Chapter 4. The Intensity-Dependent Refractive Index

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1 Chapter. The Itesity-Depedet Refractive Idex - Third order oliear effect - Mathematical descriptio of the oliear refractive idex - Physical processes that give rise to this effect Referece : R.W. Boyd, Noliear Optics, Academic Press, INC. Noliear Optics Lab. Hayag Uiv.

2 . Descriptio of the Itesity-Depedet Refractive Idex Refractive idex of may materials ca be described by t... where, : weak-field refractive idex : d order idex of refractio it t ( ) e c. c. t ( ) ( ) * ( ) : optical Kerr effect ( rd order oliear effect) Noliear Optics Lab. Hayag Uiv.

3 Polarizatio : P( ) () () eff I Gaussia uits, eff () () () () () () Noliear Optics Lab. Hayag Uiv.

4 Appedix A. Systems of Uits i Noliear Optics (Gaussia uits ad MKS uits) ) Gaussia uits ; () P( t) () () t t t... statvolt P cm statcoulomb cm # # () () dimesioless cm statvolt () cm # statvolt The uits of oliear susceptibilities are ot usually stated explicitly ; rather oe simply states that the value is give i esu (electrostatic uits). Noliear Optics Lab. Hayag Uiv.

5 ) MKS uits ; C P m V m () P( t) () () t t t... () () t t t... : MKS () P( t) : MKS # 8.85 F/m, [F] [C/V] I MKS, I MKS, () dimesioless () () dimesiol ess m V m V () () C () V Cm V Noliear Optics Lab. Hayag Uiv.

6 ) Coversio amog the systems () statvolt V (MKS) ( ) DP D P () () (Gaussia) (MKS) (Gaussia) () (MKS) () (Gaussia) () () (MKS) () (Gaussia) () (MKS) ( ) () (Gaussia) () (MKS) () (Gaussia) () (MKS) ( ) () (Gaussia) Noliear Optics Lab. Hayag Uiv.

7 Alterative way of defiig the itesity-depedet refractive idex I c I ( ) ( ) (..) c c () c () ()? cm 7 ().95 ) W c ( esu esu xample) () CS ( :.9 esu),.58, I MW/ cm,?.95 cm () esu.58 / W I Noliear Optics Lab. Hayag Uiv.

8 Noliear Optics Lab. Hayag Uiv.

9 Physical processes producig the oliear chage i the refractive idex ) lectroic polarizatio : lectroic charge redistributio ) Molecular orietatio : Molecular aligmet due to the iduced dipole ) lectrostrictio : Desity chage by optical field ) Saturated absorptio : Itesity-depedet absorptio 5) Thermal effect : Temperature chage due to the optical field 6) Photorefractive effect : Iduced redistributio of electros ad holes Refractive idex chage due to the local field iside the medium Noliear Optics Lab. Hayag Uiv.

10 Noliear Optics Lab. Hayag Uiv.

11 . Tesor Nature of the rd Susceptibility Cetrosymmetric media F m r mb( r res r) r quatio of motio : r r r b ( r r) r e ( t) / m Solutio : it it i t ( t) e e e c. c Perturbatio expasio method ; () () ( ) ( ) ( ) ( r t r t r t r ) ( t)... ( ) e i t () () () r r r e ( t) / m () () () r r r () () () () () r r r b r r r () Noliear Optics Lab. Hayag Uiv.

12 lemet with eve umber of idex rd order polarizatio : ozero elemets : (Report) P P () () i () ( q) Ner ( q ) q jkl ( mp) () ijkl q m p j ( ) (,,, ) D jkl (,,, ) () ijkl q m th -rak tesor : 8 elemets p j m k m k where, D : Degeeracy factor (The umber of distict permutatios of the frequecy m,, p ) Let s cosider the rd order susceptibility for the case of a isotropic material. ad, l l p p (Report) Noliear Optics Lab. Hayag Uiv.

13 xpressio for the oliear susceptibility i the compact form : ijkl ijkl ik jl il jk xample) Third-harmoic geeratio : ( ) ijkl ( ) ( ) ( ij kl ik jl il jk ) xample) Itesity-depedet refractive idex : ( ) ijkl ijkl ( ) ( ) ( ij kl ik jl ) ( ijkl ) il jk Noliear Optics Lab. Hayag Uiv.

14 Noliear polarizatio for Itesity-depedet refractive idex P ( ) ( ) i jkl ijkl j k l ) 6 6 P ( i i i P i vector form Defiig the coefficiets, A ad B as A 6, B6 (Maker ad Terhue s otatio) P A B Noliear Optics Lab. Hayag Uiv.

15 I some purpose, it is useful to describe the oliear polarizatio by i terms of a effective liear susceptibility, as Pi ij j A ij j B where, ij A A B B Physical mechaisms ; ij i 6 j B 6 i j B/ A6, B/A, B/A, B'/ A B'/A' B'/A' : : : molecular orietatio oresoat electroic electrostrictio respose Noliear Optics Lab. Hayag Uiv.

16 . Noresoat lectroic Noliearities 6 # The most fast respose : a / v s [a (Bohr radius).5x -8 cm, v(electro velocity)c/7] Classical, Aharmoic Oscillator Model of lectroic Noliearities Approximated Potetial : () ijkl U r m r mbr Nbe ij kl ik jl il jk ( q, m,, p) m D( ) D( ) D( ) D( ) q Nbe ij kl ik jl il jk ( ) m D () ijkl m D p (..5) where, D i Accordig to the otatio of Maker ad Terhue, Nbe A B m D D Noliear Optics Lab. Hayag Uiv.

17 Far off-resoat case, D( ), b d () Ne m d 6 / Typical value of () N 7 () 5 cm rad/s,, d m9. esu 8 cm, 8 g e.8 esu Noliear Optics Lab. Hayag Uiv.

18 . Noliearities due to Molecular Orietatio The torque exerted o the molecule whe a electric field is applied : τ P iduced dipole momet Noliear Optics Lab. Hayag Uiv.

19 Secod order idex of refractio Chage of potetial eergy : du U pd p d d d p d cos cos si * Optical field (orietatioal relaxatio time ps order) : * U Mea polarizatio : ) With o local-field correctio : N cos si ( ) cos t Noliear Optics Lab. Hayag Uiv.

20 cos dcos dexp exp U U / / kt kt Defiig itesity parameter, J / kt cos i) J cos cos exp exp J cos J cos sid sid cos sid sid N : liear refractive idex Noliear Optics Lab. Hayag Uiv.

21 Noliear Optics Lab. Hayag Uiv. ii) J cos N cos N cos N cos N

22 Noliear Optics Lab. Hayag Uiv. si cos exp si cos exp cos cos d J d J J J kt N J N 5 5 Secod-order idex of refractio : kt N 5

23 Noliear Optics Lab. Hayag Uiv. ) With local-field correctio P loc p loc PNp ad P P N P N N () N N () () () N () () N or : Loretz-Lorez law kt N 5

24 8. lectrostrictio : Tedecy of materials to become compressed i the presece of a electric field Molecular potetial eergy : U pd d Force actig o the molecule : F U desity chage Noliear Optics Lab. Hayag Uiv.

25 Noliear Optics Lab. Hayag Uiv. Icrease i electric permittivity due to the desity chage of the material : Field eergy desity chage i the material = Work desity performed i compressig the material 8 8 u st st p V V p w So, electrostrictive pressure : 8 8 p e st where, e : electrostrictive costat

26 Noliear Optics Lab. Hayag Uiv. P st CP st P Desity chage : P C where, : compressibility 8 C e For optical field, 8 C e 8 C e C e e

27 it t e c. c. C e 6 <Classificatio accordig to the Maker ad Terhue s otatio> Noliear polarizatio : P P C e 6 () ( ) 8 () ( ) C e That is, CT e A, B 6 Noliear Optics Lab. Hayag Uiv.

28 e e : For dilute gas e / : For codesed matter (Loretz-Lorez law) xample) Cs, C - cm /dye, e () x - esu Ideal gas, C -6 cm /dye ( atm), e = - 6x - () x -5 esu Noliear Optics Lab. Hayag Uiv.

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