For Amendment - Environmental Clearance [EC]

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1 SEAC, Gujarat Page 1 of 19 Synthetic Organic Chemicals 5(f) For Amendment - Environmental Clearance [EC] 1. Earlier EC letter no. and Date: SEIAA/GUJ/EC/5(f)/3670/2015 dated Basic Information of the Project: i Name & Address of the Project site (Complete details with plot no./survey no., Landmark etc. ) Macson Colour Chem Pvt. Ltd. Plot Z/12/2, Dahej, Vagra, Bharuch, Gujarat ii Name of the Applicant Mr. Keyur Patel iii Address for correspondence Plot 2424, G. I. D. C, Sachin, Surat Ph iv Contact no. and ID of the Applicant Mo. no. : formacson@gmail.com v Aerial distance of nearest Habitat (KM) Bharuch: 50 Km vi vii viii Longitude & Latitude of the Project Site: (4 corners of the site) Category as per the Schedule to the EIA Notification 2006 i.e. 1(d), 2(b), 5(f) etc. Applicability of General Conditions of EIA Notification 2006: i.e. Ensure that (1) Protected areas notified under the Wildlife (Protection) Act, 1972; (2) CEPI areas (3) Eco-sensitive areas and (4) Inter-state boundaries and international boundaries; are not located within 5 km or 10 km (as the case may be) area from the boundary of the proposed site. (1) Latitude: 21 42'10.95"N Longitude: 72 36'59.73"E (2) Latitude: 21 42'10.93"N Longitude: 72 37'2.72"E (3) Latitude: 21 42'5.59"N Longitude: 72 37'2.43"E (4) Latitude: 21 42'5.70"N Longitude: 72 36'59.62"E 5 (f) Synthetic Organic Chemicals Sub-Category: B Not applicable 3. Online application & PH reg. : a) Date of SEAC meeting for recommendation to grant TOR: b) Online application proposal no. : SIA/GJ/IND2/21198/2015 c) Date online acceptance of EC amendment application by SEAC: EDS Query on for EC Amendment d) EC issued by SEIAA: Letter no & date. SEIAA/GUJ/EC/5(f)/3670/2015 vide Page 1 of 19

2 SEAC, Gujarat Page 2 of 19 dated e) Date of presentation for Appraisal: 08/07/2013 for TOR presentation 4. Product profile: (As per EC) no. Name of the Products 1 Group 1 2 Group 2 Name of the Raw Materials CAS / CI no. of raw materials. Aryl Sulphonic Acid i. Schaeffer's Acid ii. G - Salt iii. R - Salt iv. Para Cresidine Ortho Sulphonic Acid v. Sulpho Tobias Acid vi. Dhal s Acid (2 napthylamine sulphonic Acid ) vii. Ortho Nitro Chloro Benzene Sulphonic ACID viii. Para Nitro Chloro Benzene Sulphonic ACID ix. Para Nitro Chloro Toluene Ortho Sulphonic Acid x. 5 Sulpho Salicylic Acid xi. Para Anisidine M Sulphonic Acid xii. 5 Sulpho Antranilic Acid Aryl Amination Product i. Broner s Acid ii. Amido G-Salt iii. PNAOSA Quantity End use of products Products are use as a dye intermediates 3 Group 3 4 Group 4 iv. ONAPSA Aryl Fusion Product i. Di Oxy G Salt ii. Gama Acid iii. Sulpho Gama Acid Aryl Organic Fine Chemicals i. Schaeffer s Acid Page 2 of 19

3 SEAC, Gujarat Page 3 of 19 ii. G-Salt iii. Para Cresidine Ortho Sulphonic Acid iv. Sulphanilic Acid v. R-Salt vi. Dhal s Acid vii. Bronner s Acid viii. Fluroseine ix. Urainine - 5 Group 5 Aryl Sulphonation Fine Product i. Sulphanilic Acid ii. Ortho Toludine 5 Sulphonic Acid iii. Alpha Naphthylamine Sulphonic Acid 6 Group 6 Florescence Group 7 Aryl Sulphonic Acid - SO 2 Gas 88.2 i. Schaeffer s Acid ii. PCOSA iii. Sulphanilic acid iv. G-salt Group 8 Aryl Sulphonamide 30 i. OPSAMIDE ii. Amino Phenyl Methyl Sulphone iii. PT Sulphanilide - iv. PABSA - v. NOXAMIDE - vi. MABSA - 9 Group 9 Wet Grinding Group 10 BON Product Group 11 Synthetic Organic Dyes 36 i. Acid Orange ii. Food red iii. Food red iv. Acid yellow v. Acid orange vi. Acid red vii. Acid red viii. Acid red ix. Acid yellow Group 12 Colour Former Product 21 i. RTRD Red - 13 Group 13 Para Cresidine Group 14 Sodium Naphthionate Page 3 of 19

4 SEAC, Gujarat Page 4 of Group 15 N. W. Acid The project falls under Category B of project activity 5(f) as per the schedule of EIA Notification Product wise Raw material consumption: Aryl Sulphonic Acid Product-192 MT Raw Material CAS Qty. MT/Mont h 1 Schaeffer s Salt Beta Naphthol Sulphuric Acid Potassium Chloride G-Salt Beta Naphthol Sulphuric Acid 98 % Oleum, 23 % Potassium Chloride R-Salt Beta Naphthol Sulphuric Acid Sodium Sulphate Para Cresidine Ortho Sulphonic Acid Para Cresidine Sulphuric Acid Oleum 23% Sulpho Tobias Acid Tobias Acid % Sulphuric Acid % Oleum Dil. Sulphuric Acid Dhal s Acid(2 napthylamine 5 sulphonic Acid) 7 Ortho Nitro Chloro Benzene Sulphonic Acid 8 Para Nitro Chloro Benzene Sulphonic Acid 9 Para Nitro Chloro Toluene Ortho Sulphonic Acid Tobias Acid % Sulphuric Acid % Oleum Dil. Sulphuric Acid PNT or ONCB or PNCB Oleum 23% Sulpho Salicylic Acid H2SO Salicylic Acid Soda Ash Page 4 of 19

5 SEAC, Gujarat Page 5 of Para Anisidine M Sulphonic Acid H2SO Para Anisidine Salt Sulpho Antranilic Acid Antranilic Acid Sulphuric Acid Oleum Aryl Amination Product Product-30 MT Raw Material CAS Qty. 1 Broneer s Acid Schaeffer s Acid, G Acid 2 Amido G-Salt Liquor Ammonia Sodium Bi Sulfite Ammonium bi Sulphite PNCBOSA PNAOSA Liq. Ammonia( kg ) SBS H2SO ONAPSA ONCBPSA Liq. Ammonia ( kg ) SBS H2SO Aryl Fusion Product Product-24 MT Raw Material CAS Qty 1 Di Oxy G Salt. G-Acid Caustic Soda Sulphuric Acid Gamma Acid G-Salt Liq. Ammonia SBS Caustic Lye Sulpho Gamma Acid K - Acid Caustic H2SO Page 5 of 19

6 SEAC, Gujarat Page 6 of 19 Aryl Organic Fine Chemicals Product MT Raw Material CAS Qty. 1 Schaeffer s Acid Schaeffer s Salt Soda Ash HCL G-Salt G Salt Soda Ash HCL PCOSA PCOSA Soda Ash HCL Sulphanilic Acid Sulphanilic Acid Soda Ash HCL R-Salt R- Salt Soda Ash HCL Dhal s Acid DAH S ACID Soda Ash HCL Bronner s Acid BRONNER S ACID Soda Ash HCL Fluroseine Flurosceine Soda Ash HCL Urainine Urainine Water Soda Ash HCL Aryl Sulfonation Baking Process Product MT Raw Material CAS Qty. 1 Sulphanilic Acid Aniline/Ortho Toludine/Alpha Napthylamine 2 Ortho toludine 5 98% Sulphuric Acid sulphonic acid. 3 Alpha Napthylamine Sulphonic Acid Alpha Napthylamine Page 6 of 19

7 SEAC, Gujarat Page 7 of 19 98% Sulphuric Acid Fluorescence Product -12 MT Raw Material CAS Qty. 1 Fluorescence Resorcinol Phthalic anhydride Zinc chloride (Anhydrous) Caustic Lye Hydrochloric Acid Aryl Sulphonic Acid SO 3 Gas Product MT 1 Schaeffer s Acid Raw Material CAS Qty Beta Naphthol Methanol SO3 Gas Caustic Soda PCOSA PC SO Methanol Caustic Soda Sulphanilic acid Aniline SO Caustic Soda G-salt Beta Naphthol SO Methanol Potassium Hydroxide R-Salt Beta Naphthol SO Methanol Caustic Soda Aryl Sulphonamide Product -30 MT Raw Material CAS Qty 1 OPSAMIDE ONCB Chloro sulphonic acid Ice Ammonium Hydroxide Page 7 of 19

8 SEAC, Gujarat Page 8 of 19 Caustic Soda Lye Hydro Chloric acid Sodium Hydro Sulphide Iron Acetic acid Soda Ash Sodium Bicarbonate Stream AMINO PHENYL METHYL SULPHONE 3 PT SULPHANILIDE Meta Chloro Benzene Chloro Sulfonic Acid Ice Sodium Meta Bisulphate Dimethyl Sulphate Caustic Lye HCL Sodium Hydro Sulphide Iron Acetic Acid Soda Ash Soda Bicarbonate Fuming Nitric Acid % Sulphanilic Acid NAHS Stream Para Nitro Toluene Chloro sulphonic Acid Ice Aniline Caustic Soda Lye HCl Sodium Hydro Sulphide 0.1 Iron Acetic acid Soda Ash Soda Bicarbonate Stream PABSA Nitro Benzene/ Acetanilide MABSA Chloro Sulfonic acid Ice Ammonium Hydroxide Caustic Soda Lye HCl Sodium Hydro Sulphide Iron Acetic Acid Soda Ash Soda Bicarbonate Page 8 of 19

9 SEAC, Gujarat Page 9 of 19 Stream NOXAMIDE 4 Nitro Ortho Xylene Chloro Sulfonic Acid Ice Dry Sodium Sulphate Mono Ethanol Amine Caustic Soda Lye HCL Sodium Hydro Sulphide Iron Acetic Acid Soda Ash Soda Bicarbonate Stream Wet Grinding Product -63 MT Raw Material CAS Qty. 1 Wet Grinding Substance D M Water or polar solvent BON Product Product -8.8 MT 1 BON (BETA NAPTHOL BENZYL ETHER) Raw Material CAS Qty. Beta Naphthol Benzyl Chloride DMF KOH Synthetic Organic Dyes Product - 36 MT Raw Material CAS Qty. 1 Acid Orange 7 SULPANILIC ACID Sodium Nitrate HCL BETA NAPHTHOL Soda Ash Food red 1 SODIUM NAPHTHIONATE Sodium Nitrate HCL META XYLEDENE ORTHO SULPHONIC ACID Soda Ash Food red 17 PCOSA Page 9 of 19

10 SEAC, Gujarat Page 10 of 19 Sodium Nitrate HCL SCHAEFFER S ACID Soda Ash Acid yellow 23 SULPANILIC ACID Sodium Nitrate HCL ,4 SPCP Soda Ash Acid orange 24 SULPHANILIC ACID Sodium Nitrate HCL ,4 XYLIDINE Soda Ash Acid red 33 ANILINE Sodium Nitrate HCL SULPHO GAMMA ACID Soda Ash Acid red 18 SODIUM NAPHTHIONATE Sodium Nitrate HCL G-Salt Soda Ash Acid red 27 SODIUM NAPHTHIONATE Sodium Nitrate HCL R-Salt Soda Ash Acid yellow 36 Metanilic acid Sodium Nitrate HCL Di phenyl amine Soda Ash Colour Former Products: Product - 21 MT Raw Material CAS Qty 1 RTRD Red 2,4 BDSA DEMAP Page 10 of 19

11 SEAC, Gujarat Page 11 of 19 Para Cresidine Product - 60 MT Raw Material CAS Qty 1 Para Cresidine P Cresol HNO Nitro P Cresol Di methyl Sulphate Caustic soda Nitro methyl cresol Monolithic Catalyst Methanol Sodium Naphthionate Product - 60 MT Raw Material CAS Qty 1 Sodium Alpha naphthyl amine Naphthionate sulphonic acid NaOH H2SO N. W. Acid Product MT Raw Material CAS Qty. () 1.0 N. W. Acid Alpha Naphthol MCB CISO3H Water Compliance status of the existing project: no. Particulars Brief Information/Details Remarks 1 Earlier EC details In case of EC not SEIAA/GUJ/EC/5(f)/3670/2015 vide dated obtained, Copy of CTE & CCA obtained before , 2 Compliance of EC conditions Not Applicable Unit not started yet 3 Status of inspection by RO- MoEF&CC, Bhopal.i.e. CCR- Certified Compliance Report NIL 4 Status of submission of half Not Applicable yearly returns to concern authorities. 5 Compliance of existing CC&A Not Applicable Page 11 of 19

12 SEAC, Gujarat Page 12 of 19 6 Legal actions/closure NIL directions/scn etc. issued by GPCB. 7 Any Public Complaints NIL 8 Is there any litigation pending before any court of Law against the Project? NIL 7. Salient features of the project including Water, Air and Hazardous waste no. A management: Particulars Total cost of Proposed Project (Rs. in Crores): Details There will be no increase in project cost. 1. Capital cost for EMS (Environmental Management System): - No Changes as amendment is only for way of disposal of effluent 2. Recurring cost towards the environmental protection measures: No changes. B Total Plot area ( sq. meter) sq. m. Green belt area,/tree Plantation area ( sq. meter) sq. m. C D i ii Employment generation 1. Direct No additional manpower will be require as amendment is only for way of effluent disposal. Water Source of Water Supply 2. Indirect Total (GIDC Bore well, Surface water, Tanker supply r etc...) Status of permission from the concern authority. Water consumption (KLD) Existing which will remain same The water requirement of this project is 89 KLD and will be supply by Dahej SEZ Limited. Not Applicable as there is no expansion. Existing KL/day (A) Domestic 2 (B) Gardening 3 (C) Industrial 84 Process 60 Washing & Others 14 Boiler & Cooling 10 Page 12 of 19

13 SEAC, Gujarat Page 13 of 19 1) Total water requirement for the project: 89 KLD 2) Quantity to be recycle: 0 KLD 3) Total fresh water requirement: 89 KLD iii iv Waste water generation (KLD) - Category (A) Domestic 1.5 (B) Industrial Processing 49 Washing 13 Boiler & Cooling 8 Gardening 0 Total Industrial waste water - Treatment facility with capacity (ETP, CETP, MEE, STP, Spray Dryer etc). Existing KL/Day 70 Remarks Stream 1 (15 KL/day) - Conveyed to Process recovery Plant. (No Change) Stream 2 (10 KL/day) - To common MEE of BEIL-Dahej instead of Spray dryer Stream 3 (11 KL/day) - To common MEE of BEIL-Dahej instead of ferrous sulphate/copper sulphate or Gypsum. Stream 4 (13 KL/day)- Shall be sent to ETP plant. (No change) v Mode of Disposal & Final meeting point Domestic: 1.5 KLD water is being discharged in to Septic Tank / Soak Pit System Industrial: As mention above vi In case of Common facility (CF) like CETP, Common Spray dryer, Common MEE etc., name of CF As mentioned in point iv. Membership of Common facility (CF) NOC letter from BEIL for way of disposal of effluent has been received and attached with covering letter. vii Reuse/Recycle details (KLD) 15 KLD effluent is being recycle in the process itself. E Air i Flue gas emission details of Boilers/TFH/Furnaces/DG sets etc. with capacities viz. TPH, Kcal/hr, MT/hr, Page 13 of 19

14 SEAC, Gujarat Page 14 of 19 KVA etc. There will be no change in existing APC as mentioned below: FLUE GAS EMISSION Stack Stack Attached to Stack Height Fuel Consumption APCM Steam Boiler Capacity: 2 MT/Hr Thermopack Unit Capacity : 800 U D. G. Set - Stand By Capacity : 250 KVA 2 Height - 30 Meter Diameter - 30 cm Height - 30 Meter Diameter - 30 cm Height - 10 Meter each Diameter - 25 cm each Bio fuel / Coal 5.5 MT/Day Bio fuel / Coal 4 MT/Day Diesel 400 Liters/Day Total - ii Process gas i.e. Type of pollutant gases (SO 2, HCl, NH 3, Cl 2, NO x etc.) - Multicyclone Separator, Bag Filter & Water Scrubber Multicyclone Separator & Bag Filter As Diesel shall be used as a fuel, adequate stack height shall be provide. There will be no change in existing Process gas emission control system PROCESS GAS EMISSION Vent Vent Attached to Vent Height Pollutant APCM Reaction Vessel 2 Nos Sulphonator 2 Nos Height - 15 Meter Diameter 20 cm Height - 15 Meter Diameter 20 cm NH 3 SO 2, HCl Ammnoia Scrubber Two Stage Alkali Scrubber 3. Spray Dryer Height - 15 Meter PM, SOx, NOx Alkali Scrubber iii - Fugitive emission details with its mitigation measures. As below: There shall be fugitive emissions during handling of raw materials Mitigation Measures: Vents of storage tanks shall be connected to Scrubbers to minimize fugitive Page 14 of 19

15 SEAC, Gujarat Page 15 of 19 F i emissions of gases. Hazardous waste (as per the Hazardous and Other Wastes (Management and Transboundary Movement) Rules Cat. Solid / Hazardous Waste Source of Waste In Existing EC Generation Quantity 34.3 ETP Sludge From ETP Spray Dryer Salt (Will be Removed) From Spray Dryer 26.1 Iron Sludge From Process Proposed Generation Quantity Nil 19.2 D2 Spent HCl From Process Disposal ion / sent to TSDF Site ion / sent to TSDF Site ion / sent to TSDF Site reuse in to process Spent Acid generated from manufacturing of Group 1 [Para Cresidine Ortho Sulphonic Acid, Sulpho Tobias Acid, Dhal s Acid (2 napthylamine 5 sulphonic Acid)], Group 4, Group 6, Group 7, Group 8, Group 12 and Group 15. D Spent Nitric Acid Spent Catalyst Distillation Residue From manufacturing of para cresidine From process (Group 13) From Distillation ion / reuse or sent to common MEE site ion / send to regeneratio n unit / sent to TSDF Site Page 15 of 19

16 SEAC, Gujarat Page 16 of 19 C1 --- B ion / sent to cement industries for co processing / sent to CHWIF Site Ammonium Reuse in to From Process Bi Sulphate process Ammonium Bi Sulphate generated from manufacturing of Group 2 Zinc Hydroxide FeSO 4 / CuSO 4 (Will be Removed) Gypsum (Will be Removed) 5.1 Used Oil (PNAOSA, ONAPSA) and Group 3 (Gamma Acid). From manufacturing of Group 6 - Florescence Discarded drums Discarded PP Bags / Liners Spent Solvent (Methanol) From gypsum recovery plant From gypsum recovery plant From plant & machineries From material packaging From manufacturing of Group 7 and Group Liters/Month i. e Nos/year i. e. 4 MT/Year Nos/year i. e. 20 MT/Year 341 Nil Nil 400 Liters/Month i. e Nos/year i. e. 4 MT/Year Nos/year i. e. 20 MT/Year 341 Reuse in to process ion / sold as a by product ion / send to Cement Industries / to TSDF Site ion / sent to registered recycler / reuse as a lubricant ion / Supplier / sent to registered recycler Recycle back in to the Process / to reprocessor Page 16 of 19

17 SEAC, Gujarat Page 17 of 19 D2 D2 Spent Solvent (DMF) Spent Solvent (MCB) KCl Methyl Sulphate Sodium Salt From manufacturing of Group 10 From manufacturing of Group 15 From manufacturing of Group 10 From manufacturing of Group MT/Moth MT/Moth for recovery Recycle back in to the Process / to reprocessor for recovery Recycle back in to the Process / to reprocessor for recovery ion / sold as a by product ion / sold as a by product There will reduction in quantity of Spray dryer salts and FeSO4/Gypsum waste as mode of disposal is proposed to change. ii Membership details of TSDF, CHWIF etc. Industry is a member of TSDF site of M/s. Bharuch Enviro Protection Ltd., Bharuch for the disposal of Solid / Hazardous Waste. ii G i Details of Non-Hazardous waste & its disposal (MSW and others) Solvent management & VOC emissions etc. Details of Solvent recovery (As per respective ToR) Types of solvents, Details of Solvent recovery, % recovery. reuse of recovered Solvents Industry is proposing to change the way of disposal of stream-2 and stream-3 by sending it to BEIL. (NOC is attached with covering letter) Not Applicable Spent Solvent is recycle back in to the Process / to re-processor for recovery Page 17 of 19

18 SEAC, Gujarat Page 18 of 19 ii VOC emission sources and its mitigation measures NIL 8. Details of Environmental Consultant: Particulars Details no. i Name of the Consultant Enpro Enviro Tech and Engineers Pvt. Ltd. ii Contact no. and ID of the Applicant Mo. no. : Contact: formacson@gmail.com iii Accreditation for the categories 1. Metallurgical industries (ferrous & nonferrous) - Cat. A 2. Synthetic organic chemicals industry (dye & dye intermediates; bulk drugs and intermediates excluding drug formulations; synthetic rubber; basic organic chemicals, other synthetic organic chemicals and chemical intermediates)- Cat. A 3. Common hazardous waste treatment, storage and disposal facilities (TSDFs) - Cat. A 4. Common Effluent Treatment Plant (CETPs) - Cat. A 5. Common Municipal Solid Waste Management Facility (CMSWMF) - Cat. B iv Any other details - 9. Details regarding proposed changes: no. Condition no. in which changes proposed. 1 Water: point no. 14 in EC (Way of Disposal) As per EC Stream 2 (10 KL/day) - Shall be sent to Spray Dryer. Stream 3 (11 KL/day) - Shall be used to make ferrous sulphate/copper sulphate or Gypsum. As per proposed amendment To common MEE of BEIL-Dahej instead of Spray dryer To common MEE of BEIL-Dahej instead of ferrous sulphate/copper sulphate or Gypsum. Justification For proper disposal and treatment of these two streams, it is proposed to send effluent to Common facility of MEE at BEIL for which they have given NOC letter as well. Page 18 of 19

19 SEAC, Gujarat Page 19 of 19 Name & designation of the Applicant: Keyur Patel (Partner) Stamp & Signature of Applicant: Date: General Instructions Format shall be in WORD Format (Font type- Arial, Font size- 11) Provide authenticated (with stamp & Signature) hard copy during presentation. Kindly send to : seacgujarat@gmail.com Above data shall be as per application Form-1 & PFR. Incorporate relevant details in respective column in the Format. Do not attach Annexure except copy of Certificates etc. Page 19 of 19

As per standard ToR of organic manufacturing sector issued by MoEF&CC.

ANNEXURE I Terms of Reference As per standard ToR of organic manufacturing sector issued by MoEF&CC. 1 ANNEXURE II List of Directors Sr. No. Name of Director Designation Address Telephone no. 1. Shri.