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1 Give the major organic product(s) of the following reaction. Give your answer as a text answer, with the correct answers being listed in alphabetical order. (Example: xxxx a b) 1) Li 2) Q1 3) H + A B C G - None of these products are a major product of the reaction that is shown. D E F
2 Give the major organic product(s) of the following reaction. Give your answer as a text answer, with the correct answers being listed in alphabetical order. (Example: xxxx a b) 1) Li 2) Q1 3) H + A B C G - None of these products are a major product of the reaction that is shown. D E F
3 Chem 234, Fall 2016 Exam 3 F r e q u e n c y Count 181 Average 84.0% Max 100.0% Min 16.4% 0 0% 10% 20% 30% 40% 50% 60% 70% 80% 90% 100% Exam Score
4 Exam by Day Exam Average # Test Takers 92.00% 90.00% 88.00% 86.00% 84.00% 82.00% 80.00% 78.00% 90.50% 89.50% 82.10% % 0
5 Exam 4 (Cumulative Exam) Time: Thursday, December 8: 2:00 4:00PM OR Saturday, December 10: 10:00 am Noon OR Saturday, December 10: 1:00 4:00PM Location Soc/Anthro Testing Center Chapters will be covered in this order: Chapter 18, 19, 20 Practice Exams are Posted Ex4-90A Practice Final Exam Ex4-90B Practice Final Exam Deadline for alternate arrangements is Monday, 12/5/2016 at 4:30 PM (i.e., close of business) An oral make-up exam will be required for making up the exam for all students not taking the exam on the above dates or having already made prior arrangements
6 Assignment Due Date Ex4-01-B B Claisen Condensation Friday, November 11, 2016 Ex4-02-B C Claisen Condensation Saturday, November 12, 2016 Ex4-03-B B A-B Unsaturated Rxns Sunday, November 13, 2016 Ex4-04-B C A-B Unsaturated Rxns Monday, November 14, 2016 Ex4-05-B A Carb Classification Tuesday, November 15, 2016 Ex4-06-B Hemiacetal Formation Wednesday, November 16, 2016 Ex4-07-B Carbohydrate Reactions Thursday, November 17, 2016 Ex4-08-B Kiliani-Fischer Synthesis Friday, November 18, 2016 Ex4-09-B Important Carbohydrates Monday, November 28, 2016 Ex4-10-B Carbs in Blood Types Monday, November 28, 2016 Thanksgiving Break Ex4-11-B Amino Acid Nomenclature Tuesday, November 29, 2016 Ex4-12-B B Amino Acid Naming Wednesday, November 30, 2016 Ex4-13-B Amino Acid Acid Base Thursday, December 1, 2016 Ex4-14-B Edmann Degradation Friday, December 2, 2016 Ex4-15-B Merrified Peptide Synthesis Saturday, December 3, 2016 Ex4-16-B Synthesis in Peptides Sunday, December 4, 2016
7 Veterans
8 No Class Next Friday!!!
9 Carbohydrates Simple Elemental Formula C x (H 2 O) x D-glyceraldehyde C 3 H 6 O 3 OR C 3 (H 2 O) 3 L-glyceraldehyde Enantiomers Stereoisomers which are not superimposable, but are mirror-image related
10 Aldoses vs Ketoses Aldoses Contain an aldehyde Ketoses Contain a ketone
11 D-Saccharides vs L-Saccharides Arrange so that most oxidized end of the molecule is at the top D-Saccharides Bottom-most OH to right L-Saccharides Bottom-most OH to left
12 Classify the following carbohydrate as D- or L- and as an aldose or a ketose. A. D-aldose B. D-ketose C. L-aldose D. L-ketose Q2
13 Classify the following carbohydrate as D- or L- and as an aldose or a ketose. A. D-aldose B. D-ketose C. L-aldose D. L-ketose Q2
14 How many stereoisomers are there of an aldopentose? (Hint: Remember that the number of stereoisomers is 2 n, where n is the number of chiral centers). Give your answer as an integer number Q3
15 How many stereoisomers are there of an aldopentose? (Hint: Remember that the number of stereoisomers is 2 n, where n is the number of chiral centers). Give your answer as an integer number. 3 chiral centers Q3 Number of stereoisomers = 2 3 Number of stereoisomers = 8
16 Hemiacetal Formation or 6-membered ring formation are good H + CH3OH
17 Hemiacetal Formation 4 H CH3OH 4-membered ring, too high in energy and hemiacetal does not form. Normal acetal formation occurs H + CH3OH membered ring is good for intramolecular hemiacetal formation.
18 Glucose Hemiacetal Formation From a Fischer Projection Perspective H + H2O
Give the major organic product(s) of the following reaction.
Give the major organic product(s) of the following reaction. 1) NaNO2, HCl 0 o C 2) CuCN 2016-09-23 Q1 A D B C E F There is no reaction or the correct product is not listed here. 5 of 7 Give the major
A B C D Q1
Think about this reaction in terms of mechanism. All of the intermediates of the reaction are provided. Give the intermediates in order of their appearance along the reaction coordinate. (Example: xxxx
Give the major organic product(s) of the following reaction.
Give the major organic product(s) of the following reaction. 1) CH3CH2MgBr 2) H3O 2016-09-26 Q1 + E. There is no reaction or the correct product A B is not listed here. C D Explanation CH3CH2MgBr 1) CH3CH2MgBr
Give a common name for the following compound.
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Give the major product(s) of the following reaction.
Give the major product(s) of the following reaction. HNO3 H2SO4 2016-09-12 Q1 A B E. There is no reaction or the correct product is not listed here. C D Give the major product(s) of the following reaction.
H3O+ heat I Q1
Give the major organic product(s) of the following reaction. Give your answer as a text answer, with the correct answers being listed in alphabetical order. (Example: xxxx a b) H3O + heat A B C D E F G
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