ANNEXURE- I PROPOSED TERMS OF REFERENCE. As per standard ToR of organic manufacturing sector issued by MoEF&CC.

Transcription

1 AEXURE- I PRPSED TERMS F REFERECE As per standard ToR of organic manufacturing sector issued by MoEF&CC. M/s. Jyoti m Chemical Research Centre Pvt. Ltd., Ankleshwar. 1

2 AEXURE-II LIST F DIRECTRS ame of Director Mr. Manshukh Vekaria Ms. Bhartiben M. Vekaria Address Kalpvruksh, Plot o: 408/25, pp. Shree Gattu Vidhyalaya, GIDC, Ankleshwar. Kalpvruksh, Plot o: 408/25, pp. Shree Gattu Vidhyalaya, GIDC, Ankleshwar. Telephone umber Designation Managing Director Director M/s. Jyoti m Chemical Research Centre Pvt. Ltd., Ankleshwar. 2

3 AEXURE-III PLAT LAYUT M/s. Jyoti m Chemical Research Centre Pvt. Ltd., Ankleshwar. 3

4 AEXURE- IV LIST F PRDUCTS AD THEIR PRDUCTI CAPACITY 1) Existing Product as per CCA o: AWH-51863, Date of issue 02/02/2013 Sr. o. ame of Products Existing quantity as per CCA o. AWH in (MT/Month) 1. Disperse navy Blue 3G (IGS) 2 2. Disperse Golden Yellow GG 1 3. Disperse Yellow AL Disperse Rubine 3B Disperse Scarlet RR Disperse Yellow Brown REL Disperse range ERL 1 8. Disperse Violet B Disperse Blue SE2R Disperse Yellow 7 GL Disperse Rubine S2GL Disperse Agent SS Disperse Yellow FFL 0.5 TTAL 8.75 Sr. o. 2) Proposed Product List ame of Products CAS o. Existing Quantity as per CCA o. AWH in (MT/Month) Proposed Quantity in (MT/Month) Total Quantity (MT/Month) I DISPERSE DYES (AZ Group) Representative Products: 1. Disperse navy blue 3G (IGS) 2. Disperse golden yellow GG 3. Disperse rubine 3B Disperse rubine GFL Disperse rubine 5B Disperse scarlet RR Disperse yellow brown REL 8. Disperse orange ERL (Disperse range 25) M/s. Jyoti m Chemical Research Centre Pvt. Ltd., Ankleshwar. 4

5 Sr. o. ame of Products CAS o. Existing Quantity as per CCA o. AWH in (MT/Month) 9. Disperse violet B Disperse blue SE2R Disperse yellow 7 GL Disperse rubine S2GL Disperse orange Disperse scarlet 3R (Disperse Red 50) 15. Disperse brown 3REL Disperse golden yellow GD 17. Disperse yellow Disperse yellow Disperse yellow Disperse blue Disperse violet Disperse yellow 5RX Disperse yellow M7G Disperse red Disperse red Disperse red Disperse red Disperse yellow 3 (Disperse yellow G) Proposed Quantity in (MT/Month) Total Quantity (MT/Month) II DISPERSIG AGET Representative Products: 1. Dispersing agent SS III DISPERSE DYES (Miscellaneous Type) Representative Products: Disperse yellow AL (Disperse yellow 1) 2. Disperse yellow FFL M/s. Jyoti m Chemical Research Centre Pvt. Ltd., Ankleshwar. 5

6 Sr. o. IV ame of Products CAS o. Existing Quantity as per CCA o. AWH in (MT/Month) DISPERSE DYES (Anthraquinone Group) Representative Products: Disperse blue FFR 2. Disperse blue B Disperse red Disperse blue Proposed Quantity in (MT/Month) Total Quantity (MT/Month) Disperse violet V AZ Pigments Representative Products: 1. Pigment yellow Pigment yellow Pigment yellow Pigment orange Pigment orange Pigment Rubin tonner Pigment lake red CT VI. M-8 (n-cyano ethyl methyl aniline) TTAL TE: The quantities refer is for concentrated dyes. These dyes are further diluted and standardized as per market requirement. The final sellable quantity will increase by 30-35%. M/s. Jyoti m Chemical Research Centre Pvt. Ltd., Ankleshwar. 6

7 Sr. o. AEXURE - V LIST F RAW MATERIALS CSUMPTI 1) VERALL RAW MATERIAL SCEARI ame of Raw material Existing Quantity in MT/Month Total after Proposed Expansion in MT/Month 1 6 bromo 2:4 dinitro aniline M3 A ( 3 n n diethyl amino acetanilide) Sulfuric Acid Sodium itrite Dis. Agent 045 (Phenol Base) Dada mol KS (aphthaline Base) G. Salt Para nitro aniline ethyl 4 methyl 3 cyano 6 bhydroxy pyridone (EP) 10 Hydrochloric Acid :4 dinitro chloro benzene (CB) Para amino phenol (PAP) Sodium Acetate Cyno Para nitro aniline M2 A( 3 n n diacetoxy ethyl amino toulene 16 rtho chloro para nitro aniline ,6 dichloro para nitro aniline 18 M-7 ( n cyano ethyl n acetoxy ethyl aniluine) M-8 (n cyano ethyl n ethyl aniline) M-9 n n di ethyl meta amino propionamide) M-12 (n n diethyl meta amino acetanilide) Cyno 6 Bromo Para nitro aniline Para chloro aniline Phenol Formaldehyde Sodium Sulphite Caustic Lye/Flacks Terephthaldehyde Hippuric Acid Acetic Acid Acetic Anhydride Soda Ash M-5 (3 n ndiacetoxy ethyl 4 methoxy acetanilide) cyano ethy n ethyl meta amino acetanilide ,4 dimethyl 3 cyano 6 hydroxy M/s. Jyoti m Chemical Research Centre Pvt. Ltd., Ankleshwar. 7

8 pyridone (MP) dichloro benzidine Aceto acetanilide Phenyl 3methyl pyrazolone PMP Beta naphthol carboxi 2 oxo naphthalene (B ACID) M-15 (n ethyl n hydroxy ethil aniline) chloro anthraquinone Quinazarine ,3 dichloro 1,4 diamino anthraquinone Monomethyl amine Monoethyl aniline Acrylonitrile Para amino acetanilide Monoethyl aniline Ethyl/butyl acrylate Zink chloride ) Raw material of some representative products: Sr. o. I ame of Product DISPERSE DYES (AZ Group) Disperse Golden Yellow GG Disperse Rubine 3B Disperse range 25 (ERL) Total Quantity in MT/month 80 ame of Raw Material Quantity in Ton/Ton Total Quantity in MT/month 4-Amino azobenzene HCL Sodium itrite Sodium hydroxide hydroxyquinoline- 2(1H)-one Dadamol (aphthalene based Dispersing agent) Liq. Dispersing agent 045 (Phenol based) (45%) TTAL Cyano-p-itroaniline HCL Sodim itrite Sodium hydroxide M-2A Dadamol (aphthalene based Dispersing agent) Liq. Dispersing agent 045 (Phenol based) (45%) TTAL p-itroaniline HCL Sodim itrite M/s. Jyoti m Chemical Research Centre Pvt. Ltd., Ankleshwar. 8

9 Sr. o ame of Product Disperse Blue (Blue 2RC) Disperse Yellow 119 Disperse Yellow 241 Disperse Yellow M7G 8. Disperse Blue 291 Total Quantity in MT/month ame of Raw Material Quantity in Ton/Ton Total Quantity in MT/month Sodium hydroxide M Dadamol (aphthalene based Dispersing agent) Liq. Dispersing agent 045 (Phenol based) (45%) TTAL Cyano-6-Bromo-PA HCL Sodim itrite Sodium hydroxide M Dadamol (aphthalene based Dispersing agent) Liq. Dispersing agent 045 (Phenol based) (45%) TTAL itro Aniline HCL Sodim itrite Sodium hydroxide EP Dadamol (aphthalene based Dispersing agent) Liq. Dispersing agent 045 (Phenol based) (45%) TTAL ,4-Dichloro Aniline HCL Sodim itrite Sodium hydroxide MP Dadamol (aphthalene based Dispersing agent) Liq. Dispersing agent 045 (Phenol based) (45%) TTAL p-chloro Aniline HCL Sodim itrite Sodium hydroxide EP Dadamol (aphthalene based Dispersing agent) Liq. Dispersing agent 045 (Phenol based) (45%) TTAL Bromo-2,4-DA HCL Sodim itrite Sodium hydroxide M/s. Jyoti m Chemical Research Centre Pvt. Ltd., Ankleshwar. 9

10 Sr. o. ame of Product 9. Disperse Red 13 Total Quantity in MT/month II DISPERSIG AGET Dispersing Agent SS III IV 1. DISPERSE DYES (Miscellaneous Type) Disperse Yellow AL Pigment Yellow FFL DISPERSE DYES (Anthraquinone Group) Disperse blue FFR 2. Disperse blue B ame of Raw Material Quantity in Ton/Ton Total Quantity in MT/month M Dadamol (aphthalene based Dispersing agent) Liq. Dispersing agent 045 (Phenol based) (45%) TTAL o-chloro-p-itroaniline HCL Sodium itrite Sodium hydroxide M Dadamol (aphthalene based Dispersing agent) Liq. Dispersing agent 045 (Phenol based) (45%) TTAL Formaldehyde (37%) Phenol Sodium Sulfite Caustic Lye TTAL Fresh IPA Recovered IPA Sodium Acitate ,4-DCB p-amino phenol TTAL Fresh Acetic acid Recovered Acetic acid Hippuric acid Tere phthaladehyde Acetic anhydride TTAL Fresh IPA Recovered IPA Sodium hydroxide Quinizarine Mono methyl amine (40%) Mono ethanol amine TTAL Fresh IPA Recovered IPA Sodium hydroxide Quinizarine M/s. Jyoti m Chemical Research Centre Pvt. Ltd., Ankleshwar. 10

11 Sr. o. 3. ame of Product Disperse Violet 26 Total Quantity in MT/month V AZ Pigments VI. Pigment yellow 12 Pigment yellow 83 Pigment range 13 M-8 (n-cyano ethyl methyl aniline) ame of Raw Material Quantity in Ton/Ton Total Quantity in MT/month Mono methyl amine (40%) TTAL Fresh DMF Recovered DMF Sodium Carbonate ,4 Diamino-2,3 Dichloro anthraquinone Phenol TTAL Dichlorobenzidine Hydrochloric acid Sodium itrite Caustic lye Aceto acetanilide TTAL DCB Hydrochloric acid Sodium itrite Sulfamic acid aphthol ASIRG Caustic lye Sodium bicarbonate Total Dichlorobenzidine HCL Sodium itrite Caustic lye methyl-2-phenyl-2, 4- dihydro-3h-pyrazole-3- one TTAL Acrylonitrile Mono ethyl aniline Zink chloride Vacuum salt Total 170 TTAL M/s. Jyoti m Chemical Research Centre Pvt. Ltd., Ankleshwar. 11

12 AEXURE- VI BREIF MAUFACTURIG PRCESS: I) GEERAL MAUFACTURIG PRCESS F DISPERSE DYESTUFF Disperse Dyestuff intermediate aromatic amine is diazotized using hydrochloric acid and sodium nitrite in aqueous medium in some cases using sulfuric acid in presence of dry sodium nitrite and coupled with coupling components like ethyl 4 methyl 3 cyano 6 bhydroxy 2 pyridone, 1,4 dimethyl 3 cyano 6 hydroxy 3 pyridone(mp), 3 n ndiacetoxy ethyl 4 methoxy acetanilide (M5), 3 n n diethyl amino acetanilide (M3A), n cyano ethyl n acetoxy ethyl aniluine (M7), n cyano ethyl n ethyl aniline (M8) etc. using caustic soda/soda Ash for adjustment of reaction ph conditions. Generally these reactions are carried out at 0-10 o C. Dyestuffs thus obtained are then filtered through filter press to remove water. The press cake thus obtained is then mixed with dispersing agent like dadamol, inks & liq. Dispersing agent 045(dispersing agent ss)in Kinetic dispersion mill to make smooth thick slurry which is then transferred to sand mill for further particle size reduction. When desired particle size is achieved it is transferred to spray drying. The dried powder is then transferred to blender for standerdisation then it is packed & transferred to godown. 1) Disperse Golden Yellow GG Chemical Reaction: H 2 + H H H H 4-[(E)-phenyldiazenyl]aniline C 12 H hydroxyquinolin-2(1H)-one C 9 H Golden Yellow GG C 21 H M/s. Jyoti m Chemical Research Centre Pvt. Ltd., Ankleshwar. 12

13 Material Balance: Input Kg utput Kg Ice + Water Amino azobenzene 197 Diazotization HCL 365 Reaction mass 4631 Sodim itrite 69 Total 4631 Total 4631 Reaction mass 4631 Coupling mass 9872 Ice + Water 5000 Sodium hydroxide 80 Coupling 4-hydroxyquinoline (1H)-one Total 9872 Total 9872 Coupling mass 9872 Wet Cake 1012 Washing water 2000 Filteration & Washing water to recycle 2000 Washing Effluent to ETP 8860 Total Total Wet Cake 1012 Dadamol (aphthalene 340 based Dispersing agent) K D Mill & Wet Cake 2102 Liq. Dispersing agent 045 (Phenol based) 750 Sand Mill (45%) Total 2102 Total 2102 Wet Cake 2102 Water Evaporation 1020 Drying Disperse Golden Yellow 1082 GG Total 2102 Total 2102 Disperse Golden Yellow Disperse Golden Yellow 1082 Packing 1082 GG GG Total 1082 Total 1082 M/s. Jyoti m Chemical Research Centre Pvt. Ltd., Ankleshwar. 13

14 2) Disperse rubine 3B Chemical Reaction: C H 3 H 2 C 2 + CH 3 + a HCl 2-Cyano-p-itro aniline CH 3 C 7 H M-2A C 15 H C H 3 Sodium itrite 69.0 Diazotization Coupling Hydrochloric acid 36.5 CH 3 CH 3 + acl + HCl + 2 H 2 C 2 Disperse Rubine 3B (Violet 33) C 22 H Sodium chloride Hydrochloric acid Water M/s. Jyoti m Chemical Research Centre Pvt. Ltd., Ankleshwar. 14

15 Material Balance: Input Kg utput Kg Ice + Water Cyano-p-itroaniline 163 HCL 365 Reaction mass 3597 Sodim itrite 69 Diazotization Total 3597 Total 3597 Reaction mass 3597 Coupling mass 9956 Ice + Water 6000 Sodium hydroxide 80 Coupling M-2A 279 Total 9956 Total 9956 Coupling mass 9956 Wet Cake 1300 Filteration & Washing water 2000 Washing water to recycle 2000 Washing Effluent to ETP 8656 Total Total Wet Cake 1300 Dadamol (aphthalene 425 Wet Cake 2670 based Dispersing agent) K D Mill & Liq. Dispersing agent Sand Mill 045 (Phenol based) 945 (45%) Total 2670 Total 2670 Wet Cake 2670 Drying Water Evaporation 1370 Disperse Rubine 3B 1300 Total 2670 Total 2670 Disperse Rubine 3B 1300 Packing Disperse Rubine 3B 1300 Total 1300 Total 1300 M/s. Jyoti m Chemical Research Centre Pvt. Ltd., Ankleshwar. 15

16 3) Disperse range 25 (ERL) Chemical Reaction: H 2 CH C + a HCl p-itro aniline C 6 H M-8 C 11 H Sodium itrite 69.0 Hydrochloric acid 36.5 Diazotization Coupling CH 3 C + acl + HCl + 2 H 2 2 Disperse range 25 (ERL) C 1 H Sodium chloride Hydrochloric acid Water M/s. Jyoti m Chemical Research Centre Pvt. Ltd., Ankleshwar. 16

17 Material Balance: Input Kg utput Kg Ice + Water 4000 p-itroaniline 138 HCL 365 Diazotization Reaction mass 4572 Sodim itrite 69 Total 4572 Total 4572 Reaction mass 4572 Coupling mass 9826 Ice + Water 5000 Sodium hydroxide 80 Coupling M Total 9826 Total 9826 Coupling mass 9826 Wet Cake 1006 Filteration & Washing water 2500 Washing water to recycle 2500 Washing Effluent to ETP 8820 Total Total Wet Cake 1006 Dadamol (aphthalene based Dispersing agent) 300 K D Mill & Wet Cake 1971 Liq. Dispersing agent 045 (Phenol based) 665 Sand Mill (45%) Total 1971 Total 1971 Wet Cake 1971 Water Evaporation 980 Drying Disperse range (ERL) Total 1971 Total 1971 Disperse range 25 Packing and Disperse range (ERL) Dispatch (ERL) Total 991 Total 991 M/s. Jyoti m Chemical Research Centre Pvt. Ltd., Ankleshwar. 17

18 4) Disperse Yellow 241 Chemical Reaction: H 2 CH 3 C Cl Cl 3,4-Dichloro Aniline C 6 H 5 Cl H CH 3 2-Methyl Pyridone C 8 H a HCl Sodium itrite 69.0 Hydrochloric acid 36.5 Diazotization Coupling C CH 3 H 3 C H + acl + HCl + 2 H 2 Cl Cl Disperse Yellow 241 C 14 H 10 Cl Sodium chloride Hydrochloric acid Water M/s. Jyoti m Chemical Research Centre Pvt. Ltd., Ankleshwar. 18

19 Material Balance: Input Kg utput Kg Ice + Water ,4-Dichloro Aniline 162 Diazotization HCL 365 Reaction mass 4596 Sodim itrite 69 Total 4596 Total 4596 Reaction mass 4596 Coupling mass 9840 Ice + Water 5000 Sodium hydroxide 80 Coupling 2-MP 164 Total 9840 Total 9840 Coupling mass 9840 Wet Cake 1000 Washing water 2000 Filteration & Washing water to recycle 2000 Washing Effluent to ETP 8840 Total Total Wet Cake 1000 Dadamol (aphthalene based Dispersing agent) Liq. Dispersing agent 045 (Phenol based) (45%) 315 K D Mill & Wet Cake 2015 Sand Mill 700 Total 2015 Total 2015 Wet Cake 2015 Water Evaporation 990 Drying Disperse Yellow Total 2015 Total 2015 Packing and Disperse Yellow Disperse Yellow Dispatch Total 1025 Total 1025 M/s. Jyoti m Chemical Research Centre Pvt. Ltd., Ankleshwar. 19

20 5) Disperse Yellow 119 Chemical Reaction: CH 3 H 2 2 C + H + a HCl H 3 C o-itro Aniline C 6 H Ethyl Pyridone C 9 H Sodium itrite 69.0 Hydrochloric acid 36.5 Diazotization Coupling C CH 3 H 3 C H + acl + HCl + 2 H 2 2 Disperse Yellow 119 C 15 H Sodium chloride Hydrochloric acid Water M/s. Jyoti m Chemical Research Centre Pvt. Ltd., Ankleshwar. 20

21 Material Balance: Input Kg utput Kg Ice + Water itro Aniline 138 Diazotization HCL 365 Reaction mass 3572 Sodim itrite 69 Total 3572 Total 3572 Reaction mass 3572 Coupling mass 8830 Ice + Water 5000 Sodium hydroxide 80 Coupling 2-EP 178 Total 8830 Total 8830 Coupling mass 8830 Wet Cake 935 Washing water 1500 Filteration & Washing water to recycle 1500 Washing Effluent to ETP 7895 Total Total Wet Cake 935 Dadamol (aphthalene based Dispersing agent) Liq. Dispersing agent 045 (Phenol based) (45%) 305 K D Mill & Sand Wet Cake 1915 Mill 675 Total 1915 Total 1915 Wet Cake 1915 Drying Water Evaporation 980 Disperse Yellow Total 1915 Total 1915 Disperse Yellow Packing Disperse Yellow Total 935 Total 935 M/s. Jyoti m Chemical Research Centre Pvt. Ltd., Ankleshwar. 21

22 6) Disperse Yellow M7G Chemical Reaction: H 2 CH 3 C + H + a HCl Cl H 3 C p-chloro Aniline C 6 H 6 Cl Ethyl Pyridone C 9 H Sodium itrite 69.0 Hydrochloric acid 36.5 Diazotization Coupling C CH 3 H 3 C H + acl + HCl + 2 H 2 Cl Disperse Yellow M7G C 15 H 13 Cl Sodium chloride Hydrochloric acid Water M/s. Jyoti m Chemical Research Centre Pvt. Ltd., Ankleshwar. 22

23 Material Balance: Input Kg utput Kg Ice + Water 4000 p-chloro Aniline 127 Diazotization HCL 365 Reaction mass 4561 Sodim itrite 69 Total 4561 Total 4561 Reaction mass 4561 Coupling mass 9819 Ice + Water 5000 Sodium hydroxide 80 Coupling 2-EP 178 Total 9819 Total 9819 Coupling mass 9819 Wet Cake 1179 Washing water 2000 Filteration & Washing water to recycle 2000 Washing Effluent to ETP 8640 Total Total Wet Cake 1179 Dadamol (aphthalene 292 Wet Cake 2121 based Dispersing agent) K D Mill & Liq. Dispersing agent Sand Mill 045 (Phenol based) 650 (45%) Total 2121 Total 2121 Wet Cake 2121 Water Evaporation 1121 Drying Disperse Yellow M7G 1000 Total 2121 Total 2121 Disperse Yellow M7G 1000 Packing Disperse Yellow M7G 1000 Total 1000 Total 1000 M/s. Jyoti m Chemical Research Centre Pvt. Ltd., Ankleshwar. 23

24 7) Disperse Blue (Blue 2RC) Chemical Reaction: H 2 CH 3 Br C CH a HCl 2 H CH 3 2-Cyano-6-Bromo-PA C 7 H 4 Br M-12 C 12 H Sodium itrite 69.0 Hydrochloric acid 36.5 Diazotization Coupling CH 3 CH 3 H CH 3 + acl + HCl + 2 H 2 C Br 2 Disperse Blue (Blue 2RC) C 19 H 19 Br Sodium chloride Hydrochloric acid Water M/s. Jyoti m Chemical Research Centre Pvt. Ltd., Ankleshwar. 24

25 Material Balance: Input Kg utput Kg Ice + Water Cyano-6-Bromo-PA 242 Diazotization HCL 365 Reaction mass 3676 Sodim itrite 69 Total 3676 Total 3676 Reaction mass 3676 Coupling mass 9962 Ice + Water 6000 Sodium hydroxide 80 Coupling M Total 9962 Total 9962 Coupling mass 9962 Wet Cake 1300 Filteration & Washing water 2000 Washing water to recycle 2000 Washing Effluent to ETP 8662 Total Total Wet Cake 1300 Dadamol (aphthalene 420 Wet Cake 2655 based Dispersing agent) K D Mill & Liq. Dispersing agent Sand Mill 045 (Phenol based) 935 (45%) Total 2655 Total 2655 Wet Cake 2655 Water Evaporation 1355 Drying Disperse Blue Total 2655 Total 2655 Disperse Blue Packing Disperse Blue Total 1300 Total 1300 M/s. Jyoti m Chemical Research Centre Pvt. Ltd., Ankleshwar. 25

26 8) Disperse Blue 291 Chemical Reaction: H 2 CH 3 Br 2 CH 3 CH a HCl 2 H CH 3 6-Bromo-2,4-DA C 6 H 4 Br M-10 C 13 H Sodium itrite 69.0 Hydrochloric acid 36.5 Diazotization Coupling CH 3 CH 3 CH 3 H CH 3 + acl + HCl + 2 H 2 2 Br 2 Disperse Blue 291 C 19 H 21 Br Sodium chloride Hydrochloric acid Water M/s. Jyoti m Chemical Research Centre Pvt. Ltd., Ankleshwar. 26

27 Material Balance: Input Kg utput Kg Ice + Water Bromo-2,4-DA 262 Diazotization HCL 365 Reaction mass 4696 Sodim itrite 69 Total 4696 Total 4696 Reaction mass 4696 Coupling mass Ice + Water 6500 Sodium hydroxide 80 Coupling M Total Total Coupling mass Wet Cake 1450 Filteration & Washing water 2500 Washing water to recyc 2500 Washing Effluent to ETP Total Total Wet Cake 1450 Dadamol (aphthalene based 470 K D Mill & Wet Cake 2965 Dispersing agent) Sand Mill Liq. Dispersing agent 045 (Phenol based) 1045 (45%) Total 2965 Total 2965 Wet Cake 2965 Drying Water Evaporation 1515 Disperse Blue Total 2965 Total 2965 Packing and Disperse Blue Disperse Blue Total 1450 Dispatch Total 1450 M/s. Jyoti m Chemical Research Centre Pvt. Ltd., Ankleshwar. 27

28 9) Disperse Red 13 Chemical Reaction: H 2 Cl CH 3 H a HCl o-chloro-p-itro aniline C 6 H 5 Cl M-15 C 10 H Sodium itrite 69.0 Hydrochloric acid 36.5 Diazotization Coupling CH 3 H + acl + HCl + 2 H 2 Cl 2 Disperse Red 13 C 16 H 17 Cl Sodium chloride Hydrochloric acid Water M/s. Jyoti m Chemical Research Centre Pvt. Ltd., Ankleshwar. 28

29 Material Balance: Input Kg utput Kg Ice + Water 3000 o-chloro-p-itroaniline 172 Diazotization HCL 365 Reaction mass 3606 Sodim itrite 69 Total 3606 Total 3606 Reaction mass 3606 Coupling mass 8851 Ice + Water 5000 Sodium hydroxide 80 Coupling M Total 8851 Total 8851 Coupling mass 8851 Wet Cake 1000 Filteration & Washing water 1500 Washing water to recycle 1500 Washing Effluent to ETP 7851 Total Total Wet Cake 1000 Dadamol (aphthalene 325 Wet Cake 2050 based Dispersing agent) K D Mill & Liq. Dispersing agent Sand Mill 045 (Phenol based) 725 (45%) Total 2050 Total 2050 Wet Cake 2050 Drying Water Evaporation 1050 Disperse Red Total 2050 Total 2050 Disperse Red Packing Disperse Red Total 1000 Total 1000 M/s. Jyoti m Chemical Research Centre Pvt. Ltd., Ankleshwar. 29

30 II) Dispersing Agent SS Material Balance: Input Kg utput Kg Water 5000 Formaldehyde (37%) 1340 S.S.Reactor Phenol 1075 Heat to Reaction mass 8220 Sodium Sulfite oC Sodium hydroxide 55 Total 8220 Total 8220 Reaction mass 8220 Wet Product 8220 Cool 25-35oC Total 8220 Total 8220 Dispersing Agent 8220 Dispersing Agent 8220 Packing Total 8220 Total 8220 II) GEERAL METHD FR MAUFACTURIG MISCELIEUS DISPERSE DYES In SS reactor 2 4 DCB is condensed with para amino phenol to give disperse yellow AL. In SS reactor terephthaldehyde, hippuric acid, acetic anhydride are reacted at reflux temp. To give yellow FFL (yellow 124). 4 chloro,3 nitro benzene sulfonyl chloride is reacted with aniline & ethylamine to give yellow 42Dyestuffs thus obtained are then filtered through filter press to remove water. The press cake thus obtained is then mixed with dispersing agent like dadamol, inks & liq. Dispersing agent 045(DISPERSIG AGET S7S)in Kinetic dispersion mill to make smooth thick slurry which is then transferred to sand mill for further particle size reduction. When desired particle size is achieved it is transferred to spray drying. The dried powdered is then transferred to blender for standardization then it is packed & transferred to godown. 1) Disperse yellow AL: Chemical Reaction: Cl H 2 H 2 H 2 2,4 Dinitro chlorobenzene p-amino Phenol Disperse Yellow AL C 6 H 3 Cl 2 4 C 6 H 9 C 12 H H M/s. Jyoti m Chemical Research Centre Pvt. Ltd., Ankleshwar. 30

31 Material Balance: Input Kg utput Kg Fresh IPA 30 Recovered IPA 570 Sodium Acitate 82 Diazotization Reaction mass 993 2,4-DCB 202 p-amino phenol 109 Total 993 Total 993 Reaction mass 993 Coupling mass 1423 Distillation Water 1000 and Recovered IPA 570 Crystallization Total 1993 Total 1993 Coupling mass 1423 Wet Cake 478 Washing water 1000 Filteration & Washing 0 Waste water to ETP 1945 Total 2423 Total 2423 Wet Cake 478 Water Evaporation 245 Tray Dryer Dry Cake 233 Total 478 Total 478 Dry Cake 233 Pulverization Pigment Yellow AL 233 Total 233 Total 233 Blending & Pigment Yellow AL 233 Pigment Yellow AL 233 Packing Total 233 Total 233 2) Disperse yellow FFL: Chemical Reaction: CH H H + 2 CH Terephthaladehyde C 8 H Hippuric acid C 9 H Disperse Yellow FFL C 26 H M/s. Jyoti m Chemical Research Centre Pvt. Ltd., Ankleshwar. 31

32 Material Balance: Input Kg utput Kg Fresh Acetic acid 30 Recovered Acetic acid 300 Hippuric acid 358 Diazotization Reaction mass 967 Terephthaladehyde 134 Acetic anhydride 145 Total 967 Total 967 Reaction mass 967 Distillation Coupling mass 2487 Water 2000 and Recovered Acetic acid 480 Total 2967 Crystallization Total 2967 Coupling mass 2487 Wet Cake 707 Washing water 1500 Filteration & Washing Waste water to ETP 3280 Total 3987 Total 3987 Wet Cake 707 Water Evaporation 357 Tray Dryer Dry Cake 350 Total 707 Total 707 Dry Cake 350 Pulverization Pigment Yellow FFL 350 Total 350 Total 350 Blending & Pigment Yellow FFL 350 Pigment Yellow FFL 350 Total 350 Packing Total 350 IV) GEERAL MAUFACTURIG PRCESS FR ATHRAQUIE DISPERSE DYESTUFF Anthraquinone derivatives such as quinazarine, 1 chloro anthraquinone, 2,3dichloro 1, 4 diamino antheaquinone, condensed with compound such as mono methyl amine. Monoethanol amine phenol etc. excess material is distilled out. Material is then filtered through filter press. The press cake thus obtained is then mixed with dispersing agent like dadamol, inks & liq. Dispersing agent 045(DISPERSIG AGET SS)in Kinetic dispersion mill to make smooth thick slurry which is then transferred to sand mill for further particle size reduction. When desired particle size is achieved it is transferred to spray drymg. The dried powdered is then transferred to blender for standardization then it is packed & transferred to godown. M/s. Jyoti m Chemical Research Centre Pvt. Ltd., Ankleshwar. 32

33 1) Disperse Blue FFR: Chemical Reaction: H HCH 3 H 2 CH 3 H 2 CH 2 CH 2 H H HCH 2 CH 2 H Quinizarin C 14 H Material Balance: Disperse Blue FFR C 17 H Input Kg utput Kg Fresh IPA 30 Recovered IPA 970 Sodium hydroxide 80 Reaction mass 1459 Quinizarine 240 Diazotization Mono methyl amine (40%) 78 Mono ethanol amine 61 Total 1459 Total 1459 Reaction mass 1459 Distillation Coupling mass 1489 Water 1000 and Recovered IPA 970 Total 2459 Crystallization Total 2459 Coupling mass 1489 Wet Cake 839 Washing water 1000 Filteration & Washing Waste water to ETP 1650 Total 2489 Total 2489 Wet Cake 839 Water Evaporation 459 Tray Dryer Dry Cake 380 Total 839 Total 839 Dry Cake 380 Pulverization Disperse Blue FFR 380 Total 380 Total 380 Blending & Disperse Blue FFR 380 Disperse Blue FFR 380 Total 380 Packing Total 380 M/s. Jyoti m Chemical Research Centre Pvt. Ltd., Ankleshwar. 33

34 2) Disperse Blue B: Chemical Reaction: H HCH 3 H 2 CH 3 ah / IPA H HCH 3 Quinizarin C 14 H Material Balance: Disperse Blue B C 16 H Input Kg utput Kg Fresh DMF 60 Recovered DMF 1440 Sodium Carbonate 138 Reaction mass ,4 Diamino-2,3 Diazotization Dichloro anthraquinone 307 Phenol 188 Total 2133 Total 2133 Reaction mass 2133 Coupling mass 2193 Distillation Water 1500 and Recovered DMF 1440 Total 3633 Crystallization Total 3633 Coupling mass 2193 Wet Cake 1043 Washing water 1500 Filteration & Washing Waste water to ETP 2650 Total 3693 Total 3693 Wet Cake 1043 Water Evaporation 593 Tray Dryer Dry Cake 450 Total 1043 Total 1043 Dry Cake 450 Pulverization Disperse Violet Total 450 Total 450 Blending & Disperse Violet Disperse Violet Packing Total 450 Total 450 M/s. Jyoti m Chemical Research Centre Pvt. Ltd., Ankleshwar. 34

35 3) Disperse violet 26 Chemical Reaction: H 2 H 2 Cl Cl + 2 H K 2 C 3 DMF H 2 H 2 1,4-Diamino-2,3-dichloro anthraquinone C 14 H 8 Cl Material Balance: Phenol C 6 H Disperse Violet 26 C 26 H Input Kg utput Kg Fresh DMF 60 Recovered DMF 1440 Sodium Carbonate 138 Reaction mass ,4 Diamino-2,3 Diazotization Dichloro anthraquinone 307 Phenol 188 Total 2133 Total 2133 Reaction mass 2133 Coupling mass 2193 Distillation Water 1500 and Recovered DMF 1440 Total 3633 Crystallization Total 3633 Coupling mass 2193 Wet Cake 773 Washing water 1500 Filteration & Washing Waste water to ETP 2920 Total 3693 Total 3693 Wet Cake 773 Water Evaporation 430 Tray Dryer Dry Cake 343 Total 773 Total 773 Dry Cake 343 Pulverization Disperse Violet Total 343 Total 343 Blending & Disperse Violet Disperse Violet Packing Total 343 Total 343 M/s. Jyoti m Chemical Research Centre Pvt. Ltd., Ankleshwar. 35

36 IV) GEERAL METHD FR MAUFACTURIG AZ PIGMETS The proposed products are rganic pigments. These are characterized for their physicochemical properties. Aromatic amines are diazo & tiezed with help of hydrochloric acid, sodium nitrite, phenols and epthols are dissolved in soda ash or Caustic lye solution. These solutions are known as a coupling solution, the diazo solution is mixed with coupling solution at 0 to 20 0 C and azo pigment is formed. The general chemical structure is given as under. M/s. Jyoti m Chemical Research Centre Pvt. Ltd., Ankleshwar. 36

37 1) Pigment yellow 12: Chemical Reaction: H CH 3 Cl H Cl + 2 a HCl H 2 Aceto acetanilide C 10 H '-Dichloro benzidine C 12 H 10 Cl Sodium itrite 69.0 Hydrochloric acid 36.5 Diazotization Coupling Cl H + 2 acl + 2 HCl + 4 H 2 H CH 3 C H 3 Cl Material Balance: Pigment Yellow 12 C 32 H 26 Cl Sodium chloride Hydrochloric acid Water Input Kg utput Kg Ice + Water Dichlorobenzidine 253 Diazotization HCL 730 Reaction mass 5121 Sodim itrite 138 Total 5121 Total 5121 Reaction mass 5121 Coupling mass Ice + Water 5000 Sodium hydroxide 160 Coupling Aceto acetanilide 354 Total Total Coupling mass Wet Cake 1685 Filteration & Washing water 2000 Washing water to recycle 2000 Washing Effluent to ETP 8950 Total Total Wet Cake 1685 Tray Dryer Dry Cake 1685 Total 1685 Total 1685 Dry Cake 1685 Water Evaporation 860 Pulverization Pigment Yellow Total 1685 Total 1685 Blending & Pigment Yellow Pigment Yellow Packing Total 825 Total 825 M/s. Jyoti m Chemical Research Centre Pvt. Ltd., Ankleshwar. 37

38 2) Pigment yellow 83: Chemical Reaction: C 12 H 10 2 Cl 2 + a 2 + C 12 H 14 Cl 4 + HCl + a 2 C 3 + H 3 S 3 C 36 H 32 Cl Dichlorobenzidine aphthol ASIRG Pigment Yellow 83 Material Balance: Input Kg utput Kg Water 200 DCB 50 HCl 52 Diazotization Reaction mass 667 Sodim itrite 15 Sulfamic acid 50 Ice 300 Total 667 Total 667 Reaction mass 667 Coupling mass 1260 Water 200 apthol ASIRG 60 Caustic Lye 16 Coupling Sidium bicarbonet 17 Ice 300 Total 1260 Total 1260 Coupling mass 1260 Wet Cake 340 Washing water 500 Washing Water recycle 500 Filteration Effluent to ETP 920 Total 1760 Total 1760 Water Evaporation 190 Wet Cake 340 Drying Cake 150 Total 340 Total 340 Cake 150 Pulvrizing Pigment Yellow Total 150 Total 150 Pigment Yellow Packing and Pigment Yellow Total 150 Dispatch Total 150 M/s. Jyoti m Chemical Research Centre Pvt. Ltd., Ankleshwar. 38

39 3) Pigment orange 13: Chemical Reaction: Cl CH 3 H Cl + 2 a HCl H 2 5-methyl-2-phenyl -2,4-dihydro-3H- -pyrazol-3-one 3-3'-Dichloro benzidine C 12 H 10 Cl Sodium itrite 69.0 Hydrochloric acid 36.5 C 10 H Diazotization Coupling H 3 C Cl H 3 C + 2 acl + 2 HCl + 4 H 2 Cl Material Balance: Pigment range 13 C 32 H 24 Cl Sodium chloride Hydrochloric acid Water Input Kg utput Kg Ice + Water Dichlorobenzidine 253 Diazotization HCL 730 Reaction mass 6121 Sodim itrite 138 Total 6121 Total 6121 Reaction mass 6121 Coupling mass Ice + Water 5000 Sodium hydroxide methyl-2-phenyl-2, 4- Coupling dihydro-3h-pyrazole one Total Total Coupling mass Wet Cake 1689 Washing water 2000 Filteration & Washing water to recycle 2000 Washing Effluent to ETP 9940 Total Total Wet Cake 1689 Water Evaporation 860 Tray Dryer Dry Cake 829 Total 1689 Total 1689 Dry Cake 829 Pulverization Pigment Yellow Total 829 Total 829 Blending & Pigment Yellow Pigment Yellow Packing Total 829 Total 829 M/s. Jyoti m Chemical Research Centre Pvt. Ltd., Ankleshwar. 39

40 IV) M-8 (n-cyano ethyl methyl aniline) Material Balance: Input Kg utput Kg S.S.Reactor Acrylonitrile 535 Mono ethyl aniline Heat to 70oC 1000 Reaction mass 1625 Zink chloride 90 Total 1625 Total 1625 Reaction mass 1625 Wet Product 1875 Cool at 25- Water 2000 Waste Water to ETP oC. Layer Vacuum salt 100 separation Total 3725 Total 1875 Product - M Product - M Packing Total 1875 Total 1875 M/s. Jyoti m Chemical Research Centre Pvt. Ltd., Ankleshwar. 40

41 Sr. o. Particular AEXURE- VII DETAILS F WATER CSUMPTI Quantity as per CCA - AWH Water Consumption in KL/Day Quantity as per Proposed Expansion Total Quantity After Expansion 1. Domestic Industrial 2.1 a) Process (47.5 Fresh + 6 Recycle) b) Boiler c) Cooling d) Washing e) Gardening Total (Domestic + Industries) (74 Fresh + 6 Recycle) DETAILS F WASTE WATER GEERATI Sr. o. Particulars Waste Water Generation in KL/Day Quantity as per CCA: AWH Quantity as per Proposed Expansion Total Quantity After Expansion 1. Domestic Process Boiler Cooling Washing (Recycle to next Batch) Total (Domestic + Industries) (6 KLD recycle out of total waste water actual waste water will be 39.5 KLD) ote: The unit has permission from CETP (ETL) for 4 tankers per day. M/s. Jyoti m Chemical Research Centre Pvt. Ltd., Ankleshwar. 41

42 EXISTIG WATER BALACE DIAGRAM Water Requirement 10 KL/Day Domestic 3.5 KL/Day Septic/soak pit 2.5 KL/Day Process 5.3 KL/Day Loss 2.2 KL/Day Effluent from process 3.1 KL/Day Boiler 0.5 KL/Day Cooling Tower 0.5 KL/Day 0.2 KL/Day 0.2 KL/Day Gardening 0.2 KL/Day ETL 3.5 KL/Day TTAL WATER BALACE DIAGRAM (PRPSED) Total Water Requirement 80 KL/Day (74 fresh water + 6 recycle to Process) Gardening 3.5 KL/Day Loss 1.5 Domestic 6.0 KL/Day Sewage 4.5 KL/Day Process 53.5 KL/Day (47.5 fresh + 6 recycle) Loss 21.5 Effluent 32 KL/Day 6 KLD Washing 6 KL/Day Recycle to Process 6 KL/Day Boiler 5.5 KL/Day Loss 4KLD Cooling Tower 5.5 KL/Day Loss 4KLD ETP 39.5 KL/Day Sludge to TSDF 0.5 KL/Day To ETL 39 KL/Day M/s. Jyoti m Chemical Research Centre Pvt. Ltd., Ankleshwar. 42

43 AEXURE-VIII EFFLUET TREATMET PRCESS: M/s. Shree Colosperse Pvt. Ltd. has an Effluent Treatment Plant (ETP) comprising of Primary Tertiary treatment. Washing effluent from reaction vessels cleaning, press cleaning, spray drier cleaning and from bathing comes to il and Grit separator and then into equalization tank. Equalization s tanks Then ph is adjusted to with caustic lye. This solution is passed through filter press to remove any suspended particle. The clarified effluent is sent to Enviro Technology Limited (ETL), Ankleshwar for further treatment through tankers. The sludge from the setting tanks is filtered through filter press the sludge obtained after unloading filter press is dried in sludge drying bed and sent to TSDF site of M/s. Bharuch Enviro Infrastructure Ltd. (BEIL), Ankleshwar for disposal. AME AD SIZE F ETP UITS (Proposed) SL. DESCRIPTI CAPACITY (KL). 1 Equalization Tank 40 2 eutralization Tank 15 3 Filter Press 36 size 4 Final collection tank 20 M/s. Jyoti m Chemical Research Centre Pvt. Ltd., Ankleshwar. 43

44 EFFLUET TREATMET PLAT FLW DIAGRAM CLLECTI CUM EQUALIZATI TAK UTRALATI TAK FILTER PRESS SETTLIG TAK EFFLUET CMIG FRM PLAT SLUDGE T TSDF SITE TRATED EFFLUET STRAGE TAK TREATED EFFLUET SET T ETL. M/s. Jyoti m Chemical Research Centre Pvt. Ltd., Ankleshwar. 44

45 AEXURE-IX ELECTRICITY AD FUEL CSUMPTIS Sr. Particulars Existing Proposed Total Quantity Source o. Quantity as CCA Quantity after Expansion 1. atural Gas 5500 M 3 /Month 32,500 M 3 /Month 38,000 M 3 /Month Gujarat Gas 2. Diesel 40 liter/hr 60 liter/hr 100 liter/hr Local 3. Energy- Electricity 125 KVA 175 KVA 300 KVA DGVCL M/s. Jyoti m Chemical Research Centre Pvt. Ltd., Ankleshwar. 45

46 AEXURE- X DETAILS F FLUE GAS EMISSIS Sr. o Source of emission Boiler (1 TPH) Hot Air Generator (1 lac kcal) Boiler (2 TPH) Hot Air Generator (3 lac kcal) (2 o.) D.G. Set KVA (emergency used only) Type of emission PM S 2 ox PM S 2 ox PM S 2 x PM S 2 x PM S 2 x Stack Height (meter) Existing Stack Diameter (meter) Proposed Fuel ame And qty. atural Gas 50 SM 3 /hr atural Gas 90 SM 3 /hr atural Gas 215 SM 3 /hr atural Gas 215 SM 3 /hr Diesel 40 Liter/hr Pollution control equipment Adequate stack height Wet Scrubber/Bag Filter Adequate stack height Wet Scrubber/Bag Filter - PRCESS EMISSI There is no process emission. There will be no process emission due to proposed expansion. M/s. Jyoti m Chemical Research Centre Pvt. Ltd., Ankleshwar. 46

47 AEXURE- XI DETAILS F HAZARDUS WASTE M/s. Shree Colosperse Pvt. Ltd., Ankleshwar. Sr. o. ame f The Waste Category Waste Generating Process / Step State Quantity Existing Additional Total 1 ETP Sludge 34.3 Effluent Treatment Solid MT/Annum 2 Used il 5.1 Maintenance and used lubricant oil generated from Maintenance Activities 3 Discarded Containers/ Bags/Liners 33.3 Manufacturing and Utilities Liquid KL/Annum 0.1 KL/Annum Solid 00 50, 000 os./annum Mode of disposal 12 MT/Annum Collection and Storage within premises & Transportation and Disposal at TSDF of BEIL, Ankleshwar KL/Annum 50,000 os./annum Collection and Storage within premises & Disposal by selling to registered re-processor Collection, Storage and Decontamination within premises & Disposal by selling to authorized re-cycler. M/s. Jyoti m Chemical Research Centre Pvt. Ltd., Ankleshwar. 47

48 AME F HAZARDUS CHEMICAL Sr. o. ame of Chemicals AEXURE- XII 1. Caustic Lye 2. Hydrochloric Acid 3. Phenol 4. Acetic Acid 5. Acrylonitrile 6. Formaldehyde M/s. Jyoti m Chemical Research Centre Pvt. Ltd., Ankleshwar. 48

49 CMPLIACE REPRT F CCA AEXURE- XIII Compliance report of CCA 1 CCA Amendment o: AWH-51863, Dated: 02/2/2013 Sr. o. CSET CDITI 2. The consent under Water Act-1974 for conveying the industrial effluent to the CETP of M/s.ETL for the treatment and disposal of treated effluent & The consent under Air Act-1981 Authorization under environment (Protection) Act, 1986 shall be Valid up to 24/10/2017 to operate industrial plant for manufacture of the following products. CMPLIACE The unit has manufactured the products within consented quantity. ow, unit is applying for Environment Clearance. Sr.o Product Max. quantity Mt/month 1. Disperse navy Blue 3G (IGS) Disperse Golden Yellow GG Disperse Yellow AL Disperse Rubine 3B Disperse Scarlet RR Disperse Yellow Brown REL Disperse range ERL Disperse Violet B Disperse Blue SE2RI Disperse Yellow 7GL Disperse Rubine S2GL Disperse Agent SS Disperse Yellow FFL CDITI UDER THE WATER ACT 1974: 3.1 The quantity of industrial effluent shall not exceed Total quantity of industrial effluent 3500 Lit/day. generation does not exceed the quantity 3.2 The quantity of the domestic waste water (Sewage) shall not exceed 2500 Lit/Day. 3.3 The water consumption for industrial process and other ancillary operations shall not exceed 6500 Lit/day and water consumption for domestic purpose shall not exceed 3500 Lit/day as mentioned in Form-D mentioned in the respective consent. Total quantity of domestic waste water generation does not exceed the quantity mentioned in the respective consent. Total quantity of water consumption does not exceed the quantity mentioned in the respective consent. M/s. Jyoti m Chemical Research Centre Pvt. Ltd., Ankleshwar. 49

50 submitted consent application under water Act Sewage shall be disposal of through septic/soak pit system. 3.5 The Unit shall affix of water meters as per section 4 (1) of the water (Prevention and control of pollution) Cess Act-1977 for the purpose of measuring and recording the quantity of water consumed at such places as may be required, within 15 days and it shall be presumed that the quality indicated by the meter has been consumed by the industry unit the contrary is proved. 3.6 The GIDC drainage connection given by the discharge of industrial effluent shall be disconnected & the outlet shall be sealed. 3.4 TRADE EFFLUET: The applicant shall be required to make storage facilities to store the effluent for at least 48 hours by providing acid proof brick lined impervious tanks/hdpe tanks The applicant shall make fixed arrangement for loading, the effluent from their collection tanks to the tanker of ETL. The unit shall not keep any by-pass line or system or loose or flexible pipe line for loading the effluent into the tanker of ETL Leachate from the hazardous solid waste, if any shall also be connected into a collection tank through leachate collection facilities and shall be conveyed along with industrial effluent to the CETP of ETL Magnetic flow meters shall be installed at the inlet & outlet of effluent collection tanks/etp to measure the quantity of effluent lifted into the tanker of ETL The ETIRE quantity of industrial effluent shall have to be conveyed by ETL; In no circumstances the effluent either treated or untreated shall be discharged into GIDC drain or anywhere else Disposal system for storm water shall be provided separately. In no circumstances storm water shall be mixed with industrial effluent The applicant shall be responsible for loading its effluent into the tankers of the ETL for transporting the effluent. due care shall be taken to avoid any leakage or spillage of effluent during loading the tanker. oted by unit and complied with the same. oted by unit and complied the same. oted by unit and complied the same. oted by unit. oted by unit and complied the same. oted by unit and complied the same. oted by unit and complied the same. oted by unit. oted by unit. oted by unit and complied the same. M/s. Jyoti m Chemical Research Centre Pvt. Ltd., Ankleshwar. 50

51 3.4.8 If the effluent contains heavy metals, phenols & cyanide, the ETL member unit shall have to treat the effluent within its premises to conform to the following standards ( Whichever applicable ) PARAMETERS PERMISSIBLE LIMIT Zinc (Zn) 5.0 mg/l Total Chromium 2.0 mg/l ickel (i) 3.0 mg/l Mercury (Hg) 0.01 mg/l Cyanide (as C) 0.2 mg/l Pesticides Absent Phenolic Compounds 1.0 mg/l Lead (Pb) 0.1 mg/l Copper (Cu) 3.0 mg/l Hexavelent Chromium 0.1 mg/l Cadmium (Cd) 1.0 mg/l Arsenic (As) 0.2 mg/l Selenium 0.05 mg/l BD 3600 mg/l CD mg/l Free Acidity ppm Ammonia 100 mg/l The applicant shall keep records of quality of production of each product, quantity of water consumption, quantity of effluent generated and consumption of electricity on day to day basis and required to submit the complied record of one month to GPCB & ETL on or before fifth day of the succeeding month In case of shut-down of plant for more than three days for any reason, the ETL unit member shall intimate to ETL authority & GPCB well in advance for better operation & management of CETP The applicant shall either stop or curtail its production activities if the effluent is not adequately treated by the CETP of ETL to conform to the standards specified by G.P.C.B The applicant shall representative of ETL shall have right of entry at anytime for the purpose of inspection and monitoring the effluent collection facilities/etp (If required) of the applicant In case of incinerators, the flow measuring devices for mother liquor/toxic effluent/on-biodegrable effluent/on-biodegradable effluent, light diesel oil, furnace oil, etc. i.e. fuel used for combustion, air used for combustion shall be separately provided. Incinerator temperature recording devices as well as All the parameters are within the limits. Unit has membership for discharging of treated effluent. (Effluent is sent to ETL by tanker.) oted by unit and complied the same. oted by unit. oted by unit. oted by unit. Incinerator facility is not required in plant promises. M/s. Jyoti m Chemical Research Centre Pvt. Ltd., Ankleshwar. 51

52 gaseous flow measuring devices for scrubber shall also be provided. These data of temperature & flow should be recorded everyday & submitted to GPCB & ETL on monthly basis The GIDC drainage connection given by the GIDC for discharge of industrial effluent shall be disconnected & outlet shall be sealed If the ETL authority terminates the membership of CETP, the ETL member unit shall have to close down the manufacturing activities/industrial operation of the process plant immediately until the ETL membership is resumed The applicant shall put up at the entrance a board displaying ETL membership number & date of joining of ETL, the name of unit, particulars of the products/process and the name of proprietor /partners/directors of the unit and the electricity consumer number as on the record of GEB The Environmental management Unit/Cell shall be setup to ensure implementation on and monitoring of environment safeguards and other conditions stipulated by statutory authorities. The environmental Management Cell/Unit shall directly report to the chief Executive of the organization and shall work as a focal point for internalizing environmental issued. These Cells also coordinate the exercise of environmental audit preparation of environmental statements The Environmental audit shall be out yearly and the environmental statements pretending to the previous year shall be submitting to this state board latest by 30 th September every year The Board reserves the right to revoke revoke the consent make modifications in the conditions which seems fit in accordance with provisions of Water Act In case of change of ownership/management the name and address of the new ownership / partners/directors/proprietors should immediately be intimate to the board The applicant shall have to submit EVERY MTH the certified copies of challans (endorsed by ETL) regarding the quantity of industrial effluent (o. of Tankers) delivered per month to CETP of ETL Unit have to modify/improve performance of existing Effluent treatment facilities for efficiency & adequacy in order to comply with prescribed standards in oted by unit and complied the same. oted by unit. oted by unit and complied the same. oted by unit. Environment audit will be carried out once in year through GPCB recognized Environment Auditors. (This is as per directive of Hon ble Gujarat High Court.) oted by unit. oted by unit. oted by unit. oted by unit. Unit will be following the instruction. M/s. Jyoti m Chemical Research Centre Pvt. Ltd., Ankleshwar. 52

53 respects of effective operation of effluent treatment plant with regards to notification o.p/111(3) Board s standards/33129 dated 30 th ctober 2001 in fight of High court in SCA o.4473 of 97 dated 21/02/99 4. CDITIS UDER AIR ACT 1981 : 4.1 The following shall be used as fuel in Boiler. Sr. o. Fuel Quantity 1. atural Gas 5500 M 3 /Month 4.2 The applicant shall install & operate a comprehensive adequate air pollution control system in order to achieve prescribe norms as to achieve standards The flue gas emission through stack attached to boiler/furnace shall conform to the following standards: Total quantity of natural gas consumption does not exceed the quantity mentioned in the respective consent. oted by unit. The flue gas emissions are within tolerance limit. Permissible Parameter Limit Stack o. Stack Attached To Stack height in meter 1. Boiler 13 SPM 150 mg/m 3 2. Hot Air Generation There shall be no process emission from the manufacturing process as well as any other ancillary operations The concentration of the following parameters in the ambient air within the premises of the industry shall not exceed the limits specified here under. PARAMETER PM mg/m 3 PM mg/m 3 Sx 80 mg/m 3 x 80 mg/m The applicant shall operate industrial plant/air pollution control equipment very efficiently and continuously so that the gaseous emission always conforms to the standards specified in condition no & above The consent to operate the industrial plant shall lapse if at anytime the parameters of the gaseous emission are not within the tolerance limits specified in the condition no & above. 4.3 The applicant shall provide portholes, ladder, platform etc at chimney(s) for monitoring the air emissions and S 2 X oted by unit. PERMISSIBLE LIMIT 100 ppm 50 ppm Unit will not cross the ambient air quality standards within the premises. Unit will maintain all the equipment & industrial plant regularly so they can work efficiently and continuously. oted by unit. Facility for stack monitoring like portholes, ladder and platform are M/s. Jyoti m Chemical Research Centre Pvt. Ltd., Ankleshwar. 53