Geochemistry Data Report - Oils and Gas Analyses Well 16/2-4

Transcription

1 Geohemistry Data Report - s and Gas Analyses Well Applied Petroleum Tehnology AS P. O. Box Kjeller Norway

2 Address: Applied Petroleum Tehnology AS P.O.Box Kjeller Telephone: Telefax: Report number APT08-50 Report Title Geohemistry Data Report - s and Gas Analyses Well Client StatoilHydro Client Referene Christoph Kierdorf Ann Elin Gilje Distribution StatoilHydro(3) APT (digital) Classifiation Confidential Submitted 7 th Marh 2008 Servie Order APT Number of pages 02 Authors Bine Nyj ordet Kjell Urdal Ingar Johansen Name Date Signature Reviewed by Geir Hansen Approved by Tore Haaland / /

3 Geohemistry Data Report - s and Gas Analyses Well CONTENTS Table. Number of analyses performed 2 Figure. Gas omposition (volume based) 3 Figure 2. Isotopi omposition 4 GC-WO Star diagrams 5 Steranes Triangle Plots 8 Table 2. GC of Whole (parameters) Table 3. GC of saturated ompounds (parameters) 2 Table 4. GCMS SIR of saturated ompounds (parameters) 3 Table 5. GCMS SIR of aromati ompounds (parameters) 4 Table 6. Gas Composition (volume-%) 5 Table 7. Gas Isotopes (83C (%o PDB) & 8D (%o SMOW)) 5 Table 8. Isotopes of frations, 83C (%o PDB) 6 Table 9. Extration, Asphaltene preipitation and Iatrosan data 6 Table 0. Density and topping 6 Table. GC of Whole (peak area) 7 Table 2. GC of Whole (amounts in ng/g) 20 Table 3. GC of saturated ompounds (peak area) 23 Table 4. GC of saturated ompounds (amounts in ng/g) 24 Table 5. GC of aromati ompounds (peak area) 25 Table 6. GC of aromati ompounds (amounts in ng/g) 25 Table 7. GCMS SIR of saturated ompounds (peak height) 26 Table 8. GCMS SIR of saturated ompounds (amounts in ng/g) 30 Table 9. GCMS SIR of aromati ompounds (peak height) 33 Table 20. GCMS SIR of aromati ompounds (amounts in ng/g) 37 GC Chromatograms of Whole 40 GC Chromatograms of Whole - detailed 44 GC Chromatograms of Saturated Hydroarbons 50 GC Chromatograms of Aromati Hydroarbons 54 GC-MS Chromatograms of Saturated Hydroarbons 58 GC-MS Chromatograms of Aromati Hydroarbons 79 Table 2. Referene data for GC Whole measured on NSO- 96 Table 22. Referene data for GC of Saturated Compounds measured on NSO- 97 Table 23. Referene data for GC-MS of Saturated Compounds measured on NSO- 98 Table 24. Referene data for GC-MS of Aromati Compounds measured on NSO- 99 Experimental Proedures 00 Page

4 Geohemistry Data Report - s and Gas Analyses Well Table. Number of analyses performed Analysis PWi Total Gas omposition Stable isotopes of gas Stable isotopes of frations Iatrosan Asphaltenes MPLC Density/Topping GC of Whole GC of Saturated hydroarbons GC of Aromati hydroarbons GC-MS of Saturated hydroarbons GC-MS of Aromati hydroarbons Page 2

5 Geohemistry Data Report - s and Gas Analyses Well Table»2. GC of Whole (parameters) 3 CO w E, el & m m m m E. <J C ? X 0 9? X ? A: Benz/n-C 6 B: Tol/n-C 7 X: m+p-xyl/n-c g W: Benz*0/CyC 6 C: (n-c 6 +n-c 7 )/(CyC 6 +MCyC 6 ) I: (2-MC 6 +3-MC 6 )/(l,3-dmcycs+tl,3-dmcycs+tl,2-dmcycs) F: n-c 7 /MCyC 6 H: n-c 7 *00/(CyC 6 +2-MC6+3-MC6+l,3-DMCyC5+tl,3-DMCyC5+tl,2-DMCyC5+n-C 7 +MCyC 6 ) U: CyC</MCyC 5 R: n-c 7 /2-MC 6 S: n-cy2,2-dmc 4 Page

6 Geohemistry Data Report - s and Gas Analyses Well Table 3. GC of saturated ompounds (parameters) I&it I m m m m a < 46584T 46585T 46586T 46736T I i io Page 2

7 Geohemistry Data Report - s and Gas Analyses Well Table Illliiiiiiiiiiiill GCMS SIR of saturated ompounds (parameters) w E, E. & m m m m S E, o C i 46584T 46585T 46586T 46736T iiiiiiiiiiiiiiiiiiii liliiiiilllllllllllli Illllllllllllllll i o NT a r-j %23:3 %28ap %30D %27Ts %22S %29Ts %20S 23:3/(23:3+30ap)*00 28ap/(28ap+30ap)*00 30D/(30D+30ap)*00 27Ts/(27Ts+27Tm)* 00 (32apS/(32apS+32apR)* 00 (29Ts/29Ts+30ap)*00 (29aaS/29aaS+29aaR)* 00 %PP %27dpS %C27 %C29 28/29 24:4/23:3 (29pp(R+S)/(29pp(R+S)+29aa(R+S)*00 27dpS/(27dpS+27aa(R+S))* 00 (27pp(R+S)/(27pp(R+S)+28pp(R+S)+29pp(R+S))*00 (29pp(R+S)/(27pp(R+S)+28pp(R+S)+29pp(R+S))*00 (28aa(R+S)+28pp(R+S))/(29aa(R+S)+29pp(R+S)) 24:4/23:3 Page 3

8 Geohemistry Data Report - s and Gas Analyses Well Table 5. GCMS SIR of aromati ompounds (parameters) D s CO i> IS. en E, E. C m m m m </: S "E. o C <: 46584T 46585T 46586T 46736T I < S ? <~i i p? 56 8? 90? 4 < ? MSAro ?9 < t-. 0? MSAroS 9t AR0M2: Crakl: Crak2: MSArol: MSAro2: MSAro3: MSAro4: MSAro5: MSAro6: MSAro7: MSAro8: MSAro9: (C 2 ota)/(c 2 ota+rc28ta) 4-MDBT/l-MDBT (2-MP+3-MP)/( -MP+2-MP+3-MP+9-MP) 2-MN/l-MN (2,6-DMN+2,7-DMN)/l,5-DMN 4-MDBT/DBT DBT/P 3-MP/Retene RC 2g TA/( R Page 4

9 Geohemistry Data Report - s and Gas Analyses Well Table 6. Gas Composition (volume-%) - $ 'É. r' fin Gas Gas Gas 5 e- t/5 3 O Illllii m m m Hil iff G C < ii I ~> li f f--» J! xn f>5 f> aif»/e 7. Gas Isotopes (S3C (% o PDB) & SD (% o SMOW)) t/5 Gas Gas Gas E lill C/l G & _ -= m m m E III a Li < CM rn m u p r-i n H G C Page 5

10 * * - \ Geohemistry Data Report - s and Gas Analyses Well Table 8. Isotopes of frations,, a ' $ a on P C lllllli iiiiiiiii m m m m l ffi G G r^ I FOB) g 'O ^_, < U m '-C aif»/e 9. Extration, Asphaltene preipitation and latrosan data llllllllllllllliiiiiil i i i i i E, el C m m m m S "E. o G t ^Jj C \- S o ^ aif»/e 70. Density and topping = llliiliiiilllii i ii p E. a G m m m m i i i i S a "?, ^P g I Page 6

11 Geohemistry Data Report - s and Gas Analyses Well Table. GC of Whole (peak area) $ fj CO i> C n lit ill el m m m m m m III ~ t-.85e5.92e5.7e5.86e5 C 7.9e4 3.87e4 5.85e4 2.04e4 5.84e4 3.38e4 4.63e4 2.79e4 d.84e5.2e5.48e5 9.96e4 U -.69e5.33e5.6e5.6e5 in P 2.37e5.9e5 2.23e5 2.58e5 4.84e3 4.23e3 4.43e3 6.48e3 m 3.4e4 2.83e4 3.06e4 3.7e4 5.98e4 2.4e4 2.27e4 3.52e4 i.40e5.48e5.56e5 2.89e5 ir-, IB 8.e4 8.2e4 8.5e4.60e5 2.46e5 2.38e5 2.44e5 5.40e5 O r-t 4.45e3 4.37e3 4.26e3.8e4.45e5.53e5.56e5 2.88e5 Table. ontinued, GC ( 3f Whole ( )eak area) " a p m m m m iiiiiiiiiiiiiiiiii D G.9e4.9e4.22e4 3.24e4 Table. ontinued, GC ( 3f Whole ( )eak area) ll ii iillllllllllliiiiliii i i ii j ii ii JZ C la B m m m m </: s < i C O.OOeO O.OOeO O.OOeO O.OOeO iiilllllliiiiliillil.38e3.39e3.58e3 3.28e3 3.93e5 4.62e5 4.47e5.26e6 7.9e4 4.30e4 4.49e4 6.90e4 ' i-.88e4.93e4.96e4 6.29e4 2.87e3 2.80e3 2.85e3 7.9e3 2.46e4 3.03e4 2.94e4 8.85e4 2.00e5 2.09e5 2.0e5 4.e5.2e4.9e4.4e4 4.79e4 7.60e4 7.8e4 7.48e4 2.58e5 IJT, r-t ri.46e4.45e4.39e4 5.77e4 2.79e4 3.06e4 2.86e4 8.76e4 illllllilillliiiiliilill.74e4.94e4.84e4 6.64e4 iiiiiiiiiiiiiiiiii.70e4.56e4.52e4 3.82e4 3.50e3 3.79e3 3.72e3.43e4 8.64e4 8.49e4 8.23e4 2.74e5.89e4 2.6e4 2.06e4 7.38e4 3.25e4 3.59e4 3.49e4 9.65e4 Illlllililllil 4.25e3 3.94e3 3.70e3.44e4 ~ C 3.03e4 3.35e4 3.23e4 9.02e4 2.84e5.93e5.90e5 5.0e5 5.74e3 5.8e3 6.04e3.80e4.92e4 2.7e4 2.02e4 7.98e4 5.63e4 6.26e4 6.09e4.7e5 8.50e4 8.33e4 7.88e4 3.62e5 2.48e5 2.49e5 2.39e5 8.98e5 2.7e4 2.54e4 2.4e4.04e5 Page 7

12 Geohemistry Data Report - s and Gas Analyses Well Table. ontinued, GC ( af Whole ( peak area) i ili i i i i ili i y g C p. KM m m m m f e4 5.09e4 4.6e4 3.30e5 i ;i llllllllll i ll lillliill^liilllllll 7.87e4 9.23e4 8.90e4 2.48e5 3.35e4 4.0e4 3.83e4.32e5 ililliliiliii 2.3e4 2.53e4 2.42e4 8.5e4 iiiiiiiiiiiiiiiiii 3.7e4 4.39e4 4.6e4.40e5 2.54e5 2.46e5 2.32e5.04e6 >».06e5.0e5.04e5 3.59e5 3.33e4 3.65e4 3.49e4.28e5 5.96e4 4.80e4 4.45e4.4e5 f.78e5.43e5.34e5 4.8e5 WltHa 5.63e4 4.6e4 4.39e4.3e5 IIIII 2.95e4 2.59e4 2.34e4.05e5 3.86e4 3.59e4 3.39e4.53e5 o Ie4 3.87e4 3.60e4.60e5 Page 8

13 Geohemistry Data Report - s and Gas Analyses Well Table. ontinued, GC ( rf Whole peak ( area) illlllllllllllliiiiiiiil iiiiiiiiiiliiiiiii C p. KM m m m m Illliiiiiiiiiiiili < X 9. Ie4 6.7e4 6.54e4.95e5 p 2.2e5.97e5.84e5 8.05e5 4.23e4 3.83e4 3.59e4.43e5 Ililllililllilllilliiiil 2.04e5.68e5.57e5 5.35e5 4.28e4 3.83e4 3.69e4.3e5.82e5.44e5.3e5 3.57e5 iiiiiiiiiiiiiiiiiiimiiiiiiii.78e5.30e5.22e5 2.58e5 iiiiiiiiiiiiiiiiiiiiiii 3.9e4 2.78e4 2.59e4 5.30e4 y 8.44e4 4.88e4 4.43e4 3.85e4 iiiiiiiiiiiiiisiiiiiiii.72e5.27e5.8e5.99e5 ^åmmmm^å9 4.05e4 4.2e4 3.97e4 4.78e4.58e5.4e5.08e5.4e5 y 7.30e4 7.0e4 6.52e4 6.59e4 p.65e5.27e5.7e5.0e5 Table. ontinued, GC ( rf Whole )eak ( area) io el G m m m m p. C 9 ft ili l l l ili.43e5 I.lle5.07e5 7.48e4 illlllllllllllliiiiiiiil 4.04e4 4.7e4 3.88e4 2.60e4.33e5.02e5 9.7e4 5.23e4 illlliillllllllllllll 7.82e4 7.90e4 7.34e4 4.20e4 ^åmmmm%^m.5e5 9.02e4 8.65e4 3.44e4 lllllllllllllllllilllii 5.58e4 6.80e4 6.52e4 2.75e4 iiiii^ii^iiiiiiiiiiiii I.lle5 9.28e4 8.35e4 2.83e4 llllllllllllllliilllii 9.74e4 7.99e4 7.68e4.82e4 llllllllillllllllllliiiiiliill 8.34e4 6.47e4 6.36e4.9e4 illlllllllllliillliili 7.96e4 6.00e4 6.05e4 9.25e3 7.5e4 5.73e4 5.55e4 6.42e3 6.66e4 5.36e4 5.26e4 4.84e3 llllllllllllllliilllii 5.89e4 4.58e4 4.40e4 3.48e3 l li l( i i j l j 5.49e4 4.38e4 4.25e4 2.36e3 Table. ontinued, GC ( 3f Whole ()eak area) liililiiiiiiiiiiiiil g s m a m m m m liii ii i ii iliiiilliiiiliiii 4.69e4 3.79e4 3.63e4.93e3 iiiiiilljiiiiiiiiiiiiiiii 3.98e4 3.8e4 3.08e4.2e3 3.87e4 3.35e4 3.e4.8e3 iiiiiiliii iiiiiiiiiiiiiiiii 3.0e4 2.7e4 2.6e4.06e3 tiiiiiitiiiiiiiiiiiiiiii 2.83e4 2.23e4 2.2e4 6.40e2 iiiiliiiiiiiiiiiiiiiiii 2.9e4.82e4.82e4 5.26e2 y p.53e4.30e4.3e4 O.OOeO y p.27e4.7e4.5e4 O.OOeO liigillii^llilllilliliiii.09e4 8.30e3 8.0e3 O.OOeO y' p.04e4 9.69e3 9.08e3 O.OOeO Page 9

14 Geohemistry Data Report - s and Gas Analyses Well Table 2. GC of Whole (amounts in ng/g) li l i i i i il i i i 'E. /s el C m m m m S. <J C y 7.29e6 7.33e6 6.73e6 6.84e6 3.2e6.52e6 2.37e6 7.73e5 liiiiiiiiiiiiiiiiiiiiiiiiiiiii 2.34e6.3e6.85e6.05e6 iiiiiiiiiiiiiiiiiiiiiiii 7.36e6 4.33e6 5.92e6 3.73e6 6.72e6 5.3e6 6.40e6 5.99e e6 7.37e6 8.85e6 9.62e6 Illllllliiilliilllil.92e5.62e5.75e5 2.40e5 Illllllllllliiiiliil.2e6.06e6.8e6.34e6 iiiiiiiiiiiiiiiiii 7.84e5 8.2e5 9.0e5.30e6 ililllllllllllllléliwilsiil 5.55e6 5.66e6 6.9e6.07e7 3.2e6 3.e6 3.37e6 5.9e6 9.73e6 9.2e6 9.66e6 2.00e7 iiiliiiiiliiiillili.75e5.67e5.68e5 4.35e5 5.60e6 5.72e6 6.03e6.04e7 Table 2. ontinued, GC of Whole (amounts in ng/g) i i li^ "S m m m m i i i i i G iiiiiiiiiiii 4.68e5 4.54e5 4.82e5.20e6 llillillillil 5.46e4 5.3e4 6.22e4.2e5 lilllllllliiiiiiiii^i^iiéiiiii 2.84e6.50e6.6e6 2.32e6 iiiiiiiiiii.3e5.07e5.2e5 2.92e5 7.76e6 7.83e6 8.0e6.49e7 3.00e6 2.98e6 2.95e6 9.5e6 I.0e6.7e6.3e6 3.23e6 Iiiiiiiiiiii 6.56e5 5.83e5 5.88e5.38e6 i 3.4e6 3.24e6 3.24e6.0e7 lilllllllllllllllllli Ilillllllll.26e6.34e6.35e6 3.49e6 ~.7e6.25e6.25e6 3.26e6 2.27e5 2.22e5 2.38e5 6.66e5 2.8e6 2.34e6 2.35e6 6.8e6 9.78e6 9.5e6 9.44e6 3.32e7 Table 2. ontinued, GC of Whole (amounts in ng/g) lllllllllllllllllllllllili^ll. C la B H, G m m m m S Illlllliliili 0.00e0 0.00e0 0.00e0 O.OOeO iiiiiiiiiiiiiiiiii.52e7.73e7.73e7 4.55e7 ' H 7.27e5 7.2e5 7.58e5 2.28e6 Ililillllililiiiiiiiiiili 9.5e5.3e6.4e6 3.20e6 4.4e5 4.53e5 4.50e5.76e6 5.74e5 5.52e5 5.46e5 2.3e6 Illlllllllllllliiiiiiiiii Iiiiiiiiiiiiiiiiiiiiiii 6.73e5 7.24e5 7.0e5 2.40e6 I.38e5.44e5.47e5 5.26e5 7.30e5 8.08e5 7.95e5 2.67e6 iiiiiiiiiiiiii.67e5.50e5.46e5 5.32e5.03e7 6.78e6 6.88e6.70e7 I 7.56e5 8.26e5 7.96e5 2.94e6 t-- O 3.35e6 3.8e6 3.0e6.34e7 iiiiill^llliiilllllllllllllllllll.07e6 9.66e5 9.50e5 3.82e6 Page 20

15 Geohemistry Data Report - s and Gas Analyses Well Table 2. ontinued, GC of Whole (amounts in ng/g) lllllllllllllliliiiii y g C m m m m < e6.94e6.82e6.2e7 3.04e6 3.46e6 3.44e6 8.97e6.30e6.50e6.48e6 4.77e6 iiiliiiiiiii 8.26e5 9.48e5 9.35e5 3.08e6 i il i.44e6.64e6.6e6 5.08e6 9.99e6 9.38e6 9.4e6 3.82e7 4.09e6 4.0e6 4.02e6.30e7.3e6.39e6.37e6 4.70e6 *~r 2.8e6.70e6.63e6 4.83e6 f 6.53e6 5.06e6 4.92e6.43e7 ilii 2.06e6.63e6.6e6 4.49e6.6e6 9.84e5 9.9e5 3.87e6 2.52e6.37e6.33e6 5.64e6 o 2 <.70e6.47e6.42e6 5.90e6 Page 2

16 Geohemistry Data Report - s and Gas Analyses Well Table 2. ontinued, GC of Whole (amounts in ng/g) lllllllllllllliliiiii i ili i i i C p. KM m m m m IlilliiiiiiiÉiiili e6 2.38e6 2.39e6 6.69e6 p 8.70e6 7.49e6 7.24e6 2.96e7.66e6.46e6.4e6 5.23e6 llllllllllllliiiliiil 8.0e6 6.39e6 6.7e6.96e7 lllllllllllllliliiiii.68e6.45e6.44e6 4.5e6 7.4e6 5.45e6 5.4e6.3e7 lllllllllllllliliiiii 6.96e6 4.93e6 4.77e6 9.47e6 lllllllllllllllliillll.25e6.05e6.0e6.94e6 lllllllllllllliliiiii 3.30e6.85e6.73e6.4e6 llllllllllllllllllllé^iiilllill 6.7e6 4.8e6 4.60e6 7.27e6 ^åmmmm^å9.58e6.56e6.55e6.75e6 6.9e6 4.32e6 4.22e6 5.5e6 y 2.85e6 2.65e6 2.54e6 2.4e6 l i li 6.47e6 4.78e6 4.58e6 4.03e6 Table 2. ontinued, GC of Whole (amounts in ng/g) io en G m m m m p. C 9 ft y p 5.60e6 4.20e6 4.6e6 2.73e6 Table 2. ontinued, GC of Whole (amounts in ng/g) a & 5 on *& S n m m m m iilliiiiiiiiiiliiil iiilliilll;llliiliiili.83e6.43e6.4e6 7.02e4 iliiiiiiiiiiiiillli.57e6.57e6.5e6 9.47e5.55e6.20e6.20e6 4.39e4 5.8e6 3.84e6 3.79e6.9e6 IIII.5e6.26e6.2e6 4.30e4 iliiiiiiiiiiiiillli 3.05e6 2.98e6 2.86e6.53e6.7e6.02e6.0e6 3.85e4 ^åmmmm%^m 4.47e6 3.40e6 3.37e6.25e6 tiiiiiiiiiiiiiiiiiiiiiii.0e6 8.38e5 8.57e5 2.33e4 l l l l ll iil ii 2.8e6 2.56e6 2.54e6.00e6 G p 8.52e5 6.83e5 7.05e5.9e4 4.32e6 3.50e6 3.25e6.03e6 y p 5.94e5 4.87e5 5.07e5 O.OOeO i il i l; i;l 3.79e6 3.0e6 2.99e6 6.62e5 p 4.94e5 4.39e5 4.48e5 O.OOeO 3.25e6 2.44e6 2.47e6 4.32e5 i p 4.25e5 3.2e5 3.e5 O.OOeO Illlllllllllliiililiili 3.0e6 2.26e6 2.35e6 3.37e e5 3.64e5 3.52e5 O.OOeO 2.92e6 2.6e6 2.6e6 2.34e5 2.59e6 2.02e6 2.04e6.76e5 y p 2.29e6.73e6.7e6.27e5 ( ; j ; l j 2.3e6.65e6.65e6 8.59e4 Page 22

17 Geohemistry Data Report - s and Gas Analyses Well Table 3. GC of saturated ompounds (peak area) Iiiiiiiiiiiiiiii 'E. /s el. & m m m m S. C i 46584T 46585T 46586T 46736T.05e7 7.25e6 3.28e6 3.98e7.4e7 9.52e6 5.99e6 3.80e7 r-j.55e7.0e7 6.85e6 2.83e7 2.78e6 2.33e6.5e6 6.6e6 3.08e6 2.43e6.67e6 6.3e6.67e7.09e7 7.47e6 2.24e7 iiiiiiiiiiiiiiiiiiiiiii 3.62e6 3.46e6 2.38e6 5.08e6.79e7.8e7 8.82e6.7e7 5.74e6 5.0e6 4.02e6 6.4e6.95e7.22e7 9.89e6.30e7 g.9e7.25e7.00e7 9.6e6 5.2e6 4.37e6 3.85e6 3.9e6.82e7.08e7 9.62e6 6.90e6 lllllllllllllllljllllil.06e7 8.5e6 7.4e6 5.93e6 Table 3. ontinued, GC of saturated ompounds (peak area) ex, oo "H. " a P m m m m '5 4=; 46584T 46585T 46586T 46736T lllllilllllllliiliiil.63e7 9.7e6 8.3e6 4.77e6 8.8e6 7.58e6 6.47e6 3.82e6 iisiiiiiiiiiiiiiiii.68e7.04e7 8.90e6 3.97e6 iliiiiiliilllllillllillii.37e7 8.09e6 6.94e6 2.39e6 S.26e7 7.39e6 6.35e6.56e6 Illlllllllllliiiiiill.7e7 6.82e6 5.88e6.4e6 2.07e7 6.26e6 5.42e6 7.98e5 lllllillllllllléiiiil 9.99e6 5.87e6 5.09e6 5.56e5 Illliiiillllllllllll 8.95e6 5.23e6 4.55e6 4.02e5 iliiilllllllllllllli 8.32e6 4.94e6 4.30e6 2.75e5 iliiiiiliilllllillllillii 7.9e6 4.26e6 3.70e6 2.02e5 5.86e6 3.55e6 3.09e6.48e5 5.66e6 3.43e6 2.97e6.62e5 iiiiiiiiiiiiiisiiiiiiii 4.55e6 2.83e6 2.45e6 4.73e4 Table 3. ontinued, GC of saturated ompounds (peak area) illilléiilliiiiili lllilllllllllilililiiili. C la D B H, G m m m m Iiiiiiiiiiiiiiii 46584T 46585T 46586T 46736T lllilllllllllil^illliiil 4.23e6 2.68e6 2.30e6 4.55e4 ri V 3.9e6 2.0e6.77e6 3.70e4 2.95e6.77e6.6e6 3.57e4 "IT 2.03e6.32e6.6e6 O.OOeO g.80e6.25e6.05e6 O.OOeO.29e6 7.94e5 7.e5 O.OOeO Page 23

18 Geohemistry Data Report - s and Gas Analyses Well Table 4. GC of saturated ompounds (amounts in ng/g) Iiiiiiiiiiiiiiiii 'E. /s el. & m m m m S "E. o C i 46584T 46585T 46586T 46736T 3.77e6 3.38e6.79e6 2.43e7 5.05e6 4.44e6 3.26e6 2.3 Ie7 r-j 5.55e6 4.69e6 3.73e6.72e7 9.97e5.08e6 8.2e5 3.75e6.0e6.3e6 9.07e5 3.73e6 5.97e6 5.07e6 4.07e6.36e7 iiiiiiiiiiiiiiiiiiiiiii.30e6.6e6.29e6 3.09e6 6.42e6 5.5e6 4.80e6.04e7 2.06e6 2.38e6 2.9e6 3.74e6 6.99e6 5.69e6 5.39e6 7.94e6 g 6.85e6 5.8e6 5.47e6 5.58e6.87e6 2.04e6 2.0e6.95e6 6.52e6 5.04e6 5.24e6 4.20e6 3.80e6 3.96e6 3.89e6 3.6e6 Table 4. ontinued, GC of saturated ompounds (amounts in ng/) lllllllllllllllbliill ex, oo "H. " a P o g m m m m '5 4=; 46584T 46585T 46586T 46736T iiiiiiiiiiiiiiiiiiiiiii 5.84e6 4.52e6 4.52e6 2.9e6 2.93e6 3.53e6 3.53e6 2.33e6 6.02e6 4.84e6 4.84e6 2.42e6 Table 4. ontinued, GC of saturated ompounds (amounts in ng/) lllilllllllllilililiiili illilléiilliiiiiil. C la D B H, G m m m m Iiiiiiiiiiiiiiii 46584T 46585T 46586T 46736T lllilllllllllil^illliiil.5e6.25e6.25e6 2.77e4 ri V.4e6 9.80e5 9.65e5 2.26e4.06e6 8.23e5 8.76e5 2.7e4 iliiiiiliilllllillllillii 4.90e6 3.77e6 3.78e6.46e6 "IT ; 7.27e5 6.6e5 6.30e5 O.OOeO S 4.52e6 3.44e6 3.46e6 9.52e5 g 6.45e5 5.8e5 5.74e5 O.OOeO 4.8e6 3.8e6 3.20e6 6.94e5 4.63e5 3.70e5 3.87e5 O.OOeO llllllllllllllsmiilill 3.85e6 2.92e6 2.95e6 4.86e5 lllllillllllllléiiiil 3.58e6 2.73e6 2.77e6 3.39e5 3.2e6 2.44e6 2.48e6 2.45e5 iliiilllllllllllllli 2.98e6 2.30e6 2.34e6.67e5 iliiiiiliilllllillllillii 2.57e6.98e6 2.0e6.23e5 2.0e6.66e6.68e6 9.04e4 2.03e6.60e6.62e6 9.90e4 iiiiiiiiiiiiiisiiiiiiii.63e6.32e6.33e6 2.88e4 Page 24

19 Geohemistry Data Report - s and Gas Analyses Well Table 5. GC of aromati ompounds (peak area) illlliiiiiiiiiiiill 'E. tn E, E. & m m m m S E. o C i 46584T 46585T 46586T 46736T ex. s ft ex. s aif»/e 6. GC of aromati ompounds (amounts in ng/g) y. 5 on *g- f li ^ m m m m os " E, C < 46584T 46585T 46586T 46736T tr-, ex. s s Page 25

20 Geohemistry Data Report - s and Gas Analyses Well Table 7. GCMS SIR of saturated ompounds (peak height) m/e illilliiiiiiiiiiiiiilii 'E. /s E, E. & m m m m S E, o C i 46584T 46585T 46586T 46736T 77 iiiiiiiiiiiii.64e6.70e6.53e6 6.23e4 5.24e5 3.87e5 3.45e5 4.5e4 O.OOeO 0.00e0 2.07e5 2.50e4 Table 7. ontinued, GCMS SIR of saturated ompounds (peak height) m/e 9 lllllllllllllllbliill ex, oo 00 " a P o g m m m m C 46584T 46585T 46586T 46736T o 8.89e5 7.3e5 6.33e5 3.67e e5 5.82e5 4.9e5 2.8e4 rn?4.30e6 I.lle6 9.49e5 4.6e4 lllllllliilli 3.7e6 3.87e6 3.20e6 7.70e4.39e6.20e6 9.99e5 4.4e4 9.0e6 8.66e5 7.4e5 2.26e5 7.35e6 6.9e6 5.3e6 2.3e5 s.22e6 I.lle6 9.99e5 2.5e5 7.7e6 9.25e6 7.47e6 2.57e5 r-4.84e6.67e6.45e6 3.06e5.5e6.05e6 8.73e5 3.49e4 2.47e6 2.26e6.95e6 2.88e5 Illlllllllllllliiiilll 8.42e5 7.05e5 6.3 Ie5 3.23e4 2.e6.87e6.60e6 2.24e5.40e7.53e7.36e7 3.06e5 llllllllljllliiiiisil.02e6 8.62e5 7.70e5 7.5e4 lllllillliil O.OOeO O.OOeO O.OOeO 3.45e4.02e6 9.3e5 8.00e5 8.20e4.93e7 2.e7.77e7 5.46e5 2.4e6 2.08e6.78e6.44e5 8.06e6 7.82e6 6.48e6.90e5 a; 8.42e5 7.38e5 6.27e5 5.3e4 4.43e6 3.77e6 3.29e6 9.4e4 r e5 7.05e5 5.88e5 4.95e4 illliilliiliiiliiiiiiiiili.72e6.8e6.5e6 4.97e4 Page 26

21 Geohemistry Data Report - s and Gas Analyses Well Table 7. ontinued, GCMS SIR of saturated ompounds (peak height) m/e 9 llllllllllllllliiiiii li ii iiii i C p. KM m m m m i i ii i il l 46584T 46585T 46586T 46736T X O.OOeO 0.00e0 O.OOeO O.OOeO ii^iiiiiiililillilililil 4.95e7 5.28e7 4.38e7.05e6 iiliiiill^iiiiiiiiiiiiii 4.22e6 4.8e6 3.72e e4 llllllililljjiiiiiiiil 2.52e7 2.70e7 2.29e7 4.53e5.76e7.85e7.59e7 3.8e5 2.76e6 2.69e6 2.25e6 5.23e4 WKHå 2.25e6 2.3e6.98e6 4.09e4.7e7.77e7.53e7 2.7e5 ei ro.2e7.23e7.05e7.9e5 illliilliiiliiiiililiiili.4e7.5e7.29e7.88e5 9.22e6.02e7 8.39e6.9e5 8.04e6 8.6e6 6.8e6.04e5 5.02e6 5.28e6 4.6e6 7.52e4 7.72e6 8.43e6 7.09e6.02e5 Table 7. ontinued, GCMS SIR of saturated ompounds (peak height) m/e 9 27 a p. G m m m m "E. å 46584T 46585T 46586T 46736T 5.09e6 5.34e6 4.47e6 6.6e4 Wååååååååååå 4.67e6 4.80e6 4.8e6 8.27e5 i ili i i ili i 4.50e6 4.38e6 3.86e6 5.36e5 2.82e6 2.59e6 2.9e6 3.60e5 2.55e6 2.62e6 2.2e6 2.42e5.43e7.49e7.22e7 6.75e5 8.58e6 8.46e6 7.46e6 3.60e5 ri 3.2e6 3.29e6 2.77e6.23e5 4.32e6 4.45e6 3.83e6.70e5 s 6.5e6 6.24e6 5.7e6 2.3 Ie5 i i i ji i i 5.93e6 5.99e6 5.24e6 2.2e5 3.6e6 3.53e6 3.04e6.7e5 4.40e6 4.49e6 3.83e6.55e5 ilililiilillililmiiii^siil 2.87e6 2.90e6 2.52e6 9.04e4 Page 27

22 Geohemistry Data Report - s and Gas Analyses Well Table 7. ontinued, GCMS SIR of saturated ompounds (peak height) m/e 27 llllllllllllllliiiiiii y g C p. EM m m m m i i i i il l 46584T 46585T 46586T 46736T lllllllllllllllllliiliiiliiéii 7.5e6 9.3e6 7.94e6 2.63e5 I 9.54e6 9.55e6 8.06e6 3.08e5 illliililiiiiiiliiliiilili 8.89e6.02e7 8.76e6 2.9e e6 2.25e6.86e6 7.02e4 7.32e6 9.72e6 8.33e6 2.56e5 IIIII 7.24e6 7.65e6 6.58e6 2.24e5 iiiii 3.92e6 4.00e6 3.45e6.09e5 2.95e6 3.70e6 3.9e6 7.64e e6 3.8e6 3.42e6.04e5 s* 7.5e6 8.9e6 7.44e6 2.05e5 8.74e6 9.72e6 8.63e6 2.24e5 iiiiiliilliiili i iiii iii(iliiliilli 4.86e6 6.07e6 5.3e6.3e5 8.67e6.05e7 9.08e6 2.02e5 llllllllllllllllliwiiil^ii^iili.0e7.5e7 9.93e6 2.40e5 Table 7. ontinued, GCMS SIR of saturated ompounds (peak height) m/e iiiiillliiiij iiiiiii el G m m m m [_ 46584T 46585T 46586T 46736T llllllllllllliiiisi^ill.05e7.8e7.02e7 2.42e5 r-t 6.96e6 9.30e6 7.83e6.50e5 4.3e6 4.98e6 4.33e6 9.9e4 ililllllllllllllliiiiirø^iiiil 3.84e6 4.2e6 3.52e6 6.82e4 2.65e6 2.88e6 2.50e6 4.40e4 illilillliiiliiiiiiiiiiiiil 2.30e6 3.09e6 2.6e6 4.05e4 mwlmwhå l.ilel 2.03e7.79e7 5.93e5.54e7.80e7.53e7 4.90e5 ei 5".23e7.45e7.2e7 3.32e5 CO s~.36e7.56e7.40e7 3.63e5.78e7.99e7.75e7 4.e5.75e7 2.00e7.73e7 3.88e5 4.77e6 5.20e6 4.40e6 7.75e4 illlilillililliiiiiiliill 4.42e6 4.89e6 4.3e6 7.8e4 Page 28

23 Geohemistry Data Report - s and Gas Analyses Well Abbreviations of saturated biomarkers 7a(H), 2ip(H)-25,28,30-trisnorhopane 7a, ,30-bisnorhopane 7a(H), 2 3(H)-25-norhopane 7a, 2 3, 22(R/S)-25-norhomohopane C9H34 tri yli terpane C20H36 triyli terpane C 2 ih 38 triyli terpane C23H42 triyli terpane C24H44 triyli terpane C25H 46 triyli terpane C25H 46 triyli terpane C24H42 tetrayli terpane C26H 48 triyli terpane C26H 48 triyli terpane C28H52 triyli terpane C28H52 triyli terpane C29H54 triyli terpane C29H54 triyli terpane 8a(H)-22,29,30-trisnorneohopane 7a(H)-22,29,30-trisnorhopane C 30 H 56 triyli terpane C 30 H 56 triyli terpane 7a(H), 2ip(H)-28,30-bisnorhopane 7a(H), 2ip(H)-30-norhopane 8a(H)-30-norneohopane 5a-methyl-7a(H)-27-norhopane (diahopane) 7P(H), 2a(H)-30-norhopane (normoretane) 8a(H)-oleanane 7a(H), 2ip(H)-hopane 7P(H), 2a(H)-hopane (moretane) 7a(H), 2P(H), 22(S)-homohopane 7a(H), 2P(H), 22(R)-homohopane Gammaerane 7P(H), 2a(H)-homohopane 7a(H), 2P(H), 22(S)-bishomohopane 7a(H), 2P(H), 22(R)-bishomohopane 7a(H), 2P(H), 22(S)-trishomohopane 25nor28aP 25nor29aP 25nor30aP 25nor3aP 9/3 20/3 2/3 23/3 24/3 25/3R 25/3 S 24/4 26/3R 26/3 S 28/3R 28/3S 29/3R 29/3 S 27Ts 27Tm 30/3R 30/3S 28aP 29aP 29Ts 30d 29Pa aP 30pa 3 laps 3aPR 30G 3ipa 32apS 32aPR 33aPS 7a(H), 2P(H), 22(R)-trishomohopane 7a(H), 2P(H), 22(S)-tetrakishomohopane 7a(H), 2P(H), 22(R)-tetrakishomohopane 7a(H), 2P(H), 22(S)-pentakishomohopane 7a(H), 2P(H), 22(R)-pentakishomohopane C2-5a(H), 4a(H), 7a(H)-pregnane C2-5a(H), 4P(H), 7P(H)-pregnane C22-5a(H), 4a(H), 7a(H)-pregnane C22-5a(H), 4P(H), 7P(H)-pregnane 3P(H), 7a(H), 20(S)-holestane (diasterane) 3P(H), 7a(H), 20(R)-holestane (diasterane) 3a(H), 7P(H), 20(R)-holestane (diasterane) 3a(H), 7P(H), 20(S)-holestane (diasterane) 24-methyl-3P(H), 7a(H), 20(S)-holestane (diasterane) 24-methyl-3P(H), 7a(H), 20(R)-holestane (diasterane) 24-methyl-3a(H), 7P(H), 20(R)-holestane (diasterane) 5a(H), 4a(H), 7a(H), 20(S)-holestane 5a(H), 4P(H), 7P(H),20(R)-holestane 24-ethyl-3P(H), 7a(H), 20(S)-holestane (diasterane) 5a(H), 4P(H), 7P(H),20(S)-holestane 24-methyl-3a(H), 7P(H), 20(S)-holestane (diasterane) 5a(H), 4a(H), 7a(H), 20(R)-holestane 24-ethyl-3P(H), 7a(H), 20(R)-holestane (diasterane) 24-ethyl-3a(H), 7P(H), 20(R)-holestane (diasterane) 24-methyl-5a(H), 4a(H), 7a(H), 20(S)-holestane 24-ethyl-3a(H), 7P(H), 20(S)-holestane (diasterane) 24-methyl-5a(H), 4P(H), 7P(H), 20(R)-holestane 24-methyl-5a(H), 4P(H), 7P(H), 20(S)-holestane 24-methyl-5a(H), 4a(H), 7a(H), 20(R)-holestane 24-ethyl-5a(H), 4a(H), 7a(H), 20(S)-holestane 24-ethyl-5a(H), 4P(H), 7P(H), 20(R)-holestane 24-ethyl-5a(H), 4P(H), 7P(H), 20(S)-holestane 24-ethyl-5a(H), 4a(H), 7a(H), 20(R)-holestane 24-propyl-5a(H), 4a(H), 7a(H), 20(S)-holestane 24-propyl-5a(H), 4P(H), 7P(H), 20(R)-holestane 24-propyl-5a(H), 4P(H), 7P(H), 20(S)-holestane 24-propyl-5a(H), 4a(H), 7a(H), 20(R)-holestane 33aPR 34apS 34aPR 35apS 35aPR 2aa 2pp 22aa 22PP 27dpS 27dpR 27daR 27daS 28dpS 28dpR 28daR 27aaS 27PPR 29dpS 27PPS 28daS 27aaR 29dpR 29daR 28aaS 29daS 28PPR 28PPS 28aaR 29aaS 29PPR 29PPS 29aaR 30aaS 30PPR 30PPS 30aaR Page 29

24 Geohemistry Data Report - s and Gas Analyses Well Table 8. GCMS SIR of saturated ompounds (amounts in ng/g) m/e 77 9 i i il ii i i 'E. /s E, E. & m m m m S E, o C i 46584T 46585T 46586T 46736T iiiiiiiiiiiii.08e4.49e4.60e4.03e3 3.44e3 3.39e3 3.62e3 6.89e2 <~i O.OOeO O.OOeO 2.7e3 4.4e2 lllllllliilli 2.44e4 3.39e4 3.35e4.28e3 6.62e3 7.60e3 7.77e3 3.74e3 s 8.0e3 9.75e3.05e4 4.7e3 r-4.2e4.47e4.53e4 5.08e3 rn «N.62e4.98e4 2.04e4 4.78e3.39e4.64e4.68e4 3.72e3 i ililili i i i li l 6.67e3 7.56e3 8.08e3.25e3 6.7e3 8.00e3 8.40e3.36e3.40e4.82e4.87e4 2.39e3 a; 5.53e3 6.48e3 6.58e3 8.52e2 r e3 6.9e3 6.7e3 8.22e2 Table 8. ontinued, GCMS SIR of saturated ompounds (amounts in ng/g) m/e 9 lllllllllllllllbliill ex, oo "H. OO " a P m m m m C 46584T 46585T 46586T 46736T o 5.84e3 6.4e3 6.64e3 6.09e e3 5.e3 5.5e3 4.66e2?4 8.52e3 9.74e3 9.95e3 6.90e2 9.e3.05e4.05e4 7.32e2 4.83e4 5.42e4 5.38e4 3.54e3 5.06e4 8. Ie4 7.84e4 4.27e3 7.54e3 9.22e3 9.6e3 5.80e2 Illlllllllllllliiiilll 5.53e3 6.8e3 6.62e3 5.37e2 9.20e4.34e5.43e5 5.08e3 lllllillliil O.OOeO O.OOeO O.OOeO 5.73e2.27e5.85e5.86e5 9.07e3 5.30e4 6.86e4 6.80e4 3.6e3 2.9e4 3.3e4 3.45e4.52e3 illliilliiliiiliiiiiiiiili.3e4.59e4.58e4 8.25e2 Page 30

25 Geohemistry Data Report - s and Gas Analyses Well Table 8. ontinued, GCMS SIR of saturated ompounds (amounts in ng/g) m/e 9 llllllllllllllliiiiii li ii iiii i C p. KM m m m m i i ii i il l 46584T 46585T 46586T 46736T X O.OOeO 0.00e0 O.OOeO O.OOeO ii^iiiiiiililillilililil 3.26e5 4.63e5 4.59e5.75e4 iiliiiill^iiiiiiiiiiiiii 2.77e4 3.67e4 3.9e4.56e3 llllllililljjiiiiiiiil.66e5 2.37e5 2.40e5 7.52e3.6e5.62e5.67e5 5.27e3.82e4 2.36e4 2.37e4 8.68e2.48e4 2.02e4 2.07e4 6.79e2.2e5.55e5.6e5 4.50e3 ei ro 7.95e4.08e5.0e5 3.7e3 illliilliiiliiiiililiiili 9.30e4.33e5.35e5 3.2e3 6.06e4 8.96e4 8.80e4.98e3 5.28e4 7.5e4 7.4e4.73e3 3.30e4 4.63e4 4.83e4.25e3 5.07e4 7.39e4 7.43e4.69e3 Table 8. ontinued, GCMS SIR of saturated ompounds (amounts in ng/g) m/e 9 27 a. t/ el G m m m m "E. å 46584T 46585T 46586T 46736T 3.35e4 4.68e4 4.69e4.0e3 Wååååååååååå 3.07e4 4.2e4 4.39e4.37e4 i ili i i ili i 2.96e4 3.84e4 4.05e4 8.90e3.85e4 2.27e4 2.29e4 5.98e3.68e4 2.29e4 2.32e4 4.02e3 9.40e4.3e5.28e5.2e4 5.64e4 7.42e4 7.82e4 5.97e3 ri 2.05e4 2.88e4 2.9e4 2.03e3 2.84e4 3.90e4 4.0e4 2.82e3 s 4.04e4 5.47e4 5.43e4 3.83e3 i i i ji i i 3.90e4 5.25e4 5.50e4 3.67e3 2.37e4 3.0e4 3.9e4.95e3 2.89e4 3.94e4 4.0e4 2.57e3 ilililiilillililmiiii^siil.89e4 2.55e4 2.64e4.50e3 Page 3

26 Geohemistry Data Report - s and Gas Analyses Well Table 8. ontinued, GCMS SIR of saturated ompounds (amounts in ng/g) m/e 27 llllllllllllllliiiiiii y g C p. EM m m m m i i i i il l 46584T 46585T 46586T 46736T lllllllllllllllllliiliiiliiéii 4.70e4 8.6e4 8.33e4 4.37e3 I 6.27e4 8.37e4 8.46e4 5.e3 CO ( e4 8.94e4 9.9e4 4.83e e4.97e4.95e4.7e3 4.8e4 8.52e4 8.74e4 4.25e3 IIIII 4.76e4 6.7e4 6.9e4 3.73e3 iiiii 2.57e4 3.5e4 3.62e4.8e3 Table 8. ontinued, GCMS SIR of saturated ompounds (amounts in ng/g) m/e e4 3.25e4 3.35e4.27e e4 3.34e4 3.59e4.73e3 s* 4.94e4 7.8e4 7.8e4 3.40e3 5.74e4 8.52e4 9.06e4 3.72e3 iiiiiliilliiili i iiii iii(iliiliilli 3.9e4 5.32e4 5.57e4 2.7e3 5.70e4 9.20e4 9.53e4 3.35e3 llllllllllllllllliwiiil^ii^iili 6.67e4.00e5.04e5 3.99e3 iiiiillliiiij iiiiiii G m m m m 46584T 46585T 46586T 46736T llllllllllllliiiisi^ill 6.9e4.04e5.07e5 4.02e3 r-t 4.57e4 8.6e4 8.2e4 2.48e3 2.7e4 4.36e4 4.55e4.53e3 ililllllllllllllliiiiirø^iiiil 2.52e4 3.69e4 3.69e4.3e3.74e4 2.53e4 2.62e4 7.3 Ie2 illilillliiiliiiiiiiiiiiiil.5e4 2.7e4 2.74e4 6.72e2 mwlmwhå.6e5.78e5.88e5 9.84e3.0e5.58e5.60e5 8.3e3 ei 5" 8. Ie4.27e5.27e5 5.5e3 CO s~ 8.90e4.37e5.47e5 6.02e3.7e5.75e5.84e5 6.82e3.5e5.76e5.8e5 6.44e3 3.3e4 4.56e4 4.6e4.29e3 illlilillililliiiiiiliill 2.9e4 4.29e4 4.34e4.9e3 Page 32

27 Geohemistry Data Report - s and Gas Analyses Well Table 9. GCMS SIR of aromati ompounds (peak height) m/e lllllljjlljjiiiiiiiii * 3 o IS. /s E, Z> E. & m m m m S. C i 46584T 46585T 46586T 46736T Z 5.80e8 2.63e8 2.2e8 3.0e8 iii 3.47e8.53e8.34e8.63e8 III 4.98e7 2.68e7 2.38e7 2.33e7 illlilillliilllliiiiilill 2.29e7.90e7.63e7.57e7 lllllllllililill.35e8 6.20e7 5.37e7 5.9e7 llllllllliliiiliiil.38e8 6.3 Ie7 5.49e7 5.45e7 Table 9. ontinued, GCMS SIR of aromati ompounds (peak height) m/e Illlillllllllllll "E, oo "H. E. r*. ^^^^ m m m m illiiiiiiiiiiiliil C 46584T 46585T 46586T 46736T Z e7 5.26e7 4.65e7 2.92e7 Z -i ro 6.3e7 3.03e7 2.70e7.64e7 2.07e7.39e7.25e7 7.4e6 6.e7 3.66e7 3.3e7.87e7 iiiiiiiiiiil. el 9.28e6 8.26e6 4.25e6 4.46e7 3.34e7 3.04e7.5e7 Illlliiilillliilillli 2.83e8.49e8.33e8.8e8 fin 2.8e8.5e8.06e8 2.26e7 iiliijiiilliiiiiijiii 2.22e8.08e8 9.64e7 8.54e7 a. 2.02e8 5.03e7 4.65e7 7.28e6 + Z A S r-i C 9.02e7 5.05e7 4.37e7 3.50e7.20e8 5.70e7 5.5e7 7.90e6 llllillllililliililiij 6.00e7 3.55e7 3.6e7 2.48e7 ft,.65e8 9.4e7 8.50e7.3e7 y Illlllllliiliiilllll 4.50e7 3.5e7 2.79e7 2.07e7.30e8 7.27e7 6.63e7 9.26e6 lllllliill^llllllil.07e6 2.08e6.86e6.9e6 y *.82e7.0e7 9.34e6.8e6 iiiiiiiiiiil 7.8e7 3.99e7 3.55e7 2.37e7 Illlillllllllllll 2.99e7.26e7.4e7.44e6 S r*-i.03e8 5.27e7 4.69e7 3.e7 + G.75e7 7.2e6 6.56e6 8.46e5 Page 33

28 Geohemistry Data Report - s and Gas Analyses Well Table 9. ontinued, GCMS SIR of aromati ompounds (peak height) m/e ~ p C L KM m m m m 46584T 46585T 46586T 46736T + + e. j i * ~.24e8 6.20e7 5.9e7 6.83e6 + G + t- i t-\ 5.88e7 2.82e7 2.62e7 3.9e6 iiiiiiiiiiiiiiiiiii 6.77e7 3.39e7 3.5e7 3.38e6.74e7 8.62e6 8.24e6 9.2e5 Table 9. ontinued, GCMS SIR of aromati ompounds (peak height) m/e G m m m m p T 46585T 46586T 46736T iiiiiiiiiiii 2.00e6.02e6.04e6 3.53e4 I 7.70e6 8.53e6 7.96e6 2.90e5 liiililllliiiiiii 6.86e6 6.98e6 6.75e6.94e5.35e6 8.82e5 8.76e5 2.46e4 3.9e7 2.0e7.97e7 2.6e6 iiiiiiiiiiiiiiii iiiiiiiiiii iiiiiiiiiii.52e7.59e7.47e7 4.62e5 llllllliiliilillllli.65e7 9.20e6 8.5e6 8.56e5 S G in.59e6.67e6.60e6 4.06e4 i i i i lii i j j j I.lle7 7.50e6 6.92e6 5.77e5.23e6 8.60e5 8.24e5.84e4 V 3.64e7 2.44e7 2.4e7.96e6 3C e6.9e6.89e6 4.26e4 G 5.09e7 4.30e7 3.90e7 7.83e6 < S S C a- seei ^.05e7.7e7.09e7 2.54e5 G 7.62e7 5.28e7 5.09e7 8.0e6 iiiiiiiiiiii 4.26e7 3.25e7 3.0e7 4.46e6 Illllllllll 9.e6 9.65e6 9.9e6 2.4e5.4e6 7.57e5 7.74e5.47e4 G 2.98e7 2.90e7 2.68e7 3.78e6 iiliiiillliiiiiiiiiii 4.37e6 3.78e6 3.58e6 4.45e5 < < S X )» Ji f-< fn Cl ei^ ei «; 6.36e6 6.59e6 6.28e6.8e5 iilliliiiiiiiiii 2.77e6 2.30e6 2.7e6 2.27e5 lillillllllllil.04e6 5.85e5 5.95e5 9.52e3 7.6e6 7.6e6 7.33e6 3.0e5 Page 34

29 Geohemistry Data Report - s and Gas Analyses Well Table 9. ontinued, GCMS SIR of aromati ompounds (peak height) m/e 23 llllllllllllllliiiiiii li ii ii i i C p. KM m m m m iilliiiiiiiéiiili C f 46584T 46585T 46586T 46736T IlllllllllllllllllMSiliiiillli 7.0e6 6.73e6 6.68e6 2.3e5 H 6.98e6.3e7.22e7.3e5 iiiiiiiiiiii 2.95e7 4.68e7 4.37e7 4.49e5 so.20e7.7e7.6e7.44e5 t- pi.5e7 2.24e7 2.07e7.72e5 s.34e7.86e7.77e7.20e5 Page 35

30 Geohemistry Data Report - s and Gas Analyses Well Abbreviation of aromati biomarkers C-ring monoaromati steroid R4 ABC-ring triaromati steroids K.2 RJ. Ri P(H) P(CH 3 ) p(ch 3 ) P(H) a(h) P(H) a(ch 3 ) P(CH 3 ) a(ch 3 ) a(h) a(h) P(H) p(ch 3 ) P(H) p(ch 3 ) a(h) a(h) P(H) P(CH 3 ) a(h) Substituents R 2 CH 3 H H CH 3 CH 3 CH 3 H H H CH 3 CH 3 CH 3 H CH 3 H CH 3 CH 3 CH 3 H CH 3 R 3 S(CH 3 ) S(CH 3 ) RCH 3 ) R(CH 3 ) S(CH 3 ) S(CH 3 ) R(CH 3 ) S(CH 3 ) S(CH 3 ) R(CH 3 ) S(CH 3 ) R(CH 3 ) R(CH 3 ) S(CH 3 ) S(CH 3 ) S(CH 3 ) R(CH 3 ) R(CH 3 ) R(CH 3 ) R(CH 3 ) R4 H H H H H CH 3 H CH 3 CH 3 H CH 3 CH 3 CH 3 C 2 H 5 C 2 H 5 C 2 H 5 CH 3 C 2 H 5 C 2 H 5 C 2 H 5 Label C2MA C22MA PSC 27 MA PSC27DMA PRC27DMA+ PRC27MA (XSC27MA PSC 28 MA+ arc 27 DMA+ PSC 28 DMA asc 27 DMA arc 27 MA asc 28 MA PRC 28 MA+ PRC 28 DMA PSC 29 MA+ PSC 29 DMA asc 29 MA arc 28 MA+ PRC29MA+ PRC29DMA arc 29 MA Ri CH 3 CH 3 S(CH 3 ) R(CH 3 ) S(CH3) S(CH 3 ) R(CH 3 ) R(CH 3 ) Substit uents R 2 H CH 3 CeRn CeRn C 7 H 5 C 8 Hn C 7 H 5 C 8 Hn Label C20TA C2TA SC 26 TA RC 26 TA+ SC27TA SC 28 TA RC27TA RC 28 TA Polyyli aromati hydroarbons and sulphur ompounds MN EN DMN TMN P MP EP DMP DBT MDBT Methylnaphthalene Ethylnaphthalene Dimethylnaphthalene Trimethylnaphthalene Phenanthrene Methylphenanthrene Ethylphenanthrene Dimethylphenanthrene Dibenzothiophene Methyldibenzothiophene Page 36

31 Geohemistry Data Report - s and Gas Analyses Well Table 20. GCMS SIR of aromati ompounds (amounts in ng/g) m/e llllllllllllllliiiiiil iiiiiiiiiiiiiiiiii is" en E, E. C m m m m S E. G G i 46584T 46585T 46586T 46736T 42 Z.69e6.2e6.03e6.8e6 WmmmmmWKHl.0e6 6.50e5 6.22e5 9.79e5 56 Z.45e5.4e5 I.lle5.40e5 z 6.66e4 8.05e4 7.60e4 9.45e4 Table 20. ontinued, GCMS SIR of aromati ompounds (amounts in ng/g) m/e 70 iiiiiiiiiiiiiiibiii "E, oo "H. 00 E, m m m m iiiiiiiiiiiiiiiiii 46584T 46585T 46586T 46736T Z * 2.68e5 2.23e5 2.6e5.75e5 llllllll.78e5.29e5.25e5 9.86e4 llllllll 6.02e4 5.9e4 5.8e4 4.29e4.77e5.55e5.54e5.2e5 3.9e5 2.63e5 2.50e5 3.3e5 I 3.4e4 3.94e4 3.85e4 2.56e4 iiiiiiiiiiiiiiiiiiiiiiii 4.00e5 2.68e5 2.55e5 3.28e5 Iiiiiiiiiiiiiiiiii.29e5.4e5.4e5 9.08e4 + Z ~ G 8.20e5 6.32e5 6.7e5 7.0e5 78 fin 3.44e5 2.37e5 2.4e5 7.93e4 llilljiiiillilllllllll 6.45e5 4.57e5 4.49e5 5.4e5 92 a. 2.6e5.04e5.05e5 2.55e4 i } G 2.62e5 2.4e5 2.03e5 2.e5 IIII.89e5.7e5.7e5 2.77e4 Illlllllllliiillllllll.74e5.50e5.47e5.49e5 ft, 2 2.6e5.94e5.92e5 4.58e4 illilliiiliilllllllll.3e5.34e5.30e5.24e5 a. 2.05e5.50e5.50e5 3.25e4 iilililliiliiiiiiiiii 3.0e3 8.84e3 8.68e3 7.7e3 206 ± y * 2.88e4 2.07e4 2.e4 4.4e e5.69e5.65e5.43e5 a 4.72e4 2.59e4 2.58e4 5.04e3 S 2.99e5 2.24e5 2.8e5.87e5 + G 2.75e4.49e4.49e4 2.97e3 Page 37

32 Geohemistry Data Report - s and Gas Analyses Well Table 20. ontinued, GCMS SIR of aromati ompounds (amounts in ng/g) m/e ~ li i i i C KM m m m m i i i i il ; 46584T 46585T 46586T 46736T + + e. i i *~.96e5.28e5.34e5 2.39e4 + G + t- 9.28e4 5.82e4 5.92e4.2e4 G.07e5 6.98e4 7.4e4.9e4 2.75e4.78e4.86e4 3.20e3 Table 20. ontinued, GCMS SIR of aromati ompounds (amounts in ng/g) m/e i i j i i i; S G m m m m p T 46585T 46586T 46736T iiiiiiiiiiiii 3.77e3 2.62e3 2.83e3 2.03e2.45e4 2.8e4 2.7e4.66e3 Iiiiiiiiiiiiiii.29e4.79e4.84e4 I.lle3 r- 2.53e3 2.26e3 2.39e3.4e2 6.7e4 4.32e4 4.47e4 7.57e3 i i i x ^ /l t/5 Cai 2.86e4 4.07e4 4.02e4 2.65e3 llllljiiiiiwiililllll 2.60e4.90e4.92e4 3.00e3 S G 2.99e3 4.28e3 4.37e3 2.33e2 i i i i li i j lij.75e4.55e4.57e4 2.02e e3 2.20e3 2.25e3.06e2 V 5.74e4 5.04e4 5.46e4 6.86e3 S 3C OO 5.0e3 4.88e3 5.4e3 2.45e2 G 8.04e4 8.86e4 8.82e4 2.75e4 < 2 2 C a- seei ^.97e4 2.99e4 2.97e4.46e3 G.20e5.09e5.5e5 2.84e4 l (i il Illlllllllll lllliiilllllli.7e4 2.47e4 2.5e4.38e3 6.72e4 6.70e4 6.82e4.56e4 2.4e3.94e3 2.e3 8.44el G < 4.70e4 5.97e4 6.08e4.33e4 iiliiiillliiiiiiiiiii 8.2e3 9.68e3 9.78e3 2.55e3 iiiiiiiiiiiii lllliiilllllli.20e4.69e4.7e4 6.76e2 lllllllilllllill lllliiilllllli 5.2e3 5.89e3 5.92e3.3e3.95e3.50e3.62e3 5.46el.43e4.95e4 2.00e4.78e3 Page 38

33 Geohemistry Data Report - s and Gas Analyses Well Table 20. ontinued, GCMS SIR of aromati ompounds (amounts in ng/g) m/e 23 llllllllllllllliiiiiii li ii ii i i C p. KM m m m m iilliiiiiiiéiiili C f 46584T 46585T 46586T 46736T IlllllllllllllllllMSiliiiillli.34e4.72e4.82e4.33e3 H L/.3 Ie4 3.36e4 3.33e4 7.53e2 iiiiiiiiiiii 5.55e4.20e5.9e5 2.58e3 so 2.25e4 4.39e4 4.39e4 8.29e2 t- CJ pi 2.84e4 5.73e4 5.65e4 9.85e2 s 2.52e4 4.77e4 4.83e4 6.90e2 Page 39

34 Geohemistry Data Report - s and Gas Analyses Well GC Chromatograms of Whole Page 40

35 Geohemistry Data Report - s and Gas Analyses Well Sample: NSO- Depth: na Sample type: APT-ID: 0042 Analysis: GC-FID Analysis date: 5-Feb-2008 FID: 5.570e+4 0 min n 3 Well: Depth: m Sample type: APT-ID: Analysis: GC-FID Analysis date: 5-Feb-2008 FID: 8.8e *u- J JUJIli. m 0 min Page 4

36 Geohemistry Data Report - s and Gas Analyses Well n Well: Depth: 898.0m Sample type: APT-ID: Analysis: GC-FID Analysis date: 5-Feb-2008 FID: 7.436e+4 idjjjuu 0 min n Well: Depth: m Sample type: APT-ID: Analysis: GC-FID Analysis date: 6-Feb-2008 FID: 7.287e+4 ^ 9» min Page 42

37 Geohemistry Data Report - s and Gas Analyses Well n Well: Depth: m Test: APT-ID: Analysis: GC-FID Analysis date: 6-Feb-200S FID:.576e LJ ulul 0 min Page 43

38 Geohemistry Data Report - s and Gas Analyses Well GC Chromatograms of Whole - detailed Page 44

39 Geohemistry Data Report - s and Gas Analyses Well Sample: NSO- Depth: na Sample type: APT-ID: 0042 Analysis: GC-FID Analysis date: 5-Feb-200i FID: 5.570e+4 u 2 I S u n ^ "Si, fl" 4 min ,3-D _^ i i 'I n Sample: NSO- Depth: na Sample type: APT-ID: 0042 Analysis: GC-FID Analysis date: 5-Feb-2008 FID: 5.305e I 5 UA 28 min uu I Page 45

40 Geohemistry Data Report - s and Gas Analyses Well n Well: Depth: m Sample type: APT-ID: Analysis: GC-FID Analysis date: 5-Feb-2008 FID: 8.8e+4 4 min n Well: Depth: m Sample type: APT-ID: Analysis: GC-FID Analysis date: 5-Feb-2008 FID: 3.752e+4 I o UUJMU 28 min Page 46

41 Geohemistry Data Report - s and Gas Analyses Well n Well: Depth: 898.0m Sample type: APT-ID: Analysis: GC-FID Analysis date: 5-Feb-2008 FID: 7.436e i Well: Depth: 898.0m Sample type: APT-ID: Analysis: GC-FID Analysis date: 5-Feb-2008 FID: 3.625e min. 52 Page 47

42 Geohemistry Data Report - s and Gas Analyses Well n Well: Depth: m Sample type: APT-ID: Analysis: GC-FID Analysis date: 6-Feb-2008 FID: 7.287e+4 IUULJ 4 min i Well: Depth: m Sample type: APT-ID: Analysis: GC-FID Analysis date: 6-Feb-2008 FID: 3.45e min. 32 «IWJ V UO V w rv\) UU W" v Page 48

43 Geohemistry Data Report - s and Gas Analyses Well n Well: Depth: m Test: APT-ID: Analysis: GC-FID Analysis date: 6-Feb-200i FID:.576e+5 4 min Li n Well: Depth: m Test: APT-ID: Analysis: GC-FID Analysis date: 6-Feb-2008 FID:.576e ,JlKI wwj vu_j 28 min Page 49

44 Geohemistry Data Report - s and Gas Analyses Well GC Chromatograms of Saturated Hydroarbons Page 50

45 Geohemistry Data Report - s and Gas Analyses Well n Sample: NSO- Depth: na Sample type: Fration: OTOP-OSAT APT-ID: 0042T Analysis: GC-FID Analysis date: 26-Feb-08 FID: 9.56e+5 o 0 min n Well: Depth: m Sample type: Fration: OTOP-OSAT APT-ID: 46584T Analysis: GC-FID Analysis date: 26-Feb-08 FID: 9.879e+5 S a tl 0 min Page 5

46 Geohemistry Data Report - s and Gas Analyses Well n Well: Depth: 898.0m Sample type: Fration: OTOP-OSAT APT-ID: 46585T Analysis: GC-FID Analysis date: 26-Feb- FID: 6.320e i Well: Depth: m Sample type: Fration: OTOP-OSAT APT-ID: 46586T Analysis: GC-FID Analysis date: 26-Feb-08 FID: 5.3 le min Page 52

47 Geohemistry Data Report - s and Gas Analyses Well 0.2 n Well: Depth: m Test: Fration: OTOP-OSAT APT-ID: 46736T Analysis: GC-FID Analysis date: 26-Feb-08 FID: 2.9e min Page 53

48 Geohemistry Data Report - s and Gas Analyses Well GC Chromatograms of Aromati Hydroarbons Page 54

49 Geohemistry Data Report - s and Gas Analyses Well , Sample: NSO- Depth: na Sample type: Fration: OTOP-OARO APT-ID: 0042T Analysis: GC-FID Analysis date: 26-Feb-08 FID:.494e+5 C3-napht I2-phen 0 min n C2-napht Well: Depth: m Sample type: Fration: OTOP-OARO APT-ID: 46584T Analysis: GC-FID Analysis date: 26-Feb-08 FID: 2.440e+5 C3-napht min Page 55

50 Geohemistry Data Report - s and Gas Analyses Well , C2-napht Well: Depth: 898.0m Sample type: Fration: OTOP-OARO APT-ID: 46585T Analysis: GC-FID Analysis date: 27-Feb-08 FID:.086e+5 0 min C2-napht Well: Depth: m Sample type: Fration: OTOP-OARO APT-ID: 46586T Analysis: GC-FID Analysis date: 27-Feb-08 FID:.06e min Page 56

51 Geohemistry Data Report - s and Gas Analyses Well O.OlOn Well: Depth: m Test: Fration: OTOP-OARO APT-ID: 46736T Analysis: GC-FID Analysis date: 27-Feb-08 FID:.886e min Page 57

52 Geohemistry Data Report - s and Gas Analyses Well GC-MS Chromatograms of Saturated Hydroarbons Page 58

53 Geohemistry Data Report - s and Gas Analyses Well 00.0CH Sample: NSO- Depth: na Sample type: Fration: OTOP-OSAT APT-ID: 0042T Analysis date: 27-FEB :.547e+7 i 00 0 Sample: NSO- Depth: na Sample type: Fration: OTOP-OSAT APT-ID: 0042T Analysis date: 27-FEB : 8.538e+7 2 E 8' I POf \S V -30ba %K I, i i? ra UL i 50 min Page 59

54 Geohemistry Data Report - s and Gas Analyses Well 00.0CH Sample: NSO- Depth: na Sample type: Fration: OTOP-OSAT APT-ID: 0042T Analysis date: 27-FEB :.082e+7 i 50 min Sample: NSO- Depth: na Sample type: Fration: OTOP-OSAT APT-ID: 0042T Analysis date: 27-FEB :.620e+7 ^UAA/W 50 min Page 60

55 Geohemistry Data Report - s and Gas Analyses Well 00.0CH Sample: NSO- Depth: na Sample type: Fration: OTOP-OSAT APT-ID: 0042T Analysis date: 27-FEB :.324e+7 i U 50 min Sample: NSO- Depth: na Sample type: Fration: OTOP-OSAT APT-ID: 0042T Analysis date: 27-FEB : 5.673e+6 50 min Page 6

56 Geohemistry Data Report - s and Gas Analyses Well 00.0CH Sample: NSO- > Depth: na Sample type: Fration: OTOP-OSAT APT-ID: 0042T Analysis date: 27-FEB :.76e+7, Sample: Depth: Sample type: Fration: APT-ID: Analysis: Analysis date NSO- na OTOP-OSAT 0042T GC-HRMS 27-FEB :.450e+7 40 min Page 62

57 Geohemistry Data Report - s and Gas Analyses Well Well: Depth: m Sample type: Fration: OSAT APT-ID: 46584T Analysis date: 27-FEB : 9.888e+6 i s?.l 50 min Page 63

58 Geohemistry Data Report - s and Gas Analyses Well Well: > Depth: m Sample type: Fration: OSAT APT-ID: 46584T Analysis date: 27-FEB : 9.474e+6, WWWv^vvA^A/*^ Well: Depth: m Sample type: Fration: OSAT APT-ID: 46584T Analysis date: 27-FEB : 50 min Page 64

59 Geohemistry Data Report - s and Gas Analyses Well Well: > Depth: m Sample type: Fration: OSAT APT-ID: 46584T Analysis date: 27-FEB :.858e+7, 50 min Page 65

60 Geohemistry Data Report - s and Gas Analyses Well f Well: ' Depth: m Sample type: Fration: OSAT APT-ID: 46584T Analysis date: 27-FEB :.06e+7 40 min Page 66

61 Geohemistry Data Report - s and Gas Analyses Well Well: Depth: 898.0m Sample type: Fration: OSAT APT-ID: 46585T Analysis date: 27-FEB :.029e+7 i 2 TLS : 5.4e+7, 50 min Page 67

62 Geohemistry Data Report - s and Gas Analyses Well Well: Depth: Sample type: Fration: APT-ID: Analysis: 898.0m OSAT 46585T GC-HRMS > Analysis date: 27-FEB : 9.866e+6, y *WIWUAÆA«WAM J~»WIU^^ 50 min [Well: Depth: 898.0m Sample type: Fration: OSAT APT-ID: 46585T Analysis date: 27-FEB :.55e+7 ; 50 min Page 68

63 Geohemistry Data Report - s and Gas Analyses Well Well: Depth: 898.0m Sample type: Fration: OSAT APT-ID: 46585T Analysis date: 27-FEB : 2.4e+7 50 min Well: Depth: 898.0m Sample type: Fration: OSAT APT-ID: 46585T Analysis date: 27-FEB : 5.834e+6 50 min Page 69

64 Geohemistry Data Report - s and Gas Analyses Well Well: Depth: Sample type: Fration: APT-ID: Analysis: 898.0m OSAT 46585T GC-HRMS > Analysis date: 27-FEB :.068e+7 i y WUkUL/AJMJWUJ 50 min Well: Depth: Sample type: Fration: APT-ID: Analysis: Analysis date: 898.0m OSAT 46585T GC-HRMS 27-FEB : 9.69e+6 uw 40 min Page 70

65 Geohemistry Data Report - s and Gas Analyses Well Well: Depth: m Sample type: Fration: OSAT APT-ID: 46586T Analysis date: 27-FEB : 8.663e+6 i t^åu*kah^j^ 50 min min Page 7

66 Geohemistry Data Report - s and Gas Analyses Well Well: Depth: Sample type: Fration: APT-ID: Analysis: m OSAT 46586T GC-HRMS ' Analysis date: 27-FEB : 8.440e+6, Oab --3ba gj E i III " So, 2 yy I - 30ba j 50 min Well: Depth: m Sample type: Fration: OSAT APT-ID: 46586T Analysis date: 27-FEB :.269e+7 I I il Ly 50 min Page 72

67 Geohemistry Data Report - s and Gas Analyses Well Well: > Depth: m Sample type: Fration: OSAT APT-ID: 46586T Analysis date: 27-FEB :.862e+7, 50 min. 00 Page 73

68 Geohemistry Data Report - s and Gas Analyses Well f Well: ' Depth: m Sample type: Fration: OSAT APT-ID: 46586T Analysis date: 27-FEB : 8.880e+6, Well: Depth: Sample type: Fration: APT-ID: Analysis: Analysis date: m OSAT 46586T GC-HRMS 27-FEB : 8.47e+6 40 min \JUUU I 70 \AW\IUJVJ VAJ UJ W V_ Page 74

69 Geohemistry Data Report - s and Gas Analyses Well 8.7CH Well: Depth: m Test: Fration: OSAT APT-ID: 46736T Analysis date: 27-FEB : 6.003e n Well: Depth: m Test: Fration: OSAT APT-ID: 46736T Analysis date: 27-FEB :.25e min Page 75

70 Geohemistry Data Report - s and Gas Analyses Well 9.3 n Well: Depth: m Test: Fration: OSAT APT-ID: 46736T Analysis date: 27-FEB : 2.974e+5 50 min Well: Depth: m Test: Fration: OSAT APT-ID: 46736T Analysis date: 27-FEB : 8.783e min Page 76

71 Geohemistry Data Report - s and Gas Analyses Well 00.0CH Well: Depth: m Test: Fration: OSAT APT-ID: 46736T Analysis date: 27-FEB : 9.093e+5 50 min. 00 Page 77

72 Geohemistry Data Report - s and Gas Analyses Well Well: Depth: m Test: Fration: OSAT APT-ID: 46736T Analysis date: 27-FEB : 4.742e+5 50 min. 00 Well: Depth: Test: Fration: APT-ID: Analysis: Analysis date: m OSAT 46736T GC-HRMS 27-FEB : 3.293e+6 JlJ ~-^-_Jt A_A_ 40 min Page 78

73 Geohemistry Data Report - s and Gas Analyses Well GC-MS Chromatograms of Aromati Hydroarbons Page 9

74 Geohemistry Data Report - s and Gas Analyses Well 00.0CH Sample: NSO- > Depth: na Sample type: Fration: OTOP-OARO APT-ID: 0042T Analysis date: 29-FEB :.07e :.0i7e+9 i a 4 min Sample: NSO- Depth: na Sample type: Fration: OTOP-OARO APT-ID: 0042T Analysis date: 29-FEB : : 2 432e+8 PHPT MEL]- & p -DM o & P I 38 min Page 80

75 Geohemistry Data Report - s and Gas Analyses Well Sample: NSO- Depth: na Sample type: Fration: OTOP-OARO APT-ID: 0042T Analysis date: 29-FEB : 5.698e : 5.69Ss+7 2)2.0660: 5.698tr"7 34 min Sample: NSO- Depth: na Sample type: Fration: OTOP-OARO APT-ID: 0042T Analysis date: 29-FEB : 3.354e+7 ; U R vj yiiv 70 min. 00 Page 8

76 Geohemistry Data Report - s and Gas Analyses Well 00.0CH Sample: NSO- Depth: na Sample type: Fration: OTOP-OARO APT-ID: 0042T Analysis date: 29-FEB :.226e+7 50 min. 90 Page 82

77 Geohemistry Data Report - s and Gas Analyses Well Well: ' Depth: m Sample type: Fration: OTOP-OARO APT-ID: 46584T Analysis date: 29-FEB : 5.804e : 5.804e+8 70J 096: S.804f:-r-S i H - -I - "V, + 4 min Well: ' Depth: m Sample type: Fration: OTOP-OARO APT-ID: 46584T Analysis date: 29-FEB : 2.82e : 2.:82e-g : 2 \Us^ il min Page 83

78 Geohemistry Data Report - s and Gas Analyses Well 00.0CH Well: Depth: m Sample type: Fration: OTOP-OARO APT-ID: 46584T Analysis date: 29-FEB : : 2i2.0660: 7.623e+7?.623<-7 ; 34 min. i Well: Depth: m Sample type: Fration: OTOP-OARO APT-ID: 46584T Analysis date: 29-FEB : 3.003e+7 70 min Page 84

79 Geohemistry Data Report - s and Gas Analyses Well 00.0CH Well: Depth: m Sample type: Fration: OTOP-OARO APT-ID: 46584T Analysis date: 29-FEB :.567e+7 50 min. 90 Page 85

80 Geohemistry Data Report - s and Gas Analyses Well Well: Depth: 898.0m Sample type: Fration: OTOP-OARO APT-ID: 46585T Analysis date: 29-FEB : 2.634e : 2.634s+8 HO.: 096: 2.634ft- -H p-r 4 min Well: Depth: Sample type: Fration: APT-ID: Analysis: 898.0m OTOP-OARO 46585T GC-HRMS > Analysis date: 29-FEB :.54e+8 >06.I096: J o s.i + C0-38 min Page 86

81 Geohemistry Data Report - s and Gas Analyses Well 00.0CH Well: Depth: 898.0m Sample type: Fration: OTOP-OARO APT-ID: 46585T Analysis date: 29-FEB : 5.278e : 5.27S&+7 34 min Well: Depth: 898.0m Sample type: Fration: OTOP-OARO APT-ID: 46585T Analysis date: 29-FEB-08 v 23.74: 4.75e+7 v-jl 70 min Page 87

82 Geohemistry Data Report - s and Gas Analyses Well 00.0CH Well: Depth: 898.0m Sample type: Fration: OTOP-OARO APT-ID: 46585T Analysis date: 29-FEB :.627e+7 50 min. Page 88

83 Geohemistry Data Report - s and Gas Analyses Well 00.0CH Well: Depth: m Sample type: Fration: OTOP-OARO APT-ID: 46586T Analysis date: 29-FEB : : 70J 096: 2.2e i is+8?.2.uft-fs i 9 S 4 min Well: Depth: m Sample type: Fration: OTOP-OARO APT-ID: 46586T Analysis date: 29-FEB : :.066e+8 i.ogfrg :.066e-:-N _/wji 38 min Page 89

84 Geohemistry Data Report - s and Gas Analyses Well Well: Depth: m Sample type: Fration: OTOP-OARO APT-ID: 46586T Analysis date: 29-FEB : : 5.090e+7 34 min Well: Depth: m Sample type: Fration: OTOP-OARO APT-ID: 46586T Analysis date: 29-FEB : 4.399e+7 _JUJVA_JVJ 70 min Page 90

85 Geohemistry Data Report - s and Gas Analyses Well Well: Depth: m Sample type: Fration: OTOP-OARO APT-ID: 46586T Analysis date: 29-FEB :.508e+7 50 min. Page 9

86 Geohemistry Data Report - s and Gas Analyses Well 00.0CH Well: Depth: m Test: Fration: OTOP-OARO APT-ID: 46736T Analysis date: 29-FEB : : 70J 096: 3.0e+8 3.0iie i ift--h <6 F-i J, 4 min Well: Depth: m Test: Fration: OTOP-OARO APT-ID: 46736T Analysis date: 29-FEB : : 2 27e+7 ^ u - 38 min Page 92

87 Geohemistry Data Report - s and Gas Analyses Well Well: Depth: m Test: Fration: OTOP-OARO APT-ID: 46736T Analysis date: 29-FEB : : 8.099e &K' 34 min Well: Depth: m Test: Fration: OTOP-OARO APT-ID: 46736T Analysis date: 29-FEB : 4.568e+5 70 min Page 93

88 Geohemistry Data Report - s and Gas Analyses Well Well: Depth: m Test: Fration: OTOP-OARO APT-ID: 46736T Analysis date: 29-FEB : 4.828e+5 50 min. 90 Page 94

89 Geohemistry Data Report - s and Gas Analyses Well Page 95

90 Geohemistry Data Report - s and Gas Analyses Well Table 2. Referene data for GC Whole measured on NSO- Pristane/n-C7 Benzene/Hexane i, iiiiiiiiiliisii illiiilililllllilll ^^^^^^ Page 96

91 Geohemistry Data Report - s and Gas Analyses Well Table 22. Referene data for GC of Saturated Compounds measured on NSO- Pr/n-C7 n-c5/n-c20 n-c30/n-c20 n-c7/(n-c7+n-c27) ? y J SC rj <C Page 9

92 Geohemistry Data Report - s and Gas Analyses Well Table 23. Referene data for GC-MS of Saturated Compounds measured on NSO- Ci _ S3 [23/3]/30ab 35abR/30ab 25nor30ab/25nor28ab 29aaR/27dbS 29bbS/27bbR y rs '35 zn u II M i? y * rj Our olumn resolves the 25nor28a(3 doublet, thus giving a value in the high-end region of the aeptable range speified by NIGOGA. Page 98

93 Geohemistry Data Report - s and Gas Analyses Well Table 24. Referene data for GC-MS of Aromati Compounds measured on NSO- - J -MP/P Al/El al/dl I, ^ I i ^ o o el o!>' Page 99

94 Geohemistry Data Report - s and Gas Analyses Well Experimental Proedures All proedures follow NIGOGA, 4 th Edition. Below are brief desriptions of proedures/analytial onditions. Deasphaltening Pentane is added in aess (40 times the volume of oil). The solution is stored for at least 2 hours in a dark plae before the solution is filtered or entrifuged and the weight of the asphaltenes measured. Iatrosan An Iatrosan MK-5 (TLC/FID Analyser) instrument is used. 2 ju. of extrat or diluted oil is spotted on Chromarod S-III rods before elution in hexane (25 min), toluene (8 min) and dihloromethane with 7 % methanol (vol/vol). The solvent is allowed to evaporate before the rods are plaed into the next eluation hamber. Before running the rods in the analyser, the rods are heated for 90 se. in a heating hamber at 60 C. Density An Anton Parr instrument is used. Air and distilled water is used to alibrate the instrument. All measurements are done at 5 C. NSO- is used as a referene sample, and is run in eah series of density measurements. If the visosity of the oil is very high at 5 C, a gravimetri method is used. API gravity is alulated from the density. API Gravity ( ) = 4.5/Density (g/m 3 ) Topping A rotavapor is used and ~ lml of oil is weighted aurately into a small round bottum flask. The oil is evaporated for 5 min at 90 C with the water pump turned to maximum. After the evaporation the oil is weighted again. One aliquot of NSO- is run as a referene sample together with the topping series. GC analysis of gas omponents Aliquots of the samples were transferred to exetainers. 0.-lml were sampled using a Gerstel MPS2 autosampler and injeted into a Hewlett Pakard 5890 Series II GC equipped with Porabond Q olumn, a flame ionisation detetor (FID), a thermal ondutivity detetor (TCD) and a methylization unit. Hydroarbons were measured by FID, CO2 by metylization (to CH4) and then FID and N 2 and O 2 by TCD. Carbon isotope analysis of hydroarbon ompounds and CO2 The arbon isotopi omposition of the hydroarbon gas omponents was determined by a GC-C-IRMS system. Aliquots were sampled with a syringe and analysed on a Trae GC2000, equipped with a Poraplot Q olumn, onneted to a Delta plus XP IRMS. The omponents were burnt to CO2 and water in a 000 C furnae over Cu/Ni/Pt. The water was removed by Nafion membrane separation. Repeated analyses of standards indiate that the reproduibility of 8 3 C values is better than %o PDB (2 sigma). Carbon isotope analysis of low onentration methane using the Preon. The arbon isotopi omposition of methane was determined by a Preon-IRMS system. Aliquots were sampled with a GCPal autosampler. CO2, CO and water were removed on Page 00

95 Geohemistry Data Report - s and Gas Analyses Well hemial traps. Other hydroarbons than CH4 and remaining traes of CO2 were removed by ryotrapping. The methane was burnt to CO2 and water in a 000 C furnae over Cu/Ni/Pt. The water was removed by Nafion membrane separation. The sample preparation system desribed (Preon) was onneted to a Delta plus XP IRMS for 8 3 C analysis. Repeated analyses of standards indiate that the reproduibility of 8 3 C values is better than %o PDB (2 sigma). Hydrogen isotope analysis of methane The hydrogen isotopi omposition of methane was determined by a GC-C-IRMS system. Aliquots were sampled with a GCPal and analysed on a Trae GC2000, equipped with a Poraplot Q olumn, onneted to a Delta plus XP IRMS. The omponents were deomposed to H2 and oke in a 400 C furnae. The international standard NGS-2 and an in-house standard (Std A) were used for testing auray and preision. The "true" value of NGS-2 is given to %o V-SMOW ( Repeated analyses of standards indiate that the reproduibility of 8D values is better than 0 %o PDB (2 sigma). Stable arbon and hydrogen isotope analysis of frations The samples were dissolved in a known amount of dihloromethane, and 4-5 mg of the sample (or as muh as possible) was transferred to a glass ontainer. The solvent was evaporated in an oven at 50 C. CuO and some silver wires were added to the ontainers, whih were then sealed by melting in a vauum. The samples were then ombusted in an oven at 550 C for hour (Sofer, 980). The ombustion produts CO2 and H2O were separated at -80 C. Carbon isotopi omposition of the CO2 aliquot was determined on a Finnigan MAT 25 mass spetrometer. A standard (NGS NSO-, topped oil) is analysed for eah 0 th sample. The 8 3 C value obtained for this standard is %o PDB. The variation in the isotopi values for the standard by repeated analysis over a period of five years is ± 0.3 %o. H2O( g ) aliquot was redued with Zn( s ) to Efyg) and ZnO( s ) in sealed, evauated quartz vessels at 900 C. The 8D omposition was determined by a Finnigan MAT 25 mass spetrometer. Average analysed value for GISP from IAEA is 8DVSMOW = ± 0.89 %o (one standard deviation). Given value from IAEA is ± 0.9 %o. Stable arbon isotope analysis of kerogens The samples were weighed and transferred to a 9x5 mm tin apsule. Approximately 3 mg of the samples were used. The ombustion of the samples in the presene of O2 and &2O3 at 700 C was done in a Carlo Erba NCS 2500 element analyser. Redution of NO X to N2 was done in a Cu oven at 650 C. H2O was removed in a hemial trap of KMnC>4 before separation of N2, CO2 and SO2 on a 2 m Poraplot Q GC olumn. CO2 is flushed on-line in a He flow to a Miromass Optima, Isotope Ratio Mass Spetrometer for determination of 8 3 C. A standard (USGS-24) is analysed for eah 0 th sample. The S 3 C value obtained for this standard is -6.0 ± 0.06 %o PDB (one standard deviation). Given value from IAEA is ± 0. %o PDB (one standard deviation). GC of whole oil A HP5890 II instrument is used. The olumn is a HP PONA, length 50 m, i.d. 0.2 mm, film thikness 0.5 jam. 2,2,4-tri-methyl-pentane is used as an internal standard. Temperature programme Page 0