alternatives that include explanations on the relevant principles may be used only after consultation with and approval by MGB quality management. The most current scientific level of knowledge will be applied for the evaluation. Solvents Migros generally defines, that in their products no solvents should be used, especially chlorinated solvents. Owner: ET QS 3 of 17 Issue: 3

4 3. Regulations The Migros hazardous substance requirements are considered final unless stricter Swiss/EU laws or Migros provisions concerning hazardous substances exist. Those requirements must then be adhered to as well. Particularly relevant are the REACH legislation and associated Migros regulations. The related current SVHC or candidate list must be adhered to. 4. Product classes The requirements apply to the following three product categories: Product class I Textiles for babies and children (clothing sizes 50 to 182). Product class II Textiles with direct skin contact and all clothing types that do not belong to product category 1 (e.g. underwear, linens, terry cloth products, shirts, blouses) Product class III Textiles with brief or no skin contact (e.g. jackets, coats, table linens and curtains but also textiles for walls and floors) 5. Limited Values The limited values, which are mentioned in chapter 5.2. (in table of Restricted Substances) are valid for the final products. Upon request the supplier is obliged to provide Migros with safety data sheets and/or product specifications or additional documentation showing the chemical substances/formulations used in production and conduct self-checks within 10 working days. Owner: ET QS 4 of 17 Issue: 3

5 5.1. Scope/ Basis of evaluation The following chart shows Migros' requirements for hazardous substances used in store brand textiles, which are valid for every individual textile component. The requirements are listed for each substance and pollutant group by CAS number. In addition to the current risk assessment by MGB quality management, the following general evaluation criteria apply: - If products exceed the legal limits or regulations (primarily those on azo dyes, phthalates, nickel and chromium VI), most likely they cannot be sold or must be removed from the shelves Table of Restricted Substances The limited values are valid for each component of an product. Restricted substances CAS N Material Limited values Product class I Product class II Product class III Test method 1 Azo-dyestuffs (A1) Cleavable arylamines * - Prints, Coatings 20 Textile: DIN EN (in current version) Leather: EN ISO (in current version) Allergenic dyestuffs (A2) 2 * - Synthetics and leather Prints, Coatings 20 Carcinogenic colourants (A3) DIN * - Other banned dyestuffs (A17) Prints, Coatings 20 + test methods for Pigment Red 104 and Pigment Yellow 34 (Inductively Coupled Argon Plasma Spectrometry) 4 * - Prints, Coatings 20 * Values applicable for every individual substance listed in the attachment. Owner: ET QS 5 of 17 Issue: 3

6 Restricted substances CAS N Material Limited values Product class I Product class II Product class III Test method Alkylphenols (AP) (A11) 5 Nonylphenols NP Octylphenols OP Polymers (rubber, foams, prints, coatings, etc.) Polymers (rubber, foams, prints, coatings, etc.) banned (traces 10) banned (traces 10) Extraction with Ethanol or THF/Acetonitrile, GC-MS and LC- DAD-Analysis Alkylphenol ethoxylates (APEO) (A11) 6 Nonylphenol ethoxylates NPEO Polymers (rubber, foams, prints, coatings, etc.) 100 Extraction with ethanol or THF/Acetonitrile, LC-MS- Analysis Octylphenol ethoxylates OPEO Polymers (rubber, foams, prints, coatings, etc.) Biocide finish - banned Solvent extraction / GC-MS-Analysis Chlorinated Phenols (A10) 8 Pentachlorophenol PCP Tetrachlorophenols TeCP * , wood Prints, Coatings Prints, Coatings ASE- or KOH-extraction, determination according LFGB 64, BVL B Wood: PCP-Water distillation Trichlorphenol TriCP * Values applicable for every individual substance listed in the attachment. Owner: ET QS 6 of 17 Issue: 3

7 Restricted substances CAS N Material Limited values Product class I Product class II Product class III Test method Orthophenylphenol OPP Chlorinated organic carriers (A4) * Chromium VI Natural fibers, synthetics 0.5 Leather 3 Extraction with Dichloromethane / GC-MS-Analysis (EN DIN 54232) 974 Artificial Ageing DIN EN ISO Dimethylfumarate DMF banned 0.1 Solvent extraction / GC-MS-Analysis 12 2,4-Dinitrotoluene Dyestuff, Polyurethane 1.0 Solvent extraction / GC-MS-Analysis 13 Flame retardant finish (A5) * - banned (see Appendix (A5)) Solvent extraction / GC-MS-Analysis 14 Formaldehyde Prints, Coatings, Wood Notes: For carpeting, 300 Textiles and Wood: DIN EN ISO / Japanese Rules 112 Leather: DIN EN ISO * Values applicable for every individual substance listed in the attachment. Owner: ET QS 7 of 17 Issue: 3

8 Restricted substances CAS N Material Limited values Product class I Product class II Product class III Test method Extractable heavy metals Antimony Sb Arsenic As Lead Pb Cadmium Cd Chromium Cr (total) Cobalt Co Copper Cu Nickel Ni Mercury Hg DIN ISO 105E04 Heavy metals in digested sample 16 Lead Cadmium Polymers (rubber, foams, prints, coatings, etc.) Metal parts 90 Polymers (rubber, foams, prints, coatings, etc.) Microwave designation followed by ICP/MS According to DIN EN ISO Metal parts 100 Owner: ET QS 8 of 17 Issue: 3

9 Restricted substances CAS N Material Limited values Product class I Product class II Product class III Test method Organotin compounds (A8) Dibutyltin DBT Tributyltin TBT Monobutyltin MBT DIN EN ISO (Extraction with Ethanol/ Derivation with Dimethylcarbamate / GC-MS- Analysis) Triphenyltin TPhT Dioctyltin DOT Monoctyltin MOT Polymers (rubber, foams, prints, etc.) Tetrabutyltin TeBT Tetraoctyltin TeOT DIN EN ISO (Extraction with Ethanol/ Derivation with Dimethylcarbamate / GC-MS- Analysis) Tricyclohexyltin TricycloHT μg/m² Perfluorooctan banned (0.1) sulfonates PFOS (A7) Prints, coatings 1.0 Perfluorooctanoic acid PFOA (A7) banned (0.1) banned (0.25) banned (1.0) Prints, coatings 1.0 μg/m² Extraction with Methanol/ GC-MS- Analysis Owner: ET QS 9 of 17 Issue: 3

10 Restricted substances CAS N Material Limited values Product class I Product class II Product class III Test method 20 Pesticides (A18) Total concentration of Pesticides (incl. PCP/TeCP) Solvent Extraction / GC-MS- Analysis Short chain chlorinated paraffins Solvent Extraction/ GC-MS- Analysis (C 10-C 13) - 30 Soluble mineral tanning agents (total Al, Cr, Ti, Zr) - Leather Isocyanates (A14) Sum of all Isocyanates* - Polymers (rubber, foams, prints, etc.) 1.0 Extraction with acid perspiration solution acc. to DIN EN ISO 105- E04 (Cat. II + III), Determination acc. DIN EN ISO (ICP-MS) Extraction with saliva solution acc. LFGB 64, BVL B (Kat. I), Determination acc. DIN EN ISO (ICP-MS) Extraction with DCM and derivation with 9-(Methylamino-methyl)- anthracene/ HPLC according to EN (current version) PAH 24 Benzo(a)pyrene Chrysene Benzo(b)fluoranthene Benzo(j)fluoranthene Benzo(a) anthracene Polymers (rubber, foams, prints, etc.) Benzo(k)fluoranthene Benzo(e)pyrene Dibenz(a,h)anthracene Sum of PAHs (A9) According to ZEK , Extraction with Toluene Determination with GC-MS AfPS GS 2014:01 * Values applicable for every individual substance listed in the attachment. Owner: ET QS 10 of 17 Issue: 3

11 Restricted substances CAS N Material Limited values Product class I Product class II Product class III Test method Phthalates (A6) * - Polymers (rubber, foams, prints, etc.) % - banned (traces 0.1) PVC (A15) Polymers (rubber, foams, prints, etc.) banned Solvent Extraction/ GC-MS- Analysis Beilstein method Formamide and others (A13) Formamide N-methylformamide Polymers (rubber, foams, prints, etc.) 2-phenyl-2-propanol Acetophenone VOCs (A12) Toluene banned (traces 10) Styrene Vinylcyclohexene Phenyl-cyclohexene Polymers (rubber, foams, prints, etc.) Butadiene Vinylchloride Aromatic hydrocarbons - 30 Organic volatiles - 50 Solvent extraction/ GC-MS-Analysis Solvent extraction/ GC-MS-Analysis 29 μg/cm²/woche LFGB 64, Nickel release - Metal parts 0.5 BVL B (DIN EN ISO 1811) BVL B (DIN EN 12472) Owner: ET QS 11 of 17 Issue: 3

12 Restricted substances CAS N Material Limited values Product class I Product class II Product class III Test method 30 Solvents (A16) 1,1,1-Trichloroethane ,1,2-Trichloroethane ,1-Dichloroethylene ,2-Dichloroethane Ethoxyethanol Ethoxyethyl acetate Methoxyethanol Benzene Bis(2-methoxyethyl) ether Dichloromethane Dimethylformamide (DMF) Natural Fibers, Synthetic, Leather 5 Ethylbenzene Polymers (rubber, foams, prints, etc.) 50 n-hexane Metal parts 10 n-methylpyrrolidone Phenol Tetrachloroethylene Trichlorobenzene all isomers various Sum: 5 Trichloromethan (Chloroform) Xylene all isomers ,2,3-Trichloropropan o-cresol p-cresol m-cresol Solvent extraction/ GC-MS- Analysis Owner: ET QS 12 of 17 Issue: 3

13 Appendix A The substances, which are found in the Appendix (A12 and A16), do belong to the same substance group, but for analyzing reasons are considered as two separate groups. The substances of A16 are banned and the substances of A12 are those, which must not come out of the component. (A1) Azodyes CAS N 1. 4-Aminoazobenzene o-aminoazotoluene Aminodiphenyl Amino-4-nitrotoluene o-anisidine Benzidine p-chloroaniline Chloro-o-toluidine p-cresidine ,4-Diaminoanisole ,4'-Diaminodiphenylmethane ,3'-Dichlorobenzidine ,3'-Dimethoxybenzidine ,3'-Dimethylbenzidine ,3'-Dimethyl-4,4'- diaminodiphenylmethane ,4'-Methylene-bis-(2- chloroaniline) Naphthylamine ,4'-Oxydianiline ,4'-Thiodianiline ,4-Toluenediamine o-toluidine ,4,5-Trimethylaniline ,4-Xylidine ,6-Xylidine Amino-2-ethoxynaphthalene Amino-3-fluorophenol dimethylaminoazobenzene p-toluidine m-toluidine ,4-Dinitrotoluene (A2) Allergenic dyestuffs CAS N 1. Disperse Blue 3 C.I Disperse Blue 7 C.I Disperse Blue 26 C.I Disperse Blue Disperse Blue Disperse Blue Disperse Blue Disperse Brown Disperse Orange 1 C.I Disperse Orange 3 C.I Disperse Orange 59 C.I Disperse Red 1 C.I Disperse Red 11 C.I Disperse Red 17 C.I Disperse Yellow 1 C.I Disperse Yellow 9 C.I Disperse Yellow 39 C.I Disperse Yellow Disperse Blue 1 C.I Disperse Orange 37 C.I Disperse Orange 76 C.I Disperse Yellow 23 C.I Disperse Orange ) C.I. = Color Index ( Owner: ET QS 13 of 17 Issue: 3

14 (A3) Carcinogenic colourants CAS N 1. Acid Red 26 C.I Basic Red 9 C.I Basic Violet 14 C.I Direct Black 38 C.I Direct Blue 6 C.I Direct Red 28 C.I Disperse Blue 1 C.I Disperse Orange 11 C.I Disperse Yellow 3 C.I Pigment Red 104 C.I Pigment Yellow 34 C.I Direct Brown 95 C.I (A4) Chlorinated organic carriers CAS N 1. Monochlorobenzene Dichlorobenzenes, all isomers Trichlorobenzenes, all isomers Tetrachlorobenzenes Pentachlorobenzene Hexachlorobenzene Chlorotoluenes, all isomers Monochlorotoluenes Dichlorotoluenes, all isomers Trichlorotoluenes Tetrachlorotoluenes Pentachlorotoluene (A5) Flame retardants CAS N 1. Polybrominated biphenyls PBB group 2. Tri-(2,3-dibromopropyl)-phosphate TRIS Tris-(aziridinyl)-phosphinoxide TEPA Pentabromodiphenylether pentabde Octabromodiphenylether octabde Decabromodiphenylether decabde Hexabromocyclododecane HBCDD Tris-(2-chloroethyl)-phosphate TCEP Bis-(2,3-dibromopopyl)phosphate Tetrabromobisphenol A TBBPA (A6) Phthalates CAS N 1. Di-iso-nonylphthalate DINP Di-n-octylphthalate DNOP Di(2-ethylhexyl)phthalate DEHP Di-iso-decylphthalate DIDP Butylbenzylphthalate BBP Dibutylphthalate DBP Di-iso-butylphthalate DIBP Di-C7-11-branched and linear alkyl esters DHNUP Di-C6-8-branched alkyl esters DIHP Bis(2-methoxyethyl)phthalate DMEP Di-n-hexylphthalate DNHP Di-pentylphthalate (n-, iso-, or mixed) DIPP N-pentyl-isopentylphthalate(iPnPP), 1,2-Benzenedicarboxylic acid, dipentylester, branched & linear , Dimethylphthalate DMP Diethyl phthalate DEP all other phthalates (all other ester of o-phthalic acid) various 16. Dinonyl phthalate DNP Di-n-propyl phthalate DPRP Di cyclohexyl phthalate DCHP Di-iso-octyl phthalate DIOP (A7) PFOS and PFOA CAS N 1. Perfluorooctane sulfonates PFOS several compounds 2. Perfluorooctanoic acid PFOA Owner: ET QS 14 of 17 Issue: 3

15 (A8) Organotin compounds CAS N 1. Monobutyltin MBT Monooctyltin MOT several 3. Dibutyltin DBT Dioctyltin DOT Tributyltin TBT Tricyclohexyltin TricycloHT several 7. Triphenyltin TPhT Tetrabutyltin TeBT Tetraoctyltin TeOT (A9) PAHs polycyclic aromatic hydrocarbons CAS N 1. Acenaphthene Acenaphthylene Anthracene Benz(a)anthracene Benzo(a)pyrene Benzo(e)pyrene Benzo(b)fluoranthene Benzo(g,h,i)perylene Benzo(j)fluoranthene Benzo(k)fluoranthene Chrysene Fluoranthene Fluorene Indeno(1,2,3-cd)pyrene Naphthalene Phenanthrene Pyrene Dibenz(a,h)anthracene Dibenzo(a,e)pyrene Dibenzo(a,h)pyrene Dibenzo(a,i)pyrene Dibenzo(a,l)pyrene Methylpyrene Cyclopenta(c,d)pyrene (A10) Chlorinated Phenols CAS N 1. Pentachlorophenol PCP Tetrachlorophenols (TeCP), salts and compounds, which are not mentioned below 3. 2,3,4,5-Tetrachlorophenol TeCP ,3,4,6-Tetrachlorophenol TeCP ,3,5,6-Tetrachlorophenol TeCP Trichlorophenol TriCP (A11) AP and APEO - alkylphenols and alkylphenolethoxylates CAS N 1. Nonylphenols NP, mixed isomers Octylphenols OP Nonylphenolethoxylates NPEO Octylphenolethoxylates OPEO Nonylphenol Isononylphenol Nonylphenol, branched Octylphenol Octylphenol Polyoxyethylated p-nonyl phenol Isononylphenol, ethoxylated Nonylphenol, branched, ethoxylated Nonylphenol, branched, ethoxylated Octylphenol, ethoxylated Octyl phenol ethoxylate, branched 9.5EO (1,1,3,3- tetramethylbutyl)phenol,ethoxylated - Owner: ET QS 15 of 17 Issue: 3

16 (A12) VOCs - volatile organic CAS N compounds 1. Toluene Styrene Vinylcyclohexene Phenylcyclohexene Butadiene Vinylchloride (A13) Formamide and other related substances CAS N 1. Formamide N,N-dimethylformamide N-methylformamide phenyl-2-propanol Acetophenone (14) Isocyanates CAS N 1. Diphenylmethane diisocyanate MDI Hexamethylene diisocyanate HMDI Isophorone diisocyanate IPDI Tetramethylxylene diisocyanate TMXDI Toluene diisocyanate 2,4-TDI Toluene diisocyanate 2,6-TDI (A15) Other restricted chemicals CAS N 1. Orthophenylphenol OPP Polyvinylchloride PVC Polyvinylidenchloride PVDC Polychloroprene (A16) Solvents CAS N 1. 1,1,1-Trichloroethane ,1,2-Trichloroethane ,1-Dichloroethylene ,2-Dichloroethane Ethoxyethanol Ethoxyethyl acetate Methoxyethanol Benzene Bis(2-methoxyethyl) ether Dichloromethane Dimethyl formamide Ethylbenzene n-hexane n-methyl pyrrolidone Phenol Tetrachloroethylene Trichlorobenzene all isomers various 18. Trichloromethan Xylene all isomers ,2,3-Trichloropropan o-cresol p-cresol m-cresol (A17) Colorants banned for other reasons CAS N 1. Acid Orange Acid Violet Basic Blue Basic Green 4 Several 4. Malachit Green Malachit Green chloride Malachit Green oxalate Basic Violet Basic Violet Direct Black Direct Blue Direct Blue Navy Blue: A mixture of disodium (6-(4- anisidino)-3-sulfonato-2-(3,5-dinitro-2- oxidophenylazo)-1-naphtholato)(1-(5- chloro-2-oxidophenylazo) naphtholato)chromate(1-); trisodium bis (6-(4-anisidino)-3-sulfonato-2-(3,5- dinitro-2-oxidophenylazo)-1- naphtholato)chromat 11. Solvent Blue Solvent Yellow 1 C.I Aniline p-phenylenediamine C.I Owner: ET QS 16 of 17 Issue: 3

17 (A18) Pesticides CAS N 1 Aldrine Azinphos-methyl Azinphos-ethyl Binapacryl Bromophos-ethyl Captafol Carbaryl Chlordane Chlordecone Chlordimeform Chlorfenvinphos Chlorbenzylate Coumaphos Cyfluthrin Cyhalothrin, lambda Cypermethrin Deltamethrin Diazinon Dichlofenthion o,p -Dichlorodiphenyldichloroethane (o,p -DDD) p,p -Dichlorodiphenyldichloroethane (p,p -DDD) o,p -Dichlorodiphenyldichloroethylene (o,p -DDE) p,p -Dichlorodiphenyldichloroethylene (p,p -DDE) o,p -Dichlorodiphenyltrichloroethane (o,p -DDT) and its isomers; preparations containing DDT and its isomers p,p -Dichlorodiphenyltrichloroethane (p,p -DDT) and its isomers; preparations containing DDT and its isomers 2,4-Dichlorophenoxyacetic acid, its salts and compounds ,6-Dichloro-7-(2,4,5-27 trichlorophenoxy)-2- trifluoromethylbenzimidazole (DTTB) 28 Dichlorprop Dicrotophos Dieldrine Dimethoate Dinoseb and salts Endosulfan Endosulfan, alpha Endusulfan, beta Endrine Esfenvalerate Fenvalerate Heptachlor Heptachlor epoxide Isodrin Kelevane Lindane (gamme-hch) Malathion MCPA MCPB Mecoprop Methamidophos Methoxychlor Methyl parathion Mevinophos Mirex Monocrotophos Ethyl parathion Perthane Phosphamidon Profenophos Propetamphos Quinalphos Strobane Toxaphene Tribufos (DEF) Trifluralin ,4,5-Trichlorophenoxyacetic acid and its salts and 2,4,5-Tricholorphenoxyacetyl Various compounds 2,4,5-T 65 Hexachlorcyclohexane, α Hexachlorcyclohexane, β Hexachlorcyclohexane, δ (2,4,5-Trichlorophenoxy) propionic acid and its salts and 2-(2,4,5- Trichlorophenoxy) propionyl compounds 2,4-D Various 69 Permethrin Owner: ET QS 17 of 17 Issue: 3