ANNEXURE 1. PROJECT LOCATION Location Map of Project Site in GIDC, Panoli GUJARAT

Transcription

1 ANNEXURE 1 PROJECT LOCATION Location Map of Project Site in GIDC, Panoli GUJARAT

2 LONG VIEW SHORT VIEW

3 DISTANCE OF ARABIAN SEA FROM PROJECT SITE

4 ANNEXURE 2 Sr. No. Title LAND AREA BIFURCATION Existing Area (m 2 ) Proposed Total After Expansion 1. Process area Raw material storage area Finished product storage area ETP area Utility area Hazardous storage area waste D. G Set area Admin building / R & D Lab (31.79 QC Lab and R & D) (31.79 QC Lab and R & D) 10. Underground water tank Greenbelt area Parking area Open area TOTAL

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6 ANNEXURE 4 Sr. No. LIST OF PRODUCT Name of Product Existing Quantity (MT/Month) 1. Mebendazole 1.00 Proposed 2. 2-(2-Methoxy Phenoxy) Ethyl Phthalimide 3. 2,4-Dimethoxy Benzoic Acid 4. 2,5-Dimethoxy Benzoic Acid 5. 2-[(2-Methoxy Phenoxy) Methyl] Oxirane Bromo Dimethoxy Acetophenone 7. 2-Bromo 4, 5 - Dimethoxy Benzoic Acid 8. 2-Bromo 4, 5 - Dimethoxy Benzyl Bromide 9. 2-Bromo Dimethoxy Acetophenone Methyl 2-Oxazoline 11. 3,4-Diethoxy Benzoic Acid 12. 3,4-Dimethoxy Acetophenone Bromo Veratrole Methyl Catechol Methyl Catechol Dimethyl Acetate Bromo-2-Chloro Benzoic Acid Bromo-2-Chloro-4-Ethoxy Benzophenone Nitro Veratric Acid 19. Diacetone Fructose Pyranose 20. Sesamol 21. Veratric Acid Total Note: Total production capacity for any proposed product shall not exceed 10 MT/M.

7 Sr. No. LIST OF RAW MATERIALS Raw Material 1. 2-(2-Methoxy Phenoxy) Ethyl Phthalimide Consumption (MT/Month) a. Guaiacol 4.27 b. Ethylene Dichloride 3.33 c. Sodium Hydroxide Flaks 1.35 d. Potassium Phthalimide 6.22 e. Toluene f. Methanol ,4-Dimethoxy Benzoic Acid a. 1,3- Dihydroxy Benzene 8.05 b. Dimethyl Sulphate 9.13 c. Sodium Hydroxide d. Benzene e. Acetylchloride 4.31 f. Aluminum Chloride 9.67 g. Sodium Hypo Chlorite h. Sodium Bisulphite 5.71 i. EDC j. Sulphuric Acid ,5-Dimethoxy Benzoic Acid a. 1,4- Dihydroxy Benzene 8.05 b. Dimethyl Sulphate 9.13 c. Sodium Hydroxide d. Benzene e. Acetyl Chloride 4.31 f. Aluminium Chloride 9.67 g. Sodium Hypo Chlorite h. Sodium Bisulphite 5.71 i. EDC j. Sulphuric Acid [(2-Methoxy Phenoxy) Methyl] Oxirane a. Guaiacol 7.58

8 Sr. No. Raw Material Consumption (MT/Month) b. Epichlorhydrine 5.11 c. Sodium Hydroxide 2.78 d. Toluene Bromo Dimethoxy Acetophenone a. 1,4-Dimethoxy Benzene 4.64 b. DMS 5.15 c. Sodium Hydroxide Flaks 3.27 d. EDC e. ZnCl f. Acetic Anhydride 6.50 g. HBr 6.52 h. H 2 O Bromo 4, 5 - Dimethoxy Benzoic Acid a. 3,4-Dimethoxy Benzoic Acid 7.04 b. Bromine 3.02 c. HCl d. Sodium Hydroxide Bromo 4, 5 - Dimethoxy Benzyl Bromide a. Veratrole 4.93 b. Hydrobromic Acid 5.97 c. Hydrogen Peroxide 2.40 d. EDC 9.00 e. Formaldehyde 0.97 f. Hydrobromic Acid 5.43 g. Acetic acid h. Toluene Bromo Dimethoxy Acetophenone a. Dimethoxy Benzene 5.38 b. Acetyl Chloride 3.03 c. Bromine 3.05 d. Aluminium Chloride 8.70 e. EDC Methyl 2-Oxazoline

9 Sr. No. Raw Material Consumption (MT/Month) a. Mono Ethanol Amine 9.00 b. Acetonitrile 7.72 c. H 2 SO 4 98% ,4-Diethoxy Benzoic Acid a. Catechol 6.97 b. Diethyl sulphate 9.66 c. Sodium hydroxide 5.02 d. Benzene e. Acetyl Chloride 3.74 f. Aluminium Chloride 8.39 g. Sodium Hypo Chlorite h. Sodium Bisulphite 4.95 i. EDC ,4-Dimethoxy Acetophenone a. 1,2-Dimethoxy Benzene 7.74 b. Acetyl Chloride 4.40 c. Ethylene Dichloride d. Aluminum Chloride Bromo Veratrole a. Veratrole 6.42 b. Hydrogen Peroxide 3.13 c. Hydrobromic Acid 7.77 d. EDC Methyl Catechol a. P-Cresol 8.88 b. Hydrogen Bromide (48%) 6.60 c. Ethylene Dichloride d. Hydrogen Peroxide 2.77 e. Sulphuric Acid 7.90 f. Sodium Hydroxide 9.70 g. Butanol Methyl Catechol Dimethyl Acetate a. 4-Methyl Catechol 4.75

10 Sr. No. Raw Material Consumption (MT/Month) b. Monochloro Acetic acid 7.26 c. Sodium Hydroxide 4.48 d. HCl 8.50 e. Methanol 2.39 f. Sulphuric Acid 0.40 g. Toluene Bromo-2-Chloro Benzoic Acid a. 2-Chloro Benzoic Acid 6.66 b. N-Bromosuccinimide 7.64 c. Toluene Bromo-2-Chloro-4-Ethoxy Benzophenone a. 2-Chloro Benzoic Acid 4.84 b. Bromine 2.35 c. Thionyl Chloride 3.68 d. Aluminium Chloride 4.13 e. Ethoxy Benzene 3.59 f. Toluene g. NaOH Flaks Nitro Veratric Acid a. Veratric Acid 8.02 b. Nitric Acid (69%) 8.04 c. Toluene Diacetone Fructose Pyranose a. D-Fructose 6.99 b. Acetone 4.46 c. Sulphuric Acid 3.77 d. Sodium Hydroxide 3.07 e. MDC Sesamol a. 1,2-Methylene Dioxy Benzene 9.40 b. Acetic Anhydride 7.52 c. Sodium Hydroxide 6.86 d. Methylene Dichloride 57.00

11 Sr. No. Raw Material Consumption (MT/Month) e. Zinc Chloride 1.00 f. Hydrogen Peroxide 5.25 g. Formic Acid 3.33 h. p-toluene Sulphonic Acid 0.50 i. Sodium Acetate 0.50 j. Toluene k. Sulphuric Acid 5.79 l. Methanolic Sodium Methoxide (30%) Veratric Acid a. Veratrole b. Acetylchloride 4.31 c. Aluminium Chloride 9.67 d. Sodium Hypochlorite e. Sodium Bisulphite 5.71 f. EDC g. Sodium Hydroxide 4.39 h. Sulphuric Acid 10.76

12 STORAGE DETAILS OF RAW MATERIALS AND PRODUCTS Annexure 5 Sr. No. Substance Chemical Formula CAS No. State RAW MATERIAL EXISTING Method of Storage Storage Capacity per Month in MT Means of Transportation 1. PCBA C 7 H 5 ClO Solid HDPE Bags Truck Load 2. Sodium Nitrate NaNO Solid HDPE Bags Truck Load 3. Thionyl Chloride SOCl Liquid HDPE Carboy Truck Load 4. Aluminium Chloride AlCl Solid HDPE Bags Truck Load 5. Benzene C 6 H Liquid HDPE Drum Truck Load 6. Liquor Ammonia NH 4 OH / NH 5 O Liquid HDPE Drum Truck Load 7. Caustic Soda Lye NaOH Liquid HDPE Drum Truck Load 8. Sulphur S Solid HDPE Bags Truck Load 9. Thiourea CH 4 N 2 S Solid HDPE Bags Truck Load 10. Dimethyl Sulphate C 2 H 6 O 4 S Liquid HDPE Drum Truck Load 11. MCF C 2 H 3 ClO Liquid HDPE Carboy Truck Load 12. Acetic acid C 2 H 4 O Liquid HDPE Drum Truck Load PROPOSED 13. Guaiacol C 7 H 8 O Liquid HDPE Drum Truck Load 14. Ethylene Dichloride C 2 H 4 Cl Liquid HDPE Drum Truck Load 15. Sodium Hydroxide Flaks NaOH Solid HDPE Bags Truck Load 16. Potassium Phthalimide C 8 H 4 KNO Solid HDPE Bags Truck Load

13 Sr. No. Substance Chemical Formula CAS No. State Method of Storage Storage Capacity per Month in MT Means of Transportation 17. Toluene C 7 H Liquid HDPE Drum Truck Load 18. Methanol CH 3 OH Liquid HDPE Drum Truck Load 19. 1, 3- Dihydroxy Benzene C 6 H 6 O Solid HDPE Bags Truck Load 20. Dimethyl Sulphate C 2 H 6 O 4 S Liquid MS Drum Truck Load 21. Benzene C 6 H Liquid HDPE Drum Truck Load 22. Acetyl Chloride CH 3 COCl Liquid HDPE Drum Truck Load 23. Aluminium Chloride AlCl Solid HDPE Bags Truck Load 24. Sodium Hypo Chlorite NaOCl Liquid Tanker Tanker Load 25. Sodium Bisulphite NaHSO Solid HDPE Bags Truck Load 26. Sulphuric Acid H 2 SO Liquid HDPE Carboy Truck Load 27. 1,4- Dihydroxy Benzene C 6 H 6 O Solid HDPE Bags Truck Load 28. Acetyl Chloride CH 3 COCl Liquid HDPE Drum Truck Load 29. Epichlorhydrine C 3 H 5 ClO Liquid HDPE Drum Truck Load 30. 1,4-Dimethoxy Benzene C 8 H 10 O Solid HDPE Bags Truck Load 31. Zinc Chloride ZnCl Solid HDPE Bags Truck Load 32. Acetic Anhydride C 4 H 6 O Solid HDPE Bags Truck Load 33. Hydrobromic Acid HBr Liquid HDPE Carboy Truck Load 34. Hydrogen Peroxide H 2 O Liquid HDPE Carboy Truck Load 35. 3,4-Dimethoxy Benzoic Acid (CH 3 O) 2 C 6 H 3 CO 2 H Solid HDPE Bags Truck Load 36. Bromine Br 2 - Liquid Glass Bottle Truck Load 37. Hydrochloric Acid HCL Liquid HDPE Drum Truck Load

14 Sr. No. Substance Chemical Formula CAS No. State Method of Storage Storage Capacity per Month in MT Means of Transportation 38. Veratrole C 8 H 10 O Liquid HDPE Drum Truck Load 39. Formaldehyde CH 2 O Gas HDPE Drum Truck Load 40. Acetic Acid C 2 H 4 O Liquid HDPE Drum Truck Load 41. Dimethoxy Benzene C 8 H 10 O Liquid HDPE Drum Truck Load 42. Mono Ethanol Amine C 2 H 7 NO Liquid HDPE Drum Truck Load 43. Acetonitrile C 2 H 3 N Liquid HDPE Drum Truck Load 44. Catechol C 6 H 6 O Solid HDPE Bags Truck Load 45. Diethyl Sulphate C 4 H 10 SO Liquid HDPE Drum Truck Load 46. 1,2-Dimethoxy Benzene C 8 H 10 O Liquid HDPE Drum Truck Load 47. P-Cresol C 7 H 8 O Solid HDPE Bags Truck Load 48. Butanol C 4 H 10 O Liquid HDPE Drum Truck Load Methyl Catechol C 7 H 8 O Solid HDPE Bags Truck Load 50. Monochloro Acetic Acid C 2 H 3 O 2 Cl Solid HDPE Bags Truck Load Chloro Benzoic Acid C 7 H 5 ClO Solid HDPE Bags Truck Load 52. N-Bromo Succinimide C 4 H 4 BrNO Solid HDPE Bags Truck Load 53. Thionyl Chloride SOCl Liquid HDPE Drum Truck Load 54. Ethoxy Benzene C 8 H 10 O Liquid HDPE Drum Truck Load 55. Veratric Acid (CH 3 O) 2 C 6 H 3 CO 2 H Solid HDPE Bags Truck Load 56. Nitric Acid HNO Liquid HDPE Drum Truck Load 57. D-Fructose C 6 H 12 O Solid HDPE Bags Truck Load 58. Acetone C 3 H 6 O Liquid HDPE Drum Truck Load

15 Sr. No. Substance Chemical Formula CAS No. State Method of Storage Storage Capacity per Month in MT Means of Transportation 59. Methylene Dichloride CH 2 Cl Liquid HDPE Drum Truck Load 60. 1,2-Methylene Dioxy Benzene C 7 H 6 O Liquid HDPE Drum Truck Load 61. Zinc Chloride ZnCl Solid HDPE Bags Truck Load 62. Toluene C 7 H Liquid HDPE Drum Truck Load 63. Formic acid CH 2 O Liquid HDPE Drum Truck Load 64. P-Toluene Sulphonic Acid C 7 H 8 O 3 S Solid HDPE Bags Truck Load 65. Sodium Acetate C 2 H 3 NaO Solid HDPE Bags Truck Load 66. Methanolic Sodium Methoxide CH 3 ONa Liquid HDPE Drum Truck Load PRODUCT EXISTING 1. Mebendazole C 16 H 13 N 3 O Solid HDPE Bags Truck Load PROPOSED 2. 2-(2-Methoxy Phenoxy) Ethyl Phthalimide C 17 H 15 NO Solid HDPE Bags Truck Load 3. 2,4-Dimethoxy Benzoic Acid (CH 3 O) 2 C 6 H 3 CO 2 H Solid HDPE Bags Truck Load 4. 2,5-Dimethoxy Benzoic Acid (CH 3 O) 2 C 6 H 3 CO 2 H Solid HDPE Bags Truck Load 5. 2-[(2-Methoxy Methyl] Oxirane Phenoxy) C 10 H 12 O Liquid HDPE Drum Truck Load Bromo Dimethoxy Acetophenone 2-Bromo 4, 5 - Dimethoxy Benzoic Acid (CH 3 O) 2 C 6 H 3 COCH 2 Br Solid HDPE Bags Truck Load BrC 6 H 2 (OCH 3 ) 2 CO 2 H Solid HDPE Bags Truck Load 8. 2-Bromo 4, 5 - Dimethoxy C 9 H 10 Br 2 O Liquid HDPE Drum Truck Load

16 Sr. No. Substance Chemical Formula CAS No. State Method of Storage Storage Capacity per Month in MT Means of Transportation Benzyl Bromide 9. 2-Bromo Dimethoxy Acetophenone C 10 H 11 BrO Solid HDPE Bags Truck Load Methyl 2-Oxazoline C 4 H 7 NO Liquid HDPE Drum Truck Load 11. 3,4-Diethoxy Benzoic Acid C 11 H 14 O Solid HDPE Bags Truck Load 12. 3,4-Dimethoxy Acetophenone (CH 3 O) 2 C 6 H 3 COCH Solid HDPE Bags Truck Load Bromo Veratrole C 8 H 9 BrO Liquid HDPE Drum Truck Load Methyl Catechol C 7 H 8 O Solid HDPE Bags Truck Load Methyl Catechol Dimethyl Acetate C 13 H 16 O Solid HDPE Bags Truck Load Bromo-2-Chloro Benzoic Acid C 7 H 4 BrClO Solid HDPE Bags Truck Load Bromo-2-Chloro-4-Ethoxy Benzophenone C 15 H 12 BrClO Solid HDPE Bags Truck Load Nitro Veratric Acid C 9 H 9 NO Solid HDPE Bags Truck Load 19. Diacetone Fructose Pyranose C 12 H 20 O Solid HDPE Bags Truck Load 20. Sesamol C 7 H 6 O Solid HDPE Bags Truck Load 21. Veratric Acid (CH3O) 2 C 6 H 3 CO 2 H Solid HDPE Bags Truck Load HAZARDOUS WASTE (BY PRODUCT) 1. Dil HCl Solution HCl - Liquid HDPE Drums 5.00 Truck Load 2. Aluminum Chloride Solution (Mfg. For PAC ) AlCl 3 - Liquid HDPE Drums 5.00 Truck Load 3. Zinc Chloride Solution ZnCl 2 - Liquid HDPE Drums 5.00 Truck Load

17 Sr. No. Substance Chemical Formula CAS No. State Method of Storage Storage Capacity per Month in MT Means of Transportation 4. Ammonium Sulphate Solution (NH4) 2 SO 4 - Liquid HDPE Drums Truck Load 5. Sodium Bromide Solution NaBr - Liquid HDPE Drums 7.00 Truck load 6. Sodium Sulphate Na 2 SO 4 -- Solid HDPE Bags 5.00 Truck Load

18 1. 2-(2-METHOXY PHENOXY) ETHYL PHTHALIMIDE Process Description: Charge Guaiacol, Ethyelene Dichloride, Sodium Hydroxide Flaks, Potassium Pthalimide, Toluene and Water in a reactor. Maintain the reaction mass at its desired temperature and condition. Apply cooling and separate the aq. layer for effluent and organic layer for Toluene recovery and crude product. Crude product is further recrystallize in water centrifuge it and dry the crude product and aq. Layer discard for effluent. Crude product further purified in Methanol after purification Methanol is recover and discard distillation tarry waste and dry product is pack for sale.

19 2. 2,4-DIMETHOXY BENZOIC ACID Process Description: Charge 1,3-Dihydroxy Benzene, Dimethyl Sulphate, Sodium Hydroxide, Benzene and water in a reactor. Maintain the reaction mass at its desired temperature and separate the reaction mass for Benzene recovery and aq. layer for effluent. Crude obtain form organic layer is further treated with Ethylene Dichloride, Acetyl Chloride, Aluminium Chloride and Sodium Hypochlorite in a reactor then add water and Sodium Bisulphite in a reactor and maintain reaction mass at its desired temperature and condition. Then after completion of reactor separate the Aluminium Chloride Solution and organic layer for distillation for Ethylene Dichloride recovery and crude product. The crude product is further process with Sodium Hydroxide, Ethylene Dichloride, Sulphuric Acid and water in a reactor. Centrifuge the product, centrifuge mother liquor is separate for organic layer and aqueous layer for effluent. Organic layer distilled for solvent recovery and centrifuge products is dry and pack for sale.

20 3. 2,5-DIMETHOXY BENZOIC ACID Process Description: Charge 1,4-Dimethoxy Benzene, Dimethyl Sulphate, Sodium Hydroxide, Benzene and Water in a reactor. Maintain the reaction mass at its desired temperature and separate the reaction mass for EDC recovery and aq. layer for effluent. Crude obtain form organic layer is further treated with Ethylene Dichloride, Acetyl Chloride, Aluminium Chloride and Sodium Hypochlorite in a reactor then add Water and Sodium Bisulphite in a reactor and maintain reaction mass at its desired temperature and condition. Then after completion of reactor separate the Aluminium Chloride solution and organic layer for distillation for Ethylene Dichloride recovery and crude product. The crude product is further process with Sodium Hydroxide, Ethylene Dichloride, Sulphuric Acid and Water in a reactor. Centrifuge the product, centrifuge mother liquor is separate for organic layer and aqueous layer for effluent. Organic layer distilled for solvent recovery and centrifuge products is dry and pack for sale.

21 4. 2-[(2-METHOXY PHENOXY) METHYL] OXIRANE Process Description: Charge Guaiacol, Epichlorhydrine, Sodium Hydroxide, Toluene and Water in a reactor. Maintain Reaction mass at its desired temperature and condition. Then apply cooling and separate aq. layer for effluent and organic layer for Toluene recovery and product distillation.

22 BROMO DIMETHOXY ACETOPHENONE Process Description: Charge 1,4-Dimethoxy Benzene, Sodium Hydroxide, Dimethyl Sulphate, Ethylene Dichloride in to a reactor. Then maintain it at suitable temperature and condition separate the product and aq. layer for effluent. Above product is further process with Acetic Anhydride and Zinc Chloride and water in a reactor and obtained product is carry for next stage. And it is further process with Hydrobromic acid and Hydrogen Peroxide with water and maintains reaction mass at its desired temperature. Apply cooling and centrifuge the product and aq. layer for effluent.

23 6. 2-BROMO 4, 5 - DIMETHOXY BENZOIC ACID Process Description: Charge Dimethoxy Benzoic Acid, Bromine, Hydrochloric Acid and Water in a Reactor. Maintain the reaction mass at its desired temperature and condition. Centrifuge the product aq. layer is for effluent and product is dried and pack for sale.

24 7. 2-BROMO 4, 5 - DIMETHOXY BENZYL BROMIDE Process Description: Charge EDC in glass line reactor and charge Veratrol stirred than charge HBr (48%) and addition H 2 O 2 (50%) at its desired temperature and stirred after addition over. Separation done. Aqueous layer EDC extraction & EDC layer water wash & distil out EDC. Collect crude charge in Acetic Acid and charge p-formaldehyde stirred and addition HBr in Acetic Acid in a reactor. Dumping in water product collect in Toluene and distilled out Toluene.

25 8. 2-BROMO DIMETHOXY ACETOPHENONE Process Description: Charge Dimethoxy Benzene, EDC, Acetyl Chloride, Aluminium Chloride and Bromine in a reactor. Maintain reaction mass at its desired temperature and condition. Apply cooling and dumping reaction mass in dumping vessel with water. Separate out organic layer for EDC recovery and crude for next process and Aluminium Chloride Solution manufacturing for PAC. Crude is crystallize in water and centrifuge it and dry it, aq. layer for effluent and dry product for sale.

26 9. 2-METHYL 2-OXAZOLINE Process Description: Charge Mono Ethanol Amine and Acetonitrile in a reactor and maintain reaction mass at its desired temperature and condition. During the reaction Ammonia is generated so for that add Sulphuric and Water to scrub the Ammonia which make dilute Ammonium Sulphate solution for sale. After maintain the reaction mass distilled out product in high vacuum and discard the tarry waste.

27 10. 3,4-DIETHOXY BENZOIC ACID Process Description: Charge 1,3-Dihydroxy Benzene, Diethyl Sulphate, Sodium Hydroxide, Benzene and Water in a reactor. Maintain the reaction mass at its desired temperature and separate the reaction mass for Benzene recovery and aq. layer for effluent. Crude obtain form organic layer is further treated with Ethylene Dichloride, Acetyl Chloride, Aluminium Chloride and Sodium Hypochlorite in a reactor then add Water and Sodium Bisulphite in a reactor and maintain reaction mass at its desired temperature and condition. Then after completion of reactor separate the Aluminium Chloride Solution and organic layer for distillation for Ethylene Dichloride recovery and crude product. The crude product is further process with Sodium Hydroxide, Ethylene Dichloride, Sulphuric Acid and water in a reactor. Centrifuge the product, centrifuge mother liquor is separate for organic layer and aqueous layer for effluent. Organic layer distilled for solvent recovery and centrifuge products is dry and pack for sale.

28 11. 3,4-DIMETHOXY ACETOPHENONE Process Description: Charge 1,2-Dimethoxy Benzene, Acetyl Chloride, Ethylene Dichloride, Aluminium Chloride and water in a reactor and maintain reaction mass at its desired temperature. Apply cooling and separate the Aluminium Chloride Solution and organic layer is distilled for Ethylene Dichloride recovery, crude product is packed and sale.

29 12. 4-BROMO VERATROLE Process Description: Charge Veratrole, Ethylen Dichloride, Hydrogen Peroxide and Hydro Bromic Acid in a reactor. Maintain the reaction mass at its desired temperature. Apply cooling and separate the Organic layer and aqueous layer send to ETP. Organic layer for distillation of solvent and crude product in high vacuum distillation.

30 13. 4-METHYL CATECHOL Process Description: P-Cresol, Ethylene Dichloride and Water are charged to the reactor vessel followed by addition of HBr solution and Hydrogen Peroxide one by one respectively and the reaction is maintain at desire temperature. Distilled out the Ethylene Dichloride and thus the crude obtain is further process with Sodium Hydroxide, Sulphuric Acid, Butanol and Water. Separate the aqueous layer and organic layer. Butanol is distll out and followed by product. Product is ready for pack to selling.

31 14. 4-METHYL CATECHOL DIMETHYL ACETATE Process Description: Charge 4-Methyl Catechol Mono Chloro Acetic Acid, Sodium Hydroxide and Hydrochloric Acid in a reactor. Maintain the reaction mixture at its desired temperature and condition. Thenapply cooling and centrifuge the mass and dry the reaction mass and it is further reacted with Methanol in presence of Sulphuric Acid, Toluene and water.then centrifuge it,centrifuge aqueous mother liquor discarded to ETP and organic layer for toluene recovery.product is dry for sale.

32 15. 5-BROMO-2-CHLORO BENZOIC ACID Process Description: Charge 2-Chloro Benzoic Acid, N-bromosuccinimide, Toluene and water in a reactor. Maintain the reaction mass at its desired temperature and condition. Apply cooling and centrifuge the product. Centrifuge product is drying in dryer and centrifuge mother liquor is separate for Toluene recovery and aq. layer for effluent.

33 16. 5-BROMO-2-CHLORO-4-ETHOXY BENZOPHENONE Process Description: Charge 2-Chlorobenzoic Acid, Toluene, Bromine in a reactor. Maintain it and start addition of Thionyl Chloride and Aluminium Chloride in a reactor. Maintain Mass at its desired temperature and condition then dump the mass in a water and separate Aluminium Chloride Solution and organic layer for Toluene distillation and collect product.

34 17. 6-NITRO VERATRIC ACID Process Description: Charge Veratric Acid, Toluene, Water in a rector and then slowly start addition of Nitric Acid in a reactor. Maintain it its desired temperature and condition. After maintain the reaction mass centrifuge it then separate the centrifuge mother liquor for Toluene recovery and aq. layer for effluent and centrifuge product for dry for pack and sale.

35 18. DIACETONE FRUCTOSE PYRANOSE Process Description: Charge D-Fructose, Acetone, Sulphuric Acid and Sodium Hydroxide in a rector. Maintain reaction mixture at its desired temperature. Apply cooling and filter Sodium Sulphate and crude is further treated with Methylene Dichloride and water. Separate the aq. Layer for effluent and organic layer for Methylene Dichloride recovery and crude is further re-crystallize by water. Centrifuge the mother liquor and centrifuge product is dry for pack and sale.

36 19. SESAMOL Process Description: 1,2-Methylene Dioxy Benzene, Acetic Anhydride, Sodium Hydroxide, Methylene Dichloride and Zinc Chloride and Water are charge to the reactor vessel and maintain at its desire temperature. Then followed by dump the mass in water and thus organic and aqueous layer are separated. Discard aqueous layer and distill out Methylene Dichloride and crude for the next process from organic layer. Obtain crude was further Process with Hydrogen Peroxide, Formic Acid with the use of catalyst and solvent like Toluene. Reaction is maintain and separate out organic layer and aqueous layer. Organic layer, distill out Toluene and followed by crude is further processed with Sodium Hydroxide, Methanol and Sulphuric Acid. A product is obtained and filters out it and evaporates to dryness. The dry product is pack to sale.

37 20. VERATRIC ACID Process Description: Charge Veratrole, Ethylene Dichloride, Acetyl Chloride, Aluminium Chloride and Sodium Hypochlorite in a reactor then add Water and Sodium Bisulphite in a reactor and maintain reaction mass at its desired temperature and condition. Then after completion of reactor separate the Aluminium Chloride solution and organic layer for distillation for Ethylene Dichloride recovery and crude product. The crude product is further process with Sodium Hydroxide, Ethylene Dichloride, Sulphuric Acid and water in a reactor. Centrifuge the product, centrifuge mother liquor is separate for organic layer and aqueous layer for effluent. Organic layer distilled for solvent recovery and centrifuge product is dry and packs for sale.

38 ANNEXURE 7 Source of Water: GIDC, Ankleshwar Sr. No. Category WATER CONSUMPTION & WASTE WATER GENERATION WATER CONSUMPTION (KL/day) Existing Proposed Total After Expansion WASTEWATER GENERATION (KL/day) Existing Proposed Total After Expansion 1. Domestic 1.00 Nil Nil 1.00 i. TOTAL 1.00 Nil* Nil* 1.00 Industrial 2. Process ** ** Washing Boiler Cooling Scrubber # *** Gardening ii. TOTAL GRAND TOTAL (i + ii + iii) Note: * Granted quantity is sufficient after addition of proposed products. ** Maximum water consumption and waste water generation take in product no. 15 (i.e. 5-Bromo-2-Chloro Benzoic Acid). # Maximum scrubber water consumption takes place in product no. 9 (i.e. 2-Methyl 2-Oxazoline). *** Maximum scrubber waste water generation take place in product no. 16 (i.e. 5-Bromo-2-Chloro-4-Ethoxy Benzophenone).

39 DISPOSAL OF WASTEWATER: EXISTING: 1. Domestic effluent shall be disposed in to Septic tank / Soak pit system. 2. Industrial wastewater generated from manufacturing process and other ancillary operation shall be allowed into in-house ETP for primary treatment. Treated water will be sent to M/s. NCTL for its further treatment and final disposal. PROPOSED: 1. Domestic effluent shall be disposed in to Septic tank / Soak pit system. 2. Industrial effluent after primary treatment into ETP, it is esteemed that 3.00 m 3 /day of waste water is disposed to CETP of M/s. ETL after getting prior permission from GPCB, as we have already permission for only 3.00 m 3 /day for disposal in CETP. For proposed quantity (15.45 m 3 /day), it will be allowed in to in-house ETP for primary treatment. Then primary treated water will be sent to common MEE facility M/s. Ankleshwar Cleaner Process Technology Centre Ltd. (ACPTCL) for final disposal.

40 ANNEXURE 8 DESCRIPTION OF EFFLUENT TREATMENT PLANT (EXISTING) Effluent generated from the process and other ancillary operation is directly goes to collection tank no. 1. Then primary and neutralization treatment by Soda Ash and further treatment by Hydrogen Peroxide and Ferrous Sulphate given to ETP tank no 2. Sludge is filtered and mother liquor goes to ETP tank no 3. From there treated water will goes to CETP of M/s. NCTL for its further treatment. Dried sludge is transfer to Hazardous Waste Storage Area for its final disposal to TSDF site. DESIGN DATA OF EFFLUENT TREATMENT PLANT Sr. No. Name of the unit Size/Capacity Qty. 1. Tank No. 1 7 x 6.1 x Tank No x 7.9 x Tank No. 3 6 x 8.1 x ETP Tank No 1 Effluent Collection tank ETP Tank No 2 Primary treat. And neutralization (Peroxide + Ferrous sulphate treatment) Effluent Sludge Filtration ETP Tank No 3 Send to NCTL

41 DESCRIPTION OF EFFLUENT TREATMENT PLANT (PROPOSED) Effluent generated from the process and other ancillary operation will be directly goes to collection tank no. 1. Then primary and neutralization treatment by Soda Ash and further treatment by Hydrogen Peroxide and Ferrous Sulphate given to ETP tank no 2. Sludge will be filtered and mother liquor goes to ETP tank no 3. From there 3.0 m 3 /day of primary treated water will goes to CETP of M/s. ETL after getting prior permission from GPCB for its further treatment and other quantity of treated water will be sent to common MEE facility M/s. Ankleshwar Cleaner Process Technology Centre Ltd. (ACPTCL) for final disposal. Dried sludge will transfer to Hazardous Waste Storage Area for its final disposal to TSDF site. DESIGN DATA OF EFFLUENT TREATMENT PLANT Sr. No. Name of the unit Size/Capacity Qty. 1. Tank No. 1 7 x 6.1 x Tank No. 2 7 x 8 x Tank No. 3 6 x 8.1 x ETP Tank No 1 Effluent Collection tank ETP Tank No 2 Primary treat. And neutralization (Peroxide + Ferrous sulphate treatment) Effluent Sludge Filtration ETP Tank No 3 To Common MEE of M/s. ACPTCL 3.0 KL/Day Send to ETL

42 DETAILS OF FUEL & PROCESS GAS EMISSION ANNEXURE 9 Stack Attached to Stack Height & Dia. Fuel Consumption Air Pollution Control System Parameters Permissible Limit Industrial Boiler (Capacity: 800 Kg/Hr) Reaction Vessels-1 Thermic Fluid Heater (Capacity: 5.0 Lac Kcal/Hr) D. G. Set 01 Nos. (Stand by) (Capacity: 250 KVA) Reaction Vessels-2 Reaction Vessels m & 0.30 m 11.0 m & 0.15 m 15.0 m & 0.30 m 7.0 m & 0.15 m 12.0 m & 0.15 m Natural Gas 400 m 3 /day Existing Not Required -- Scrubber Natural Gas 900 m 3 /day HSD 68 L/Hr -- Proposed Not Required Not Required PM SO 2 NO X SO 2 HCl Chlorine Ammonia H 2 S PM SO 2 NO X 150 mg/nm ppm 50 ppm 40 mg/nm 3 20 mg/nm 3 09 mg/nm mg/nm 3 45 mg/nm mg/nm ppm 50 ppm Acid Scrubber NH mg/nm 3 Water Scrubber SO 2 HCl 40 mg/nm 3 20 mg/nm 3 Note: Unit will install one stand by D. G Set which will be used in case of power failure or emergency. NH 3 gas generated from reaction column will be scrubbed into acid scrubber by using H 2 SO 4 and generated Ammonium Sulphate solutions recovers as a byproduct. HCl generated from reaction column will be scrubbed into water scrubber. Generated Dil. HCl solution recovers as a by-product.

43 HAZARDOUS/SOLID WASTE GENERATION & IT S MANAGEMENT ANNEXURE 10 Sr. No Type of Waste Empty Barrels / Containers / Liners Contaminated with Hazardous Chemicals / Wastes Chemical Sludge from Waste Water Treatment Used or Spent Oil Distillation Residue Aluminum Chloride Dil. Solution HCl Category Source of Generation Raw material & Finished product packing material Effluent Treatment Plant Thermopack & D. G Set Quantity (MT/Year) Total After Existing Additional Expansion Process Process (By- Products) Zinc Chloride Ammonium Sulphate Sodium Bromide Solution Sodium Sulphate Disposal Collection, Storage, Reuse, Transportation & Disposal by selling it authorized decontamination to GPCB Registered Vendor after Detoxification & Decontamination Collection, Storage, Transportation & Disposal at TSDF site BEIL for secured landfill. Collection, Storage, Transportation & Disposal by reuse in plant & machinery as lubricant or sell it to authorized re-refiners / recyclers. Collection, Storage, Transportation and Disposal at TSDF site for incineration. Collection, Storage, Transportation & Disposal by sell out to authorized users who are having authorization with valid CCA and rule 9 permission to receive this waste. Note: Unit will get membership of TSDF site for disposal of extra quantity of hazardous waste after getting EC but before start of proposed production.

44 MANAGEMENT OF DOMESTIC WASTE Adequate number of collection bins, separately for biodegradable and non-biodegradable waste will be provided as per Municipal Solid Waste (Management and Handling) Rule, Waste from such bins will be collected separately on daily basis. The non-biodegradable wastes will be sold to recyclers and the biodegradable wastes will be collected and disposed to bin of GIDC.

45 ANNEXURE 11 DETAILS OF FIRE & SEFTY (A) SAFETY PRECAUTION DURING STORAGE, HANDLING & TRANSPORTATION 1. Flame proof type equipments and lighting will be provided. 2. Portable containers such as drums, barrels and carboys are stored and handled carefully. 3. Store room consists of impervious walls and floors and provision for safe disposal of spillage. 4. Before handling, check corrosion of nails or weakening of packing by the chemical. 5. For transporting carboys used carboy trolley. 6. Safe way to empty a carboy is to move liquid by suction from vacuum pump or start the siphon by means of rubber bulb. 7. Before pilling, empty carboys are thoroughly drained and stoppers replaced. 8. Dangerous substance should be handled and stored under the supervision of a competent person who is familiar with the risks and the precautions to be taken. 9. When dangerous substances are to be handled or stored, the workers concerned should be given adequate information concerning their nature and the special precautions to be observed in handling them. 10. Where corrosive substances are handled or stored, special precautions are taken to prevent damage to the containers and to render any spillage harmless. 11. Workers handling harmful substances should thoroughly wash their hands and face with soap and water before taking any food or drink. 12. Proper and sufficient fire fighting arrangement should be provided in and around the storage. 13. Open storage should be protected from direct sun-rays, excessive heat, and continuous dampness and away from highly flammable substances and hot processes. 14. Containers should be always labeled and a strong policy exists with respect to handling, storage and use of flammable materials. 15. The quantity of stored chemicals in a chemical plant at any time should be minimum required quantity for normal working.

46 (B) SAFETY PRECAUTION DURING ACTIVITY 1. In case of doubt as to the nature of the risk or the precautions to be taken, the necessary instructions should be obtained from the MSDS and the competent authority. 2. Special precautions, such as the provision of mats, sling nets, boxes and high sided pallets are taken to prevent breakage of or damage to containers of dangerous substance. 3. If containers of dangerous substances are broken or damaged to a dangerous extent, work to be stopped and the workers concerned removed to a safe place until the danger has been eliminated. 4. Non-Sparking tools are provided and used in explosive atmosphere. 5. Toxic materials are not to be stacked with flammable materials. 6. Volatile materials are kept in a cool shed. 7. While working at storage, process, handling, use or transfer of chemicals, appropriate personal protective equipment like helmet, goggles, face shield, gloves, boots, apron, respirator etc are worn by workers to protect themselves in case of any accidental discharge or exposure. Training for use and maintenance of fire fighting equipments are most essential. (C) SAFETY PRECAUTION DUE TO UTILITY 1. Water sensitive chemicals are stored in a watertight cabinet in a cool and dry location segregated from all other chemicals. 2. Stored chemicals are not exposing directly to heat or sunlight, or highly variable temperatures. 3. Chemicals are not stored in the personal staff refrigerators, even temporarily. 4. Chemicals are not stored with food and drink. 5. All employees are informed about skin irritants and provided with approved protective equipment or devices and regular medical checkup are maintained to ensure that there is no ill effect. 6. Substances which are decompose dangerously under the influence of air, elevated temperature or pressure, or contact with catalyst, appropriate safety measures contained in the written procedure are followed. 7. Chemicals which are spilled or contaminated should not be simply discarded in the refuse bin, but disposed of according to instruction from the supervision.