High Pressure Lab at UT Austin

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1 High Pressure Lab at UT Austin Jackson School of Geosciences is funded by John and Katherine Jackson s generous endowment, the most generous contribution ever to a single department; ~280 million dollars Geology Foundation has a total endowment of ~ million dollars. Jackson School of Geosciences matches $124K to support Lin s EFree grant of $300K to fully support a postdoc for 4.5 years. Strong ties to energy related research, including oil exploration, CO2 sequestration, gas hydrates, bio-geosciences, water resource, and climate change. Center for Frontiers of Subsurface Energy Security (CFCES) at UT Austin. Afu Lin joined UT Austin as a faculty in July Welcome prospective students and scholars; 5 years of scholarships in the initial offer to PhD students (tuition, salary, and insurance) Assistant Professor Afu Lin Postdoc Fellow Dr. Zhu Mao PhD Student Cecilia Xu

2 UT Austin s Facilities For High-Pressure Research Sample prep lab with microscope, EDM, mechanical drilling, and many types of DAC Planned: fast laser spectroscopy and HP gas loading system Optical Raman system with Verdi V2 laser and Andor iccd Table for Ultrafast Laser Spectroscopy Planned Gas Loading System (~LLNL) Lab Under Construction Raman study in an EHDAC

3 UT Austin s Expertise In Situ Synchrotron and Optical Spectroscopies at High PT IXS Techniques Diffraction at >Mbars and HT High-resolution IXS Mössbauer spectroscopy X-ray emission spectroscopy Resonant X-ray emission X-ray Raman spectroscopy Properties at Extremes Structures/Transitions/EoS Lattice dynamics/phonon DoS Hyperfine parameters (QS/IS) Total spin momentum (S) 3d-4f electronic structures Local Electronic structures Pressure, Temperature, X-Composition, t-time IXS in LHDAC Wide-opening EHDAC X-ray Diffraction at 2 Mbars cbn insert with ultrapure Be

4 Research Interest in EFree 3d/4f-electron compounds under P-T P T extremes Extreme stress/strain using dynamic DAC Cutting-edge science/high-profile publications

5 1. 3d Transition Metal Compounds 3d transition metals form a series of compounds with a uniquely wide range of electronic properties. Here UT Austin team aims to study y their electronic structures and associated changes (interplays) in physical properties, including spin transitions, metallization, and magnetic transitions under high pressure-temperature conditions using an array of recently developed synchrotron IXS and high P-T P T techniques Geosciences Implications Novel materials

6 2. 4f-electron Metals and Compounds McMahan, 1998 Research will focus on the interconnected 4f-electron elements and compounds, focusing on discovering new structures in the vast P-T space and understanding the interplays between their crystal structures, electronic structures (including trivalent and divalent states), and lattice dynamics. Ties to DOE/LLNL/CDAC research interests.

7 3. Stress/Strain Extremes and Kinetics Anelasticity σij=cijklεkl Nemat-Nasser and Choi, 2005 Seismic Attenuation Factor (Q Factor) 2π Q 2πE Material properties can behave quite differently at various regimes of stress/strain rates. Anelasticity arises from the time-dependent relation between stress and strain. Require vigorous technical developments! Q ΔE E 1 Δ E

8 Complementary Expertise and Facilities from EFree Information/expertise for building HP apparatus and lab at UT Austin Access and collaboration in synchrotron and optical spectroscopies Theoretical understanding on 3d-4f compounds Help with recruit a postdoc and students with strong background in physics and X-ray/optical X spectroscopies.. The project will involve a postdoc (4.5 yrs) and a number of graduate students.

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