M/s. Aarti Industries Limited (Unit-III), GIDC Estate, Jhagadia. As per standard ToR of organic manufacturing sector issued by MoEF&CC.

Transcription

1 ANNEXURE I PROPOSED TERMS OF REFERENCE As per standard ToR of organic manufacturing sector issued by MoEF&CC. M/s.Jyoti Om Chemical Research Centre Pvt. Ltd., Ankleshwar. 11

2 A B D C E F H G I J N NW NE W SW KEY PLAN: E SE S NORTH 8 8 KLJ Organics Ltd. SURVEY NO 136 Chemie Organics India PLOT NO. 758/1-2-3 GIDC ROAD SURVEY NO 135 DCM GIDC ROAD AARTI INDUSTRIES LIMITED UNIT-1 GIDC ROAD UNIT-2 PLOT NO. 779 GIDC ROAD AJANTA PLOT NO. 778 UPL EXPANSION PANOLI INTERMEDIATE PLOT NO. 756/4 A/B PLOT NO. 756/3A,B, 756/2A,B PLOT NO. 756/5/A/B GIDC ROAD 4 Security Cabin 5.0x5.0M 30.0 M W I D E R O AD PLOT NO. 756/6 PLOT NO. 756/7 STAR PLOT NO. 756/8,756/9 ENDEKA CERAMIC PANOLI INTERMEDIATE GIDC ROAD 7 GIDC ROAD 7 SURVEY NO. 126 KEY PLAN GENERAL NOTES: 2 Security Cabin 5.0x5.0M TANKER MOVEMENT GATE Hydrogenation Separation Plant 6 Ca(OH)2 Plant 20M x12.0m 15 Multi story Building ( Division 3 Office Sitting,Dining,Locker& Change Room,Fire Tender & Ambulance Parking,Central Safety Office&OHC 20M x12.0m 16 4 Security Cabin 5.0x5.0M 17 Security Cabin 12x8M 6 FLOURINATION PLANT 32.0x20.6M 24.0 x 18.0mtr. 8M WIDE ROAD CENTRAL HYDRANT & RAW WATER STORAGE (ABOVE GROUND / UG) TECHNOLOGY 6 BUILDING 30 CAR PARKING 9M WIDE ROAD 9 Hydrogenation Plant 75 TWO WHEELER PARKING TOTAL PLOT AREA 42,735 Sqm. GREEN BELT 5,570 Sqm. 3 Sub Station 40.0x35.0M 5 5 PIPE RACK BAY AREA FOR COOLING TOWER 24.0x10.0M CT-1 CT-2 TCNB TANK FARM x13.17M 9M WIDE ROAD PIPE RACK BAY 4 10 HYDROGENATION & NITRATION TANK FARM 30.36x26.4M 8 Production Plant X30.0M 5 PILOT PLANT 40.0x29.0M 4 12 TCNB 20.6x18.0M 9M WIDE ROAD 132,5 DCNB 20.6x10.0M 3 3 REWINDER WAREHOUSE S.P.P. PAPER MACHINE AREA 14 2,5 DCNB FARM 20.6x12.8M FINISHING HOUSE B.S.R X ETP Plant 30.0x29.0M 9M WIDE ROAD R0101 ID 2300 HEIGHT: C0101 CHLORINATOR ID 1000 HEIGHT: C0102 ID 1350 HEIGHT: ACID STRIPPER 6C0103 BZ COLUMN ID 850 HEIGHT: C0105 BZ COLUMN ID 1900 HEIGHT: C0104 DCB COLUMN ID 1400 HEIGHT: R0101 MCB COLUMN ID 2300 HEIGHT: R0101 TOLUENE CHLORINATION Residue storage shed & Chilled Water vam 20.5x10.5M 1 Hydrogen Plant 75.0x20.0M ID 2300 HEIGHT: R0101 6R0101 PIPE RACK BAY ID 2300 HEIGHT: PIPE RACK BAY PIPE RACK BAY ID 2300 HEIGHT: ST0410 Ø3400mm CAP.40KL Toluene Chlorination Tank Farm 14.0x13.5M 19 6ST0413 Ø3100mm CAP.30KL x12.5 6ST0408B Ø8000mm CAP.500KL 6ST0407 Ø5700mm CAP.200KL NO. DESCRIPTION DRAWN CHECKED DATE REVISIONS 1 PLOT NO:- 758/1-2-3, G.I.D.C. INDUS. ESTATE, JHAGADIA A B C D E F G H I J A0 1

3 LIST OF DIRECTORS WITH ADDRESS ANNEXURE III SR. NAME OF DESIGNATION ADDRESS TELEPHONE NO. DIRECTOR NO. 1. Shri. Rajendra V Chairman & 1401, Antriksh, Gogri Managing Director Murar Road, Mulund (West), Mumbai Shri. Rashesh C ViceChairman 601, Antriksh, Murar Gogri Managing Director Road, Mulund (West), Mumbai Shri. Parimal H Whole -time Director A-1403, 14 th floor, Desai Runwal heights, LBS marg, Mulund (West), Mumbai Shri. Manoj M Whole -time Director Dunhill Villa Co. Op Chheda Hsg-Soc.Ltd, esant Road, Santracruz (West), Mumbai Shri. Kirit R Mehta Whole -time Director 10, Pushpendra Mansion, Phirojshah Mehta Road, Santracruz (West), Mumbai Smt. Hetal Gogri Whole -time Director 558-B, Gopal Sadan, Gala Block No.801, 8 th floor, Jamshed Road, Matunga (East)Mumbai Shri. Renil R Gogri Whole -time Director 1401, Antriksh, Murar Road, Mulund (West), Mumbai M/s.Jyoti Om Chemical Research Centre Pvt. Ltd., Ankleshwar. 13

4 Sr. No. 1. LIST OF PRODUCTS AND THEIR PRODUCTION CAPACITY ALONG WITH RAWMATERIAL LIST OF PRODUCTS AND THEIR PRODUCTION CAPACITY Name of Product Organic products 2,4/2,3/2,5/3,4 Di Chloro Nitro Benzene And/Or Application of Product Used in Dyes and Dyes Intermediate CAS No / / / / 2. 2,3,4/2,3,5 Tri Chloro Nitro Benzene Used in Dyes and Dyes And/Or Intermediate 3. 2,4,5/2,3,6 Tri Chloro Nitro Benzene Used in Dyes and Dyes / And/Or Intermediate DC3FNB And/Or Used in Dyes and Dyes Intermediate 5. 4-Nitro N-methyl Phthalimide Used In Polymer ,2,4 Tri Chloro Benzene And/Or Used in Dyes and Dyes Intermediate 7. 1,2,3 Tri Chloro Benzene And/Or Used in Dyes and Dyes Intermediate 8. Used in Dyes,Pharma, Para Chloro Toluene (PCT) And/Or Perfumes 9. Ortho Chloro Toluene (OCT) Used in Dyes,Pharma, And/Or Perfumes Chloro 4 Nitro Toluene And/Or Chloro 2 Nitro Toluene And/Or Chloro 2 Nitro Toluene DCDFB(1,3- DI CHLORO 4,6-DI FLORO BENZENE) And/Or 26DCFB (2,6 DI CHLORO FLORO BENZENE) Ortho Dichloro Benzene (only Physical Separation) Para Dichloro Benzene (only Physical Separation) Meta Dichloro Benzene (only Physical Separation) Used in Dyes and Dyes Intermediate Used in Dyes and Dyes Intermediate Used in Dyes and Dyes Intermediate Raw Material for Pharama Intermediate Raw Material for Pharama Intermediate Used in Dyes and Dyes Intermediate Used in Dyes and Dyes Intermediate Used in Dyes and Dyes Intermediate ANNEXURE IV Total Quantity in MT/Month M/s.Jyoti Om Chemical Research Centre Pvt. Ltd., Ankleshwar

5 Total Inorganic Products 18. Hydrogen Used in chemical reaction and process 3000Nm3/Hr. Inorganic Co-Products 19. Potassium chloride Raw material for various Reduction process. 282 Used in organic chemistry Nitrosyl Sulphuric Acid to prepare diazonium salts from amines. 405 Sr. No LIST OF RAW MATERIALS Name of Products Name of Raw materials Raw Material Consumption in MT/Month 2,4/2,3/2,5/3,4 Di Chloro Nitro Benzene And/Or 2,3,4/2,3,5 Tri Chloro Nitro Benzene 2,4,5/2,3,6 Tri Chloro Nitro Benzene 2, 4 DC3FNB CAS No. MDCB Conc. Nitric Acid Sulphuric Acid Soda Solution Total ,2,3 TCB Conc. Nitic Acid Sulphuric Acid Soda Solution Total ,2,4 TCB Conc. Nitic Acid Sulphuric Acid Soda Solution Total ,2,4/1,2,3 TCB Sodium carbonate Nitric acid (98%) Sulfuric acid (98%) Total Phthalic anhydride Methylamine (Aq. 40%) Nitro N-Methyl Xylene Phthalimide Nitric acid (98%) Sulfuric acid (98%) Total ,2,3/1,2,4 Tri Chloro Ortho DiChloro Benzene Benzene Recovered Ortho DiChloro M/s.Jyoti Om Chemical Research Centre Pvt. Ltd., Ankleshwar. 15

6 7 8 Para/Ortho Chloro Toluene 2-chloro-4-nitro Toluene 9 6-Chloro-2-Nitro Toluene & 4-Chloro- 2-Nitro Toluene DCDFB 2.6 DCFB Benzene Chlorine Total Toluene Catalyst Chlorine Total PNT Chlorine Total ONT Chlorine Total DFCNB as is Chlorine Caustic lye Total ,3 Dichloronitrobenzene (2, DCNB) KF Sulfolane PEG Chlorine Sodium bicarbonate (10%) Total M/s.Jyoti Om Chemical Research Centre Pvt. Ltd., Ankleshwar. 16

7 ANNEXURE V BRIEF PROCESS DESCRIPTION 1. 2,4/2,3/2,5/3,4 DI CHLORO NITRO BENZENE Manufacturing Process: Mixed acid containing concentrated nitric acid and concentrated sulphuric acid is reacted with 2, 5 Di Chloro benzene to produce 2, 5 Di Chloro nitro benzene. The reaction gets completed in series of nitrators with cooling coils and jackets. Reaction is followed by dil. sulphuric acid separation, washing by water and soda ash, drying to get a 2, 5 Di Chloro nitro benzene and unreacted 2, 5 Di Chloro benzene. Unreacted 2, 5 Di Chloro Benzene is recovered by steam distillation and recycled. Chemical reaction: C 6 H 4 Cl 2 + HNO 3 = C 6 H 3 Cl 2 NO 2 + H 2 O M/s.Jyoti Om Chemical Research Centre Pvt. Ltd., Ankleshwar. 17

8 Material balance: M/s.Jyoti Om Chemical Research Centre Pvt. Ltd., Ankleshwar. 18

9 2. 2,3,4/2,3,5 TRI CHLORO NITRO BENZENE Manufacturing process: 1,2,3/1,2,4 Tri Chloro Benzene is subjected to nitration reaction using nitric acid along with sulphuric acid as dehydrating agent to yield 2,3,4/2,4,5 TRI CHLORO NIRTO BENZENE & CRUDE TCNB. Chemical Reaction: 3. 2,4,5/2,3,6 TRI CHLORO NITRO BENZENE Manufacturing process: 1,2,3/1,2,4 Tri Chloro Benzene is subjected to nitration reaction using nitric acid along with sulphuric acid as dehydrating agent to yield 2,3,6/2,4,5 TRI CHLORO NIRTO BENZENE & CRUDE TCNB. Chemical Reaction: M/s.Jyoti Om Chemical Research Centre Pvt. Ltd., Ankleshwar. 19

10 Material Balance of 2, 3, 4/2,3,5 TRI CHLORO NITRO BENZENE M/s.Jyoti Om Chemical Research Centre Pvt. Ltd., Ankleshwar. 20

11 Material Balance of 2,4,5/2,3,6 TRI CHLORO NITRO BENZENE: M/s.Jyoti Om Chemical Research Centre Pvt. Ltd., Ankleshwar. 21

12 DC3FNB (NITRATION PRODUCT) Manufacturing process: Process involves fluorination of 2,3 dichloronitrobenzene using potassium fluoride as the fluorination agent in sulfolane solvent using phase transfer catalyst. Process involves preparation of 2,6 Dichlorofluorobenze from 2-fluoro-3-chloronitrobenzene using chlorine gas the chlorinating agent producing as Nox as by product. The process involves manufacturing 2,4 Dichloro-3-fluoronitrobenzene by nitration of 2,6 Dichlorofluorobenzene in nitrating mixture. Chemical Reaction: M/s.Jyoti Om Chemical Research Centre Pvt. Ltd., Ankleshwar. 22

13 Material Balance: 5. 4-NITRO-N-METHYPHTHALIMIDE Process Description: Process involves condensation of Phthalic anhydride and methylamine in xylene solvent. It gives N-methylphthalimide (NMP) after that it is subjected to nitration of N-methyl phthalimide in nitrating mixture. The product is sold as wet cake. Chemical Reaction: M/s.Jyoti Om Chemical Research Centre Pvt. Ltd., Ankleshwar. 23

14 Material Balance: M/s.Jyoti Om Chemical Research Centre Pvt. Ltd., Ankleshwar. 24

15 6. 1,2,3-TRI CHLORO BENZENE AND 1,2,4- TRI CHLORO BENZENE Manufacturing Process: The chlorine in the gaseous form is reacted with either benzene or ortho di chloro benzene in the chlorinator; Reaction is followed by benzene or Ortho di chloro benzene recovery then separation of crude tri chloro benzene. Crude product is then subjected to Flash Distillation to get pure product. Chemical Reaction: Material Balance: M/s.Jyoti Om Chemical Research Centre Pvt. Ltd., Ankleshwar. 25

16 7. ORTHO CHLORO TOLUENE & PARA CHLORO TOLUENE BRIEF MANUFACTURING PROCESS The chlorine in the gaseous form is reacted with toluene in the chlorinator. Reaction is followed by toluene recovery then separation of crude chloro toluene. Crude product is then subjected to Flash Distillation to get pure product. CHEMICAL REACTION M/s.Jyoti Om Chemical Research Centre Pvt. Ltd., Ankleshwar. 26

17 MATERIAL BALANCE: M/s.Jyoti Om Chemical Research Centre Pvt. Ltd., Ankleshwar. 27

18 8. 2- CHLORO 4-NITRO TOLUENE Brief manufacturing process: The chlorine in the gaseous form is reacted with Para nitro toluene in the chlorinator, Reaction is followed by Para nitro toluene recovery then separation of crude chloro nitro toluene. Crude product is then subjected to Flash Distillation to get pure products. Chemical reaction: Material Balance: M/s.Jyoti Om Chemical Research Centre Pvt. Ltd., Ankleshwar. 28

19 9. 6-CHLORO 2 -NITRO TOLUENE AND 4-CHLORO 2-NITRO TOLUENE Brief manufacturing process The chlorine in the gaseous form is reacted with ortho nitro toluene in the chlorinator; Reaction is followed by ortho nitro toluene recovery then separation of crude chloro nitro toluene. Crude product is then subjected to Flash Distillation to get pure products. Chemical reaction Material Balance: M/s.Jyoti Om Chemical Research Centre Pvt. Ltd., Ankleshwar. 29

20 10. 2,6 DI CHLORO FLORO BENZENE Brief manufacturing process Process involves fluorination of 2,3 Chloronitrobenzene using potassium fluoride as the fluorination agent in sulfolane solvent using phase transfer catalyst. Further process involves preparation of 2,6 Dichlorofluorobenze from 2-fluoro-3-chloronitrobenzene using chlorine gas the chlorinating agent producing as Nox as by product Chemical reaction ½ Cl2 NO g/mol 246.5Material Balance: M/s.Jyoti Om Chemical Research Centre Pvt. Ltd., Ankleshwar. 30

21 NO2 gas NSA (35%) Sulphuric Acid (98%) Nitrosyl Sulphuric Acid Total Total 11. 1,3- DI CHLORO 4,6-DI FLORO BENZENE Brief manufacturing process Chlorination of 2, 4 Di floro Chloro nitrobenzene gives 1, 3 Di Chloro, 4, 6 Di floro Benzene. Chemical reaction Cl NO2 F F +1/2 Cl2(gas) Cl Cl F F + NO Material Balance: NO2 gas NSA (35%) Sulphuric Acid Nitrosyl Sulphuric Acid (98%) Total Total M/s.Jyoti Om Chemical Research Centre Pvt. Ltd., Ankleshwar. 31

22 12. PHYSICAL SEPARATION OF METADICHLORO BENZENE AND ORTHO DICHLORO BENZENE AND PARA DICHLORO BENZENE Process description: Crude product is subjected to Flash Distillation to get pure product. Material balance: HYDROGEN Manufacturing Process: Methanol and demineralized water mixture as per certain ratio, after pressurized, evaporated and superheated, reaches a certain temperature and pressure. The mixed and superheated gas, under the action of the catalyst, takes place the reactions of catalyzed cracking and shifting of carbon monoxide simultaneously and forms finally the mixed gases of hydrogen, carbon dioxide and the residual carbon monoxide with a small quantity, etc. The cracked gas during the reaction, after purification and separation, is fed to the section of PSA to remove the impurities and then the qualified gas is delivered. Reaction CH3OH+H2O CO2+3H M/s.Jyoti Om Chemical Research Centre Pvt. Ltd., Ankleshwar. 32

23 Material balance: M/s.Jyoti Om Chemical Research Centre Pvt. Ltd., Ankleshwar. 33

24 DETAILS OF WATER CONSUMPTION ANNEXURE VI Sr. Purpose Total fresh water Recycled Total Water No. consumption (KL/day) Water (KL/day) Consumption (KL/day) A Domestic B Industrial 1)Process ) Washing ) Cooling ) Gardening Total (B) Total (A+B) DETAILS OF WASTE WATER GENERATION Sr. No. Purpose Total wastewater generation in KL/day A Domestic 28 B Industrial 1)Process 285 2) Washing 10 3) Cooling 50 Total (B) 345 Total (A+B) 373 DETAILS OF WASTE WATER GENERATION (With HCl Neutralization and Discharge) Sr. No. Purpose Total wastewater generation in KL/day A Domestic 28 B Industrial 1)Process 478 2) Washing 10 3) Cooling 50 Total (B) 538 Total (A+B) 566 M/s.Jyoti Om Chemical Research Centre Pvt. Ltd., Ankleshwar. 34

25 WORST CASE SCENARIO FOR WATER CONSUMPTION, WASTEWATER GENERATION AND HAZARDOUS WASTE Sr. No Product Product Quantity Raw material consumption Water consumption Effluent generation Residue TPM TPM KL PD KL PD MT PM Nitration 1 24,23,25,34 DCNB ,3,4,235 TCNB ,4,5, TCNB ,4 DC3FNB Nitro N-methyl Phthalimide Chlorination 5 1,2,4 TCB ,2,3 TCB PCT OCT CHLORO 4 NITRO TOLUENE CHLORO 2 NITRO TOLUENE CHLORO 2 NITRO TOLUENE De Nitro chlorination 12 2,6,DC Benzonitrile DCDFB DCFB Physical Seperation 15 odcb/pdcb/mdcb Total M/s.Jyoti Om Chemical Research Centre Pvt. Ltd., Ankleshwar. 35

26 WATER BALANCE DIAGRAM (in KLD) Total Water Consumption from GIDC 878 (Fresh (850KLD) + Reuse (28 KLD)) Gardening 28(R) Domestic 30 Process 225 Cooling 585 Washing 10 STP 28 To ETP 285 Water from raw material and reaction 60 Blow Down 50 Washing 10 ETP 345 NCT 345 M/s.Jyoti Om Chemical Research Centre Pvt. Ltd., Ankleshwar. 36

27 WATER BALANCE DIAGRAM (in KLD) (HCl dilution) Total Water Consumption from GIDC 878 (Fresh (850 KLD) + Reuse (28 KLD)) Gardening 28(R) Domestic 30 Process 225 Cooling 585 Washing 10 STP 28 Water from raw material, HCl neutralization and reaction 253 Blow Down 50 To ETP 478 Washing 10 ETP 538 NCT 538 M/s.Jyoti Om Chemical Research Centre Pvt. Ltd., Ankleshwar. 37

28 DETAILS OF EFFLUENT TREATMENT PLANT The dilute effluent from process plant and washing is taken to oil & grease trap for separation, oil and grease is skimmed off from the top. Effluent is then pumped to ph correction tank where ph is neutralized between 7.00 to 8.00 and compressed air is used for agitation. Then it is transferred to equalization tank where effluent from blow down (Cooling tower) is added and it is passed through filter press, where sludge is sent to decanter for sludge dewatering then it is taken to equalization tank after that effluent is pumped to primary settling tank where suspended solids are settled and the sludge is taken into membrane filter to separate the solid. Dried sludge is stored in a sludge storage tank. Clear water from settling tank is taken into aeration tank In this tank, extended type aeration system is adopted. Biological treatment is given to the effluent. Overflow is taken into secondary settling tank for excess sludge settling, biomass is recirculated in aeration tank if required or sent to membrane filter press. Overflow from secondary settling tank is passed through activated carbon filter + Sand filter and then taken into collection tank from where it will be sent to NCT. Diltue HCl, if not sold will be neutralized and passed through filter press and the filterate will be sent to collection tank followed by sand filter and carbon filter and final disposal to NCT after achieving GPCB prescribed Norms. M/s.Jyoti Om Chemical Research Centre Pvt. Ltd., Ankleshwar. 38

29 FIGURE: ETP FLOW DIAGRAM Process water + Washing Water Oil and Grease trap ph correction tank Primary settling tank Filter Press Aeration Tank Dilute HCl Collection tank Blow down (Cooling tower) Equalization tank Secondary settling tank Filter Press Filter Press Neutralization tank Filter Press Solid Collection Holding tank Carbon and Sand Filter GIDC Pipeline M/s.Jyoti Om Chemical Research Centre Pvt. Ltd., Ankleshwar. 39

30 PROPOSED EQUIPMENT LIST OF EFFLUENT TRETMENT PLANT WITH DIMENSION Sr Name of equipment Capacity, Size (in Meter) MOC no KL Dia Height Quantity 1 Oil & Grease trap 50 RCC ph correction tank 100 RCC with acid proof brickline Equalization tank 150 RCC Primary settling tank 100 RCC Aeration tank 400 RCC Secondary settling tank 150 RCC Sand Filter -- MS Carbon Filter -- MS Holding tank 100 RCC Guard Pond/Tank 300 RCC Filter Press -- As per standard WASTE WATER CHARACTERISTICS OF DIFFERENT STREAMS Sr. No. Parameters Units Blow down (Cooling tower) Effluent generation Washing water Process stream from floor & after HCl reactor washing Neutralization Capacity in KLD PH TSS mg/l TDS mg/l Ammonical Nitrogen mg/l C.O.D. mg/l M/s.Jyoti Om Chemical Research Centre Pvt. Ltd., Ankleshwar. 40

31 APPROXIMATE STAGE WISE REDUCTION IN EFFLUENT TREATMENT PLANT Sr. No. Parameters Units Composite Sample After Primary treatment Membrane filter press After Secondary treatment 1 st Stage 2 nd Stage Tertiary treatment CPCB norms for discharge to pipeline 1. ph TSS mg/l TDS mg/l Ammonical Nitrogen mg/l C.O.D. mg/l % COD REDUCTION % *Note-This is an approximate projection M/s.Jyoti Om Chemical Research Centre Pvt. Ltd., Ankleshwar. 41

32 DETAILS OF ELECTRICITY AND FUEL CONSUMPTION Sr. Name Requirement Source No. Total 1. Diesel 660 Litre/Hr. Local Market 2. Steam 30 MT/Hr. Aarti Industries Limited, Jhagadia 3. Energy - Electricity 3500 kva DGVCL DETAILS OF FLUE GAS EMISSIONS ANNEXURE VII Sr. No. Stack Attached To 1. D.G. Set (Standby) (2 Nos) Capacity= 1500 KVA (Each) Stack Height in Meter DETAILS OF PROCESS EMISSION Fuel APCM Type of Emission 11 Diesel -- PM SO2 NOX Permissible Limit 150mg/ Nm ppm 50ppm Sr. No. Stack attached to Stack Height in Meter APCM Parameter Permissible Limit 1. Scrubber connected to 11 Water scrubber NOX 25 Mg/Nm 3 Nitration Reactors. followed by Alkali Scrubber 2. Scrubber connected to 11 Water Scrubber HCl 20 Mg/Nm 3 Chlorination Reactor followed by Alkali Scrubber 3. Scrubber connected to 11 Sulphuric Acid NOX 25 Mg/Nm 3 De-nitration Reactor Scrubber followed by water 4. PSA Adsorber 26 Water scrubber VOC -- M/s.Jyoti Om Chemical Research Centre Pvt. Ltd., Ankleshwar. 42

33 DIAGRAM OF WATER SCRUBBER FOLLOWED BY CAUSTIC SCRUBBER DIAGRAM OF SUPHURIC ACID SCRUBBER FOLLOWED BY WATER SCRUBBER M/s.Jyoti Om Chemical Research Centre Pvt. Ltd., Ankleshwar. 43

34 DIAGRAM OF WATER SCRUBBER DETAILS OF SCRUBBER Sr. Name of Units Capacity Quantity MOC No. 1. Alkali Scrubber 10 KL 1 HDPE/PP FRP 2. Sulphuric Acid Scrubber 10 KL 1 HDPE 3. Water Scrubber 10 KL 3 HDPE/PP FRP SPECIFICATIONS OF SCRUBBER SYSTEM Description Details Water Scrubber Alkali Scrubber Acid Scrubber Velocity gas 10 kg/hr 10 kg/hr 10 kg/hr Gas flow 10 Kg/Hrs 10 Kg/Hrs 10 Kg/Hrs Blower Capacity 75 CFM 75 CFM 75 CFM Pump Capacity 2500 L/Hrs 2500 L/Hrs 2500 L/Hrs Scrubbing media Water NaOH H2SO4 Column diameter 300 mm 100 mm 300 mm Column packed height 3 M 3 M 3 M Total column height 4.5 M 4.5 M 4.5 M M/s.Jyoti Om Chemical Research Centre Pvt. Ltd., Ankleshwar. 44

35 DETAILS OF HAZARDOUS WASTE GENERATION & DISPOSAL Sr. No. Name of Waste 1. ETP Waste Distillation Residue Discarded containers/bags 4. Used oil 5. Insulation Waste 6. Spent Carbon Off Specification Product Hydrochloric Acid(HCl) Nitrosyl Sulphuric Acid Dil. Sulphuric Acid (70%) Source of generation ETP Process Process Maintenance Maintenance ANNEXURE VIII Category Total Quantity Mode of disposal ETP, APCM and Process 28.3 Process Process Process Process 120 MT/Month 488 MT/Month 20 MT/Month 500 Lit/Month -- 2 MT/Month 5 MT/month MT/Month By-Product/Co-Product MT/Month MT/Month MT/Month Collection, Storage, Transportation, disposal to TSDF. Collection, Storage, transportation, disposal at Incineration / Coprocessing. Collection, Storage, Decontamination, Disposal by sold to authorize recyclers. Collection, Storage, Transportation, Disposal by selling to registered reprocessors. Collection, Storage, Transportation disposal by at TSDF Site. Collection, Storage, transportation, sent for coprocessing/incineration. Collection, Storage, transportation, disposal at CHWIF. Sold to end users having Rule-9 permission under Hazardous and other waste rules, 2016 or It will be neutralized and sent for treatment to ETP. Sold to end users having Rule-9 permission under Hazardous and other waste rules, 2016 Sold to end users having Rule-9 permission under Hazardous and other waste rules, 2016 M/s.Jyoti Om Chemical Research Centre Pvt. Ltd., Ankleshwar. 45

36 DETAILS OF SOLID WASTE Sr. Waste Quantity Area Kept for Mode of Disposal No. storage 1. Glass Waste ( Z 13) 2 MT/Year 2 sq. m Landfill site 2. Paper waste (Z44) 1 MT/Year Landfill site 3. Bio-Medical Waste 0.5 MT/Year Will be disposed off as per Bio Medical Waste Rules 4. Cotton waste 1 MT/Year Incineration Facility 5. Wooden Waste 2 MT/Year Authorized Scrap Vendors 6. E-waste 1 MT/Year Authorized E-Waste handlers M/s.Jyoti Om Chemical Research Centre Pvt. Ltd., Ankleshwar. 46