SHODEX. by Showa Denko K.K.

Transcription

1 selectosil For Availability and Ordering nformation please contact your Phenomenex Technical Consultant. SHODEX Selectosil/ High efficiency polymer columns Excellent mechanical and chemical stability Wide application range High temperature GPC applications Nomenclature of Packing Materials PHM polyhydroxymethacrylate PMM polymethylmethacrylate PS polystyrene PVA polyvinyl alcohol S-DVB styrene-divinylbenzene co-polymer Separation Modes AFC affinity chromatography GPC gel permeation chromatography (organic-soluble SEC) GFC gel filtration chromatography (water-soluble SEC) HC hydrophobic interaction chromatography C ion chromatography EC ion-exchange chromatography EX ion-exclusion chromatography LEX ligand-exchange chromatography NPC normal phase chromatography P & A partition and adsorption chromatography RPC reversed phase chromatography SEC size-exclusion chromatography (includes GPC & GFC) Guide for Column Selection Molecular Separation Solubility Weight Mode Column Page over 000 under 000 SEC GPC KF , K , KD ,..., KF , KF-0.5 HQ-06L HQ SEC GPC KF , K , KD , LF-80,..., KF , KF-0 HQ-0.5L HQ RPC RSpak DE-, L, DM Sample over 000 SEC EC HC OHpak SB HQ, SUGAR KS , PROTEN KW EC QA-85, DEAE-85, SP-85, CM AXpak WA HC PH RPC RSpak RP AFFNTY AFpak...5 Waterinsoluble Watersoluble under 000 SEC SB HQ, SUGAR KS LEC SUGAR SC0, SP EX RSpak KC-8, SUGAR SH0, SUGAR SH8...6, 5 EC AXpak WA C C S-90 E, S-50 E, C -5A, Y-5, YK-, T RPC RSpak DE-6,, DS NPC SUGAR SZ55, RSpak DC-6...5, 7 AFFNTY AFpak...5 CHRAL ORpak CDBS, CDA, CDB, CDC HQ Phenomenex

2 Organic GPC Columns has a wide variety of columns for GPC (or SEC) using organic solvents. The columns are packed with porous S- DVB gels specially developed for GPC use. Five types of GPC columns packed in different solvents are available. Custom columns packed in other solvents, such as quinoline, o-dichlorobenzene, ethyl acetate, tetrachloroethane and dimethylacetamide are available upon request. Series name n-column solvent Applications GPC KF-800 series THF (tetrahydrofuran) General purpose GPC GPC K-800 series Chloroform General purpose GPC GPC KD-800 series DMF (dimethylformamide) Polar compounds such as melamine resin, phenolic resin, polyurethane and polyvinylpyrrolidone GPC LF-80 THF Wide linear molecular weight GPC HFP-800 series HFP (hexafluoroisopropanol) Engineering plastics such as polyamide (Nylon) and polybutylterephthalate at ordinary temperature GPC HT-800 series Toluene High temperature GPC up to 0 C GPC UT-800 series Toluene Ultra high temperature GPC up to 0 C. Polymer samples in which ultra-high molecular weight portion is included GPC KF-600 series THF Semi-micro GPC GPC KF-00HQ series THF Semi-micro GPC for organic polymer analysis App D 0766 Calibration Curves for GPC KF-800 Series Column: Dimensions: 0 7 GPC KF-800 series 8 x 00 mm App D 0768 Calibration Curves for GPC Mixed Bed Columns Column: Dimensions: 0 7 GPC KF-800L series and KF-806M 8 x 00 mm App D 559 Polystyrene Standards Column: GPC KF-80 Eluent: THF Detector: 5 nm Sample:. PS, %. PS, %. PS %. n-propylbenzene % 5. Benzene % Molecular Weight (Polystyrene) KF-80 KF-806 KF-80 KF-807 KF-805 KF-80.5 KF-80 KF-80 KF-806M Elution Volume Elution (ml) volume (ml) Molecular Weight (Polystyrene) KF-805L KF-80L KF-80L KF-806L KF-807L KF-806M Elution Volume Elution volume (ml) (ml) min App D 7 Phenol Resin Eluent: THF Detector: 5 nm Temperature: 0 C App D 55 PEEK Resin Column: GPC K-806M x Eluent: CHCl /Cl CHCOOH=90/0 Detector: R Sample: PEEK 0. %, 50 µl App D 55 Polyvinylpyrrolidone Column: GPC KD-806M x Eluent: 0.0 M LiBr /DMF Detector: R Temperature: C Sample: Polyvinylpyrrolidone 0.5 %, 50 µl LF-80 (linear column) KF-80L (mixed-bed column) 0 0 min min min Phenomenex

3 Organic GPC Columns (continued) App D 55 Polyamide (Nylon) Column: GPC HFP-806M x Eluent: 5 mm TFA-Na in HFP Detector: R Temperature: 0 C App D 55 mproved Resolution from Solvent Peak Column: Dimensions: Eluent: Flow Rate: Detector: Sample: GPC KF-806L + KF-800D 8 x 00 mm + 8 x 00 mm THF.0 ml/min 5 nm Polystyrene standards. MW,80,000. MW,000. MW 07,000. MW 6, MW, MW 0 (Propylbenzene) App D 555 Low Density Polyethylene Column: GPC UT-806M x, HT-806M x Eluent: 0. % BHT in o-dichlorobenzene Detector: R Temperature: 0 C Sample:. LDPE Polyamide6/ 5 6 Polyamide KF-806L min UT - 806M X min Polyamide6 Polyamide66 KF-806L+KF-800D UT - 806M X min min min ORDERNG NFORMATON Standard Columns Column Type / Part No.: THF Chloroform DMF D x Length (mm) Plate Number Exclusion Limit GPC KF-80 GPC K-80 GPC KD-80 8 x 00 >6,000.5 x 0 (KD-80,.5 x 0 ) GPC KF-80 GPC K-80 GPC KD-80 8 x 00 >6,000 5 x 0 GPC KF-80.5 GPC K-80.5 GPC KD x 00 >6,000 x 0 GPC KF-80 GPC KD-80 8 x 00 >6,000 7 x 0 GPC KF-80 GPC K-80 GPC KD-80 8 x 00 >6,000 x 0 5 GPC KF-805 GPC K-805 GPC KD x 00 >0,000 x 0 6 GPC KF-806 GPC K-806 GPC KD x 00 >0,000 ( x 0 7 ) GPC KF-807 GPC KD x 00 >5,000 ( x 0 8 ) Note: 80, 80, 805, 806 and 807 are available packed in HFP. Mixed bed columns are specially designed to have wide linear molecular weight ranges. These mixed bed columns are highly recommended for correcting non-linear sections of molecular weight calibration curves. Mixed Bed Columns Column Type / Part No.: THF Chloroform DMF HFP D x Length (mm) Plate Number Exclusion Limit GPC KF-80L GPC K-80L 8 x 00 >6,000 7 x 0 GPC KF-80L GPC K-80L 8 x 00 >6,000 x 0 5 GPC KF-805L GPC K-805L 8 x 00 >0,000 x 0 6 GPC K-806L 8 x 00 >0,000 ( x 0 7 ) GPC KF-806M GPC KD-806M GPC HFP-806M* 8 x 00 >,000 ( x 0 7 ) GPC KF-807L 8 x 00 > 5,000 ( x 0 8 ) * HFP-806M plate number is >8,000 and the effective molecular weight range is 0 ~0 7. Phenomenex

4 Organic GPC Columns (continued) ORDERNG NFORMATON High Temperature GPC Columns Column Type D x Length Exclusion Usable Toluene (mm) Limit Temperature ( C) Price GPC HT-80 8 x 00 7 x GPC HT-80 8 x 00 x GPC HT x 00 x GPC HT x 00 ( x 0 7 ) 00-0 Note: Exclusion Limits in parentheses,( ), are estimated values. Solvent-Peak Separation Columns* Column Type THF Chloroform D x Length (mm) Price GPC KF-800D GPC K-800D 8 x 00 *These columns make the elution of low-molecular weight components slower and can be used to separate them from a solvent peak or other troublesome peaks. Wide Linear Working Range D x Length Plate Exclusion Column (mm) Number Limit Price GPC LF-80 8 x 00 > 7,000 7 x 0 Downsized GPC Columns Column Type THF D x Length (mm) Particle Size (μm) Pore Size (Å) Plate Number Exclusion Limit (Polystyrene) Price GPC KF x 50 0 >7,000,500 GPC KF x >7,000 5,000 GPC KF x >7,000 0,000 GPC KF x >7,000 70,000 GPC KF x >6,000 00,000 GPC KF x >7,000,000,000 GPC KF x 50 0,000 >7,000 (0,000,000) GPC KF-606M 6.0 x 50 0 >8,000 (0,000,000) GPC KF x 50 8 >,000 >5,000 (00,000,000) GPC KF-G.6 x 0 8 Guard Column Notes: For all column types. Recommended flow rate: 0. to 0.6 ml/min; Max. usable flow rate: 0.8 ml/min; Max. usable temperature 5 C. μm Semi-micro GPC Columns Column Type D x Length (mm) Plate Number Exclusion Limit (Polystyrene) Price GPC KF-0 HQ.6 x 50 5,000,500 GPC KF-0 HQ.6 x 50 5,000 5,000 GPC KF-0.5 HQ.6 x 50 5,000 0,000 GPC KF-0 HQ.6 x 50 5,000 70,000 GPC KF-0 HQ.6 x 50 5,000 00,000 GPC KF-05L HQ.6 x 50 8,000,000,000 GPC KF-06L HQ.6 x 50 8,000 (0,000,000) GPC KF-G.6 x 0 Guard column Comparison Between KF-00 HQ Series (Semi-micro GPC) and KF-800 Series (Standard Type). The plate number has increased by.5 times or more. The consumption of eluent has decreased to less than one fourth KF-00 series columns are best suited to determine molecular weight distribution and analysis of low molecular weight materials in polymer. Based on a μm SDVB copolymer packing material, improvements over older GPC columns include higher resolution, less solvent usage, better detection limits, and assurance of linear calibration curves. Column: GPC (A) KF-0HQ (.6 x 50 mm) (B) KF-80 (8.0 x 00 mm) Eluent: THF Flow Rate: (A) 0. ml/min (B).0 ml/min Detector: 5 nm Temperature: 5 C njection volume: 5 µl KF-0 HQ vs. KF-80 App D 7 Phenomenex

5 GFC (Aqueous GPC) Columns has a wide variety of columns for GFC. Three types of GFC columns packed with different gel materials are available. Series Name Packing Material Applications OHpak SB-800HQ PHM gel Used for general purpose GFC of water-soluble polymers, proteins and enzymes SUGAR KS-800 Sulfonated PS gel Mono, di, tri, oligo and polysaccharides, starches and celluloses PROTEN KW-800 Porous silica gel GFC of proteins, glycoproteins and peptides App D 0769 Calibration Curves for OHpak SB-800HQ Series Column: OHpak SB-800HQ Eluent: Water 0 7 Sample:. P-800. P-00. P P P P P-0 8. P-5 9. P P-. Maltotriose. Maltose 0. Glucose Molecular Weight (Pullulan) SB-80HQ SB-80.5HQ SB-806HQ SB-805HQ SB-80HQ SB-80HQ 5 SB-806MHQ App D 557 Hyaluronic Acid Column: OHpak SB-805 HQ x (600 mm total length) Eluent: 0. M NaNO Detector: R Temperature: 0 C Sample: Hyaluronic Acid min Elution Volume (ml) min App D 077 Dietary Fiber Column: SUGAR KS-80 x (600 mm total length) Eluent: Water Flow Rate: 0. ml/min Detector: R Temperature: 80 C njection Volume: 0 µl Sample: Dietary Fiber. Glycerol ORDERNG NFORMATON Aqueous GPC Columns D x Length Plate Exclusion Column Type/Part No. (mm) Number Limit Price OHpak SB-80HQ 8 x 00 >0,000 x 0 OHpak SB-80.5HQ 8 x 00 >5,000 x 0 OHpak SB-80HQ 8 x 00 >5,000 x 0 5 OHpak SB-80HQ 8 x 00 >5,000 x 0 6 OHpak SB-805HQ 8 x 00 >0,000 x 0 6 OHpak SB-806HQ 8 x 00 >0,000 ( x 0 7 ) OHpak SB-806MHQ 8 x 00 >0,000 ( x 0 7 ) OHpak SB-807HQ 8 x 00 >,500 (5 x 0 8 ) SUGAR KS-80 (Na + ) 8 x 00 >5,000 x 0 SUGAR KS-80 (Na + ) 8 x 00 >5,000 x 0 SUGAR KS-80 (Na + ) 8 x 00 >5,000 5 x 0 SUGAR KS-80 (Na + ) 8 x 00 >5,000 x 0 5 SUGAR KS-805 (Na + ) 8 x 00 >8,000 5 x 0 6 SUGAR KS-806 (Na + ) 8 x 00 >8,000 (5 x 0 7 ) PROTEN KW x 00 >0,000 5 x 0 PROTEN KW-80 8 x 00 >0,000.5 x 0 5 PROTEN KW-80 8 x 00 >0,000 6 x 0 5 Note: Exclusion Limits in parentheses,( ), are estimated values. Calibration Standards ORDERNG NFORMATON Calibration Standards Standard Type/Part No. Material Content MW Range Applications Price STANDARD P-8 Pullulan 0. g x 8 grades 5, ,000 GFC (aqueous GPC) STANDARD SM-05 PS 0.5 g x 0 grades,00 -,000,000 GPC with THF, chloroform, toluene, etc. See p. for full line of Polymer Calibration Standards. Phenomenex

6 Columns for PROTENS and Nucleic Acids on-exchange Columns EC series columns are suited for the analysis of proteins and nucleic acids. AXpak WA-6 is suited for the analysis of nucleic acids. ORDERNG NFORMATON EC Series Columns D x Length Plate Column Type/Part No. (mm) Number Packing Material Functional Group Price EC QA-85 8 x 75 >,000 PHM gel Quaternary ammonium (strong anion) EC DEAE-85 8 x 75 >,000 PHM gel Diethylaminoethyl (weak anion) EC SP-85 8 x 75 >,000 PHM gel Sulfopropyl (strong cation) EC CM-85 8 x 75 >,000 PHM gel Carboxymethyl (weak cation) AXpak WA-6 6 x 50 >,500 PHM gel Diethylaminoethyl (weak anion) Affinity Columns D x Length Ligand Compound Capacity/ Column Type/Part No. (mm) Ligand Load/g Column Applications Price AFpak AAB-89 8 x 50 Aminobenzamidine 00 µmol Serine proteases AFpak AAF-89 8 x 50 Acriflavine 0 µmol ATP Na.8 mg RNA, DNA, vitamins AFpak AAM-89 8 x 50 5'AMP 0 µmol Lactic dehydrogenase.5 mg NAD, ATP enzymes AFpak AAV-89 8 x 50 Avidin 5 mg Biotin 8 µg Biotin derivatives AFpak ACA-89 8 x 50 Concanavalin A 5 mg Glycoproteins, polysaccharides AFpak ACB-89 8 x 50 Cibacron Blue 0 µmol BSA 0 mg Albumin, NAD dependent enzymes AFpak AHR-89 8 x 50 Heparin 5 mg Lysozyme mg Lipoproteins, blood coagulation factors AFpak ALC-89 8 x 50 LCA (Lentil lectin) 7 mg Glycoproteins, polysaccharides AFpak APA-89 8 x 50 Protein A 8 mg gg human 0 mg Human gg, immune complexes AFpak APG-89 8 x 50 Protein G 5 mg gg human 0 mg gg immune complex AFpak ARC-89 8 x 50 RCA- 0 mg Glycoproteins, polysaccharides AFpak AST-89 8 x 50 Soybean trypsin inhibitor 0 mg Trypsin-like proteases AFpak AWG-89 8 x 50 Wheat germ agglutinin mg Glycoproteins, polysaccharides Other Columns D x Length Plate Packing Functional Separation Column Type/Part No. (mm) Number Material Group Mode Applications Price HC PH-8 8 x 75 >,000 PHM gel Phenyl HC Proteins RSpak NN-6 6 x 50 >5,000 PHM gel P&A Cystine and cysteine Columns for Sugar Analysis Series Name SUGAR series SUGAR KS-80 Applications Effective separation is possible for sugars and sugar alcohols using mixed modes such as SEC, EX, LEC and P&A. Suited for the separation of mono, di and oligosaccharides by mixed mode such as SEC and LEC. Ordering nformation Sugar Columns Column Type/ D x Length Plate Exclusion Packing Counter Separation Part No. (mm) Number Limit Material on Mode Price SUGAR SH0 8 x 00 >5,000,000 S-DVB gel H + SEC + EX SUGAR SH8 8 x 00 >5,000 0,000 S-DVB gel H + SEC + EX SUGAR SC0 8 x 00 >,000,000 S-DVB gel Ca + SEC + LEC SUGAR SC8 8 x 00 >,000 0,000 S-DVB gel Ca + SEC + LEC SUGAR SP080 8 x 00 >0,000,000 S-DVB gel Pb + SEC + LEC SUGAR SC 6 x 50 >5,000 S-DVB gel Ca + P&A + LEC SUGAR SZ55 6 x 50 >5,000 S-DVB gel Zn + P&A + LEC SUGAR KS-80 8 x 00 >5,000,000 S-DVB gel Na + SEC + LEC Aside from the columns listed here, there are other columns that can be used for sugar separations. Disaccharides of similar molecular weight can be separated by NPC using RSpak DC-6. SUGAR KS-800 series and OHpak SB-800 HQ series can also be used for sugar separations by SEC. Phenomenex 5

7 Columns for Organic Acids KC-8 enables an effective organic acids separation using a mixed mode of EX, SEC and P&A. Organic acids also can be separated by RPC using RSpak DE-6. ORDERNG NFORMATON RSpak Column Type*/ D x Length Plate Packing Counter Part No. (mm) Number Material on Price RSpak KC-8 8 x 00 >5,000 S-DVB gel H+ *Note: RSpak KC-8 was formerly known as onpak KC-8. on Chromatography Columns Great alternative to Dionex onpac AS, ASA and AS columns High efficiency, general purpose C column mproved, high-speed separation of EPA Method 00 analytes Fluoride well-resolved from water dip Patent-pending gel eliminates overlap of carbonate system peak Anions Column: S-90 E Dimensions:.0 x 50 mm Eluent:.8 mm Na CO.7 mm NaHCO Flow Rate:.0 ml/min Sample: 0 µl. Fluoride mg/l 5. Nitrate 0 mg/l. Chloride mg/l 6. Phosphate 5 mg/l. Nitrite 5 mg/l 7. Sulfate 5 mg/l. Bromide 0 mg/l App D 75 offers an innovative C column for the suppressor method that improves both the separation speed and resolution of anions in most matrices. With high theoretical plates (>5000/m for Sulfate), the column easily and efficiently separates organic and inorganic anions such as EPA Method 00 analytes, acetate, formate, methacrylate and oxalate. High loading and exceptional resistance to loading combine with features such as improved separation of the fluoride peak from the water dip. The patent-pending PVA gel was also specifically engineered to optimize the elution behavior of the carbonate ion so as not to interfere with the quantitation of EPA Method 00 anions. App D 76 Organic Acids and norganic Anions Column: S-50 E Dimensions:.0 x 50 mm Eluent:. mm Na CO / NaHCO Flow Rate: 0.7 ml/min Sample: 0 µl. Fluoride mg/l 7. Bromide 0 mg/l. Acetate 0 mg/l 8. Nitrate 0 mg/l. Formate mg/l 9. Phosphate 5 mg/l. Methacrylate 0 mg/l 0. Sulfate 5 mg/l 5. Chloride mg/l. Oxalate 5 mg/l 6. Nitrite 5 mg/l ORDERNG NFORMATON C Columns Column Type/ D x Length Plate Packing Part No. (mm) Number Material Functional Group Applications Price C S-90 E.0 x 50 >5,000 (SO ) PVA Quaternary ammonium norganic anions and organic acids C S-90 G.6 x 0 (Guard) (General purpose) C S-50 E*.0 x 50 >,000 PVA Quaternary ammonium norganic anions and organic acids C -5A.6 x 00 >,000 PHM gel Quaternary ammonium norganic anions C Y-5.6 x 50 >,000 Cations (general purpose) C Y-G.6 x 0 (Guard) C YK-.6 x 5 >,500 Hydrophilic Polymer Carboxyl Simultaneous separation of monovalent Coated Silica and divalent cations C YK-G.6 x 0 (Guard) C YS-50.6 x 5 >5,500 PVA Cations, Alkylamines, Transition Metal ions C YS-G.6 x 0 (Guard) C T-5.6 x 50 >,000 S-DVB gel Sulfo (H + ) Transition metal ions (packed in PEEK column) C T-G.6 x 0 (Guard) *Use C S-90G guard. 6 Phenomenex

8 Polymer-BASED Reversed Phase Columns RSpak RP8 DS DE DM NN Applications 500 Å column well-suited for protein and peptide analysis. Suited for analysis of hydrophilic substances that cannot be retained by ODS columns, such as medicines and food additives. Suited for wide applications because its characteristics are similar to those of ODS columns. Suited for analysis of amino acids and polypeptides. Suited for analysis of complex samples that are composed of neutral and basic substances. Generally, neutral substances are separated by reversed phase mode, acid substances by ionexclusion mode and basic substances by reversed phase mode and ion-exchange mode. ORDERNG NFORMATON RSpak Column Type/Part No. Plate Number D x Length (mm) Price RSpak RP8-5 >,000.6 x 50 RSpak DS-6 >6, x 50 RSpak DE-6 >7, x 50 RSpak DE- >,000.6 x 50 RSpak DE-L >7,000.6 x 50 RSpak DE-G (DE-6P) (guard column).6 x 0 RSpak DM-6 >, x 50 RSpak DM-G (DM-6P) (guard column).6 x 0 RSpak DC-6 >5, x 50 RSpak NN-6 >5, x 50 App D 55 Catecholamines Column: RSpak DE-6 Dimensions: 6 x 50 mm Eluent: 0.05 M KH PO % H PO Flow Rate: 0.6 ml/min Detection: 5 nm Sample: Catecholamines 5 µl. Norepinephrine 0.0 %. Epinephrine 0.0 %. Dopamine 0.0 % App D 55 Water-Soluble Vitamins Column: RSpak DM-6 Dimensions: 6 x 50 mm Eluent: M Na HPO M KH PO + 7 % CH OH Flow Rate: 0.6 ml/min Detection: 5 nm Sample: 0.05 % each, µl. Vitamin C*. Vitamin B. Vitamin B6. Vitamin B 5. Vitamin B 6. Caffeine App D 555 Tryptic Digest of Myoglobin Column: RSpak RP8-5 Dimensions:.6 x 50 mm Eluent: A: % Acetonitrile in 0. % TFA B: 95 % Acetonitrile in 0. % TFA Gradient: Linear B 0 % to 50 %, 0 min Detection: 0 nm *Note that Vitamin C easily oxidizes in this mobile phase min min min Phenomenex 7

9 MSpak PK-A and A Polymer Based Cartridge Columns Ultrafast On-Line SPE and analysis columns for LC/MS or LC/UV by column switching. For direct injection and analysis of drugs from serum, plasma or other body fluids Unique polymer based cartridge system cartridge dimensions 0 x.0 mm D and 0 x.0 mm D Also for ultrafast on-line SPE for LC/MS/MS Ordering nformation MSpak Column Type/Part No. D x length (mm) Unit Price MSpak PK-A p x 0 /pk MSpak PK-A 5p x 0 5/pk MSpak PK-A p x 0 /pk MSpak HLD Holder ea CHRAL COLUMNS Wide range of applications Durable polymer matrix enables wide ph stability Chemically modified cyclodextrins improve enantioselectivity Cyclodextrin phases for the direct separation of enantiomers have become increasingly popular due to their wide applicability. Showa Denko has taken these useful phases a few steps further by modifying the cyclodextrins with carboxymethyl (CM) functionality and bonding them to a chemically and physically stable polymer backbone. Modification of the cyclodextrins improves enantioselectivity for many compounds compared to native cyclodextrins. Utilization of durable polymethacrylate polymer as the anchor for this stationary phase enables use of highly alkaline and acidic mobile phases, not possible with silica-based CD phases. Separation of enantiomers of amino acids and their derivatives, amino alcohols, carboxylic acids, amines, alcohols and others are routinely performed with these columns. Basic Structure of CD Bonded Phase Guard Columns Use of a guard column immediately before the analytical or preparative column is highly recommended to protect the packing materials in the analytical column from contaminants or readily adsorbable substances. The guard column should be replaced at regular intervals. ORDERNG NFORMATON Guard Columns Guard Column/ D x Length Associated Part No. (mm) Column Price GPC KF-G.6 x 0 KF-800 GPC KD-G.6 x 0 KD-800 GPC AT-G 8.0 x 50 AT-800S OHpak SB-G 6.0 x 50 SB-800 HQ OHpak SB-LG 8.0 x 50 SB-000 OHpak SB-807G 8.0 x 50 SB-807 HQ PROTEN KW-G 6.0 x 50 KW-800 SUGAR KS-G 6.0 x 50 KS-800 SUGAR SH-G 6.0 x 50 SH0 SUGAR SH-G 6.0 x 50 SH8 SUGAR SC-LG 6.0 x 50 SC0 SUGAR SC-LG 6.0 x 50 SC8 C S-90G.6 x 0 S-90E, S-50E C YK-G.6 x 0 YK- C Y-G.6 x 0 Y-5 C YS-G.6 x 0 YS-50 RSpak KC-G 6.0 x 50 KC-8 RSpak DE-G.6 x 0 DE-6 RSpak DM-G.6 x 0 DM-6 Comparison of Retention Behavior Between Modified and Unmodified CD Bonded Phases Bonded Phase Met - NA* POPA** α Rs α Rs CD CM-CD.... * Met-NA: Methionine -naphthylamide ** POPA: -Phenoxypropionic acid ORDERNG NFORMATON Chiral Columns Column Type/Part No. D x Length (mm) Ligand Price ORpak CDA-5 HQ.6 x 50 α-cyclodextrin derivatives ORpak CDB-5 HQ.6 x 50 β-cyclodextrin derivatives ORpak CDC-5 HQ.6 x 50 γ-cyclodextrin derivatives ORpak CDBS-5.6 x 50 β-cyclodextrin derivatives See p. 08 for additional chiral stationary phases. 8 Phenomenex