-~~ Barbara Johnson, PE Associate

Transcription

1 <!/jt Golder Associates March 24, 2017 Project No.: Metropolitan Council Environmental Services Industrial Waste Division 390 Robert St. N. St. Paul, MN Attention: Ms. Ashley Corbeille RE: FEBRUARY 2017 SAMPLING RESULTS SMR INDUSTRIAL DISCHARGE PERMIT NUMBER 2289 SOUTHEAST PUMP AND TREAT SYSTEM CANADIAN PACIFIC SHOREHAM FACILITY Dear Ms. Corbeille: On behalf of Canadian Pacific, enclosed is the February 2017 Sampling Results Self-Monitoring Report for the site located at 28th & Central Avenue NE, Minneapolis MN. In accordance with the Metropolitan Council Environmental Services (MCES) Industrial Discharge Permit Number 2289, effective October 1, 2016 (MCES permit), this submittal documents the quality of water discharged from the groundwater pump and treat system owned by Canadian Pacific. Required information for the discharge is provided as follows: Attachment A- Sampling Results - SMR. Attachment B - analytical data from for the February 2017 monthly sampling event. Attachment C - Field Instrument ph Calibration Records Analytical results from the February 2017 sampling event 1 showed that the treated discharge water was in compliance with the MCES permit discharge limitations during this reporting period. If you have any questions or comments, please do not hesitate to contact Barbara Johnson at (651) Thank you for your assistance in this matter. Very truly yours, GOLDER ASSOCIATES INC. At~l?l/ff Alan Phillips Project Geologist -~~ Barbara Johnson, PE Associate Cc: Ms. Aimee Zack, CP Ms. Claire Mackler, Golder 1 Note that sample point SP-01 is identified as sample SE EFFLUENT in the analytical results from February 2017 (Attachmen_t_B... ~ Golder Associates Inc West County Rd. B, Ste. 105 Roseville, MN USA Tel: (651) Fax: (651) Golder Associates: Operations in Africa, Asia, Australasia, Europe, North America and South America

2 Attachment A SAMPLING RESULTS SELF-MONITORING REPORT

3 Metropolitan Council Environmental Services Industrial Waste & Pollution Prevention Section 390 North Robert Street St. Paul, Minnesota For MCES Use Only Permit No: Staff: Received: 0 L 45 E SAMPLING RESULTS - SMR for Standard and Special Discharge Permits Please complete Page 2 of this form for each monitoring point with sampling requirements in Attachment A of the Permit. 1. Permittee Name: Canadian Pacific Railway Permit No: Facility Address: 28th Ave NE & Central Ave NE, Minneapolis, MN Reporting Period: Year: 20_1_1 Choose applicable period below: Quarterly Reporter: [!] Jan-Mar Apr-Jun D Jul-Sep D Oct-Dec Semi-Annual Reporter: D Jan-Jun D Jul-Dec Annual Reporter: D Jan-Dec D No discharge/no sampling this period. If checked, proceed to section 9 below and do not complete page Proper Sampling: Were all samples collected and composited according to permit requirements? [!) Yes r-- 1 No If No, add explanation below: 5. Proper Analysis: Were all analyses conducted per permit requirements? Ej Yes D No If No, add explanation below: 6. Representative DischaJlJ,2: Are the an~ical results representative of the wastewater discharged during this monitoring event? l_!j Yes LJ No If No, add explanation below: 7. Compliance Status: Compare the analytical results with the corresponding discharge limits in your Permit. Do any analytical results exceed the corresponding discharge limit(s) in your Permit? D Yes [!] No If Yes, add explanation below: When did you become aware of the exceedance(s)? 8. General comments regarding submission: Total suspended solids, chemical oxygen demand, are sampled quarterly while volatile organic compounds are sampled monthly. An entry of "NS" in the following sample result tables indicates that the given parameter was not analyzed during the February 2017 sampling event. 9. Certification Statement: "I certify under penalty of law that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to ensure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who manage the system, or those persons directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties under law for submitting false information, including the possibility of fine and imprisonment for known violations." Name (print): Signature: Barbara Johnson, PE 3 / bsjohnson@golder.com Title: Date: Authorized Representative for Canadian Pacific 3j;?/f/;zo/7 Phone: Report form help sheet Page 1 of 2 SMR-SR-2016

4 Sample Results: Submit one result sheet for each sampling day per monitoring point. Enter daily values for each sampling event from one monitoring point, in accordance with requirements in the Industrial Discharge Permit (Section B). Daily and long-term values shall be compared to Discharge Limitations in Permit Section A.1 for compliance determinations. Attach all laboratory data sheets and supporting calculations. Monitoring Point: SP-01 Description: Effluent discharge line Sample Start Date & Time: 2/15/17 12:55 Sample End Date & Time: 2/15/ : ~ Discharge volume through monitoring point on sampling day: 23,250 (estimated) gallons Sample collected by: D Permittee EJ Other, name: Golder Associates Inc. Sample composited by: D Permittee D Other, name: Substance Method of collection: IL!J Manual D Automatic Composite method: N_A Analytical Sample Laboratory Result Unit Detection Limits Analysis Method Sample Method Result Container Type Name ph 7.0 S.U H+ Grab-Single Other Field Measurement Total Suspended Solids NS mg/i Chemical Oxygen Demand NS mg/i 1, 1-Dichloroethane mg/i EPA 8260 Grab - Single Vial - 40ml clear 1, 1-Dichloroethene mg/i EPA 8260 Grab - Single Vial - 40ml clear cis-1,2-dichloroethene mg/i EPA 8260 Grab - Single Vial - 40ml clear T etrach loroethene mg/i EPA 8260 Grab - Single Vial - 40ml clear 1, 1, 1-Trichloroethane mg/i EPA 8260 Grab - Single Vial - 40ml clear Trichloroethene mg/i EPA 8260 Grab - Single Vial - 40ml clear mg/i mg/i mg/i mg/i mg/i mg/i mg/i mg/i Page 2 of 2 SMR-SR-2016

5 Attachment B ANALYTICAL DATA FROM PACE ANALYTICAL SERVICES, LLC February 2017

6 #=CL# LIMS USE: FR - ALISON ZOLL LIMS OBJECT ID: February 20, 2017 Alison Zoll Golder Associates Inc. 744 Broad Street 25th Floor Newark, NJ RE: Pace Project No.: Dear Alison Zoll: Enclosed are the analytical results for sample(s) received by the laboratory on February 16, The results relate only to the samples included in this report. Results reported herein conform to the most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. If you have any questions concerning this report, please feel free to contact me. Sincerely, Laurie Woelfel laurie.woelfel@pacelabs.com Project Manager Enclosures Page 1 of 16

7 #=CP# CERTIFICATIONS Pace Project No.: Green Bay Certification IDs 1241 Bellevue Street, Florida/NELAP Certification #: E87948 Illinois Certification #: Kentucky UST Certification #: 82 Louisiana Certification #: Minnesota Certification #: New York Certification #: North Dakota Certification #: R-150 Virginia VELAP ID: South Carolina Certification #: Texas Certification #: T Wisconsin Certification #: Wisconsin DATCP Certification #: USDA Soil Permit #: P Federal Fish & Wildlife Permit #: LE51774A-0 Page 2 of 16

8 #=SS# SAMPLE SUMMARY Pace Project No.: Lab ID Sample ID Matrix Date Collected Date Received Water 02/15/17 08:00 02/16/17 08: SE EFFLUENT Water 02/15/17 12:55 02/16/17 08:50 Page 3 of 16

9 #=SA# SAMPLE ANALYTE COUNT Pace Project No.: Lab ID Sample ID Method Analysts Analytes Reported Laboratory EPA 8260 HNW 71 PASI-G SE EFFLUENT EPA 8260 HNW 71 PASI-G Page 4 of 16

10 #=AR# ANALYTICAL RESULTS Pace Project No.: Sample: Lab ID: Collected: 02/15/17 08:00 Received: 02/16/17 08:50 Matrix: Water Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 8260 MSV Analytical Method: EPA 8260 Acetone <3.0 ug/l /17/17 14: Allyl chloride <2.2 ug/l /17/17 14: Benzene <0.50 ug/l /17/17 14: Bromobenzene <0.23 ug/l /17/17 14: Bromochloromethane <0.34 ug/l /17/17 14: Bromodichloromethane <0.50 ug/l /17/17 14: Bromoform <0.50 ug/l /17/17 14: Bromomethane <2.4 ug/l /17/17 14: Butanone (MEK) <3.0 ug/l /17/17 14: n-butylbenzene <0.50 ug/l /17/17 14: sec-butylbenzene <2.2 ug/l /17/17 14: tert-butylbenzene <0.18 ug/l /17/17 14: Carbon tetrachloride <0.50 ug/l /17/17 14: Chlorobenzene <0.50 ug/l /17/17 14: Chloroethane <0.37 ug/l /17/17 14: Chloroform <2.5 ug/l /17/17 14: Chloromethane <0.50 ug/l /17/17 14: Chlorotoluene <0.50 ug/l /17/17 14: Chlorotoluene <0.21 ug/l /17/17 14: ,2-Dibromo-3-chloropropane <2.2 ug/l /17/17 14: Dibromochloromethane <0.50 ug/l /17/17 14: ,2-Dibromoethane (EDB) <0.18 ug/l /17/17 14: Dibromomethane <0.43 ug/l /17/17 14: ,2-Dichlorobenzene <0.50 ug/l /17/17 14: ,3-Dichlorobenzene <0.50 ug/l /17/17 14: ,4-Dichlorobenzene <0.50 ug/l /17/17 14: Dichlorodifluoromethane <0.22 ug/l /17/17 14: ,1-Dichloroethane <0.24 ug/l /17/17 14: ,2-Dichloroethane <0.17 ug/l /17/17 14: ,1-Dichloroethene <0.41 ug/l /17/17 14: cis-1,2-dichloroethene <0.26 ug/l /17/17 14: trans-1,2-dichloroethene <0.26 ug/l /17/17 14: Dichlorofluoromethane <0.21 ug/l /17/17 14: ,2-Dichloropropane <0.23 ug/l /17/17 14: ,3-Dichloropropane <0.50 ug/l /17/17 14: ,2-Dichloropropane <0.48 ug/l /17/17 14: ,1-Dichloropropene <0.44 ug/l /17/17 14: cis-1,3-dichloropropene <0.50 ug/l /17/17 14: trans-1,3-dichloropropene <0.23 ug/l /17/17 14: Diethyl ether (Ethyl ether) <2.2 ug/l /17/17 14: Ethylbenzene <0.50 ug/l /17/17 14: Hexachloro-1,3-butadiene <2.1 ug/l /17/17 14: Isopropylbenzene (Cumene) <0.14 ug/l /17/17 14: p-isopropyltoluene <0.50 ug/l /17/17 14: Methylene Chloride <0.23 ug/l /17/17 14: Methyl-2-pentanone (MIBK) <2.1 ug/l /17/17 14: Date: 02/20/ :52 PM Page 5 of 16

11 #=AR# ANALYTICAL RESULTS Pace Project No.: Sample: Lab ID: Collected: 02/15/17 08:00 Received: 02/16/17 08:50 Matrix: Water Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 8260 MSV Analytical Method: EPA 8260 Methyl-tert-butyl ether <0.17 ug/l /17/17 14: Naphthalene <2.5 ug/l /17/17 14: n-propylbenzene <0.50 ug/l /17/17 14: Styrene <0.50 ug/l /17/17 14: ,1,1,2-Tetrachloroethane <0.18 ug/l /17/17 14: ,1,2,2-Tetrachloroethane <0.25 ug/l /17/17 14: Tetrachloroethene <0.50 ug/l /17/17 14: Tetrahydrofuran <2.0 ug/l /17/17 14: Toluene <0.50 ug/l /17/17 14: ,2,3-Trichlorobenzene <2.1 ug/l /17/17 14: ,2,4-Trichlorobenzene <2.2 ug/l /17/17 14: ,1,1-Trichloroethane <0.50 ug/l /17/17 14: ,1,2-Trichloroethane <0.20 ug/l /17/17 14: Trichloroethene <0.33 ug/l /17/17 14: Trichlorofluoromethane <0.18 ug/l /17/17 14: ,2,3-Trichloropropane <0.50 ug/l /17/17 14: ,1,2-Trichlorotrifluoroethane <0.81 ug/l /17/17 14: ,2,4-Trimethylbenzene <0.50 ug/l /17/17 14: ,3,5-Trimethylbenzene <0.50 ug/l /17/17 14: Vinyl chloride <0.18 ug/l /17/17 14: m&p-xylene <1.0 ug/l /17/17 14: o-xylene <0.50 ug/l /17/17 14: Surrogates 4-Bromofluorobenzene (S) 95 % /17/17 14: Dibromofluoromethane (S) 99 % /17/17 14: Toluene-d8 (S) 102 % /17/17 14: Date: 02/20/ :52 PM Page 6 of 16

12 #=AR# ANALYTICAL RESULTS Pace Project No.: Sample: SE EFFLUENT Lab ID: Collected: 02/15/17 12:55 Received: 02/16/17 08:50 Matrix: Water Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 8260 MSV Analytical Method: EPA 8260 Acetone <3.0 ug/l /17/17 10: Allyl chloride <2.2 ug/l /17/17 10: Benzene <0.50 ug/l /17/17 10: Bromobenzene <0.23 ug/l /17/17 10: Bromochloromethane <0.34 ug/l /17/17 10: Bromodichloromethane <0.50 ug/l /17/17 10: Bromoform <0.50 ug/l /17/17 10: Bromomethane <2.4 ug/l /17/17 10: Butanone (MEK) <3.0 ug/l /17/17 10: n-butylbenzene <0.50 ug/l /17/17 10: sec-butylbenzene <2.2 ug/l /17/17 10: tert-butylbenzene <0.18 ug/l /17/17 10: Carbon tetrachloride <0.50 ug/l /17/17 10: Chlorobenzene <0.50 ug/l /17/17 10: Chloroethane <0.37 ug/l /17/17 10: Chloroform <2.5 ug/l /17/17 10: Chloromethane <0.50 ug/l /17/17 10: Chlorotoluene <0.50 ug/l /17/17 10: Chlorotoluene <0.21 ug/l /17/17 10: ,2-Dibromo-3-chloropropane <2.2 ug/l /17/17 10: Dibromochloromethane <0.50 ug/l /17/17 10: ,2-Dibromoethane (EDB) <0.18 ug/l /17/17 10: Dibromomethane <0.43 ug/l /17/17 10: ,2-Dichlorobenzene <0.50 ug/l /17/17 10: ,3-Dichlorobenzene <0.50 ug/l /17/17 10: ,4-Dichlorobenzene <0.50 ug/l /17/17 10: Dichlorodifluoromethane <0.22 ug/l /17/17 10: ,1-Dichloroethane 16.4 ug/l /17/17 10: ,2-Dichloroethane <0.17 ug/l /17/17 10: ,1-Dichloroethene 4.9 ug/l /17/17 10: cis-1,2-dichloroethene 14.8 ug/l /17/17 10: trans-1,2-dichloroethene <0.26 ug/l /17/17 10: Dichlorofluoromethane <0.21 ug/l /17/17 10: ,2-Dichloropropane <0.23 ug/l /17/17 10: ,3-Dichloropropane <0.50 ug/l /17/17 10: ,2-Dichloropropane <0.48 ug/l /17/17 10: ,1-Dichloropropene <0.44 ug/l /17/17 10: cis-1,3-dichloropropene <0.50 ug/l /17/17 10: trans-1,3-dichloropropene <0.23 ug/l /17/17 10: Diethyl ether (Ethyl ether) <2.2 ug/l /17/17 10: Ethylbenzene <0.50 ug/l /17/17 10: Hexachloro-1,3-butadiene <2.1 ug/l /17/17 10: Isopropylbenzene (Cumene) <0.14 ug/l /17/17 10: p-isopropyltoluene <0.50 ug/l /17/17 10: Methylene Chloride <0.23 ug/l /17/17 10: Methyl-2-pentanone (MIBK) <2.1 ug/l /17/17 10: Date: 02/20/ :52 PM Page 7 of 16

13 #=AR# ANALYTICAL RESULTS Pace Project No.: Sample: SE EFFLUENT Lab ID: Collected: 02/15/17 12:55 Received: 02/16/17 08:50 Matrix: Water Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 8260 MSV Analytical Method: EPA 8260 Methyl-tert-butyl ether <0.17 ug/l /17/17 10: Naphthalene <2.5 ug/l /17/17 10: n-propylbenzene <0.50 ug/l /17/17 10: Styrene <0.50 ug/l /17/17 10: ,1,1,2-Tetrachloroethane <0.18 ug/l /17/17 10: ,1,2,2-Tetrachloroethane <0.25 ug/l /17/17 10: Tetrachloroethene 33.4 ug/l /17/17 10: Tetrahydrofuran <2.0 ug/l /17/17 10: Toluene <0.50 ug/l /17/17 10: ,2,3-Trichlorobenzene <2.1 ug/l /17/17 10: ,2,4-Trichlorobenzene <2.2 ug/l /17/17 10: ,1,1-Trichloroethane 12.1 ug/l /17/17 10: ,1,2-Trichloroethane <0.20 ug/l /17/17 10: Trichloroethene 4.8 ug/l /17/17 10: Trichlorofluoromethane <0.18 ug/l /17/17 10: ,2,3-Trichloropropane <0.50 ug/l /17/17 10: ,1,2-Trichlorotrifluoroethane <0.81 ug/l /17/17 10: ,2,4-Trimethylbenzene <0.50 ug/l /17/17 10: ,3,5-Trimethylbenzene <0.50 ug/l /17/17 10: Vinyl chloride <0.18 ug/l /17/17 10: m&p-xylene <1.0 ug/l /17/17 10: o-xylene <0.50 ug/l /17/17 10: Surrogates 4-Bromofluorobenzene (S) 93 % /17/17 10: Dibromofluoromethane (S) 100 % /17/17 10: Toluene-d8 (S) 97 % /17/17 10: Date: 02/20/ :52 PM Page 8 of 16

14 #=QC# QUALITY CONTROL DATA Pace Project No.: QC Batch: QC Batch Method: EPA 8260 Associated Lab Samples: , Analysis Method: Analysis Description: EPA MSV METHOD BLANK: Associated Lab Samples: , Parameter Units Blank Result Matrix: Water Reporting Limit MDL Analyzed 1,1,1,2-Tetrachloroethane ug/l < /17/17 08:20 1,1,1-Trichloroethane ug/l < /17/17 08:20 1,1,2,2-Tetrachloroethane ug/l < /17/17 08:20 1,1,2-Trichloroethane ug/l < /17/17 08:20 1,1,2-Trichlorotrifluoroethane ug/l < /17/17 08:20 1,1-Dichloroethane ug/l < /17/17 08:20 1,1-Dichloroethene ug/l < /17/17 08:20 1,1-Dichloropropene ug/l < /17/17 08:20 1,2,3-Trichlorobenzene ug/l < /17/17 08:20 1,2,3-Trichloropropane ug/l < /17/17 08:20 1,2,4-Trichlorobenzene ug/l < /17/17 08:20 1,2,4-Trimethylbenzene ug/l < /17/17 08:20 1,2-Dibromo-3-chloropropane ug/l < /17/17 08:20 1,2-Dibromoethane (EDB) ug/l < /17/17 08:20 1,2-Dichlorobenzene ug/l < /17/17 08:20 1,2-Dichloroethane ug/l < /17/17 08:20 1,2-Dichloropropane ug/l < /17/17 08:20 1,3,5-Trimethylbenzene ug/l < /17/17 08:20 1,3-Dichlorobenzene ug/l < /17/17 08:20 1,3-Dichloropropane ug/l < /17/17 08:20 1,4-Dichlorobenzene ug/l < /17/17 08:20 2,2-Dichloropropane ug/l < /17/17 08:20 2-Butanone (MEK) ug/l < /17/17 08:20 2-Chlorotoluene ug/l < /17/17 08:20 4-Chlorotoluene ug/l < /17/17 08:20 4-Methyl-2-pentanone (MIBK) ug/l < /17/17 08:20 Acetone ug/l < /17/17 08:20 Allyl chloride ug/l < /17/17 08:20 Benzene ug/l < /17/17 08:20 Bromobenzene ug/l < /17/17 08:20 Bromochloromethane ug/l < /17/17 08:20 Bromodichloromethane ug/l < /17/17 08:20 Bromoform ug/l < /17/17 08:20 Bromomethane ug/l < /17/17 08:20 Carbon tetrachloride ug/l < /17/17 08:20 Chlorobenzene ug/l < /17/17 08:20 Chloroethane ug/l < /17/17 08:20 Chloroform ug/l < /17/17 08:20 Chloromethane ug/l < /17/17 08:20 cis-1,2-dichloroethene ug/l < /17/17 08:20 cis-1,3-dichloropropene ug/l < /17/17 08:20 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Date: 02/20/ :52 PM Page 9 of 16

15 #=QC# QUALITY CONTROL DATA Pace Project No.: METHOD BLANK: Associated Lab Samples: , Parameter Units Blank Result Matrix: Water Reporting Limit MDL Analyzed Dibromochloromethane ug/l < /17/17 08:20 Dibromomethane ug/l < /17/17 08:20 Dichlorodifluoromethane ug/l < /17/17 08:20 Dichlorofluoromethane ug/l < /17/17 08:20 Diethyl ether (Ethyl ether) ug/l < /17/17 08:20 Ethylbenzene ug/l < /17/17 08:20 Hexachloro-1,3-butadiene ug/l < /17/17 08:20 Isopropylbenzene (Cumene) ug/l < /17/17 08:20 m&p-xylene ug/l < /17/17 08:20 Methyl-tert-butyl ether ug/l < /17/17 08:20 Methylene Chloride ug/l < /17/17 08:20 n-butylbenzene ug/l < /17/17 08:20 n-propylbenzene ug/l < /17/17 08:20 Naphthalene ug/l < /17/17 08:20 o-xylene ug/l < /17/17 08:20 p-isopropyltoluene ug/l < /17/17 08:20 sec-butylbenzene ug/l < /17/17 08:20 Styrene ug/l < /17/17 08:20 tert-butylbenzene ug/l < /17/17 08:20 Tetrachloroethene ug/l < /17/17 08:20 Tetrahydrofuran ug/l < /17/17 08:20 Toluene ug/l < /17/17 08:20 trans-1,2-dichloroethene ug/l < /17/17 08:20 trans-1,3-dichloropropene ug/l < /17/17 08:20 Trichloroethene ug/l < /17/17 08:20 Trichlorofluoromethane ug/l < /17/17 08:20 Vinyl chloride ug/l < /17/17 08:20 4-Bromofluorobenzene (S) % /17/17 08:20 Dibromofluoromethane (S) % /17/17 08:20 Toluene-d8 (S) % /17/17 08:20 Qualifiers LABORATORY CONTROL SAMPLE: Parameter Units Spike Conc. LCS Result LCS % Rec % Rec Limits 1,1,1-Trichloroethane ug/l ,1,2,2-Tetrachloroethane ug/l ,1,2-Trichloroethane ug/l ,1,2-Trichlorotrifluoroethane ug/l ,1-Dichloroethane ug/l ,1-Dichloroethene ug/l ,2,4-Trichlorobenzene ug/l ,2-Dibromo-3-chloropropane ug/l ,2-Dibromoethane (EDB) ug/l ,2-Dichlorobenzene ug/l Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Date: 02/20/ :52 PM Page 10 of 16

16 #=QC# QUALITY CONTROL DATA Pace Project No.: LABORATORY CONTROL SAMPLE: Parameter Units Spike Conc. LCS Result LCS % Rec % Rec Limits 1,2-Dichloroethane ug/l ,2-Dichloropropane ug/l ,3-Dichlorobenzene ug/l ,4-Dichlorobenzene ug/l Benzene ug/l Bromodichloromethane ug/l Bromoform ug/l Bromomethane ug/l Carbon tetrachloride ug/l Chlorobenzene ug/l Chloroethane ug/l Chloroform ug/l Chloromethane ug/l cis-1,2-dichloroethene ug/l cis-1,3-dichloropropene ug/l Dibromochloromethane ug/l Dichlorodifluoromethane ug/l Ethylbenzene ug/l Isopropylbenzene (Cumene) ug/l m&p-xylene ug/l Methyl-tert-butyl ether ug/l Methylene Chloride ug/l o-xylene ug/l Styrene ug/l Tetrachloroethene ug/l Toluene ug/l trans-1,2-dichloroethene ug/l trans-1,3-dichloropropene ug/l Trichloroethene ug/l Trichlorofluoromethane ug/l Vinyl chloride ug/l Bromofluorobenzene (S) % Dibromofluoromethane (S) % Toluene-d8 (S) % Qualifiers MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MS Spike Parameter Units Result Conc. MSD Spike Conc MS Result MSD Result MS % Rec MSD % Rec Max % Rec Limits RPD RPD 1,1,1-Trichloroethane ug/l ,1,2,2-Tetrachloroethane ug/l < ,1,2-Trichloroethane ug/l < ,1,2-Trichlorotrifluoroethane ug/l < ,1-Dichloroethane ug/l ,1-Dichloroethene ug/l Qual Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Date: 02/20/ :52 PM Page 11 of 16

17 #=QC# QUALITY CONTROL DATA Pace Project No.: MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MS Spike Parameter Units Result Conc. MSD Spike Conc MS Result MSD Result MS % Rec MSD % Rec Max % Rec Limits RPD RPD 1,2,4-Trichlorobenzene ug/l < ,2-Dibromo-3- ug/l < chloropropane 1,2-Dibromoethane (EDB) ug/l < ,2-Dichlorobenzene ug/l < ,2-Dichloroethane ug/l < ,2-Dichloropropane ug/l < ,3-Dichlorobenzene ug/l < ,4-Dichlorobenzene ug/l < Benzene ug/l < Bromodichloromethane ug/l < Bromoform ug/l < Bromomethane ug/l < Carbon tetrachloride ug/l < Chlorobenzene ug/l < Chloroethane ug/l < Chloroform ug/l < Chloromethane ug/l < cis-1,2-dichloroethene ug/l cis-1,3-dichloropropene ug/l < Dibromochloromethane ug/l < Dichlorodifluoromethane ug/l < Ethylbenzene ug/l < Isopropylbenzene (Cumene) ug/l < m&p-xylene ug/l < Methyl-tert-butyl ether ug/l < Methylene Chloride ug/l < o-xylene ug/l < Styrene ug/l < Tetrachloroethene ug/l Toluene ug/l < trans-1,2-dichloroethene ug/l < trans-1,3-dichloropropene ug/l < Trichloroethene ug/l Trichlorofluoromethane ug/l < Vinyl chloride ug/l < Bromofluorobenzene (S) % Dibromofluoromethane (S) % Toluene-d8 (S) % Qual Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Date: 02/20/ :52 PM Page 12 of 16

18 #=QL# QUALIFIERS Pace Project No.: DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL - Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean-Up U - Indicates the compound was analyzed for, but not detected. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI - The NELAC Institute. LABORATORIES PASI-G Pace Analytical Services - Green Bay Date: 02/20/ :52 PM Page 13 of 16

19 #=CR# QUALITY CONTROL DATA CROSS REFERENCE TABLE Pace Project No.: Lab ID Sample ID QC Batch Method QC Batch Analytical Method Analytical Batch EPA SE EFFLUENT EPA Date: 02/20/ :52 PM Page 14 of 16

20 Company Name: Branch/Location: Project Contact: {Please Print Clearly) 1ceAnaJytical UPPER MIDWEST REGIO~ f ~/" MN: ~700 WI: 9\~69-24b Je't'YI ~vj '. I Quote#: i -- - Phone: CHAIN OF CUSTODY Mail To Contact: *Preservation Codes Project Number: A=None B=HCL C=H2S04 D=HN03 E=DI Water F=Methanol G=NaOH Project Name: Project State: Sampled By (Print): H=Sodium Bisulfate Solution FILTERED? (YES/NO)!=Sodium Thiosulfate J=Other Mall To Company: Mail To Address: Invoice To Contact: of Page 15 of 16,1LJS/ltJ3 Sampled By (Sign): Invoice To Company: PO#: Regulatory Program: Invoice To Address: Data Package Options (bltlable) D EPA Level Ill 0 EPA Level lv PACE LAB# MS/MSD 0 On your sample (billable) 0 NOT needed on your sample CLIENT FIELD ID A=Alr B = Biota Matrix Codes W=Water OW = Drinking Water GW:::: Ground Water SW = Surface Water DATE o 2. l S' l 7-0WO -2-()() I.,,/rr-/111 e>s~ Se eft\v...e ~t ll./'5/111\t 155" Invoice To Phone: CLIENT COMMENTS LAB COMMENTS (lab Use Only) ~ \) Profile# Rush Turnaround Time Requested- Prelims (Rush TAT subject to approval/surcharge) Date Needed: Transmit Prelim Rush Results by (complete what you want): Emall#1: Emall#2:,Telephone: Fax: Samples on HOLD are subject to special pricing and release of llablllty DatefTime: IReceived By: ~;rm DatefTime: Date!Time: (~js I PACE Project No. 4ovl.f 67lt?3 I o oc Receipt Temp=, 3 Sample Receipt ph.dodlet:. / \ OK/ Adjusted itosb Seal r.01!lal?7.!un2006l

21 Sample Condition Upon Receipt Pace Analytical Services, Inc Bellevue Street, Suite 9 -~An-alyticat (-~aa Project#: (Client Name: G2\ J.pr.. W0#: Courier: r Fed Ex UPS i Client r Pace ::>ther: \ J.,,)(t \tc() Tracking#: L C: 2- v Custody Seal on Cooler/Box Present: yes - no Seals inta~es r no Custody Seal on Samples Present: r ye~ no Seals intact: r yes - no Packing Material: p-!:3ubble Wrap _v.-au'bble Bags r~. r Other If II Thermometer Used S )2. -{ 0 Type of Ice: Yyet.. lue Dry None...-p-samples on ice, cooling process has begun Cooler Temperature Uncorr: 3 /Corr "3 10 ogical Tissue is Frozen: r yes Temp Blank Present: ~s rno Temp should be above freezing to 6 C for all sample except Biota. Frozen Biota Samples should be received s o c. Chain of Custody Present: ~es ONo ON/A 1. Chain of Custody Filled Out:,Z!Yes ONo ON/A 2. Chain of Custody Relinquished: 'es ONo ON/A 3. Sampler Name & Signature on COC: O'fes ONo ON/A 4. Samples Arrived within Hold Time: ~ONo ON/A 5. Comments: - VOA Samples frozen upon receipt 0Yes ONo Datemme: Short Hold Time Analysis (<72hr): 0Yes r.:jno' ON/A 6. Rush Tum Around Time Reauested: 0Yes ~ON/A 7. Sufficient Volume: _,i;a<(es ONo ON/A 8. Correct Containers Used: 0Yes ONo ON/A 9. -Pace Containers Used: )2l'Yes ONo ON/A -Pace IR Containers Used: Oves ONo l;jnra Containers Intact:,,eiYe~ ONo ON/A 10. rno :::o;:+ij\}tents: Initials: ~ Filtered volume received for Dissolved tests Oves ONo~A 11. Sample Labels match COC: ~s ONo ON/A 12. -Includes date/time/id/analysis Matrix: w All containers needing preservation have been checked. (Non-Compliance noted in 13.) 0Yes ONo ptliiia rhn03 r H2S04 rnaoh r NaOH +ZnAct All containers needing preservation are found to be in ~ compliance with EPA recommendation. OYes ONo /A (!:!,t'9~ H2E ~ NaC2':!+Zn~_?~9.:. ~~':! ~12) exceptions: OA, lifonn, TOC, TOX, TOH, ~ Initial when l~ab Std #ID of l~iatet O&G, WIDR., enolics, OTHER: Yes 0No completed preservative ime: Headspace in VOA Vials ( >6mm ): 0Yes ~ ON/A 14. Trip Blank Present: ffies 0No ON/A 15. Trip Blank Custody Seals Present Pace Trip Blank Lot# (if purchased):... )'l? Client Notification/ Resolution: ~ ONo ON/A If checked, see attached form for additional comments LJ Project Manager Review: Date: V/n.efo F-GB-C-031-Rev.03 (9Apri12015) SCUR Form Page 16 of 16

22 Attachment C FIELD INSTRUMENT ph CALIBRATION RECORDS

23 Cft9Gold~ 1\ssocm.tes Field Instrument ph Calibration Records INSTRUMENT (MAKE/MODEL NO.) Sper Scientific/ STANDARD INFORMATION Page _l_of_l_ INSTRUMENT NO. Project Number:----"0'-=23.;;;;...;;6;...;;.1.;;;;...;; ,17... Project Name: GP-Shoreham Yard Standard Vendor: Field Environmental Instruments Prepared Date: NA Where Prepared: NA Purchase Date: 11/17/2016 Expiration Date: Varies Grade: NIA Units: Standard Units Standard 4.0 c Lot# F Ex~ Date 6/14/18 Standard 7.0 c Lot# F Ex~ Date 6/29/18 Standard 10.0 c Lot# F Ex~ Date 5/10/17 DATE TIME TEMP STD INSTRUMENT PASS/ CALIBRATED SAMPLER %DEV (mm/dd/yy) (hr:min) DEGC VALUE RESPONSE FAIL (YES, NO) INITIALS 2/15/(7 I 300 1'1.0 l,o 7~0 0 F 1" Af 2/rr/t 7 / ''.)()) f3.5 ~to t-t.. o 0 p y.h L/fV 17 \ 30'1 ;~,o ro.d () p y _jp 11 11/n \filh \6.o 7.0 7~0 ().p 1 IJ-f ' - L{L7ff7 l~o~ ~ ~') uco '-\._o 0 ~ 1 U' - 2-{L1 /l1 H.. oi \ s. ') to. n ff.\.j) () \? '( ~ -., - 3//~ '/7 1)2t) ll.() 7 '-(!) 7.. o 0 f ' l'i 1//)//7 i ')2-6 \'75' li~o ~-0 0 p 1 11-f 3//"f//7 )1;,} I).'> l<' O }<'.(J 0 r 'r!df 3/2-2.//7 lb1'6 l"\1) 7 \(} 7,(J 0 ~ "f j / f 3 /1--1-//7 c...1,0 l6v\2._, ')" \.I,~ 6 ~ v I f P 3JV-/l7 i ~ ''\'7 ''11,- ~.. o,"i \) fj 0 ~ I t'f./ Acceptable calibration check is if the meter reads within +/- 0.2 ph units of the value of appropriate calibration standard. \\MINI V-FS I \Projects\Golder Projects\023 PROJECTS\ Shoreham Yard File Review\East Side Southeast P&T System\Data\2017\pH_ Calibration Form.doc Golder Associates REV-2-03/07