experiment11 Molecular Structures

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59 experiment11 OBJECTIVES To determine the number of

To determine the Lewis structure of molecules.

1 59 experiment11 OBJECTIVES To determine the number of valence electrons in molecules. To determine the Lewis structure of molecules. To determine the electron pair geometry and geometry (shape) of molecules. To determine the hybridization of molecules. To build molecular models. To draw three-dimensional picture of models. Students will work in pairs. You do not need to write a full lab report for this experiment. Complete the Chem21 worksheet assignment. IN THE LAB

2 60 EXPERIMENT 11: WASTE None SAFETY Students need to wear goggles for this experiment. A team of researchers looking into developing new drugs are using molecular modeling to see how the new drugs fit into the cell s receptors for this drug. Molecular modeling uses mathematical models to describe molecular properties and behaviors of molecules and generally displays that information in the form of a picture. Before the researchers can build their mathematical models, they need you to help provide some information about the basic structures of some simple molecules. For each of the molecules in the lists below, use your model kit to construct a model of the compounds and to provide the researchers with the following information: Total number of electrons: 1. Valence electrons 2. electrons 3. Non-bonding electrons Number of bonds single, double, triple Hybridization Number of electron groups Electron geometry Molecular geometry 3-D drawing of molecule All information needs to be provided to your supervisor through the Chem21 Web site, so that it can easily be converted into the mathematical models. Your TA will tell you which list you should report on. Your supervisor has provided the following instructions in regards to using the molecular model kits available to you. Materials Molecular model set with the following parts: 16 sp 3 (black) 10 sp 2 (gray) 2 half double bond (blue) 4 double bond (purple) 4 octahedral (metallic gold) 2 linear (orange) 2 trigonal (copper) 1 triple bond (yellow) 2 bond extenders (silver) marker balls Model Sets 12 white (hydrogen) 6 green (halogens) 6 red (oxygen and nitrogen) 2 hot pink (undesignated atoms) These model sets are from Darling Models ( Sets similar to this one and many others are available at a very reasonable price if you are interested in having your own set or if you will be taking Organic Chemistry. Most Organic Chemistry courses will require or recommend that you have a model set.

EXPERIMENT 11: 61 Assembly and Disassembly of Molecular Visions Atoms Darling Models ; pieces shown in Figure 11.1. 1. Slide the U openings together at right angles (see Figure 11.3). 2.

Pull sharply with the left hand and push sharply with the right hand until there is a second click as shown in Figure 11

3 EXPERIMENT 11: 61 Assembly and Disassembly of Molecular Visions Atoms Darling Models ; pieces shown in Figure Slide the U openings together at right angles (see Figure 11.3). 2. Pinch the two pieces together until they click (see Figure 11.4). 3. Grasp the two pieces against the central U. Pull sharply with the left hand and push sharply with the right hand until there is a second click as shown in Figure Figure From top to bottom, sp 3 piece, trigonal atoms, octahedral pieces, and linear bond. The Atom Figure The final step to assemble the tetrahedral atom with bonds. Figure The U shaped center of the atom piece. Each atom consists of a U shaped center as shown in Figure 11.2, with two or three bonds. The bonds end in a rod or tube. The small teeth at the opening of the U serve to grip the square at the end of the other piece, locking the two pieces to form an atom with bonds. The procedure for joining two atom pieces is shown in the following paragraphs. The tetrahedron may be taken apart by gently spreading the V shaped bonds on one piece, to unlock the teeth, while pushing it out of its locked position. This may be accomplished in one motion with one hand, by placing two or four fingers across the V of one piece and the ball of the thumb on the opposite side. A gentle squeeze will spread the V slightly and push the two pieces apart. In Figure 11.5, the left hand stabilizes the piece while the right hand spreads both pieces and separates them. The Tetrahedral Atom Figure Assembling the tetrahedral atom with bonds. Figure Disassembling the tetrahedral atom.

62 EXPERIMENT 11: The Trigonal-Bipyramid Atom The Octahedral Atom Figure 11.6. Assembly of a trigonal bipyramid.

The octahedral atom is assembled by pushing the two octahedral pieces together. Figure 11.7.

The octahedral atom is disassembled by placing two fingers of each hand around the horizontal bonds of

A linear bond is joined at right angles with a trigonal atom using the same push-pull motion as for the

4 62 EXPERIMENT 11: The Trigonal-Bipyramid Atom The Octahedral Atom Figure Assembly of a trigonal bipyramid. Figure Assembly of an octahedral atom. The octahedral atom is assembled by pushing the two octahedral pieces together. Figure Disassembly of a trigonal bipyramid. The octahedral atom is disassembled by placing two fingers of each hand around the horizontal bonds of each respective piece and gently pulling the pieces apart as shown in Figure A linear bond is joined at right angles with a trigonal atom using the same push-pull motion as for the tetrahedral atom. The trigonal bipyramid is disassembled by slightly spreading the opening of the trigonal atom with the thumbs while using the two fingers of the right hand to pull the linear bond toward the user. Figure Disassembly of the octahedral atom.

5 EXPERIMENT 11: 63 Creating Bonds between Atoms Bonds are formed between atoms by joining the rod of one atom with the tube of another. The pieces should be gripped firmly as shown to prevent bending of the rod. Electron Groups Electron groups are any electron cloud that acts to repel another group of electrons. This would include single, double, triple bonds as well as lone pairs. The idea of an electron group or cloud is at the heart of the VSEPR model describing the repulsive interactions that result from coulombic forces within atoms. How much of a repulsive force occurs determines the geometry of the molecule (Table 11.1). Figure Creating bonds between atoms. Instructions courtesy of Darling Models TM, P.O. Box 1818, Stow, OH or on the Web at Hybridization When atoms come together to form molecules, the orbitals found within the atom are not the same as they were when they were a single atom. Hybridization is the mathematical way in which the changes in the shapes and energies of orbitals are described and occurs most frequently with atoms in the interior of molecules. The type of hybridization that occurs depends on the number of available orbitals participating in the bonding, such that the number of atomic orbitals that goes in equals the number of degenerate hybrid orbitals that come out. Table VSEPR geometry. # of e Groups e Pair Geometry # of Lone Pairs Molecular Geometry Ideal Bond Angles 2 linear 0 linear trigonal planar 0 trigonal planar trigonal planar 1 bent tetrahedral 0 tetrahedral tetrahedral 1 trigonal pyramid tetrahedral 2 bent trigonal bipyramidal 0 trigonal bipyramidal 90, 120, trigonal bipyramidal 1 seesaw 90, 120, trigonal bipyramidal 2 t-shaped 90, trigonal bipyramidal 3 linear octahedral 0 octahedral 90 6 octahedral 1 square pyramidal 90 6 octahedral 2 square planar 90

6 64 EXPERIMENT 11: Drawing Molecules in 3-D Use the model you build to help you draw a 3-D drawing of the molecule. Rotate the molecule so that as many bonds and/or lone pairs as possible are in the same plane. Draw this portion of the molecule. Without moving the model, look for bonds projecting out of the plane. Any bonds projected toward you should be indicated with a solid wedge and bonds projected away from you should be drawn with a dashed triangle. See example for water molecule shown on page 66. The lone pairs are in the plane, while one O H bond projects toward you and the other O H bond is projecting out of the plane away from you. Multiple Central Atoms For molecules with more than one central atom, give the electron pair geometry and geometry (shape) around each central atom. Mark the information for each atom so that it is apparent which information goes with which atom. See the second example for more information. Table List of molecules. List 1 List 2 List 3 List 4 1 CCl 4 NH 4 + PO 4 3 CF 4 2 PCl 5 NO 2 NO 3 CO 2 3 SO 3 2 PBr 5 SbF 5 CH 3 Cl 4 CO 3 2 PCl 6 IF 3 AsI 5 5 ICl 2 ICl 3 ICl 2 + BrF 5 6 CHCH NH 2 NH 2 C 2 O CH 3 OH CH 3 OCH 3 (O is bonded to two carbons) CH 3 CHO CHOCH 3 (O is bonded to two carbons) 8 CH 3 CN CH Cl CH 3 COO CH 3 NH 2 9 SF 6 XeF 2 SeF 4 SF 2 10 XeF 4 ClO 3 PCl 3 PF 3 11 C 6 H 6 (all carbons in the ring, don t forget resonance structures) O 3 (center O, don t forget resonance structures) C 6 F 6 (all carbons in the ring, don t forget resonance structures) O=CN (don t forget resonance structures) 12 C 7 H 14 (all carbons in the ring) C 4 H 8 (all carbons in the ring) C 5 H 10 (all carbons in the ring) C 6 H 6 (all carbons in the ring)

7 EXPERIMENT 11: 65 For you and your lab partner to work on the same computer, you will need to have two different browsers open. For example, you would need to log onto Chem21 using Internet Explorer while your lab partner logged onto Chem21 using Chrome or Firefox. You and your lab partner MUST enter the same List Number so that you are working on the same list of molecules. Compound 1: CH 3 CH Number of Number of Bonds Valence Non- Points Single Double Triple Points Hybridization/Geometry Electron Groups Hybridization Electron Geometry Molecular Geometry 3D Drawing

8 66 EXPERIMENT 11: Examples Compound 1: H 2 O Number of Number of Bonds Valence Non- Points Single Double Triple Points Hybridization/Geometry Electron Groups Hybridization Electron Geometry Molecular Geometry 4 sp 3 tetrahedral bent 3D Drawing

9 EXPERIMENT 11: 67 Compound 2: CH 3 CH Number of Number of Bonds Valence Non- Points Single Double Triple Points Hybridization/Geometry Electron Groups Hybridization Electron Geometry Molecular Geometry 3 sp 2 trigonal planar trigonal planar 3D Drawing

10 68 EXPERIMENT 11:

Chapter 13: Phenomena

Chapter 13: Phenomena Phenomena: Scientists measured the bond angles of some common molecules. In the pictures below each line represents a bond that contains 2 electrons. If multiple lines are drawn together