Trace metals geochemical background in soil in the Suape Port and Industrial Complex, Pernambuco Brazil
|
|
- Alvin Robinson
- 6 years ago
- Views:
Transcription
1 The Sustainable City IX, Vol Trace metals geochemical background in soil in the Suape Port and Industrial Complex, Pernambuco Brazil E. Santos de Lima & A. de Souza Moraes Centro de Tecnologia e Geociências, Universidade Federal de Pernambuco-UFPE, Brazil Abstract The implantation of new industries and infrastructure (roads and piers) in the Suape Industrial Portuary Complex together with the weathering action are responsible for the transportation of particulate matter to the surrounding water bodies. A geochemical behavior study of trace metals was done in the watershed of Tatuoca River aiming to show the geochemical affinity among the chemical elements in order to identify its origin. Thirty six soil samples were collected using helical auger samples and four 50 cm long core samples were collected at the bottom of the river using a percussion sampler. The stream sediment core samples were divided into 5 cm intervals. The samples were analyzed by ICP/AES for: Al, Ba, Be, Cd, Co, Cr, Cu, Fe, La, Li, Mo, Ni, Pb, Sc, Sr, Ti, V, Y, Zn and Zr. Principal component analysis and concentration maps were used to interpret the data. Comparing the soil results to that of stream sediment profiles one can conclude that the stream sediments collected closer to the infrastructure and industrial implementation works are richer in sand fraction, Mo, Zr and Zn. On the other hand, the stream sediment profile further away from the construction works are richer in Fe, Cr, V, Ni, Cd and Pb. The understanding of the geochemical behavior of chemical elements present in the watershed (geogenic or anthropogenic) is important in land use occupation and also in establishing a local background value to evaluate future environmental impacts due to trace metals present in stream sediments. Keywords: soil and stream sediments, trace and heavy metals, background metal level. doi: /sc141462
2 1722 The Sustainable City IX, Vol. 2 1 Introduction The Suape Complex is an industrial and harbor business area in Brazil. Many industries are operating (e.g. petrochemical plants, shipyards, food processing, etc.) in this complex and several other are being in process of concluding their plants to begin operation (refinery, shipyards, etc). The Tatuoca River is part of the Suape estuarine system whose catchment area is totally included in the Suape area. The sanity of estuarine ecosystems can be evaluated through the monitoring of their bottom sediments. Some chemical elements that have a known toxic potential are often used as quality indicator of bottom sediments [1, 2, 6 8]. It is not uncommon that bottom sediments are influenced by the soils present in the basin catchment area. So it is important to consider the geogenic contribution to the present chemical composition of bottom sediments. Even though it is very difficult to separate anthropogenic from the geogenic source in this work we will try to establish if the trace element is from natural or anthropogenic origin. In the Tatuoca River basin sugar-cane plantation was the main land use for centuries, so the soil may contain residuals of fertilizers and pesticides and that also could contribute to the present chemical composition of the bottom sediments. Using geochemistry as a monitoring tool one can interpret the processes that occurred in the river basin catchment area and project the future scenario taking into consideration the ongoing pressure and the resilience of the environment. In order to achieve the main objective of this work, it is necessary to use multivariate statistical methods. 2 Materials and methods Soils samples were collected to determine the natural metal contribution to the bottom sediments and the core samples were collected in order to see the time evolution of the bottom sediments in the Tatuoca River and if any anthropogenic source could be detected. The sampling sites are shown in Fig. 1. The 36 soil samples were collected in the area shown as set soil and the 4 bottom sediments core were collected in the points numbered P1 to P4. Core samples P1 and P2 were collected closer to the area where new industries (refinery and petrochemical plant) is being constructed, core sample P3 was collected in a more restricted area, so could represent an environment not impacted by the port activities and the P4 sample collected in an area that may have influence of intense dredging in the port basin. The 36 soil samples were collected using a helical auger samples and were distributed in grid 100m x 100m and were collected at a 50cm depth. The 4 four 50 cm long core samples were collected at the bottom of the river using a percussion sampler with 4cm diameter. The cores were store at 4 C and then divided into 5cm intervals. After the division the subsamples were oven dried at 50 C. The same drying procedure was applied to the soil samples. Afterwards the samples were homogenized in a porcelain mortar and an aliquot of each sample (1g) was solubilized in acqua regia solution in a hot plate at 100 C for 12 hours. After reaching room temperature then the solution was filtered and place in a 50 ml
3 The Sustainable City IX, Vol volumetric flask and volume completed with HNO 3 solution at 5%. The chemical analysis were done by ICP/AES technique were the following elements were determined: Al, Fe, Ca, K, Mg, P, Ti, Ba, Cr, Cu, La, Li, Mo, Ni, Pb, Sc, Sr, V, Y, Zn, Zr. The grain size distribution was achieved by the use of a sieve shaker and separated into sand fraction (>0.063mm) and silt + clay (<0.063mm). Figure 1: Sample location sites at Suape Industrial Port, Pernambuco, Brazil. 3 Results and discussions The mean and standard deviation values of the analysis performed in the soil and sediment samples are shown in table 1. Values below detection limit of the analytical method (MDL) were used in the statistical analyses as 50% of the MDL so all the raw data could be used. 3.1 Soil To better visualize the results of soil analysis, distribution concentration maps were done (Fig. 2). In these maps chromium, nickel and vanadium show a similar surface distribution which is expected due to their natural chemical affinity.
4 1724 The Sustainable City IX, Vol. 2 Table 1: Analytical results for soil and sediment samples (mean and standard deviation values).
5 The Sustainable City IX, Vol Figure 2: Distribution of chromium (a), lead (b), nickel (c), zinc (d), sand (e), molybdenum (f), vanadium (g) and zirconium (h). Comparing the trace metal concentration in the soil to the standard values established by the World Health Organization (WHO) and by the Brazilian Companhia de Tecnologia de Saneamento Ambiental (CETESB) one can observe that chromium concentration is much higher than the Brazilian standard value of 40 mg.kg -1 and lead slightly above the standard value of 17 mg.kg -1. The worldwide average value for molybdenum in soils is 1.2 mg.kg -1 [4], whereas in the studied soil it was found an average of 0.9 mg.kg -1, but concentration up to 2 mg.kg -1 is found. The higher concentration could be related to fertilizer used at the times the main land use was agricultural use. It can also be observed in Fig. 2 that the sand and silt + clay surface grain size distribution does not show correlation with the trace element concentration in the soil suggesting that the trace metal distribution in the soil is not related to the particle grain size distribution in the soil. Zirconium presents relatively low contents (23.6 mg.kg -1 ) comparing to its worldwide average (230 mg.kg -1 ) [4]. Due to its resistance to weathering it was expected a good correlation with the sand grain size fraction, a fact that was not observed (Fig. 2). This suggests that the processes that determined the coarser grain size fraction in the soil are different from the geochemical processes that kept the zirconium in the same area. The frequent rainfall is responsible for transporting the weathered material into the Tatuoca River. Land use is also an important factor in the transport of
6 1726 The Sustainable City IX, Vol. 2 weathered material to the river. Many chemical elements are lost, while others are fixed in the soil or sediment depending on physical-chemical conditions of the environment. In the studied area there are two predominant types of soil, Argisol (Ultisol) and Gleysol [3]. Thus, it is possible to suggest that the presence of two types of soil has provided distinct pedological materials that were later responsible for the formation of bottom sediments. 3.2 Bottom sediments Trace element distributions along the sediment core (P1, P2, P3 and P4) were made for the same elements previously shown in the soil. Thus, chromium, lead, nickel, zinc, grain size fraction, molybdenum, vanadium and zirconium distribution in each core are shown in Fig. 3. Chromium, lead, nickel and zinc contents (Table 1) showed no concern about the toxicity thresholds established by the USEPA, which uses the approximation of Long et al. [5] to characterize the contamination of sediments. A more detailed interpretation about the geochemical behavior of chromium, lead, nickel and zinc, is limited because the depositional system that prevails in the environment is influenced by strong human intervention, the adsorption capacity of the deposited material, as well the hydrodynamics in each of the sampled sites. Nevertheless, it can be seen that the concentrations of chromium in P1, P2, P3 and P4 cores are depleted in respect to levels found in the soil. Lead, nickel and zinc showed content values about the same as the ones found in the soil, with the exception of P3, which contains values slightly above soil average. This may be due to its higher clay content when compared to P1, P2 and P4. The other elements shown in Fig. 3 do not have a toxic threshold limit established, but helps establish their behavior along with the other elements of this work. As an example, molybdenum, which showed significant increase in concentration in sediment profiles, but in the soil samples in the drainage area, has low content in this element. So, it is likely that the increase in molybdenum in the bottom sediments could be a result of anthropogenic activities in the area or could be related to the higher adsorption capacity of the fine material in the bottom sediments. Zirconium, differently from the soil samples, does not follow the tendency to accumulate with the coarser grain size fraction. For sediment samples, zirconium, as well as most of the elements analyzed in this work shows an association with the finer fraction in profile P3, which is a typical adsorption behavior in the clay size fraction in sediments. Core samples P1 and P2 behave virtually as a single core sample, with some minor differences, but they constitute a material with strong influences of port infrastructure works. The P3 core profile has a different geochemical signature, which could be a result of being isolated from the infrastructure port works, whereas core profile P4 proved to be the one featuring the strongest anthropogenic interference.
7 The Sustainable City IX, Vol Figure 3: Trace element distribution along core profiles. 3.3 Statistical analysis A Principal Components Analysis was performed with data from soil and sediments (a total of 72 samples: 36 soil and 36 sediment samples). As shown in Fig. 4, there is a grouping between the cores samples P1 and P2 on the negative side of the axis of PC1, which contains 33% of the variance information. Such clustering suggests that these two profiles have some similarity. In this same side of the axis are also all soil samples which show a tendency to form two groups, one in the positive sector and another in the negative sector of PC2 axis. On the positive side of the axis of PC1 are located the samples of profiles P3 and P4, but P3 is farthest from the axis. One can conclude that profiles P1 and P2 samples are very similar to each other and also to the surrounding soils, since they are grouped on the same side
8 1728 The Sustainable City IX, Vol. 2 of the PC1 axis. P3 samples plot in the more positive side of PC1 corroborating their distinct geochemical behavior. It can also be noticed that the P4 profile samples show some geochemical similarity with the soil samples and with profiles samples P1 and P2. Observing the second graph obtained by the PCA (Fig. 4(B)), a fraction of the soil samples located above the dashed line, in Fig. 4(A), correlates with molybdenum and the coarser grain size fraction. It is found that below the dashed line are virtually all elements analyzed and the finer grain size fractions, the majority of soil samples and profile samples P3. P4 is the closest to the mouth of the Tatuoca River, therefore have more influence of dredging action in the port of Suape in addition to a higher energy condition. This fact may be responsible for the behavior of molybdenum which sometimes is associated to fine grain size fraction sometimes is associated to the coarser grain size fraction of the soil. As more alkaline environments tend to favor the molybdate ion (MoO 4 2- ), it is possible that it could concentrate closer to the mouth of the river as a result of changes in hydrodynamics and dredging. Figure 4: Soil and bottom sediments graphs obtained through statistical analyses. (A) PCA loadings graph; (B) PCA scores graph; (C) Dendrogram. The P3 profile that was collected in a restricted area in the Tatuoca River, with lesser human activities, showed a uniformity of its chemical content and may be considered a natural geochemical pattern for the studied area. It can also
9 The Sustainable City IX, Vol be suggested that due to its high fine grain size particle content the adsorption of chemical element is more efficient. It is noteworthy that molybdenum does not show the same behavior as the other elements in the profile P3, which corroborates the fact that it is an element added to the system. Fe, Cr, V, Sc, Ti and Cu show an interdependence in the soil and in the bottom sediment cores suggesting that the origin of ferrous metals is geogenic. The elements that appear associated with calcium, such as strontium, lead, phosphorus and barium form a distinct group and may come from the addition of elements to agricultural correctives, which by its historical use may have affected the entire watershed, including profile P3. A dendrogram was prepared for this group of samples using the Ward's method and the Euclidean distance (Fig. 4(C)). The dendrogram shows that there is a hierarchical grouping which relates some soil samples to profile P3, as already observed in the PCA. From the findings in Fig. 4 we can say that the statistical analysis could separate two compartments by their geochemical affinity: one formed by P1, P2 and soil samples and another one formed by P3 and P4 bottom sediment core samples, which have more pronounced sedimentary features. 4 Conclusions The land use in the area primarily sugarcane plantation responsible for addition of fertilizers and pesticides to the soil and the present industrial boom responsible for the land removal are responsible for the geochemical signature of bottom sediments in the Tatuoca River. Through the use of multivariate it was possible to highlight geochemical grouping and interpret the source of chemical elements in the bottom sediments. The sediment cores were differentiated into three different groups according to main sediment load source, being the port infrastructure works responsible for the geochemical signature of the bottom sediment cores. Regarding the quality of the soil in the drainage basin and bottom sediment of the River Tatuoca, it can be stated that the area has suffered an important environmental impact, but according to results of the present study but they are not yet considered polluted. References [1] Chagas-Spinelli, A.C., Kato, M.T., de Lima, E.S. & Gavazza, S.S. Bioremediation of a tropical clay soil contaminated with diesel oil. Journal of Environmental Management, 113, pp , [2] Dorraji, S.S., Golchin & A., Ahmadi, S. The effects of hydrophilic polymer and soil salinity on corn growth in Sandy and loamy soils. Clean Soil, Air Water, 38 (7), pp , [3] Embrapa Solos. Sistema Brasileiro de Classificação de Solos, EMBRAPA, Brasília, 412p, 1999.
10 1730 The Sustainable City IX, Vol. 2 [4] Koljonen, T (Ed). The geological atlas of Finland. Part 2. Till. Geological Survey of Finland, Espoo, 218p, [5] Long, E.R., MacDonal, D.D., Smith, S.L. & Calder, F.D. Incident of adverse biological affects within ranges of chemical concentrations in marine and estuarine sediments. Environmental Management, 19, pp , [6] Morales-Caseles, C., Riba, I., Sarasquete, & C., Ángel DelValss, T. Using a classical weight-of-evidence approach for 4-years monitoring of the impact of an accidental oil spill on sediment quality. Environment International, 34, pp , [7] Santos Bermejo, S.C., Beltran, R. & Gomez Ariza, J.L. Spatial variations of heavy metal contamination in sediments from Odiel River (Southwest Spain). Environment International, 29, pp , [8] Yaman, M., Ince, M. & Cengiz, E. Distribution study of U, V, Mo and Zr in different sites of Lakes Van and Hazar, river and seawater. Clean Soil, Air, Water, 39 (6), pp , 2011.
Identification of geochemically distinct regions at river basin scale using topography, geology and land use in cluster analysis
Identification of geochemically distinct regions at river basin scale using topography, geology and land use in cluster analysis Ramirez-Munoz P. and Korre, A. Mining and Environmental Engineering Research
More informationSediment characteristics of Beaver Lake and implications for remediation; A Pilot Project.
Sediment characteristics of Beaver Lake and implications for remediation; A Pilot Project. Delphine Faugeraux Leah Bendell A report to the Stanley Park Ecological Society. September 15 th 2011. Abstract
More informationINÁCIO Manuela, FERREIRA António, FERREIRA Luís, ALMEIDA Luís, PEREIRA Virgínia, PINTO Manuel
Scientific registration n 0 : 1893 Symposium n 0 : 2 Presentation: poster Multi-purpose Soil Geochemical Mapping of Portugal: preliminary results Différentes applications de la cartographie géochimique
More informationSpatial and Temporal distribution of metals in sediments of a tropical lagoon, SW coast of India: Environmental Indicators ABSTRACT
Spatial and Temporal distribution of metals in sediments of a tropical lagoon, SW coast of India: Environmental Indicators C.P. Priju 1 and A.C. Narayana 2 * 1 Department of Marine Geology & Geophysics
More informationEVALUATION OF MIGRATION OF HEAVY METAL CONTAINING SEDIMENT RESULTING FROM WATER EROSION USING A GEO- INFORMATION MODEL
EVALUATION OF MIGRATION OF HEAVY METAL CONTAINING SEDIMENT RESULTING FROM WATER EROSION USING A GEO- INFORMATION MODEL János Tamás, Elza Kovács University of Debrecen, Centre of Agricultural Sciences Department
More informationEnvironmental impact assessment study of the new offshore dumping sites for Šventoji port in Lithuania
Environmental impact assessment study of the new offshore dumping sites for Šventoji port in Lithuania Introduction Summary In 2003 Lithuanian Ministry of Transport initiated the preparation of feasibility
More informationICP-OES Application Note Number 35
ICP-OES Application Note Number 35 Rapid measurement of major, minor and trace levels in soils using the Varian 730-ES Vincent Calderon Varian, Inc. Introduction As part of the global strategy for sustainable
More informationGEMAS: A European scale geochemical atlas for environmental management and mineral exploration
GEMAS PROJECT GEMAS: A European scale geochemical atlas for environmental management and mineral exploration Clemens Reimann 40 Years Listening to the Beat of the Earth 2007: Eurometaux contacts EuroGeoSurveys:
More informationTHRESHOLD LIMIT VALUES FOR HEAVY METALS IN SOILS IN THE FUNCTION OF SPATIAL AND TEMPORAL VARIATION OF GEOCHEMICAL FACTORS. P. SIPOS and T.
THRESHOLD LIMIT VALUES FOR HEAVY METALS IN SOILS IN THE FUNCTION OF SPATIAL AND TEMPORAL VARIATION OF GEOCHEMICAL FACTORS P. SIPOS and T. PÓKA Laboratory for Geochemical Research, Hungarian Academy of
More informationStickney Avenue Depositional Zone (SADZ) Investigation
The Ottawa River: A Report to the Community Stickney Avenue Depositional Zone (SADZ) Investigation May 22, 2007 Presented by: Scott Bell, P.E., BCEE (LimnoTech) Kelly Bensman (Hull & Associates) SADZ Location
More informationCurrent State of Extraction Don t Be Deceived! Sharon F. Webb, Ph.D. Director of Quality Program
Current State of Extraction Don t Be Deceived! Sharon F. Webb, Ph.D. Director of Quality Program Overview Factors Purpose of Dissolution Quality Objectives of Program Effectiveness of Dissolution Technique
More informationThe Baltic Soil Survey
The Baltic Soil Survey C. Reimann, U. Siewers, T. Tarvainen, L. Bityukova, J. Erikson, A. Gilucis, V. Gregorauskiene, V. Lukashev, N. Matinian & A. Pasieczna PROJECT AIM: create a comparable database
More informationDistance weighted approach to modeling sediment metal concentrations in Johnson Creek Watershed, Portland Oregon. Janardan Mainali Geog593 12/07/2017
Distance weighted approach to modeling sediment metal concentrations in Johnson Creek Watershed, Portland Oregon Janardan Mainali Geog593 12/07/2017 Distance-weighted approach to modeling sediment metal
More informationLecture 15: Adsorption; Soil Acidity
Lecture 15: Adsorption; Soil Acidity Surface Complexation (Your textbook calls this adsorption ) Surface Complexation Both cations and anions can bind to sites on the external surfaces of soil minerals
More informationContamination of peat and moss samples 190 km from the Flin Flon Cu-Zn smelter, Canada: implications for exploration.
Contamination of peat and moss samples 19 km from the Flin Flon Cu-Zn smelter, Canada: implications for exploration. Paul Polito, Kurt Kyser, Dave Lawie, Steve Cooke, Chris Oates Location of the Harmin
More informationCurrent issues in establishing geochemical background of trace elements
Geochemistry and the Environment Division Institute of Chemistry Jan Kochanowski University in Kielce Current issues in establishing geochemical background of trace elements Agnieszka Gałuszka & Zdzisław
More informationGUAMA RIVER AND GUAJARA BAY, BELEM - AMAZON REGION
2007 International Nuclear Atlantic Conference - INAC 2007 Santos, SP, Brazil, September 30 to October 5, 2007 ASSOCIAÇÃO BRASILEIRA DE ENERGIA NUCLEAR - ABEN ISBN: 978-85-99141-02-1 210 Pb GEOCHRONOLOGY
More informationAn Investigative Study on Heavy Metal Content in Sediment of Bellandur Lake, Bengaluru
An Investigative Study on Heavy Metal Content in Sediment of Bellandur Lake, Bengaluru Anoop Toolahalli 1, Dr. K. M. Sham Sundar 2 1MTech student, Department of Civil Engineering, U B D T College of Engineering,
More informationGrain size distribution of surface sediment. Mineralogy of different sediment fractions. Geochemistry of surface sediment fine fraction
TRACE ELEMENT N DFFERENT MARNE SEDMENT FRACTONS OF THE GULF OF TUNS: CENTRAL MEDTERRANEAN SEA Noureddine Zaaboub1*, Walid Oueslati2, Saadi Abdeljaoued2, F. Javier Huertas3, Alberto López-Galindo3 1 National
More informationTHE EFFECT OF SEDIMENT GRAIN SIZE ON HEAVY METAL CONTENT*
Water resources and wetlands, Editors: Petre Gâştescu, William Lewis Jr., Petre Breţcan Conference Proceedings, 14-16 September 2012, Tulcea - Romania ISBN: 978-606-605-038-8 THE EFFECT OF SEDIMENT GRAIN
More informationSpatial decision making in Armenia based on multidisciplinary environmental research
EU FP7 EcoArm2ERA Integration into ERA Integration of spatial decision support systems and evidence based modeling in National/Regional Policy applications and regulatory systems: scientific and policy
More informationAssess the Potential for Accumulation of Toxic Trace Elements in Biota near Burton Island Ash Disposal Site Indian River Bay, Delaware
Assess the Potential for Accumulation of Toxic Trace Elements in Biota near Burton Island Ash Disposal Site Indian River Bay, Delaware Gerhardt Riedel Ph.D. Smithsonian Environmental Research Center Bartholomew
More informationDISTRIBUTION OF METALS IN PARTICLE SIZE FRACTIONS IN SOILS OF TWO FORESTED CATENAS (SMOLENSK MOSCOW UPLAND)
28 GEOGRAPHY Olga A. Samonova 1, Elena N. Aseyeva 2 * 1 Faculty of Geography, Moscow State University, Moscow, 119991, Russia; e-mail: оsamonova@mail.ru 2 Faculty of Geography, Moscow State University,
More informationOnly healthy soil can grow a nutrient dense food. You are what you eat!
Understanding How Cation Nutrients & Soil Structure are Related By Michael Martin Meléndrez Only healthy soil can grow a nutrient dense food. You are what you eat! Soil Must be able to hold onto water,
More informationSimple, reliable analysis of high matrix samples according to US EPA Method 6020A using the Agilent 7700x/7800 ICP-MS
Simple, reliable analysis of high matrix samples according to US EPA Method 6020A using the Agilent 7700x/7800 ICP-MS Application note Environmental Authors Steve Wilbur, Craig Jones Agilent Technologies,
More informationAssessment at mid-black Sea coast of Turkey for recovery valuable heavy metals from sediments
European Water 58: 173-177, 2017. 2017 E.W. Publications Assessment at mid-black Sea coast of Turkey for recovery valuable heavy metals from sediments A. Şimşek * and G. Bakan Department of Environmental
More informationREMOVAL OF HEAVY METALS USING COMBINATION OF ADSORBENTS - A CASE STUDY USING INDUSTRIAL WASTE WATER
REMOVAL OF HEAVY METALS USING COMBINATION OF ADSORBENTS - A CASE STUDY USING INDUSTRIAL WASTE WATER PROJECT REFERENCE NO. : 37S1399 COLLEGE : DAYANANDA SAGAR COLLEGE OF ENGINEERING, BANGALORE BRANCH :
More informationInvestigation of Nutrient Elements in Cucurbita pepo Using Atomic Absorption Spectrometry
Available online at www.ilcpa.pl International Letters of Chemistry, Physics and Astronomy 2 (2013) 11-17 ISSN 2299-3843 Investigation of Nutrient Elements in Cucurbita pepo Using Atomic Absorption Spectrometry
More informationGeochemical Data Evaluation and Interpretation
Geochemical Data Evaluation and Interpretation Eric Grunsky Geological Survey of Canada Workshop 2: Exploration Geochemistry Basic Principles & Concepts Exploration 07 8-Sep-2007 Outline What is geochemical
More informationGEOCHEMISTRY OF MAJOR AND MINOR ELEMENTS FROM SUR- FACE SEDIMENTS OF LAKONIKOS GULF, GREECE
GEOCHEMISTRY OF MAJOR AND MINOR ELEMENTS FROM SUR- FACE SEDIMENTS OF LAKONIKOS GULF, GREECE Karageorgis, A.P., Kanellopoulos, Th.D., Papageorgiou, A., Taxiarchi, M., Kambouri, M. Institute of Oceanography,
More informationDetailed Sedimentology and Inorganic Geochemistry of the Dolgeville Formation and Utica Group of the Central Mohawk Valley, NY
Detailed Sedimentology and Inorganic Geochemistry of the Dolgeville Formation and Utica Group of the Central Mohawk Valley, NY Daniel Miserendino Jeffrey T. Pietras Introduction and Purpose Drill cores
More informationBishopville Prong Study
Bathymetric and Sediment Assessment in the Bishopville Prong of St. Martin River Darlene V. Wells, Richard A. Ortt, Jr., and Stephen Van Ryswick Funded by MCBP 2011-2012 Implementation Grant Objectives
More informationUse of Near Infrared Spectroscopy to Determine Chemical Properties of Forest Soils. M. Chodak 1, F. Beese 2
Use of Near Infrared Spectroscopy to Determine Chemical Properties of Forest Soils M. Chodak 1, F. Beese 2 1 Institue of Environmental Sciences, Jagiellonian University, Gronostajowa 3, 3-387 Kraków, Poland,
More informationSediment Sampling Protocols
Sediment Sampling Protocols February 2017 Sampler Training Workshop Thomas Seal, ES III Watershed Monitoring Section (WMS) Water Quality Assessment Program DEAR Tallahassee Sediment Sampling in Large and
More informationIntroduction Investigation of Geochemistary and Introduction Promissing Area in 1: Noor Sheet
Introduction Investigation of Geochemistary and Introduction Promissing Area in 1:100000 Noor Sheet Ghaderi,Shahrbanoo a *,Dr.Rasa,Iraj b,dr.hezareh,mohamadreza c, a Islamic,Azad University Research and
More informationAcid Soil. Soil Acidity and ph
Acid Soil Soil Acidity and ph ph ph = - log (H + ) H 2 O H + + OH - (H + ) x (OH - )= K w = 10-14 measures H + activity with an electrode (in the lab), solutions (in the field) reflects the acid intensity,
More informationGeochemistry of Landscapes Covered by Glacially Crushed Debris. William W. Shilts
Geochemistry of Landscapes Covered by Glacially Crushed Debris William W. Shilts Comminution (crushing) processes dominate glacial sediment production and deposition, trumping chemical weathering, hydrology,
More informationWhat are Metal Leaching and Acid Rock Drainage and Why are They Important to Mining?
What are Metal Leaching and Acid Rock Drainage and Why are They Important to Mining? Lake Superior Working Group Workshop October 27 th, 2009 Bill Price Environment Group, Mining and Mineral Sciences Lab.
More informationInfluence of land use in small karst catchments on the chemical status of peloid sediments on the eastern Adriatic coast
Influence of land use in small karst catchments on the chemical status of peloid sediments on the eastern Adriatic coast Slobodan Miko 1, Šparica Marko 1, Georg Koch 1, Martina Šparica Miko 1, Stanislav
More informationMulti Analyte Custom Grade Solution. Aluminum, Potassium, Magnesium, ANALYTE CERTIFIED VALUE ANALYTE CERTIFIED VALUE
1.0 ACCREDITATION / REGISTRATION INORGANIC VENTURES is accredited to ISO Guide 34, "General Requirements for the Competence of Reference Material Producers" and ISO/IEC 17025, "General Requirements for
More informationProject Copper CBC. Bahia Brazil -August
Project Copper CBC Bahia Brazil -August - 2016 The Company The CBC Mineração Ltda is a company of BETONITA group created to develop this project copper. It s a solid group in the brasilian market very
More informationPlant Nutrition and Transport. Chapter 29
Plant Nutrition and Transport Chapter 29 Overview: Underground Plants The success of plants depends on their ability to gather and conserve resources from their environment. The transport of materials
More informationWhat monitoring techniques are appropriate and effective for detecting CO2 migration in groundwater: isotope-based monitoring Philippe Négrel
What monitoring techniques are appropriate and effective for detecting CO2 migration in groundwater: isotope-based monitoring Philippe Négrel Acting in complicity with Pauline Humez. Results from Pauline
More informationGeochemical Study of Coastal Sediments In uenced by River-Transported Pollution: Southern Evoikos Gulf, Greece
PII: S0025-326X(99)00174-5 Marine Pollution Bulletin Vol. 40, No. 1, pp. 77±82, 2000 Ó 2000 Elsevier Science Ltd. All rights reserved Printed in Great Britain 0025-326X/00 $ - see front matter Geochemical
More informationUltra-fast determination of base metals in geochemical samples using the 5100 SVDV ICP-OES
Ultra-fast determination of base metals in geochemical samples using the 5100 SVDV ICP-OES Application note Geochemistry, metals, mining Authors John Cauduro Agilent Technologies, Mulgrave, Australia Introduction
More informationMuck. Kevin Henderson, P.E. Evergreen Engineering, Inc. Presentation to Rivers Coalition 9/29/16
Muck Kevin Henderson, P.E. Evergreen Engineering, Inc. Presentation to Rivers Coalition 9/29/16 LITERATURE REVIEW Schropp (1994) defined muck sediments as sediment with greater than 60% silts and clays,
More informationEnvironmental Implications A Case Study
Grain Size Variations and Its Environmental Implications A Case Study DR PURANDARA BEKAL SCIENTIST, NATIONAL INSTITUTE OF HYDROLOGY HARD ROCK REGIONAL CENTER HANUMAN NAGAR BELGAUM, KARNATAKA Particle Transport
More informationGeochemical and geophysical techniques application to characterize a mining silt pond from Cartagena- Union (Murcia): potential pollution pathways
Geochemical and geophysical techniques application to characterize a mining silt pond from Cartagena- Union (Murcia): potential pollution pathways Faz, A. (2), Aracil, E. (1), Martínez-Pagán, P. (2),Acosta,
More informationInvestigation of Nutrient Elements in Cucurbita pepo Using Atomic Absorption Spectrometry
International Letters of Chemistry, Physics and Astronomy Online: 2013-09-21 ISSN: 2299-3843, Vol. 7, pp 11-17 doi:10.18052/www.scipress.com/ilcpa.7.11 2013 SciPress Ltd., Switzerland Investigation of
More informationMulti-Element Analysis of Petroleum Crude Oils using an Agilent 7900 ICP-MS
Multi-Element Analysis of Petroleum Crude Oils using an Agilent 7900 ICP-MS Application note Energy and fuels Authors Jenny Nelson, Agilent Technologies, USA Ed McCurdy, Agilent Technologies, UK Introduction
More informationAppendix 07 Principal components analysis
Appendix 07 Principal components analysis Data Analysis by Eric Grunsky The chemical analyses data were imported into the R (www.r-project.org) statistical processing environment for an evaluation of possible
More informationAdsorption of ions Ion exchange CEC& AEC Factors influencing ion
Adsorption of ions Ion exchange CEC& AEC Factors influencing ion exchange- Significance. Adsorption of ions Ion adsorption and subsequent exchange are important processes that take place between soil colloidal
More informationCharacterization of Sand Formation from a Crude Oilfield
This work by IJARBEST is licensed under Creative Commons Attribution 4.0 International License. Available at https://www.ijarbest.com Characterization of Sand Formation from a Crude Oilfield 1 A. Sivasakthi,
More informationEXCHANGE OF HEAVY METALS BETWEEN SEDIMENT AND WATER IN THE WLOCLAWEK RESERVOIR ON THE VISTULA RIVER
Sediment and Stream Water Quality in a Changing Environment: Trends and Explanation (Proceedings of the Vienna Symposium, August 1991) IAHS Publ. no. 203, 1991. ECHANGE OF HEAVY METALS BETWEEN SEDIMENT
More informationSCOPE OF ACCREDITATION TO ISO/IEC 17025:2005
SCOPE OF ACCREDITATION TO ISO/IEC 17025:2005 FUGRO SUHAIMI LIMITED Chemical and Calibration Laboratories King Abdul-Aziz Port Road PO Box 2165 Dammam, Kingdom of Saudi Arabia 31451 Mohammed B. Hameed Phone:
More informationIAEA-TECDOC-9SO. Sampling, storage
IAEA-TECDOC-9SO Sampling, storage The IAEA does The originating Sections of this publication in the IAEA were: Agency's Laboratories, Seibersdorf Physics Section International Atomic Energy Agency Wagramerstrasse
More informationRemoval of Heavy Metals Fe 3+, Cu 2+, Zn 2+, Pb 2+, Cr 3+ and Cd 2+ from Aqueous Solutions by Using Eichhornia Crassipes
Portugaliae Electrochimica Acta 2010, 28(2), 125-133 DOI: 10.4152/pea.201002125 PORTUGALIAE ELECTROCHIMICA ACTA ISSN 1647-1571 Removal of Heavy Metals Fe 3+, Cu 2+, Zn 2+, Pb 2+, Cr 3+ and Cd 2+ from Aqueous
More informationS.K. Sahoo 1 *, Z.S. Zunic 2, R. Kritsananuwat 1, H. Arae 1 and S. Mishra 1
S.K. Sahoo 1 *, Z.S. Zunic 2, R. Kritsananuwat 1, H. Arae 1 and S. Mishra 1 1, Japan 2 Institute of Nuclear Sciences Vinca, Beograd, Serbia E-mail:sahoo@nirs.go.jp 3rd TRE-ICEP Veszprém-Hungary, May 16-18,
More informationPriority Pollutants in Untreated and Treated Discharges from Coal Mines
Priority Pollutants in Untreated and Treated Discharges from Coal Mines Charles A. Cravotta III Research Hydrologist USGS Pennsylvania Water Science Center New Cumberland, PA Presented March, 28, 2012,
More informationResearch Progress Report April 2014 University of Waterloo & Wilfrid Laurier University Researchers
Research Progress Report April 2014 University of Waterloo & Wilfrid Laurier University Researchers Project Title: Sediment Core Sampling to Assess Contaminant Deposition to the Slave River Delta Over
More informationOriginal Research An Investigation of Sediment Pollution in the Anzali Wetland
Pol. J. Environ. Stud. Vol. 22, No. 1 (2013), 283-288 Original Research An Investigation of Sediment Pollution in the Anzali Wetland Maryam Zare Khosheghbal 1 *, Amir H. Charkhabi 2, Forood Sharifi 2,
More informationProcessing Stream Sediment Geochemical Data for Geology and Dilution: An Example from Northern Vancouver Island
Processing Stream Sediment Geochemical Data for Geology and Dilution: An Example from Northern Vancouver Island Dennis Arne, PGeo (BC), RPGeo (AIG), Principal Consultant Geochemistry, CSA Global Yao Cui,
More informationOverview. Rock weathering Functions of soil Soil forming factors Soil properties
UN-FAO A. Healthy soils are the basis for healthy food production. B. A tablespoon of normal topsoil has more microorganisms than the entire human population on Earth. C. It can take up to 1,000 years
More informationProf. Dr. Biljana Škrbić, Jelena Živančev
5 th CEFSER Training Course Analysis of chemical contaminants in food and the environment Faculty of Technology, University of Novi Sad, Novi Sad, Republic of Serbia 7-11 May 2012 Analysis of heavy elements
More informationEnvironmental Aspects of Oil Shale Development: A Review
Environmental Aspects of Oil Shale Development: A Review Tom Wildeman, Ron Klusman, & Jim Ranville Dept. of Chemistry & Geochemistry Colorado School of Mines Background During the last oil shale development
More informationGround Water & UST Samples: Containers, Preservation and Hold Times Table
Ground Water & UST Samples: Containers, Preservation and Hold Times Table North Carolina Division of Water Resources, Water Sciences Section Chemistry Laboratory Reference: 40 CFR Part 136.3 Table II Listed
More informationGeogenic versus Anthropogenic Metals and Metalloids
Geogenic versus Anthropogenic Metals and Metalloids Geochemical methods for evaluating whether metals and metalloids are from geogenic versus anthropogenic sources 1 Definitions Geogenic from natural geological
More informationSediment and sedimentary rocks Sediment
Sediment and sedimentary rocks Sediment From sediments to sedimentary rocks (transportation, deposition, preservation and lithification) Types of sedimentary rocks (clastic, chemical and organic) Sedimentary
More informationPamela Reilly and Julia Barringer
Pamela Reilly and Julia Barringer U.S. Geological Survey New Jersey Water Science Center This information is preliminary and is subject to revision. It is being provided to meet the need for timely best
More informationUPSTREAM-DOWNSTREAM CONTAMINATION GRADIENT OF THE FLUVIAL URBAN SYSTEM IN CHENNAI (Tamil Nadu, India)
UPSTREAM-DOWNSTREAM CONTAMINATION GRADIENT OF THE FLUVIAL URBAN SYSTEM IN CHENNAI (Tamil Nadu, India) Saravanan S.P. a,b, Desmet. M. a, Ambujam N.K. b, Thenmozhi D. b, Manikandabharath K. b, Rukkumany
More informationSteven Noble MDEQ - WRD Enbridge Response Unit
EPA situation report, October 19, 2012 Steven Noble MDEQ - WRD Enbridge Response Unit Brief history of the spill Monitoring Monitoring the impacts Follow the oil The Current Situation A Look at the Future
More informationWorldwide Open Proficiency Test for X Ray Fluorescence Laboratories PTXRFIAEA13. Determination of Major, Minor and Trace Elements in a Clay Sample
Worldwide Open Proficiency Test for X Ray Fluorescence Laboratories PTXRFIAEA13 Determination of Major, Minor and Trace Elements in a Clay Sample IAEA Laboratories, Seibersdorf November 2017 CONTENTS
More informationEvaluation of Nutrient and Heavy Metal Pollution in Maozhou River in Shenzhen City
IOP Conference Series: Earth and Environmental Science PAPER OPEN ACCESS Evaluation of Nutrient and Heavy Metal Pollution in Maozhou River in Shenzhen City To cite this article: Daiwen Zhu et al 2018 IOP
More informationSource Control Early Action Focused Feasibility Study
Source Control Early Action Focused Feasibility Study Empirical Mass Balance Model Results or the Lower Passaic River Edward A. Garvey, PhD, PG Malcolm Pirnie, Inc. Remedial Options Workgroup Meeting June
More informationEnvironmental Resources Management
Figure 1: Concentration of Metals and Metalloid (Cr, Cu, Ni, Pb, Zn, As; mean +SD) in sediment samples collected from Pit Specific Sediment Chemistry Monitoring for CMP 1 in January 2014. Figure 2: Concentration
More informationShirley E. Clark, Ph.D., P.E., D. WRE Robert E. Pitt, Ph.D., P.E., BCEE, D. WRE
Shirley E. Clark, Ph.D., P.E., D. WRE Robert E. Pitt, Ph.D., P.E., BCEE, D. WRE Current PA Guidance Many guidance documents apply expected pollutant removals based on literature. However, typically presented
More informationPee Dee Explorer. Science Standards
Science Standards About Pee Dee Explorer What does it mean when someone says they are from the "Pee Dee" of South Carolina? A place is bigger than its physical geography. A "sense of place" weaves together
More informationIgneous rocks + acid volatiles = sedimentary rocks + salty oceans
The Lithosphere Weathering physical processes chemical processes biological processes weathering rates Soil development soil formation processes types of soils and vegetation soil properties physical chemical
More informationTopic 3: Periodicity OBJECTIVES FOR TODAY: Fall in love with the Periodic Table, Interpret trends in atomic radii, ionic radii, ionization energies &
Topic 3: Periodicity OBJECTIVES FOR TODAY: Fall in love with the Periodic Table, Interpret trends in atomic radii, ionic radii, ionization energies & electronegativity The Periodic Table What is the periodic
More informationMulti Analyte Custom Grade Solution. Calcium, Iron, Potassium,
1.0 ACCREDITATION / REGISTRATION INORGANIC VENTURES is accredited to ISO Guide 34, "General Requirements for the Competence of Reference Material Producers" and ISO/IEC 17025, "General Requirements for
More informationEssential Chemistry for Biology
1 Chapter 2 Essential Chemistry for Biology Biology and Society: More Precious than Gold A drought is a period of abnormally dry weather that changes the environment and one of the most devastating disasters.
More informationFish Passage Studies III: Sediment Redistribution and Impact Analysis: Springborn Dam - Enfield, Connecticut
University of Massachusetts Amherst ScholarWorks@UMass Amherst International Conference on Engineering and Ecohydrology for Fish Passage International Conference on Engineering and Ecohydrology for Fish
More informationSingle-Element Standards for AAS
Single-Element Standards for AAS for AAS Flame Silver Ag in 2-5% HNO 3 Aluminium Al in 2-5% HCl Aluminium Al in 2-5% HNO 3 Arsenic As in 2-5% HCl Arsenic As in 2-5% HNO 3 Gold Au in 2-5% HCl Boron B in
More informationRiver bank erosion risk potential with regards to soil erodibility
River Basin Management VII 289 River bank erosion risk potential with regards to soil erodibility Z. A. Roslan 1, Y. Naimah 1 & Z. A. Roseli 2 1 Infrastructure University, Kuala Lumpur, Malaysia 2 Humid
More informationThe Geochemistry of Natural Waters
The Geochemistry of Natural Waters Surface and Groundwater Environments Third Edition James I. Drever University of Wyoming Prentice Hall Upper Saddle River. NJ 07458 Contents 3 Preface xi 1 The Hydrologie
More informationCopyright SOIL STRUCTURE and CLAY MINERALS
SOIL STRUCTURE and CLAY MINERALS Soil Structure Structure of a soil may be defined as the mode of arrangement of soil grains relative to each other and the forces acting between them to hold them in their
More informationSediment and Sedimentary rock
Sediment and Sedimentary rock Sediment: An accumulation of loose mineral grains, such as boulders, pebbles, sand, silt or mud, which are not cemented together. Mechanical and chemical weathering produces
More informationA SEDIMENT ANALYSIS OF THE THREE DOG SITE (SS21), SAN SALVADOR ISLAND, COMMONWEALTH OF THE BAHAMAS. Joshua J. O Brien
A SEDIMENT ANALYSIS OF THE THREE DOG SITE (SS21), SAN SALVADOR ISLAND, COMMONWEALTH OF THE BAHAMAS Joshua J. O Brien http://www.luislondon.co.uk/travel/bahamas%20map.gif Background Earliest known archaeological
More informationEffects of Suspended Sediments on Daphnia Magna. Advanced Environmental Seminar May 9, 2016 By Alexandria Watts, Ben Van Gorp, and Tommy Jenkins
Effects of Suspended Sediments on Daphnia Magna Advanced Environmental Seminar May 9, 2016 By Alexandria Watts, Ben Van Gorp, and Tommy Jenkins Project Daphnia Introduction: The main purpose of the experiment
More informationMobility of Zn, Pb, and Cd from sediments
Mobility of Zn, Pb, and Cd from sediments contaminated with mining wastes Mélida Gutiérrez, Ph.D. Geography, Geology and Planning, Missouri State University Geological Society of America Indianapolis,
More informationScreening of Algae Material as a Filter for Heavy Metals in Drinking Water
1 Screening of Algae Material as a Filter for Heavy Metals in Drinking Water 2 ABSTRACT Calcium alginate beads generated from alginic acid sodium salt from brown algae were 3 used to explore the adsorption
More informationAkvaplan-niva rapport
Grunnlagsundersøkelse på Snøhvit og Område C i Barentshavet, 2003 Akvaplan-niva rapport APN-411.2785-1 Introduction Statoil and Norsk Hydro commissioned Akvaplan-niva AS to perform baseline surveys at
More informationTrace Metal Dynamic Extraction from Five Pumps in Hydrochloric Acid. Submitted to: Reto Schoeb Levitronix GmbH. Submitted by:
CT Associates, Inc. 72 Shady Oak Road, Eden Prairie, MN 55344-356 Telephone: (952) 470-066 Fax: (952) 942-0293 Website: http://www.ctassociatesinc.com Trace Metal Dynamic Extraction from Five Pumps in
More informationPhysical Geography: Patterns, Processes, and Interactions, Grade 11, University/College Expectations
Geographic Foundations: Space and Systems SSV.01 explain major theories of the origin and internal structure of the earth; Page 1 SSV.02 demonstrate an understanding of the principal features of the earth
More informationICP/MS Multi-Element Standards
Standards Ultra Pure Matrix Special Packaging Traceability to National Reference Materials AccuStandard s ICP/MS Standards are formulated to meet the needs of this very special instrument. As matrix effect
More informationCHAPTER - 7 GEOCHEMISTRY. Geochemistry deals with the distribution and migration of geochemical signals within
CHAPTER - 7 GEOCHEMISTRY 7.1. INTRODUCTION: Geochemistry deals with the distribution and migration of geochemical signals within the earth in space and time. The history of geochemistry naturally includes
More informationAquatic Sediment Sampling and Analyses
Aquatic Sediment Sampling and Analyses Richard B. Shepard, Ph.D. March 16, 2011 Introduction Collecting sediment samples for analysis of contaminants particularly in river systems is not just a matter
More informationEffect of Oxygenation on Speciation, Behavior, and Fate of Chromium in Estuarine Sediments
Effect of Oxygenation on Speciation, Behavior, and Fate of Chromium in Estuarine Sediments www.epa.gov/.../newsletter/images/allied1988.jpg www.epa.gov/.../images/allied_tents.jpg Amar R. Wadhawan and
More informationChapter 6. Weathering, Erosion, and Soil
Chapter 6 Weathering, Erosion, and Soil Introduction Rocks and minerals disintegrate and decompose by the processes of physical and chemical weathering. This breakdown occurs because the parent material
More informationThe river basin-coastal zone continuum: heavy metal contents in stream and marine sediments, NW Aegean Sea (EUROCAT Project)
The river basin-coastal zone continuum: heavy metal contents in stream and marine sediments, NW Aegean Sea (EUROCAT Project) Aristomenis P. Karageorgis 1, Nikolaos P. Nikolaidis 2 1 Institute of Oceanography,
More information