Give the major product(s) of the following reaction.
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1 Give the major product(s) of the following reaction. HNO3 H2SO Q1 A B E. There is no reaction or the correct product is not listed here. C D
2 Give the major product(s) of the following reaction. HNO3 H2SO Q1 A B E. There is no reaction or the correct product is not listed here. C D
3 Exam 1 Time: Tuesday, September 20: 7:00 9:00PM OR Wednesday, September 21: 7:00 9:00PM OR Thursday, September 22: 7:00 10:00PM Location Soc/Anthro Testing Center Chapters will be covered in this order: Chapter 11, 14, 15, 19, 13 Practice Exams are Posted B A Practice Exam 1A B B Practice Exam 1B Deadline for alternate arrangements is Monday, 9/19/2016 at 4:30 PM (i.e., close of business) An oral make-up exam will be required for making up the exam for all students not taking the exam on the above dates or having already made prior arrangements
4 Order of Coverage (Exam 1) Homework Assignment Due Date 1 B IR Functional Groups (wdeadline) Tuesday, August 23 2 B Mass Spec - Molecular Ion (wdeadline) Wednesday, August 24 3 B Mass Spec - Isotope Effects (wdeadline) Thursday, August 25 4 B Number of Peaks 1H NMR Spectra (wdeadline) Friday, August 26 5 B Number of Peaks 13C NMR (wdeadline) Saturday, August 27 6 B Theoretical NMR Chemical Shift (wdeadline) Sunday, August 28 7 B Theoretical NMR Integration (wdeadline) Monday, August 29 8 B Theor. NMR Spin-Spin Splitting (wdeadline) Tuesday, August 30 9 B NMR Spectroscopy Problems (wdeadline) Wednesday, August B C NMR Structure ID (wdeadline) Thursday, September 1 11 B A Nomenclature Alkyl Halides (wdeadline) Friday, September 2 12 B B Alkyl Halide Nomenclature (wdeadline) Saturday, September 3 13 B A Halogenation of Alkanes (wdeadline) Sunday, September 4 14 B B Halogenation of Alkanes (wdeadline) Monday, September 5
5 Order of Coverage (Exam 1) Homework Assignment Due Date 15 B A Oxidation and Anti-oxidants (wdeadline) Tuesday, September 6 16 B Aromaticity (wdeadline) Wednesday, September 7 17 B B Arene Nomenclature (wdeadline) Thursday, September 8 18 B A Halogenation of Arenes (wdeadline) Friday, September 9 19 B B Halogenation of Arenes (wdeadline) Friday, September 9 20 B A Arene Rxns Inorganic Acids (wdeadline) Saturday, September B B Arene Rxns Inorganic Acids (wdeadline) Saturday, September B A Friedel-Crafts (wdeadline) Sunday, September B B Friedel-Crafts (wdeadline) Sunday, September B Arene Mechanistic Issues (wdeadline) Wednesday, September B B Arene Mechanisms (wdeadline) Wednesday, September B A Nucleophilic Aromatic Subs (wdeadline) Thursday, September B B Nucleophilic Aromatic Subs (wdeadline) Friday, September 14 Exam 1 September 20, 21, 22
6 Give the major organic product(s) of the following reaction. Give your answer as a text answer, with the correct answers being listed in alphabetical order. Br2 FeBr Q2 A B C D E. None of the above.
7 Give the major organic product(s) of the following reaction. Give your answer as a text answer, with the correct answers being listed in alphabetical order. Br2 FeBr Q2 A B C D E. None of the above.
8 Give the major organic product(s) of the following reaction. Give your answer as a text answer, with the correct answers being listed in alphabetical order. Br2 FeBr Q3 A B C D E. None of the above.
9 Give the major organic product(s) of the following reaction. Give your answer as a text answer, with the correct answers being listed in alphabetical order. Br2 FeBr Q3 A B C D E. None of the above.
10 Give the major organic product(s) of the following reaction. Give your answer as a text answer, with the correct answers being listed in alphabetical order. H3O Q4 A B D. None of the above. C
11 Give the major organic product(s) of the following reaction. Give your answer as a text answer, with the correct answers being listed in alphabetical order. H3O Q4 A B D. None of the above. C
12 Friedel-Crafts Reactions Reactions of Arenes with Carbocations Several ways of generating C + Friedel-Crafts only react with benzene or activated arenes
13 Method 1 Acyl Carbocations GENERATING CARBOCATIONS Most commonly used Friedel-Crafts Reaction
14 Acyl Carbocation Examples AlCl4 - AlCl3
15 Acyl Carbocation Examples AlCl4 - AlCl3
16 Acyl Carbocation Examples AlCl4 - AlCl3 No Reaction
17 Give the major organic product(s) of the following reaction. Give your answer as a text answer, with the correct answers being listed in alphabetical order Q5 AlCl 3 A C B D - There is no reaction or the correct product is not listed here.
18 Give the major organic product(s) of the following reaction. Give your answer as a text answer, with the correct answers being listed in alphabetical order Q5 AlCl 3 A C B D - There is no reaction or the correct product is not listed here.
19 Give the major organic product(s) of the following reaction. Give your answer as a text answer, with the correct answers being listed in alphabetical order. AlCl3, Q6 A B C D - There is no reaction or the correct product is not listed here.
20 Give the major organic product(s) of the following reaction. Give your answer as a text answer, with the correct answers being listed in alphabetical order. AlCl3, Deactivated arenes do not react in Friedel-Crafts Reactions Q6 A B C D - There is no reaction or the correct product is not listed here.
21 Method 2 Alkyl Carbocations GENERATING CARBOCATIONS
22 Alkyl Carbocations Behave Like Alkyl Carbocations Secondary AlCl3 Tertiary AlCl3 Aryl AlCl3 No Reaction
23 Notable Things About Alkyl Carbocations - 1 PRIMARY CARBOCATIONS CAN BE FORMED
24 Notable Things About Alkyl Carbocations - 2 CARBOCATIONS CAN REARRANGE
25 Give the major organic product(s) of the following reaction. Give your answer as a text answer, with the correct answers being listed in alphabetical order. (Example: xxxx a b) Q7 AlCl3 D - There is no reaction or the correct product is not listed here. A B C
26 Give the major organic product(s) of the following reaction. Give your answer as a text answer, with the correct answers being listed in alphabetical order. (Example: xxxx a b) Q7 AlCl3 D - There is no reaction or the correct product is not listed here. A B C
27 AlCl 3 Method 3 Carbocations from Anhydrides GENERATING CARBOCATIONS
28 HF Method 4 Carbocations from Alkenes GENERATING CARBOCATIONS No needed!
A B C D E F G Q1. heat
Give the final product of the following reaction. Give your answer as a text answer. If more than one species is correct, put your answers in alphabetical order. HNO3 H2SO4 A B C D E F G 2016-09-09 Q1
Q1. Intensity of M+1 peak x Intensity of M peak 2.57% x 46.60% Number of carbon atoms = Number of carbon atoms =
The mass spectrum of an unknown compound has a molecular ion peak with a relative intensity of 46.60% and an M+1 peak of 2.57%. How many carbon atoms are in the compound? (Fill in an integer number) Number
Give the major organic product(s) of the following reaction.
Give the major organic product(s) of the following reaction. 1) NaNO2, HCl 0 o C 2) CuCN 2016-09-23 Q1 A D B C E F There is no reaction or the correct product is not listed here. 5 of 7 Give the major
Give the major organic product(s) of the following reaction.
Give the major organic product(s) of the following reaction. 1) CH3CH2MgBr 2) H3O 2016-09-26 Q1 + E. There is no reaction or the correct product A B is not listed here. C D Explanation CH3CH2MgBr 1) CH3CH2MgBr
Give a common name for the following compound.
Give a common name for the following compound. A. Benzyl Phenoate B. Phenyl Phenoate C. Benzyl Benzoate D. Phenyl Benzoate E. Phenyl Phenylacetate F. Phenyl Phenylethanoate G. Phenyl Benzylacetate 2016-10-07
A B C D Q1
Think about this reaction in terms of mechanism. All of the intermediates of the reaction are provided. Give the intermediates in order of their appearance along the reaction coordinate. (Example: xxxx
H3O+ heat I Q1
Give the major organic product(s) of the following reaction. Give your answer as a text answer, with the correct answers being listed in alphabetical order. (Example: xxxx a b) H3O + heat A B C D E F G
A B C D E F Q1
Give the major organic product(s) of the following reaction. Give your answer as a text answer, with the correct answers being listed in alphabetical order. (Example: xxxx a b) 1) Li 2) 2016-11-11 Q1 3)
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