Activity Formal Charge and VSEPR Theory for Expanded Octets
|
|
- Robert Fletcher
- 6 years ago
- Views:
Transcription
1 Activity Formal Charge and VSEPR Theory for Expanded Octets Directions: This Guided Learning Activity (GLA) goes over formal charge and the structures of molecules with expanded octets. Part A introduces expanded octets and formal charge. Part B discusses drawing Lewis structures of expanded octets and Part C demonstrates how to predict the electron and molecular geometries of expanded octets using VSEPR Theory. This worksheet is accompanied by an indepth key. See for additional materials. Part A Formal Charge Formal charge is defined as the charge an atom in any compound would have if the electrons were being shared equally between the atoms in a covalent bond. It helps us determine whether a central atom will form an expanded octet. (We will discuss expanded octets in Part B below.) We use the following equation to calculate formal charge: Formal charge (F.C.) = #valence electrons #nonbonding electrons #bonds For example, we can assign a formal charge to each atom in HF: F.C. (H) = = 0 F.C. (F) = = 0 So the formal charge on H is 0 and the formal charge on F is 0. Keep in mind that we assign a formal charge to each individual atom in a molecule, treating individual atoms in a molecule as separate atoms. The sum of each of the formal charges on the atoms in a molecule or an ion will be equal to the total charge of the molecule or ion. Practice: Determine the formal charge of each element in the molecules below: a) ClF 3 We must calculate the formal charge of the chlorine and each of the fluorine atoms. Since the fluorine atoms are equivalent, they will all have the same formal charge. F.C. (Cl) = = 0 F.C. (F) = = 0 We can also label the molecule with the individual formal charge on each atom: Activity Page 1 of 7
2 b) NO 3 We must calculate the formal charge of the nitrogen atoms and each of the oxygen atoms. In this example, two of the oxygen atoms are equivalent (the single bond O) and the other is not (the double bond O=). The equivalent oxygen atoms will have the same formal charge, but the double bond oxygen will have a different formal charge: F.C. (N) = = +1 F.C. (O) = = 1 F.C. (O=) = = 0 We can once again label the molecule with the individual formal charge on each atom: Example #1 Determine the formal charge of each element in the ions below: a) PO 4 3 b) OCN Part B Lewis Structures and Expanded Octets Atoms in the third period and below on the periodic table are able to form expanded octets, which means they are able to have more than 8 electrons in their valence shell. This is because atoms in Period 3 and beyond, the dorbitals can be occupied. We just saw one example of an expanded octet in Part A, the ClF 3 molecule. Although the chlorine atom has 10 electrons in its valence shell, it is stable because it has a formal charge of 0. A molecule is the most stable when the formal charge on each of its atoms is closer to or equal to 0 and/or when any negative formal charge is assigned to the most electronegative atom. Keep in mind that the formal charge on a molecule or ion must be equal to the total charge on the molecule or ion. We also assign formal charges to Lewis structures to help us determine which structure is most stable when there is more than one way to draw a Lewis structure. For example, if we draw the Lewis structure for the sulfate ion, SO 4 2, by following only the octet rule, we would get the following structure: Activity Page 2 of 7
3 Although it does follow the octet rule, the most stable Lewis structure of the sulfate ion actually has 12 electrons in the valence shell of sulfur, as shown below: The reason why the second Lewis structure is more stable is because of the rules of formal charge. The figure below shows the formal charge of each atom on each molecule: Notice that the all five of the atoms in the structure on the left have nonzero formal charge and sulfur has a very high formal charge of +2. Once we form double bonds to the sulfur from two of the oxygen atoms, it significantly reduces the formal charge on the molecule, shown in the structure on the right. Example #2 Draw the Lewis structure for each ion. Expand the octet on the central atom to reduce formal charge if necessary. a) ClO 4 b) SO 3 2 Part C VSEPR Theory for Expanded Octets The Valence Shell Electron Repulsion (VSEPR) Theory states that electron groups position themselves around the nucleus to minimize interactions between the groups. You may recall discussing molecular shapes for molecules that have 2, 3, and 4 electron groups around the central atom in Chemistry 151. When there are more than four electron groups around the central atom, as in the case with expanded Activity Page 3 of 7
4 octets, more kinds of electron and molecular shapes are introduced by the Valence Shell Electron Pair Repulsion (VSEPR) Theory, as shown in the table below. Refer to GLA VSPER Theory for a review of additional molecular and electron geometries. A complete list of the electron and molecular geometries is included at the end of this GLA. Number of electron groups around the central atom Number of bonding electron groups Number of lone pair electrons Electron geometry Molecular geometry Bond Angle Example 5 0 Trigonal Bipyramidal SeeSaw Trigonal Bipyramidal 3 2 TShaped 120, 2 3 Linear 6 0 Octahedral Octahedral Square Pyramidal Square Planar Activity Page 4 of 7
5 3 3 TShaped 2 4 Linear Practice: Draw the Lewis structure of each of the following molecules or ions. Determine the electron and molecular geometry of each. a) ClF 3 The chlorine atom has five electron groups around it. Three of the electron groups are bonds and the other two are lone pairs: Electron geometry: trigonal bipyramidal Molecular geometry: Tshaped b) XeF 4 The xenon atom has six electron groups around it. Four of the electron groups are bonds and the other two are lone pairs: Electron geometry: octahedral Molecular geometry: square planar Example #3 Draw the Lewis structure of each of the following molecules. Determine the electron and molecular geometry of each. a) ICl 5 b) SF 4O Activity Page 5 of 7
6 Part D Extra Practice Draw the Lewis structure of each of the following molecules or ions. Determine the formal charge on each atom and expand the octet on the central atom, if necessary, to reduce formal charge. Determine the electron and molecular geometries. 1. BrF 5 2. SF 6 3. IBr 4 4. SO 2 5. ClO 2 6. XeF 2O 3 7. PO 4 8. SF 4 9. NNO 10. NNN Activity Page 6 of 7
7 Table of Electron and Molecular Geometries Source: Openstax Chemistry Textbook (available free at at Activity Page 7 of 7
Practice Worksheet for Lewis Structures (Mahaffy Ch )
Practice Worksheet for Lewis Structures (Mahaffy Ch. 10.1 10.5 ) 1. Main concepts Lewis Structures a. Connectivity b. Bonds & Lone pairs c. Electron Geometry & Molecular Shape d. Resonance Structures Formal
More informationActivity Hybrid Atomic Orbitals
Activity 201 8 Hybrid Atomic Orbitals Directions: This Guided Learning Activity (GLA) discusses Hybrid Atomic Orbitals, which are the basis for Valence Bond Theory. Part A introduces σ- and π-bonds. Part
More informationLewis Structure. Lewis Structures & VSEPR. Octet & Duet Rules. Steps for drawing Lewis Structures
Lewis Structure Lewis Structures & VSEPR Lewis Structures shows how the are arranged among the atoms of a molecule There are rules for Lewis Structures that are based on the formation of a Atoms want to
More informationStructures, Shapes and Polarity. of Molecules. Level 2 recap: - Polar and non polar bonds - Lewis diagrams - Lone pairs - Shapes - Polarity
Structures, Shapes and Polarity Level 2 recap: - Polar and non polar bonds - Lewis diagrams - Lone pairs - Shapes - Polarity of Molecules Do now: Brainstorm what you know/remember about these L2 concepts
More informationVSEPR. Valence Shell Electron Pair Repulsion Theory
VSEPR Valence Shell Electron Pair Repulsion Theory Vocabulary: domain = any electron pair or bond (single, double or triple) is considered one domain. bonding pair = shared pair = any electron pair that
More informationLewis structures show the number and type of bonds between atoms in a molecule or polyatomic ion.
VSEPR & Geometry Lewis structures show the number and type of bonds between atoms in a molecule or polyatomic ion. Lewis structures are not intended to show the 3-dimensional structure (i.e. shape or geometry)
More informationBonding and Molecular Structure - PART 1 - VSEPR
Bonding and Molecular Structure - PART 1 - VSEPR Objectives: 1. Understand and become proficient at using VSEPR to predict the geometries of simple molecules and ions. 2. Become proficient at predicting
More informationFill in the chart below to determine the valence electrons of elements 3-10
Chemistry 11 Atomic Theory IV Name: Date: Block: 1. Lewis Diagrams 2. VSEPR Lewis Diagrams Lewis diagrams show the bonding between atoms of a molecule. Only the outermost electrons of an atom (called electrons)
More informationChemistry and the material world Lecture 3
Chemistry and the material world 123.102 Lecture 3 Electronic bookkeeping we need a way of finding out in which proportions two or more atoms make up a molecule is it CH 3 or CH 4 or CH 5? counting valence
More informationCHEMICAL BONDING. Chemical Bonds. Ionic Bonding. Lewis Symbols
CHEMICAL BONDING Chemical Bonds Lewis Symbols Octet Rule whenever possible, valence electrons in covalent compounds distribute so that each main-group element is surrounded by 8 electrons (except hydrogen
More informationChapter 13: Phenomena
Chapter 13: Phenomena Phenomena: Scientists measured the bond angles of some common molecules. In the pictures below each line represents a bond that contains 2 electrons. If multiple lines are drawn together
More informationEx. 1) F F bond in F = 0 < % covalent, no transfer of electrons
#60 Notes Unit 8: Bonding Ch. Bonding I. Bond Character Bonds are usually combinations of ionic and covalent character. The electronegativity difference is used to determine a bond s character. Electronegativity
More informationValence Shell Electron Pair Repulsion Model
Valence Shell Electron Pair Repulsion Model Why? Molecules adopt a shape that minimizes their energy. In most cases simply considering the repulsive energy of electron pairs is sufficient to predict molecular
More informationExperiment 15. The Valence Shell Electron Pair Repulsion (VSEPR) Theory of Directed Valency: An exercise
Experiment 15 The Valence Shell Electron Pair Repulsion (VSEPR) Theory of Directed Valency: An exercise Attempts to understand and predict the shapes of molecules using either the valencebond theory or
More informationAP Chemistry- Practice Bonding Questions for Exam
AP Chemistry- Practice Bonding Questions for Exam Multiple Choice Identify the choice that best completes the statement or answers the question. 1. Which of the following is a correct Lewis structure for
More informationMolecular Geometry. Objectives N H H. The objectives of this laboratory are to:
Objectives The objectives of this laboratory are to: Molecular Geometry Write Lewis structure representations of the bonding and valence electrons in molecules. Use the VSEPR model to predict the molecular
More informationValence Shell Electron Pair repulsion
Molecular Geometry Valence Shell Electron Pair repulsion The valence shell electron pair repulsion model (VSEPR model) assumes that electron pairs repel one another. (VSEPR) model gives helps determine
More information(A) 1 bonding pair (B) 1 bonding pair and 1 lone pair (C) 2 bonding pairs (D) 2 bonding pairs and 2 lone pairs
AP Chemistry - Problem Drill 13: Lewis Structures and VSPER No. 1 of 10 1. Lewis structure is used to model covalent bonds of a molecule or ion. Covalent bonds are a type of chemical bonding formed by
More informationCHEM 110 Exam 2 - Practice Test 1 - Solutions
CHEM 110 Exam 2 - Practice Test 1 - Solutions 1D 1 has a triple bond. 2 has a double bond. 3 and 4 have single bonds. The stronger the bond, the shorter the length. 2A A 1:1 ratio means there must be the
More information2011, Robert Ayton. All rights reserved.
Chemical Bonding Outline 1. Lewis Dot Structures 2. Bonds 3. Formal Charges 4. VSEPR (Molecular Geometry and Hybridzation) 5. Common Resonance Structures and Dimerization Review 1. Lewis Dot Structures
More informationChapter 10 Molecular Geometry and Chemical Bonding Theory. Copyright Cengage Learning. All rights reserved. 10 1
Chapter 10 Molecular Geometry and Chemical Bonding Theory Copyright Cengage Learning. All rights reserved. 10 1 Molecular geometry is the general shape of a molecule, as determined by the relative positions
More informationHonors Chemistry Unit 6 ( )
Honors Chemistry Unit 6 (2017-2018) Lewis Dot Structures VSEPR Structures 1 We are learning to: 1. Represent compounds with Lewis structures. 2. Apply the VSEPR theory to determine the molecular geometry
More informationExperiment 21 Lewis structures and VSEPR Theory
Experiment 21 Lewis structures and VSEPR Theory Introduction 1. Lewis Structures and Formal Charge LG.N. Lewis, at the University of California at Berkeley devised a simple way to understand the nature
More informationCovalent Compounds: Bonding Theories and Molecular Structure
CHM 123 Chapter 8 Covalent Compounds: Bonding Theories and Molecular Structure 8.1 Molecular shapes and VSEPR theory VSEPR theory proposes that the geometric arrangement of terminal atoms, or groups of
More informationExample: Write the Lewis structure of XeF 4. Example: Write the Lewis structure of I 3-. Example: Select the favored resonance structure of the PO 4
Expanded valence shells (extended octets) more than 8e - around a central atom Extended octets are formed only by atoms with vacant d-orbitals in the valence shell (p-elements from the third or later periods)
More informationChemical Bonding II: Molecular Geometry and Hybridization of Atomic Orbitals
Chemical Bonding II: Molecular Geometry and Hybridization of Atomic Orbitals 1 Chemical Bonding II Molecular Geometry (10.1) Dipole Moments (10.2) Valence Bond Theory (10.3) Hybridization of Atomic Orbitals
More informationCHEMISTRY. Chapter 10 Theories of Bonding and Structure. The Molecular Nature of Matter. Jespersen Brady Hyslop SIXTH EDITION
CHEMISTRY The Molecular Nature of Matter SIXTH EDITION Jespersen Brady Hyslop Chapter 10 Theories of Bonding and Structure Copyright 2012 by John Wiley & Sons, Inc. Molecular Structures Molecules containing
More informationIllinois Central College CHEMISTRY 130 Laboratory Section: To predict the shapes of molecules based on their Lewis Structures.
Exercise 12 Page 1 Illinois Central College CEMISTRY 130 Laboratory Section: Molecular Structure Name: Objectives To predict the shapes of molecules based on their Lewis Structures. Background The Valence
More informationCHEMISTRY - MCMURRY 7E CH.7 - COVALENT BONDING AND ELECTRON DOT STRUCTURES
!! www.clutchprep.com CONCEPT: ELECTRONIC GEOMETRY When drawing a compound you have to take into account two different systems of geometrical shape. The simpler system known as electronic geometry or shape
More informationMolecular Geometry. Valence Shell Electron Pair. What Determines the Shape of a Molecule? Repulsion Theory (VSEPR) Localized Electron Model
Molecular Geometry Learn Shapes you will Because the physical and chemical properties of compounds are tied to their structures, the importance of molecular geometry can not be overstated. Localized Electron
More informationChemical Bonding I: Basic Concepts
Chemical Bonding I: Basic Concepts Chapter 9 Chang & Goldsby Modified by Dr. Hahn Copyright McGraw-Hill Education. All rights reserved. No reproduction or distribution without the prior written consent
More informationGeneral and Inorganic Chemistry I.
General and Inorganic Chemistry I. Lecture 1 István Szalai Eötvös University István Szalai (Eötvös University) Lecture 1 1 / 29 Outline István Szalai (Eötvös University) Lecture 1 2 / 29 Lewis Formulas
More informationPolar bonds, polar molecules and the shape of molecules.
Chapter 3 Polar bonds, polar molecules and the shape of molecules. Polar and non-polar bonds In homonuclear diatomic molecules such as H 2 or Cl 2 electrons are shared equally between equal atoms. The
More informationVSEPR. Ch10. Valence Shell Electron Pair Repulsion theory allows you to predict molecular shape. Lewis Dot theory extended to 3 dimensions.
Ch10 VSEPR Valence Shell Electron Pair Repulsion theory allows you to predict molecular shape. Lewis Dot theory extended to 3 dimensions. version 1.5 Nick DeMello, PhD. 2007-2016 Valence Shell Electron
More informationGroup 1 Group 2 Group 3 Group 4 Group 5 Group 6 Group 7 Group 8. Na Mg Al Si P S Cl Ar
CHM 111 Chapters 7 and 8 Worksheet and Study Guide Purpose: This is a guide for your as you work through the chapter. The major topics are provided so that you can write notes on each topic and work the
More informationMolecular Geometry & Polarity
Molecular Geometry & Polarity Learn Shapes you will Because the physical and chemical properties of compounds are tied to their structures, the importance of molecular geometry can not be overstated. Localized
More informationREVIEW: VALENCE ELECTRONS CHEMICAL BONDS: LEWIS SYMBOLS: CHEMICAL BONDING. What are valence electrons?
REVIEW: VALENCE ELECTRONS 13 CHEMICAL BONDING What are valence electrons? Which groups on the periodic table readily give up electrons? What group readily accepts electrons? CHEMICAL BONDS: What are chemical
More informationChem 121 Exam 4 Practice Exam
Chem 121 Exam 4 Practice Exam 1. What is the correct electron configuration for bromine? b. 1s 2 2s 2 2p 6 3s 2 3p 6 3d 9 4s 2 4p 6 c. 1s 2 2s 2 2p 6 3s 2 3p 6 3d 10 4s 2 4p 5 d. 1s 2 2s 2 2p 6 3s 2 3p
More informationChapter 9 Molecular Geometries. and Bonding Theories
Chapter 9 Molecular Geometries and Bonding Theories Coverage of Chapter 9 9.1 All 9.2 All 9.3 All 9.4 All 9.5 Omit Hybridization Involving d Orbitals 9.6 All 9.7 and 9.8 Omit ALL MOLECULAR SHAPES The shape
More informationB. Draw the best dot structure you can for HNNH, where the atoms are connected as written.
Recitation, Week 15, Fall 2018 14. (Unit II) The proper assignments of oxidation numbers (ON) are necessary for recognizing and balancing redox reactions (e.g. questions IV and V on page 3), but they are
More informationHelpful Hints Lewis Structures Octet Rule For Lewis structures of covalent compounds least electronegative
Helpful Hints Lewis Structures Octet Rule Lewis structures are a basic representation of how atoms are arranged in compounds based on bond formation by the valence electrons. A Lewis dot symbol of an atom
More informationThe Shapes of Molecules. Chemistry II
The Shapes of Molecules Chemistry II Lewis Structures DEFINITIN: A structure of a molecule showing how the valence electrons are arranged. 1) nly the valence electrons appear in a Lewis structure. 2) The
More information5 Polyatomic molecules
s manual for Burrows et.al. Chemistry 3 Third edition 5 Polyatomic molecules Answers to worked examples WE 5.1 Formal charges in N 2 (on p. 221 in Chemistry 3 ) Use formal charges to decide whether oxygen
More informationChapter 7. Chemical Bonding I: Basic Concepts
Chapter 7. Chemical Bonding I: Basic Concepts Chemical bond: is an attractive force that holds 2 atoms together and forms as a result of interactions between electrons found in combining atoms We rarely
More informationMolecular Geometry and Chemical Bonding Theory
Molecular Geometry and Chemical Bonding Theory The Valence -Shell Electron -Pair Repulsion (VSEPR) Model predicts the shapes of the molecules and ions by assuming that the valence shell electron pairs
More informationN = 727 Mean = 68% Diff T-Test P-Value SI 223 (31%) 71% No SI 504 (69%) 66% Test 2 - Letter Grade Distribution by SI Attendance
CHEM 200/202 Exam 2 N = 727 Mean = 68% Diff T-Test P-Value SI 223 (31%) 71% No SI 504 (69%) 66% 5%
More informationCHM2045 F13--Exam # MULTIPLE CHOICE. Choose the one alternative that best completes the statement or answers the question.
CHM2045 F13--Exam #2 2013.10.18 MULTIPLE CHOICE. Choose the one alternative that best completes the statement or answers the question. 1) A valid Lewis structure of cannot be drawn without violating the
More informationCovalent Bonds: overlap of orbitals σ-bond π-bond Molecular Orbitals
Covalent Bonding What is covalent bonding? Covalent Bonds: overlap of orbitals σ-bond π-bond Molecular Orbitals Hybrid Orbital Formation Shapes of Hybrid Orbitals Hybrid orbitals and Multiple Bonds resonance
More informationShapes of Molecules. Lewis structures are useful but don t allow prediction of the shape of a molecule.
Shapes of Molecules Lewis structures are useful but don t allow prediction of the shape of a molecule. H O H H O H Can use a simple theory based on electron repulsion to predict structure (for non-transition
More informationChapter 9 Molecular Geometry. Lewis Theory-VSEPR Valence Bond Theory Molecular Orbital Theory
Chapter 9 Molecular Geometry Lewis Theory-VSEPR Valence Bond Theory Molecular Orbital Theory Sulfanilamide Lewis Structures and the Real 3D-Shape of Molecules Lewis Theory of Molecular Shape and Polarity
More informationCOVALENT BONDING CHEMICAL BONDING I: LEWIS MODEL. Chapter 7
Chapter 7 P a g e 1 COVALENT BONDING Covalent Bonds Covalent bonds occur between two or more nonmetals. The two atoms share electrons between them, composing a molecule. Covalently bonded compounds are
More informationSubtopic 4.2 MOLECULAR SHAPE AND POLARITY
Subtopic 4.2 MOLECULAR SHAPE AND POLARITY 1 LEARNING OUTCOMES (covalent bonding) 1. Draw the Lewis structure of covalent molecules (octet rule such as NH 3, CCl 4, H 2 O, CO 2, N 2 O 4, and exception to
More information8.3 Bonding Theories > Chapter 8 Covalent Bonding. 8.3 Bonding Theories. 8.1 Molecular Compounds 8.2 The Nature of Covalent Bonding
Chapter 8 Covalent Bonding 8.1 Molecular Compounds 8.2 The Nature of Covalent Bonding 8.3 Bonding Theories 8.4 Polar Bonds and Molecules 1 Molecular Shape What information does a structural formula give
More informationChapter 9 The Shapes of Molecules Cocaine
Chapter 9 The Shapes of Molecules 1 Cocaine 10.1 Depicting Molecules & Ions with Lewis Structures 2 Number of Covalent Bonds 3 The number of covalent bonds can be determined from the number of electrons
More informationChapters 8 and 9. Octet Rule Breakers Shapes
Chapters 8 and 9 Octet Rule Breakers Shapes Bond Energies Bond Energy (review): The energy needed to break one mole of covalent bonds in the gas phase Breaking bonds consumes energy; forming bonds releases
More informationCHEM1101 Worksheet 6: Lone Pairs and Molecular Geometry
CHEM1101 Worksheet 6: Lone Pairs and Molecular Geometry Model 1: Oxidation numbers Oxidation numbers are a useful accountancy tool to help keep track of electrons in compounds and reactions. This is particularly
More informationChapter 4. Molecular Structure and Orbitals
Chapter 4 Molecular Structure and Orbitals Chapter 4 Table of Contents (4.1) (4.2) (4.3) (4.4) (4.5) (4.6) (4.7) Molecular structure: The VSEPR model Bond polarity and dipole moments Hybridization and
More informationMolecular Geometry and intermolecular forces. Unit 4 Chapter 9 and 11.2
1 Molecular Geometry and intermolecular forces Unit 4 Chapter 9 and 11.2 2 Unit 4.1 Chapter 9.1-9.3 3 Review of bonding Ionic compound (metal/nonmetal) creates a lattice Formula doesn t tell the exact
More informationCHEMISTRY - ZUMDAHL 2E CH.4 - MOLECULAR STRUCTURE AND ORBITALS.
!! www.clutchprep.com CONCEPT: ELECTRONIC GEOMETRY When drawing a compound you have to take into account two different systems of geometrical shape. The simpler system known as electronic geometry or shape
More informationForm J. Test #4 Last Name First Name Zumdahl, Chapters 8 and 9 November 23, 2004
Form J Chemistry 1441-023 Name (please print) Test #4 Last Name First Name Zumdahl, Chapters 8 and 9 November 23, 2004 Instructions: 1. This exam consists of 27 questions. 2. No scratch paper is allowed.
More informationEXPERIMENT #13 Lewis Structures and Molecular Geometry
OBJECTIVES: EXPERIMENT #13 s and Draw Lewis structures of atoms, ions, and molecules Build models of linear, trigonal planar tetrahedral, trigonal bipyramidal, and octahedral arrangements of electron pairs
More information2. Write the electron configuration notation and the electron dot notation for each: (a) Ni atom (b) Ni 2+ ion (c) Ni 3+ ion
EXTRA HOMEWORK 2A 1. Predict whether each of the following types of matter will be bonded with ionic, covalent, or metallic bonds, and identify whether each will be composed of atoms, ions, or molcules
More informationName Unit Three MC Practice March 15, 2017
Unit Three: Bonding & Molecular Geometry Name Unit Three MC Practice March 15, 2017 1. What is the hybridization of the oxygen atom in water? a) sp b) sp 2 c) sp 3 d) It is not hybridized 2. When a double
More informationLET S FIRST REVIEW IONIC BONDING
COVALENT BONDING LET S FIRST REVIEW IONIC BONDING In an IONIC bond, electrons are lost or gained, resulting in the formation of IONS in ionic compounds. K F K F K F K F K F K F K + F _ The compound potassium
More informationCheck Your Solution A comparison with the figures in Figure 4.31 on page 234 of the student textbook confirms the results.
Predicting the Shape of a Molecule (Student textbook page 236) 11. What molecular shape is represented by each of the following VSEPR notations? a. AX 3 b. AX 5 E You need to assign a molecular shape that
More informationChemical Bonding II. Molecular Geometry Valence Bond Theory Phys./Chem. Properties Quantum Mechanics Sigma & Pi bonds Hybridization MO theory
Chemical Bonding II Molecular Geometry Valence Bond Theory Phys./Chem. Properties Quantum Mechanics Sigma & Pi bonds ybridization MO theory 1 Molecular Geometry 3-D arrangement of atoms 2 VSEPR Valence-shell
More informationA DOT STRUCTURE FOR A LARGER MOLECULE ETHANOL! Count valence electrons
212 A DOT STRUCTURE FOR A LARGER MOLECULE Count valence electrons Pick central atom and draw skeletal structure - central atom is usually the one that needs to gain the most electrons! - skeletal structure
More informationExperiment 12 Molecular Architecture
Experiment 12 Molecular Architecture PRE-LABORATORY QUESTIONS The following preparatory questions should be answered before coming to laboratory. They are intended to introduce you to several ideas that
More informationCh 13: Covalent Bonding
Ch 13: Covalent Bonding Section 13: Valence-Shell Electron-Pair Repulsion 1. Recall the rules for drawing Lewis dot structures 2. Remember the special situations: - Resonance structures - ormal charges
More informationWhat Do Molecules Look Like?
What Do Molecules Look Like? The Lewis Dot Structure approach provides some insight into molecular structure in terms of bonding, but what about 3D geometry? Recall that we have two types of electron pairs:
More informationCHAPTER 8 BONDING: GENERAL CONCEPTS
Advanced Chemistry Name Hour Advanced Chemistry Approximate Timeline Students are expected to keep up with class work when absent. CHAPTER 8 BONDING: GENERAL CONCEPTS Day Plans for the day Assignment(s)
More informationEXAM II Material. Part I Chemical Bonding I Lewis Theory Chapter 9 pages A. Drawing electron dot structures HOW TO:
CHEMISTRY 112 LECTURE EXAM II Material Part I Chemical Bonding I Lewis Theory Chapter 9 pages 376-386 A. Drawing electron dot structures HOW TO: 1. Write e- dot structure for the individual atoms. 2. a)
More informationExperiment #2. Lewis Structures
Experiment #2. Lewis Structures A Lewis structure shows how the valence electrons are arranged and indicates the bonding between atoms in a molecule. We represent the elements by their symbols. The shared
More informationWould you expect SeF6 to be soluble in water? Yes No Explain your answer in terms of the shape and polarity of SeF6.
COLLATED QUESTIONS Lewis structures and shapes (up to six electron pairs about the central atom for molecules and polyatomic ions, including those with multiple bonds), polarity of molecules. 2017:3 (c)
More informationIntroduction to VSEPR Theory 1
1 Class 8: Introduction to VSEPR Theory Sec 10.2 VSEPR Theory: The Five Basic Shapes Two Electron Groups: Linear Geometry Three Electron Groups: Trigonal Planar Geometry Four Electron Groups: Tetrahedral
More information: O: (1) (2) (3) (4) Page 1 of 6 : : : : : : (8) H H
Experiment #12 MOLECULAR MODELS An aspect of chemistry, which traditionally proves to be difficult to many students, is the visualization of compounds, ions, and molecules in three dimensional space. In
More informationLewis Structures and Molecular Shapes
Lewis Structures and Molecular Shapes Rules for Writing Lewis Structures 1. Determine the correct skeleton structure (connectivity of atoms). Usually, the most electronegative atoms go around the edges
More informationCH 222 Chapter Seven Concept Guide
CH 222 Chapter Seven Concept Guide 1. Lewis Structures Draw the Lewis Dot Structure for cyanide ion, CN -. 1 C at 4 electrons = 4 electrons 1 N at 5 electrons = 5 electrons -1 charge = + 1 electron Total
More information10-1. The Shapes of Molecules, chapter 10
10-1 The Shapes of Molecules, chapter 10 The Shapes of Molecules; Goals 10.1 Depicting Molecules and Ions with Lewis Structures 10.2 Valence-Shell Electron-Pair Repulsion (VSEPR) Theory 10.3 Molecular
More informationCopyright The McGraw-Hill Companies, Inc. Permission required for reproduction or display. Chapter 10. The Shapes of Molecules 10-1
Chapter 10 The Shapes of Molecules 10-1 The Shapes of Molecules 10.1 Depicting Molecules and Ions with Lewis Structures 10.2 Valence-Shell Electron-Pair Repulsion (VSEPR) Theory and Molecular Shape 10.3
More informationChapter 9 Molecular Geometry and Bonding Theories
Chapter 9 Molecular Geometry and Bonding Theories molecular shapes the VSEPR model molecular shape and molecular polarity covalent bonding and orbital overlap hybrid orbitals multiple bonds 9.1 Molecular
More information8.2 Hybrid Atomic Orbitals
420 Chapter 8 Advanced Theories of Covalent Bonding Answer: (a) is a π bond with a node along the axis connecting the nuclei while (b) and (c) are σ bonds that overlap along the axis. 8.2 Hybrid Atomic
More informationWhat is Bonding? The Octet Rule. Getting an Octet. Chemical Bonding and Molecular Shapes. (Chapter Three, Part Two)
Chemical Bonding and Molecular Shapes (Chapter Three, Part Two) What is Bonding? Bonding describes how atoms interact with each other in an attractive sense. There are three types of bonding: Ionic bonding
More informationLecture 17 - Covalent Bonding. Lecture 17 - VSEPR and Molecular Shape. Lecture 17 - Introduction. Lecture 17 - VSEPR and Molecular Shape
Chem 103, Section F0F Unit VI - Compounds Part II: Covalent Compounds Lecture 17 Using the Valence-Shell Electron-Pair Repulsion (VSEPR) Theory to predict molecular shapes Molecular shape and polarity
More informationChapter 9 Molecular Geometry and Bonding Theories
Lecture Presentation Chapter 9 Geometry James F. Kirby Quinnipiac University Hamden, CT Shapes Lewis Structures show bonding and lone pairs, but do not denote shape. However, we use Lewis Structures to
More informationMolecular Models: The shape of simple molecules and ions
Molecular Models: The shape of simple molecules and ions Background The shape of a molecule is very important when investigating its properties and reactivity. For example, compare CO 2 and SO 2. Carbon
More informationAt the end of this lesson, students should be able to :
At the end of this lesson, students should be able to : (a) Explain Valence Shell Electron Pair Repulsion theory (VSEPR) (b) Draw the basic molecular shapes: linear, planar, tetrahedral, and octahedral.
More informationUNIVERSITY OF VICTORIA. CHEMISTRY 101 Mid-Term Test 2, November
NAME Student No. SECTIN (circle one): A01 (Codding) A02 (Sirk) A03 (Briggs) Version A UNIVERSITY F VICTRIA CEMISTRY 101 Mid-Term Test 2, November 19 2010 Version A This test has two parts and 8 pages,
More informationChem 1075 Chapter 12 Chemical Bonding Lecture Outline. Chemical Bond Concept
Chem 1075 Chapter 12 Chemical Bonding Lecture Outline Slide 2 Chemical Bond Concept Recall that an atom has and electrons. Core electrons are found to the nucleus. Valence electrons are found in the s
More informationChemical Bonding. Types of Bonds. Ionic Bonding. Resonance Structures. Molecular Geometries. VSEPR Basic Shapes 3-D Notation Hybridization (Lab)
Chemical Bonding Types of Bonds Ionic Bonding Lewis Structures Covalent Bonding Resonance Structures Octet Rule Polar Molecules Molecular Geometries VSEPR Basic Shapes 3-D Notation Hybridization (Lab)
More informationAnnouncements. 10pm Room assignments for Exam III and TA Exam Review Sessions are posted on website. Look under Exam Info link
Announcements 1. Exam #3: Thursday, Dec. 6 th, 7:00-8:15pm (Conflict: 5:15-6:30pm) No calculators allowed 2. Activity 3: Making Models of Molecules lab write-up due tomorrow in discussion 3. Lon-capa HW
More informationbond energy- energy required to break a chemical bond -We can measure bond energy to determine strength of interaction
bond energy- energy required to break a chemical bond -We can measure bond energy to determine strength of interaction ionic compound- a metal reacts with a nonmetal Ionic bonds form when an atom that
More informationChapter 10. Geometry
Chapter 10 Molec cular Geometry 1 CHAPTER OUTLINE Molecular Geometry Molecular Polarity VSEPR Model Summary of Molecular Shapes Hybridization Molecular Orbital Theory Bond Angles 2 MOLECULAR GEOMETRY Molecular
More informationChapter 9: Molecular Geometries and Bonding Theories Learning Outcomes: Predict the three-dimensional shapes of molecules using the VSEPR model.
Chapter 9: Molecular Geometries and Bonding Theories Learning Outcomes: Predict the three-dimensional shapes of molecules using the VSEPR model. Determine whether a molecule is polar or nonpolar based
More informationCHEMICAL BONDING. Valence Electrons. Chapter Ten
CHEMICAL BONDING Chapter Ten Valence Electrons! The electrons occupying the outermost energy level of an atom are called the valence electrons; all other electrons are called the core electrons.! The valence
More informationCHM 151LL: Geometry of Covalent Compounds
CM 151LL: Geometry of Covalent Compounds Introduction Octet Rule A Lewis structure (or electrondot formula) is a twodimensional structural formula showing the arrangement of electrons around atoms in covalently
More informationChapter 9. Molecular Geometry and Bonding Theories
9.1 Molecular Shapes Read Sec. 9.1 and 9.2, then complete the Sample and Practice Exercises in these sections. Sample Exercise 9.1 (p. 347) Use the VSEPR model to predict the molecular geometries of a)
More informationLESSON 10. Glossary: Molecular Geometry. a quantitative measure of the degree of charge separation in a molecule. Dipole moment
LESSON 10 Glossary: Molecular Geometry Dipole moment Electronegativity Molecular geometry Pi bond Polar covalent bond Sigma bond Valence-shell electronpair repulsion (VSEPR) model a quantitative measure
More informationChemical Bonding AP Chemistry Ms. Grobsky
Chemical Bonding AP Chemistry Ms. Grobsky What Determines the Type of Bonding in Any Substance? Why do Atoms Bond? The key to answering the first question are found in the electronic structure of the atoms
More informationCHEMISTRY 112 LECTURE EXAM II Material
CHEMISTRY 112 LECTURE EXAM II Material Part I Chemical Bonding I Lewis Theory Chapter 9 pages 376-386 A. Drawing electron dot structures HOW TO: 1. Write e- dot structure for the individual atoms. 2. a)
More information