SiKÉMIA: Tailor-made Innovation. General overview

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1 SiKÉMIA: Tailor-made Innovation for your R&D General overview

2 SiKÉMIA SiKÉMIA : General Information SiKÉMIA is a French company specialized in the field of materials Surface Functionalization : glass, metals, alloys, metal oxides Founded in 2009 Located on the campus of the Montpellier University of Sciences 2

3 Franck MARTIN CEO PhD «Organic Chemistry» SiKÉMIA : Human Resources Aude MEZY Project Manager PhD «Materials», MBA Guillaume GRACY Chemist Production / Research Adeline Garcia Colorist / Chemist Research / Production Celine SCHMITT Project Manager PhD «Organic Chemistry» Kassem AMRO Project Manager PhD «Organic Chemistry» Scientific Council 3

4 SiKÉMIA: SAMs Technology The Coupling Agents assemble in a Monolayer to form a SAM Terminal Function gives the New Properties to the Surface of the Materials nm The Monomolecular Layer forms a Strong Chemical Bond with the Surface. Chemical Process: Easy to operate Process Self-Assembled Monolayer Low cost: 1mg of coupling agent for 1 m 2 of functionalized surface Lasting and Transparent coating Surface and Interface New Properties: Reactivity, Surface Energy, Charge, Tribological, Mechanical, Electronical properties Applications: Hydrophobation, Lubrication, Bio-Immobilization, Anti-Corrosive, Anti-icing, Self-cleaning, Primer, Epilam, etc. 4

5 SiKÉMIA: Expertise SiKÉMIA proposes a specific methodology which combines the development of Innovative Coupling Agents with Chemical Surface Functionalization. Anchoring Group: Covalent Binding to the Surface Organosylil Compounds: R-SiX 3 Si-O-Si Bonds Silica, SiO x /Si, etc. Organophosphorus Compounds: R-P=O(OX) 2, R-O-P=O(OX) 2 M-O-P Bonds Metals and Metalic Oxides: TiO 2, ZrO 2, Al 2 O 3, Fe 2 O 3, ITO, Ti, Cu, Steel, Apatites, CaCO 3, etc. Organosulfur Compounds: R-SH Coinage metals: Gold, Silver, Palladium, etc. M-S Bonds 5

6 SiKÉMIA: Linkers POSS: Polyhedral Oligomeric Silsesquioxane 8 active functions : T8 Partially condensed silsesquioxanes : T7 1 active function : T7+1 Specific molecules with inorganic silicate core and an organic exterior The chemical composition is a hybrid, intermediate (RSiO 1.5 ) between silica (SiO 2 ) and silicone (R 2 SiO). POSS molecule contains covalently bonded reactive functionalities suitable for polymerization or grafting. 6

7 SiKEMIA: MOFs Ligands (g to Kg) MOFs: Metal Organic Frameworks 3D materials possessing a thermal stability and a well ranked porosity obtained by the assembly of metallic entities with organic ligands 7

8 SiKÉMIA Offer: Go along with R&D of Company SiKÉMIA helps Manufacturers to create new products by solving technical difficulties with a broad range of Products and Services Products: Coupling Agents Catalog (approx. 200) Innovative Organosilyl and Organophosphorus compounds Services (Research Contract): Custom Synthesis (Assessment for one original compound in silicium, phosphorus and sulfur chemistry) Development of Functionalized Surfaces Licensing: 4 patents: 2011, 2012 (Cosmetic) and 2016 (Watch Industry, Electronic) 8

9 SiKÉMIA: Production Scale Final Product: mg to Kg SiKÉMIA Production High Purity > 95% Quote delivred within 24 hours Stock items shipped within 24 hours Assistance Scale up: Kg to Ton SiKÉMIA via CFKB and Arevipharma Final Product Outpout < 3000 Tons per year ISO 9001 certified Quality System 9

10 SiKÉMIA: Technical Analysis Platform X-ray Photoelectron Spectroscopy (XPS) Thermal Analysis (DSC, TGA, DTA) NMR 1 H, 19 F, 29 Si, 31 P Mass Spectroscopy Elemental Analysis Atomic Force Microscopy Scanning Electron Microscopy Brunauer, Emett et Teller Dynamic light scattering X-Ray Diffraction Contact Angle Infrared Spectroscopy UV-Visible Spectroscopy Transmission Electron Microscopy 10

11 Health Sector Industry SiKÉMIA: Markets Life Technologies, Roche Diagnostics, Affymetrix, etc. Polymer / Chemical Industry Michelin, BASF, DOW, Solvay, etc. Cosmetic & Luxury Industry L Oréal, LVMH, Breitling, etc. Distributors Sigma-Aldrich, Alfa Aesar, ABCR, etc. Public Research Institute CEA, Stanford, MPI, UCLA, Columbia, etc. 11

12 SAM s for Surface Passivation SiKEMIA: Coating uses SAM s for Surface Activation 12

13 SiKEMIA: Coating uses Additives in a matrix: paints, resins, polymers. Functionalized Surface Ex: Epoxy paint on cadmium screw without or with SiKEMIA s additive 13

14 SiKÉMIA: Functionalization of powder P O O O P O O O P O O O P O O O Treated Powder Powder New Surface Properties To improve their Stability To improve Dispersibility To Allow phase Transfer Hydrophobic Treatments Lipophobic Treatment Hydrophilic Treatments StabilizingTreatment Patents WO and WO

15 SiKÉMIA : French ANR / European Projects French ANR project (2014) : SUPREME B Health Industry: Biosensors Role of SiKÉMIA : Surface functionalisation of HDSC ITN European Project (2014) : PROMIS Electronics Industry: Optics-photonics Role of SiKÉMIA : PhD mentoring H2020 European Project (2015) : EIROS Aeronautic Industry: Anti-Icing Role of SiKÉMIA : Functionalisation of nanoparticles for the development of self-healing composite materials H2020 European Project (2016) : H-CCAT Catalysis sector : New hybrid materials for heterogeneous catalysis Role of SiKÉMIA : Synthesis of precursor materials ERA-MIN 2 European Project (2018) : MetRecycle Environment sector: Recycling of «heavy metals» Role of SiKÉMIA : Synthesis of coupling agents 15

16 Lauréat Contact: Franck MARTIN Phone: +33 (0) address: 16