Institute of Materials Science of Mulhouse. Vincent Roucoules. UMR 7361 CNRS. 27 th november, 2017 SULZBACH- ROSEMBERG (GERMANY)

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1 Institute of Materials Science of Mulhouse Director(s): Mulhouse Cathie Vix Vincent Roucoules UMR 7361 CNRS 10,0 µ 27 th november, 2017 SULZBACH- ROSEMBERG (GERMANY)

2 Institute of Materials Science of Mulhouse 2

3 Institute of Materials Science of Mulhouse o Multi-and transdisciplinarity research in the field of: Functional Materials Surfaces and Interfaces o 200 papers/year 5 patents/ year Synthesis Functionalisation Processing Performance Testings Industrial application Surface/bulk characterizations - modeling 3

4 Institute of Materials Science of Mulhouse o 160 persons including a permanent staff of 100 persons o 9 technical platforms, Iso 9001 certified 33 facilities for length-scale characterizations o Advanced specialized equipment in unique configuration o Over 100 students/an o A strong academic and industrial network at the national and international level o 8 research areas (teams) 4

5 Technical Plateforms Microscopy (confocal, SEM (3), TEM (2)) Spectroscopy (IR, FTIR, Raman, XPS) Near field Microscopy (AFM, STM, STM TS low temperature, spin polarized STM ) X-Ray diffraction (XRD, SAXS/WAXS) 5

6 Technical Plateforms Physical-chemical characterization (adsorption, calorimetry, chromatography...) Mechanical and thermomechanical tests Common services : workshop, electronics, vacuum techniques, store Solid NMR (C, Si, F, Al, Na, P, H) 6

7 A dense network of academic partnerhips Over 100 french partnerships and 70 international partnerships 7

8 A dense network of industrial partnerships 50 industrial partners/ year Various sectors of activities o Aeronautic and aerospace o Automotive, o Sustainable building, o Chemistry o Energy storage, o Nutritional, o Cosmetic, o Health, implantable medical devices o Agriculture, agro-industry 8

9 8 main research areas o Functional Polymers Engineering Radical chemistry, plasma-assisted polymerization, macromolecular engineering, photopolymerizations Development of radical polymerization systems in the presence of oxygen J. Lalevée, J. Am. Chem. Soc. 2013, Nanoletter Fabrication of new functional polymers, such as surfaces with adaptative or responsive properties. V. Roucoules, ACS Nano

10 8 main research areas o Controlled porous materials: Development of new oxide-based porous solids (zeolite) à study of their adsorption properties and their energetic behavior zeolite IM-17 Shaping of zeolites for molecular decontamination in space 10

11 8 main research areas o Molecules, Nano-and microstructures Fabrication of Functional Micro-Nanostructures by unconventional methods based on photopolymerization and/or autoassembling à Study of the properties of molecular systems and nano-microstructures Photomaterials for Optics and Nanosciences O. Soppera, Ad. Interfaces Materials 2016, 2015 Wetting and self-assembly V. Luchnikov, Soft matter 2015, 2016 New method to monitor adhesion L. Vonna, Nanoletter 2015 Rapid 3D Microprototyping of Chemical sensors A. Spagenberg, Advanced Materials 2016, 2 patents 11

12 8 main research areas o Physics of low dimensional systems Synthesis, characterization, electronic properties, band structure engineering, functionalization of 2D Materials Graphene, Germanene. Molecules supramolecular assemblies/ 2D and 3D monocrystal o Vertical tunneling junctions (organic/inorganic heterostructures) An example of dispersion measured on Graphene First realization of an epitaxial 2D germanene layer on Aluminum substrate C. Pirri, Nanoletters 2015 J. Phys.chem;

13 8 main research areas o Multi-scale numerical modelling From structures to properties From the molecule to the material - Numerical simulations with quantum methods (Density Functional Theory) and classical methods (Molecular Dynamics, Monte Carlo) Comparison between experiment and simulation (adsorption isotherms, scanning tunneling microscopy images, ) Full DFT description of a 2D nanoporous supramolecular network on a silicon surface Ph. Sonnet - J. Phys.Chem Monte Carlo simulation of the 1,2-dichlorobenzene adsorption in the FAU Continuous germanene layer zeolite at 298 K on Al(111): analysis of the interface electronic states and charge transfer, Ph.Sonnet, J. Phys.chem

14 8 main research areas o Biomaterials/Biointerfaces Material synthesis using biological templates Process engineering for biological applications K. Anselme, ACS Applied Materials and Interfaces 2013 K. Anselme, Biomaterials

15 8 main research areas o Carbon and hybrid materials Carbon-based materials for energy storage, environmental and industrial applications. Understanding of interaction mechanisms between carbon materials / environment (solid, liquid, gas) during working conditions (applications) or during transformation processes. Design of novel carbon-based nanostructured materials with controlled features (porosity, surface chemistry, structures) M/C ou MX n /C, X=C,N,O,S et M= transition metal 10 µm 15

16 8 main research areas Transfers, Reactivity, Materials and Clean Processes (TRM2P) Team manager : Simona Bennici 16

17 Research staff Simona Bennici Jocelyne Brendlé Liva Dzene Patrick Dutournié Mejdi Jeguirim Lionel Limousy Permanent staff 3 Post doctoral positions 8 PhD students 4 master students 1 research engineer Non-permanent staff 17

18 Positionning and Strategy Experimental characterization - modeling 18

19 Transfer Reactivity Materials and Clean Processes Synthesis/elaboration and functionalization of materials - Carbon materials from solid biomasses - Lamellar compounds - Organic-inorganic hybrids (phyllosilicate type) - Composites and nanocomposites Processes design from targeted applications (experimental and modeling) - Membrane filtration (water rectification, ) - Energy storage (reversible thermochemical heat storage) - Torrefaction, pyrolysis, gasification (biochar/activated carbon for soil ) - Adsorption/controlled release/encapsulation (medicals, fertilizers, cosmetics ) Sawdust Soil Biomass production Pyrolysis Biochar OMWW Development of a circular economy at the territory scale Olive mill wastewater: From a pollutant to green fuels, agricultural water source and bio-fertilizer, ACS Sustainable Chemistry and Engineering,

20 Some specific setups of TRM2P Convective pilot dryer Adsorption/Catalytic FBR setup UF/NF pilot 20

21 Institute of Materials Science of Mulhouse Director(s): Mulhouse Cathie Vix Vincent Roucoules UMR 7361 CNRS 10,0 µ 27 th november, 2017 SULZBACH- ROSEMBERG (GERMANY)

22 Positionning and Strategy Scientific strategy of the group: Synthesis of functional materials adapted to the final process Use of characterization techniques and development of modeling methods to study mass and heat transfers in process conditions (knowledge model, inverse techniques,...) Applications: Energy storage, membrane filtration, material and energy valorisation of biosourced products, adsorption / desorption of active molecules à from the laboratory scale to the semi-pilot scale. 22