Certificate of pesticide multi-residue analysis by MSMS detection

Transcription

1 Multi-residue methods: all the mentioned substances will be searched for. The general reporting limit (RL) (mg/kg) is mentioned on the right side of each pesticide. The limit of quantification may vary depending on the matrix The abbreviated method name as used by the laboratory is mentioned in [brackets]. This certificate may only be used in correlation with this laboratory method code as mentioned on an analysis-report. New pesticides or updates of the certificate are indicated in green For an up to date list of the accredited analyses or the current version of this document: check our website: [GMS] Multi-residue method by GC-MSMS for 199 compounds, isomers and degradation products - quantification of pesticides in fruit, vegetables and potatoes. (for cereals and cereal products use GMS4, R.L. for tobacco between [ ], other commodities on request) 1,2-dibromo-3-chloropropane [0.2] acetochlor 0.01 aclonifen 0.01 [0.04] acrinathrin alachlor 0.01 benalaxyl (including benalaxyl-m) benfluralin 0.01 benzoylprop-ethyl 0.01 bifenazate [0.1] bifenox 0.01 [0.1] bifenthrin biphenyl 0.1 [0.2] bromophos-ethyl bromopropylate butachlor 0.01 butafenacil 0.01 butralin butylate 0.01 cadusafos carbophenothion [0.04] chinomethionat 0.02 [0.04] chlorbenside 0.01 chlordane (sum of cis- + trans-) chlordimeform [0.1] chlorfenapyr [**] chlorfenson 0.01 chlormephos 0.01 chlorobenzilate chloroneb 0.01 chlorothalonil chlorpropham 1 (chlorpropham & 3-chloroaniline 1 ) 0.01 chlorpyrifos (-ethyl) [0.01] chlorpyrifos-methyl chlorthal-dimethyl (DCPA) chlozolinate coumaphos 0.01 crimidine 0.01 cycloate 0.01 cyflufenamid 0.01 cyfluthrin (sum of isomers) cyhalofop-butyl cyhalothrin (lambda-) cyanofenphos 0.01 cypermethrin (sum of isomers) DDD 1 (o,p ) DDE 1 (o,p ) DDT 1 (sum of p,p -DDT, o,p -DDT, p-p -DDE and p,p - TDE (DDD) expressed as DDT) deltamethrin desmetryn 0.01 diazinon dichlobenil 0.01 dichlofenthion 0.01 dichlofluanid [0.1] diclofop-methyl 0.01 dichlormid 0.01 dichlorvos dicloran dicofol 1 (sum of isomers) dieldrin (sum of aldrin + dieldrin) dimethachlor 0.01 diphenylamine [0.1] ditalimfos edifenphos 0.01 endosulfan (sum alpha- + beta- + -sulphate) endrin [0.1] EPN EPTC 0.01 ethalfluralin 0.01 ethion ethofumesate (sum of ethofumesate + ethofumesate-2- keto, expressed as ethofumesate) ethoprophos [0.016] ethoxyquin /7

2 etofenprox etridiazole 0.05 [0.1] etrimfos famoxadone [0.04] fenchlorphos fenitrothion fenpropathrin fenpropimorph fenson 0.01 fenvalerate (sum of isomers) fipronil (sum fipronil + sulfone metabolite, expressed as fipronil) flucythrinate (sum of isomers) fludioxonil flumetralin fluthiacet-methyl [0.1] fluvalinate-tau (sum of isomers) [0.04] formothion HCH (sum of alpha- + beta- + delta- + epsilon-) heptachlor (sum of heptachlor and heptachlor epoxide expressed as heptachlor) 0.01 hexachlorobenzene (HCB) [0.006] imazamethabenz (-methyl) ipconazole [0.1] iprodione [0.04] isocarbophos isofenphos(-ethyl) isofenphos-methyl isoprocarb 0.01 isoxadifen-ethyl 0.01 lindane (gamma HCH) malathion (sum of malathion + malaoxon) mecarbam [**] mepronil methacrifos methidathion methoprene 0.01 methoxychlor 0.01 metrafenone metribuzin mevinphos (sum of isomers) mirex [0.04] nitralin 0.01 nitrofen nitrothal-isopropyl oxadiargyl 0.01 oxadiazon oxychlordane oxyfluorfen 0.01 paraoxon-ethyl [0.1] parathion (-ethyl) parathion-methyl 1 (sum of parathion-methyl + paraoxon-methyl 1 ) pebulate 0.01 pendimethalin pentachloroanisol permethrin (sum of isomers) phenothrin 0.02 [0.04] phenylphenol (ortho-) [0.1] phorate phosalone phosmet 1 (phosmet and phosmet-oxon 1, expressed as phosmet) [**] phoxim [0.04] piperonyl butoxide pirimiphos-ethyl pirimiphos-methyl pretilachlor 0.01 procymidone profluralin prometryn propanil 0.05 [0.1] propargite [**] propyzamide prothiofos pyrazophos pyridaben pyriproxyfen pyroquilon 0.01 quinalphos quinoxyfen quintozene PCNB (sum of quintozene + pentachloroaniline) silthiofam spirodiclofen spiromesifen [**] sulfotep sulprofos 0.01 TCMTB 0.02 [0.04] tecnazene tefluthrin terbacil 0.01 terbuthylazine terbutryn 0.01 tetrachlorvinphos tetradifon tiocarbazil 0.05 [0.1] tolclofos-methyl tolfenpyrad 0.01 tolylfluanid 1 (sum of tolylfluanid 1 + DMST) [0.1] transfluthrin 0.02 [0.04] triallate 0.01 trifluralin vinclozolin **: not in tobacco 2/7

3 Certificate of pesticide residue analysis cereals, cereal products and fatty products [GMS4] Multi-residue method by GC-MSMS for 195 compounds, isomers and degradation products - quantification of pesticides in cereals and cereal products (other commodities on request) 1,2-dibromo-3-chloropropane acetochlor 0.01 aclonifen 0.01 acrinathrin alachlor 0.01 benalaxyl (including benalaxyl-m) benfluralin 0.01 benzoylprop-ethyl 0.01 bifenazate bifenox 0.01 bifenthrin biphenyl 0.1 bromophos-ethyl bromopropylate butachlor 0.01 butafenacil 0.01 butralin butylate 0.01 cadusafos carbophenothion chinomethionat 0.02 chlorbenside 0.01 chlordane (sum of cis- + trans-) chlordimeform chlorfenapyr chlorfenson 0.01 chlormephos 0.01 chlorobenzilate chloroneb 0.01 chlorothalonil chlorpropham 1 (chlorpropham & 3-chloroaniline 1 ) chlorpyrifos (-ethyl) chlorpyrifos-methyl chlorthal-dimethyl (DCPA) chlozolinate coumaphos 0.01 crimidine 0.01 cycloate 0.01 cyflufenamid 0.01 cyfluthrin (sum of isomers) cyhalofop-butyl cyhalothrin (lambda-) cyanofenphos 0.01 cypermethrin (sum of isomers) DDD 1 (o,p ) DDE 1 (o,p ) DDT 1 (sum of p,p -DDT, o,p -DDT, p-p -DDE and p,p - TDE (DDD) expressed as DDT) deltamethrin desmetryn 0.01 diazinon dichlobenil 0.01 dichlofenthion 0.01 diclofop-methyl 0.01 dichlormid 0.01 dichlorvos dicloran dieldrin (sum of dieldrin + aldrin) 0.01 dimethachlor 0.01 diphenylamine ditalimfos edifenphos 0.01 endosulfan (sum alpha- + beta- + -sulphate) endrin 0.01 EPN EPTC 0.01 ethalfluralin 0.01 ethion ethofumesate (sum of ethofumesate + ethofumesate-2- keto, expressed as ethofumesate) ethoprophos ethoxyquin etofenprox etridiazole etrimfos famoxadone 0.01 fenchlorphos fenitrothion fenpropathrin fenpropimorph fenson 0.01 fenvalerate (sum of isomers) fipronil (sum fipronil + sulfone metabolite, expressed as fipronil) flucythrinate (sum of isomers) fludioxonil flumetralin fluvalinate-tau (sum of isomers) formothion HCH (sum of alpha- + beta- + delta- + epsilon-) 0.01 heptachlor (sum of heptachlor and heptachlor epoxide expressed as heptachlor) 0.01 hexachlorobenzene (HCB) imazamethabenz (-methyl) ipconazole iprodione isocarbophos isofenphos(-ethyl) isofenphos-methyl isoprocarb 0.01 Datum: april 2, /7

4 isoxadifen-ethyl 0.01 lindane (gamma HCH) 0.01 malathion (malathion + malaoxon) mecarbam mepronil methacrifos methidathion methoprene 0.01 methoxychlor 0.01 metrafenone metribuzin mevinphos (sum of isomers) mirex nitralin 0.01 nitrofen nitrothal-isopropyl oxadiargyl 0.01 oxadiazon 0.01 oxychlordane oxyfluorfen 0.01 paraoxon-ethyl parathion (-ethyl) parathion-methyl 1 (sum of parathion-methyl + paraoxon-methyl 1 ) pebulate 0.01 pendimethalin pentachloroanisol permethrin (sum of isomers) phenothrin 0.02 phenylphenol (ortho-) phorate phosalone phosmet 1 (phosmet and phosmet-oxon 1, expressed as phosmet) phoxim piperonyl butoxide pirimiphos-ethyl pirimiphos-methyl pretilachlor 0.01 procymidone profluralin prometryn propanil 0.05 propargite 0.05 propyzamide prothiofos pyrazophos pyridaben pyriproxyfen pyroquilon 0.01 quinalphos quinoxyfen quintozene PCNB (sum of quintozene + pentachloroaniline) silthiofam spirodiclofen spiromesifen sulfotep sulprofos 0.01 TCMTB 0.02 tecnazene tefluthrin terbacil 0.01 terbuthylazine terbutryn 0.01 tetrachlorvinphos tetradifon tiocarbazil 0.05 tolclofos-methyl tolfenpyrad 0.01 transfluthrin 0.02 triallate 0.01 trifluralin vinclozolin [LMS] Multi-residue method by LC-MSMS for 286 compounds, isomers and degradation products - quantification of pesticides in fruit, vegetables, potatoes and cereals (R.L. for tobacco between [], other commodities on request) 6-benzylaminopurine 0.01 acephate [0.04] acetamiprid acibenzolar-s-methyl aldicarb 1 (sum of aldicarb + -sulfone 1 + -sulfoxide 1 ) allethrin 0.01 [**] ametryn 0.01 amidosulfuron 0.01 amisulbrom 0.01 atrazine 0.01 azaconazole 0.01 azadirachtin [**] azamethiphos azimsulfuron azinphos-ethyl azinphos-methyl azoxystrobin beflubutamid 0.01 bendiocarb 0.01 benfuracarb 1 * bensulfuron-methyl /7

5 benthiavalicarb-isopropyl bispyribac-sodium 0.01 bitertanol 0.02 [0.04] bixafen 0.01 boscalid (nicobifen) bromacil 0.02 [0.1] bromfenvinphos-methyl 0.01 bromuconazole bupirimate 0.01 buprofezin 0.01 carbaryl [0.1] carbendazim (sum of carbendazim + benomyl) carbetamide 0.01 carbofuran 1 (sum of carbofuran + 3-hydroxy-carbofuran 1 ) 0.01 carbosulfan [0.05] carboxin carfentrazone-ethyl chlorantraniliprole 0.01 chlorbromuron [0.05] chlorfenvinphos 0.01 chlorfluazuron chloridazon chloroxuron chlorsulfuron 0.01 chlortoluron clethodim (sum of sethoxydim + clethodim) 0.01 clodinafop 0.01 clodinafop-propargyl 0.01 clofentezine clomazone 0.01 cloquintocet-mexyl 0.01 cyazofamid cyclanilide 0.01 cymiazole cymoxanil 0.01 cyproconazole cyprodinil 0.01 demeton-s-methyl [0.012] diclobutrazol 0.01 dicrotophos diethofencarb 0.01 difenoconazole diflubenzuron [0.05] diflufenican 0.01 dikegulac dimethenamid 0.01 dimethoate (sum of dimethoate & omethoate) dimethomorph dimoxystrobin diniconazole dinotefuran 0.01 disulfoton 1 (sum of disulfoton 1 + -sulfone 1 + -sulfoxide 1 ) diuron dodemorph 0.01 dodine epoxiconazole ethametsulfuron-methyl 0.01 ethiofencarb (sum of ethiofencarb + -sulfone + -sulfoxide, expressed as ethiofencarb) ethirimol ethoxysulfuron 0.01 etoxazole fenamidone fenamiphos 1 (sum of fenamiphos 1, -sulfone 1 & - sulfoxide 1 ) fenarimol 0.01 fenazaquin 0.01 fenbuconazole fenhexamid [0.05] fenobucarb 0.01 fenoxaprop-p 0.01 fenoxaprop-p-ethyl 0.01 fenoxycarb fenpiclonil 0.01 fenpropidin 0.01 fenpyroximate fensulfothion 1 (sum of fensulfothion + -sulfon 1, expressed as fensulfothion) fenthion 1 (sum of fenthion + -sulfone 1 + -sulfoxide 1 ) 0.01 [0.1] fenuron flazasulfuron 0.01 florasulam 0.01 flonicamid fluazifop-p-butyl (sum of fluazifop-p-butyl + free acid) 0.01 [0.05] fluazinam flubendiamide 0.01 flufenacet flufenoxuron fluopicolide 0.01 fluoxastrobin fluopyram 0.01 flupyrsulfuron-methyl-sodium 0.01 fluquinconazole flurochloridone 0.01 [0.05] fluroxypyr [0.1] flurtamone 0.01 flusilazole flutolanil 0.01 flutriafol 0.01 fonofos 0.01 [0.1] foramsulfuron* 0.01 forchlorfenuron fosthiazate fuberidazole /7

6 furalaxyl 0.01 furathiocarb haloxyfop-methyl (sum of haloxyfop-methyl + free acid) heptenophos 0.01 hexaconazole hexazinone 0.01 hexythiazox imazalil (=enilconazole) imazamox 1 *** 0.01 imazapyr imazosulfuron 0.01 imidacloprid indoxacarb (sum of S & R isomers) iodosulfuron-methyl-sodium iprobenfos 0.01 iprovalicarb isonoruron 0.01 isoprothiolane 0.01 isoproturon isoxaben kresoxim-methyl 0.01 lenacil 0.01 linuron lufenuron [0.1] mandipropamid 0.01 mefenpyr-diethyl 0.01 mepanipyrim (sum of mepanipyrim and mepanipyrim-2- hydroxypropyl, expressed as mepanipyrim) 0.01 mesosulfuron-methyl 0.01 metaflumizone 0.01 metalaxyl (sum of metalaxyl & metalaxyl-m) metamitron [0.05] metazachlor 0.01 metconazole methabenzthiazuron methamidophos methiocarb 1 (sum of methiocarb + -sulfon 1 + -sulfoxide 1 ) methomyl (sum of methomyl + thiodicarb) methoprotryne 0.01 methoxyfenozide metobromuron [0.05] metolachlor (including metolachlor-s) metosulam 0.01 metoxuron metsulfuron-methyl molinate monocrotophos monolinuron monuron 0.01 myclobutanil 0.01 naftylacetamide 0.01 napropamide 0.01 nicosulfuron nitenpyram [0.1] novaluron nuarimol 0.01 ofurace 0.01 omethoate oxadixyl [0.05] oxamyl oxycarboxin 0.01 oxydemeton-methyl 1 (oxydemeton-methyl 1 + demeton-s-methylsulfone) paclobutrazol penconazole 0.01 pencycuron 0.01 penoxsulam 0.01 pethoxamid 0.01 phenmedipham phenthoate [**] phosphamidon picolinafen [0.05] picoxystrobin pinoxaden 0.01 pirimicarb (sum of pirimicarb + pirimicarb-desmethyl) prochloraz profenofos 0.01 promecarb 0.01 propachlor 0.01 propaquizafop propham 0.01 propiconazole propoxur 0.01 proquinazid 0.01 prosulfocarb prosulfuron prothioconazole prothioconazole-desthio pymetrozine 1 * pyraclofos 0.01 pyraclostrobin 0.01 pyraflufen-ethyl 0.01 pyrethrins [0.04] pyridaphenthion pyrifenox pyrimethanil 0.01 quinclorac [0.05] quizalofop-ethyl 0.01 quizalofop 0.01 [0.05] rimsulfuron 0.01 rotenone sethoxydim 0.01 siduron 0.01 simazine 0.01 spinosad (sum of spinosyn A & D) spirotetramat spiroxamine /7

7 sulfosulfuron 0.01 tebuconazole tebufenozide tebufenpyrad tepraloxydim 0.01 terbufos tetraconazole tetramethrin 0.01 thiabendazole thiacloprid thiamethoxam (sum of thiamethoxam + clothianidin) [0.04] thifensulfuron-methyl thiobencarb 0.01 thiophanate-methyl [0.05] triadimefon + triadimenol (sum) triasulfuron triazophos 0.01 tribenuron-methyl trichlorfon [0.1] tricyclazole 0.01 tridemorph trifloxystrobin triflumizole triflumuron 0.01 triflusulfuron-methyl 0.01 triforine trinexapac-ethyl [0.1] triticonazole 0.01 vamidothion zoxamide *: not in acidic matrices **: not in tobacco ***: not in cereals [LMS2] Multi-residue method, by LC-MSMS in negative mode for 22 compounds, isomers and degradation products - quantification of selected pesticides (majority acidic herbicides) in fruit, vegetables, potatoes and cereals (R.L. for tobacco between [], other commodities on request) 2,4-D ,4-DB CPA ,4,5-T bentazone bromoxynil clopyralid 1 (3,6-DCP) [0.4] dicamba dichlorophen dichlorprop (2,4-DP) dinocap [0.2] dithianon * hexaflumuron ioxynil MCPA MCPB mecoprop (MCPP) picloram [0.1] prohexadione-ca [0.4] sulfentrazone teflubenzuron triflumuron * : only on pear, LOD value 1 : not under accreditation 7/7