[AMI] Multi-residue method, by LC-MSMS, for the quantification of amitraz and its metabolites in fruit, vegetables, cereals and cereal products

Transcription

1 Multi-residue methods: all the mentioned substances will be searched for. The general reporting limit (RL) (mg/kg) is mentioned on the right side of each pesticide. The limit of quantification may vary depending on the matrix The abbreviated method name as used by the laboratory is mentioned in [brackets]. This certificate may only be used in correlation with this laboratory method code as mentioned on an analysis-report. New pesticides or updates of the certificate are indicated in green For an up to date list of the accredited analyses or the current version of this document: check our website: [AMI] Multi-residue method, by LC-MSMS, for the quantification of amitraz and its metabolites in fruit, vegetables, cereals and cereal products amitraz - 2,4-dimethylphenylformamide (DMF) N-2,4-dimethylphenyl-N-methylformamidine (DMFP) [CL1B] 1 Multi-residue method for the determination of captan & folpet in fruit and vegetables captan - folpet [CL2] Multi-residue method for the determination of organochlorine pesticides in milk and milk products aldrin chlordane (cis+trans+oxy-) pp'-dde pp'-ddd (TDE) pp'-ddt op-ddt DDT (sum) dieldrin α-endosulfan endrin 1 (sum) HCB HCH (sum) alfa-hch beta-hch heptachlor 1 (sum) lindane (gamma HCH) nitrofen pentachloraniline (PCA) quintozene (PCNB) quintozene (sum) [CS] Multi-residue method for the determination of dithiocarbamates in leafy vegetables, endive, leek (determined as CS 2 ) RL of CS 2 : 0.5 mg/kg Ferbam mancozeb maneb metiram propineb thiram zineb other dithiocarbamates [CS2] Multi-residue method for the determination of dithiocarbamates in fruit, vegetables (other than in [CS]-method), cereals and tobacco (determined as CS 2 ) RL of CS 2 : 0.05 mg/kg [RL tobacco: 0.5 mg/kg] Ferbam mancozeb maneb metiram propineb thiram zineb other dithiocarbamates 1/10

2 [DTC] 1 Multi-residue method for the determination of dithiocarbamates in fruit, vegetables and cereals - RL of CS 2 : mg/kg Ferbam mancozeb maneb metiram propineb thiram zineb other dithiocarbamates [GIB] 1 Multi-residue method, by LC-MSMS, for the quantification of Gibberellic acid in cereals and cereal products gibberellic acid A gibberellic acid A4 gibberellic acid A7 [GLY1] Multi-residue method, by LC-MSMS, for the quantification of glyphosate, AMPA and glufosinate in fruit, vegetables and cereals AMPA glufosinate glyphosate [GMS] Multi-residue method by GC-MSMS for 168 compounds, isomers and degradation products - quantification of pesticides in fruit, vegetables, potatoes, soil and water (for cereals and cereal products use GMS4, other commodities on request) aclonifen 0.02 acrinathrin - alachlor atrazine - benalaxyl (including benalaxyl-m) - benfluralin bifenazate 0.05 bifenox 0.05 bifenthrin - biphenyl 0.1 bromophos-ethyl - bromopropylate - bupirimate - buprofezin butralin - cadusafos - carbophenothion chinomethionate chlordane (sum of cis +trans) - chlorfenapyr ** - chlorfenson chlorobenzilate - chlorothalonil - chlorpropham (chlorpropham & 3-chloroaniline) chlorpyriphos-ethyl chlorpyriphos-methyl - chlorthal-dimethyl (DCPA) - chlozolinate - clomazone cyfluthrin (sum of isomers) - cyhalofop-butyl - cyhalothrin (lambda) - cypermethrin (sum of isomers) - cyprodinil - DDD (o,p ) - DDE (o,p ) - DDT (sum of p,p -DDT, o,p -DDT, p-p -DDE and p,p -TDE (DDD) expressed as DDT) - deltamethrin - diazinon - dichlofluanid dichlorvos - dicloran - dieldrin (sum of aldrin + dieldrin) - dicofol 1 (sum of isomers) - diethofencarb - diphenylamine ditalimfos - dodemorph - endosulfan (sum alfa + beta + -sulfate) - endrin EPN - 2/10

3 ethion - ethofumesate - ethoprofos ethoxyquin 1 - etofenprox - etrimfos - famoxadone fenarimol - fenazaquin 0.02 fenchlorphos - fenitrothion - fenpropathrin - fenpropimorph - fenvalerate (sum of isomers) - fipronil - flucythrinate - fludioxonil - flumetralin - flutolanil - fluvalinate-tau total formothion - furalaxyl - HCH 1 (sum of alfa + beta + delta + epsilon) - heptenophos - hexachlorobenzene (HCB) iprodione isocarbophos - isofenphos(-ethyl) - isofenphos-methyl - kresoxim-methyl - lindane 1 (gamma HCH) - malathion (sum of malathion + malaoxon) - mecarbam ** - mepanipyrim - mepronil - metazachlor - methacrifos - methidathion - metrafenone - metribuzin - mevinphos (sum of isomers) - mirex 1 myclobutanil - nitrofen - nitrothal isopropyl - nuarimol - oxadiazon - oxychlordane - oxyfluorfen paraoxon-ethyl parathion-ethyl - parathion-methyl 1 (sum of parathion-methyl + paraoxonmethyl)- penconazole - pendimethalin - pentachloroanisol - permethrin (sum of isomers) - phenylphenol (ortho-) phorate - phosalone - phosmet ** - phoxim 0.02 piperonyl butoxide - pirimiphos-ethyl - pirimiphos-methyl - procymidone - profenofos - profluralin - prometryn - propargite ** - propoxur - propyzamide - prothiofos - pyraclostrobin - pyrazophos - pyridaben - pyriproxyfen - quinalphos - quinoxyfen - quintozene PCNB (sum of quintozene + pentachloro-aniline) - silthiofam - simazine - spirodiclofen - spiromesifen ** - sulfotep - tecnazene - tefluthrin - terbufos terbuthylazine - tetrachlorvinphos - tetradifon - tolclofos-methyl - tolylfluanid 1 (sum of tolylfluanide + DMST 1 ) triazophos - trifluralin - vinclozolin - **: not in tobacco [GMS2] 1 Multi-residue method for the quantification of pesticides by GC-MSMS in vegetable oil (complementary to GMS3) aclonifen 0.02 alachlor benalaxyl (including benalaxyl-m) - bifenazate 0.05 bifenox 0.05 biphenyl 0.1 3/10

4 bromophos-ethyl - bromopropylate - cadusafos chinomethionate chlordane (sum of cis + trans) chlorfenson chlorobenzilate chlorothalonil - chlorpropham (chlorpropham + 3-chloroaniline) - chlorpyriphos-ethyl - chlorpyriphos-methyl - chlorthal-dimethyl (DCPA) - chlozolinate - cyhalofop-butyl DDD (o,p ) - DDE (o,p ) - DDT (sum of p,p -DDT, o,p -DDT, p-p -DDE and p,p -TDE (DDD) expressed as DDT) - diazinon - dichlofluanid dichlorvos - dicloran - dicofol (total) - dieldrin (sum of dieldrin + aldrin) - diphenylamine ditalimfos endosulfan (sum of alfa +beta + -sulfate) - endrin EPN - ethion - ethofumesate - ethoprophos - ethoxyquin - etofenprox etrimfos - famoxadone 0.02 fenchlorphos - fenitrothion - fludioxonil - formothion - HCH (sum of alfa + beta + delta + epsilon) - hexachlorobenzene - iprodione isocarbophos - isofenphos(-ethyl) - isofenphos-methyl - lindane - malathion (malathion + malaoxon) - mecarbam - mepronil - methacrifos methidathion - metrafenone metribuzin mevinphos (sum of isomers) - mirex nitrofen - oxadiazon oxyfluorfen paraoxon-ethyl parathion-ethyl - parathion-methyl (sum of parathion-methyl + paraoxonmethyl) - pendimethalin - pentachloranisol phenylphenol (ortho-) phosalone - phosmet - piperonyl butoxide - pirimiphos-ethyl - pirimiphos-methyl - procymidone - prometryn - prothiofos pyrazophos - pyriproxyfen - quinalphos quintozene PCNB (sum of quintozene + pentachloroaniline) - silthiofam spirodiclofen spiromesifen sulfotep - tecnazene - terbuthylazine tetrachlorvinphos - tetradifon - tolclofos-methyl - tolylfluanid (sum of tolyfluanid + DMST) vinclozolin - [GMS3] 1 Multi-residue method for the quantification of pesticides (mainly pyrethroids) by GC-MSMS in fatty products like oils, cacao, babyfood, meat, milk,... (complementary to GMS2) acrinathrin - benfluralin bifenthrin - butralin - carbophenothion 0.02 chlorfenapyr cyfluthrin total - cyhalothrin (lambda) - cypermethrin (sum of isomers) - deltamethrin - fenpropathrin - fenvalerate (sum of isomers) - flucythrinate (sum of isomers) - flumetralin - 4/10

5 fluvalinate-tau total nitrothal isopropyl - oxychlordane - permethrin (sum cis+trans) - phorate - profluralin propargite - pyridaben - tefluthrin trifluralin - [GMS4] Multi-residue method by GC-MSMS for 154 compounds, isomers and degradation products - quantification of pesticides in cereals and cereal products (other commodities on request) aclonifen 0.02 acrinathrin - alachlor atrazine - benalaxyl (including benalaxyl-m) - benfluralin bifenazate 0.05 bifenox 0.05 bifenthrin - biphenyl bromophos-ethyl - bromopropylate - buprofezin butralin - cadusafos - carbophenothion - chinomethionate chlordane (sum of cis + trans) chlorfenapyr - chlorobenzilate - chlorothalonil - chlorpropham (chlorpropham & 3-chloroaniline) - chlorpyriphos-ethyl chlorpyriphos-methyl - chlorthal-dimethyl (DCPA) - chlozolinate - cyfluthrin (sum of isomers) - cyhalofop-butyl - cyhalothrin (lambda) - cypermethrin (sum of isomers) - cyprodinil - DDD (total = o,p +p,p ) - DDE (total = o,p +p,p ) - DDT (total = o,p +p,p ) - deltamethrin - diazinon - dichlorvos - dicloran - dieldrin (sum of dieldrin + aldrin) diphenylamine ditalimfos - dodemorph endosulfan (sum of alfa +beta + -sulfate) - endrin EPN - ethion - ethofumesate - etofenprox - ethoprofos ethoxyquin 1 etrimfos - famoxadone fenarimol - fenazaquin fenchlorphos - fenitrothion - fenpropathrin - fenpropimorph - fenvalerate (sum of isomers) - fipronil - flucythrinate - fludioxonil - flumetralin - fluvalinate-tau total formothion - furalaxyl - HCH 1 (sum of alfa + beta + delta + epsilon) heptenophos - hexachlorobenzene (HCB) iprodione isocarbophos - isofenphos(-ethyl) - isofenphos-methyl - kresoxim-methyl - lindane 1 (gamma HCH) malathion (malathion + malaoxon) - mecarbam - mepronil - metazachlor - methacrifos - methidathion - metrafenone - metribuzin - mevinphos (sum of isomers) - nitrofen - nitrothal isopropyl - nuarimol - oxadiazon oxychlordane - oxyfluorfen paraoxon-ethyl parathion-ethyl - 5/10

6 parathion-methyl 1 (sum of parathion-methyl + paraoxonmethyl 1 ) - penconazole - pendimethalin - pentachloranisol - permethrin (sum of isomers) - phenylphenol (ortho-) phorate - phosalone - phosmet - phoxim 0.02 piperonyl butoxide - pirimiphos-ethyl - pirimiphos-methyl - procymidone - profenofos - profluralin - prometryn - propargite propoxur - propyzamide - prothiofos - pyraclostrobin - pyrazophos - pyridaben - pyriproxyfen - quinalphos - quinoxyfen - quintozene PCNB (sum of quintozene + pentachloro-aniline) - silthiofam - simazine - spirodiclofen - spiromesifen - sulfotep - tecnazene - tefluthrin - terbufos terbuthylazine - tetrachlorvinphos - tetradifon - tolclofos-methyl - triazophos - trifluralin - [LMS] Multi-residue method by LC-MSMS for 188 compounds, isomers and degradation products - quantification of pesticides in fruit, vegetables, potatoes, cereals, soil and water (R.L. for tobacco between [ ], other commodities on request) acephate acetamiprid - acibenzolar-s-methyl - aldicarb 1 (sum of aldicarb + -sulfon 1 + -sulfoxide 1 ) - amidosulfuron azadirachtin 1 azamethiphos - azimsulfuron 1 - azinphos-ethyl - azinphos-methyl - azoxystrobin - bendiocarb benfuracarb *1 - benthiavalicarb-isopropyl - bitertanol 0.02 boscalid (nicobifen) bromuconazole - carbaryl ** - carbendazim (sum of carbendazim + benomyl) - carbetamide carbofuran 1 (sum of carbofuran + 3-hydroxy-carbofuran 1 ) carbosulfan carboxin 1 carfentrazone-ethyl - chlorbromuron - chlorfenvinphos chloridazon - chloroxuron - chlorsulfuron chlortoluron - clofentezine 1 - cyazofamid - cymiazole 1 - cymoxanil cyproconazole - demeton-s-methyl dicrotophos - difenoconazole - diflubenzuron 1 - dimethoate (sum of dimethoate & omethoate) - dimethomorph - dimoxystrobin - diniconazole - disulfoton 1 (sum of disulfoton 1 + -sulfone 1 + -sulfoxide 1 ) - diuron - dodine epoxiconazole - ethiofencarb - ethirimol - etoxazole - fenamidone - fenamiphos 1 (sum of fenamiphos 1, -sulfone 1 & -sulfoxide 1 ) fenbuconazole - fenhexamide - fenobucarb 6/10

7 fenoxycarb - fenpropidin fenpyroximate - fensulfothion fenthion 1 (sum of fenthion + -sulfon 1 + -sulfoxide 1 ) fenuron - florasulam flazasulfuron flonicamid - fluazifop-p-butyl (sum of fluazifop-p-butyl + free acid) fluazinam flufenacet - flufenoxuron 1 - fluroxypyr fluoxastrobin 1 - flupyrsulfuron-methyl-na fluquinconazole - flurtamone flusilazole - flutriafol foramsulfuron* forchlorfenuron - fosthiazate - fuberidazole - furathiocarb - haloxyfop-methyl (sum of haloxyfop-methyl + free acid) hexaconazole - hexythiazox - imazalil (=enilconazole) - imidacloprid - indoxacarb (sum of S & R isomers) - iodosulfuron-methyl-sodium - iprovalicarb - isoproturon - isoxaben - lenacil linuron - lufenuron mandipropamid metalaxyl (sum of metalaxyl & metalaxyl-m) - metamitron - metconazole - methabenzthiazuron - methamidophos - methiocarb 1 (sum of methiocarb + -sulfon 1 + -sulfoxide 1 ) - methomyl (sum of methomyl + thiodicarb) - methoxyfenozide - metobromuron - metolachlor - metoxuron 1 - metsulfuron-methyl - molinate - monocrotophos - monolinuron napropamide nicosulfuron - nitenpyram 1 novaluron 1 omethoate oxamyl - oxydemeton-methyl 1 (oxydemeton-methyl 1 + demeton-s-methylsulfone) oxadixyl 1 paclobutrazol - pencycuron pethoxamid phenmedipham ** - phenthoate **1 - phosphamidon - picolinafen - picoxystrobin - pinoxaden pirimicarb - prochloraz - promecarb propaquizafop 1 propham propiconazole - proquinazid prosulfocarb - prosulfuron - pymetrozine *1 - pyraflufen-ethyl pyridaphenthion - pyrifenox - pyrimethanil quinclorac 1 quizalofop-ethyl rotenone - spinosad (sum of spinosin A & D) - spirotetramat 1 spiroxamine - sulfosulfuron tebuconazole - tebufenozide - tebufenpyrad - tepraloxydim tetraconazole - thiabendazole - thiacloprid - thiamethoxam (sum of thiametoxam + clothianidin) thifensulfuron-methyl - thiophanate-methyl triadimefon + triadimenol (sum) - triasulfuron - trichlorfon 1 - tricyclazole tridemorph - trifloxystrobin - trinexapac-ethyl 1 - triflumizole - triforine - triticonazole 7/10

8 vamidothion - zoxamide - *: not in acidic matrices **: not in tobacco ***: not in cereals [LMS2] Multi-residue method, by LC-MSMS in negative mode for 22 compounds, isomers and degradation products - quantification of selected pesticides (majority acidic herbicides) in fruit, vegetables, potatoes, cereals, soil and water (R.L. for tobacco between [ ], other commodities on request) 2,4-D - [0.02] 2,4-DB - [0.02] 4-CPA - [0.02] 2,4,5-T 1 - [0.02] bentazone - [0.02] bromoxynil - [0.02] clopyralid 1 (3,6-DCP) [0.4] dicamba - [0.02] dichlorophen - [0.02] dichlorprop (2,4-DP) - [0.02] dinocap [0.2] dithianon * hexaflumuron - [0.02] ioxynil - [0.02] MCPA - [0.02] MCPB - [0.02] mecoprop (MCPP) - [0.02] picloram [0.1] prohexadione-ca [0.4] sulfentrazone - [0.02] teflubenzuron - [0.02] triflumuron - [0.02] * : only on pear, LOD value [LMS3] Multi-residue method, by LC-MSMS, for the quantification of diafenthiuron, dazomet and pyridate in fruit and vegetables diafenthiuron dazomet pyridate (sum of pyridate and pyridafol expressed as pyridate) [LMS5] Multi-residue method, by LC-MSMS, for the fast quantification of selected pesticides in fruit, vegetables, potatoes and cereals (other commodities on request) for use in the belgian preharvest controls abamectin 1 B1a&B1b - acetamipirid 1 - ametoctradin 1 azoxystrobin 1 - boscalid - carbendazim (sum of carbendazim + benomyl) - carbetamide - cyproconazole - cyprodinil - difenoconazole 1 - dimethoate 1 (sum of dimethoate 1 & omethoate 1 ) - dimethomorph - fenamidone 1 - fenhexamid 1 - formetanate - flonicamid 1 - imazalil - imidacloprid - indoxacarb 1 isoxaflutole 1 - linuron - mandipropamid 1 mepronil - mesotrione 1 metalaxyl (sum of metalaxyl & metalaxyl-m) - methiocarb (sum of methiocarb + -sulfon + -sulfoxide) - methomyl (sum of methomyl + thiodicarb) - metobromuron 1 - myclobutanil - oxadixyl 1 oxamyl 1 pirimicarb (sum of pirimicarb + pirimicarb-desmethyl 1 ) - propamocarb - 8/10

9 propyzamide prosulfocarb 1 - pymetrozine 1 - pyraclostrobin 1 spinosad 1 (sum of spinosyn A 1 & D 1 ) - spirotetramat 1 sulcotrione tebuconazole 1 - thiabendazole - thiacloprid 1 thiophanate-methyl - [MEC] 1 Multi-residue method, by LC-MSMS, for the quantification of mectins in fruit, vegetables, cereals and cereal products abamectin (sum abamectin B1a+ B1b) emamectin benzoate ( sum emamectin benzoate B1a + B1b) ivermectin B1a [P2] Multi-residue method for the determination of organophosphorus pesticides in cereals and cereal products - to be used as babyfood ingredient. This method is also applicable (and validated) for seeds. milk, oil, meat, liver,... with matrix-dependant RL s (all in the same order of magnitude of cereals) chlorpyrifos - chlorpyrifos-methyl - diazinon - dichlofenthion - dichlorvos - ethion - ethoprofos - etrimfos - fenchlorfos - fenitrothion - heptenofos - malathion - methidathion - mevinphos parathion - parathion-methyl - pirimiphos-ethyl - pirimiphos-methyl - sulfotep - [PAH] 1 Multi-residue method, by LC-MSMS, for the quantification of polycyclic aromatic hydrocarbons in oils and oilseeds Bena[a]anthracene Benzo[a]pyrene Benzo[b]fluoranthene Benzo[g,h,i]perylene Benzo[k]fluoranthene Chrysene Dibenz[a,h]anthracene Indeno[1,2,3-c,d]pyrene [QAC] Multi-residue method, by LC-MSMS, for the quantification of quaternairy amonium compounds in fruit, vegetables and cereals BAC-C10 BAC-C12 BAC-C14 BAC-C16 DDAC-C10 DDAC-C12 DDAC-C14 9/10

10 [QU1] Multi-residue method, by LC-MSMS, for the quantification of chlormequat and mepiquat in fruit, vegetables and cereals chlormequat - mepiquat - [QU2] 1 Multi-residue method, by LC-MSMS, for the quantification of diquat and paraquat in fruit, vegetables and cereals diquat - (cereals 0.05) paraquat - (cereals 0.05) Specific individual methods for the determination of residues of pesticides in fatty products and tobacco. benzo[a]pyrene - Specific individual methods for the determination of residues of pesticides in fruit and vegetables asulam 1 - bromine [BR] 5 chlorprofam [CIPC] (method applies only to potatoes) ethephon - fosetyl-aluminium maleic hydrazide 1 5 (tobacco 20) nicotine nitrate [NIT] 50 pentachlorophenol 1 - sulfur 1-5 thiram 1 [TMTD] Specific individual methods for the determination of residues of pesticides in soil bromine 1 [BR2]- 0,5 mg/kg Specific individual methods for the determination of residues of pesticides in water bromine 1 [BR2] - 0,5 mg/l nitrate 1 [NIT] - 1 mg/l 1 : not under accreditation 10/10