Rate Law from D table. Arrhenius Eqn intro Basics

Transcription

1 Sept (day 1) 7 (day 2) 8 (ABCD) (day 3) Lunch time meeting in Mr.Kailley s room. Solubility and formulas Discuss the yearly schedule and other class startup items. *I will post answers for this temporarily under extra resources heading on website this weekend. Then next week I will place answers in the binder in my classroom. PPT colours, some demos 11 (day 4) 12 (day 5) 13 (day 6) 14 (day 7) Rxn type synthesis 15 (day 8) Rxn type synthesis Rxn types Decomposition Col 1,2 rxns Extra reactions Quiz on just formula writing and states Rxn type Organic MCCI activity Demos 18 (day 9) Energy Toolkit 19 (Gr 8 retreat) (day 10) 20 (day 11) Kinetics Intro Rate Law from D table 21 (day 12) 22 PRO-D day 25 (day 13) 26 (day 14) 27 (day 15) 28 (day 16) 29 (ABCD) (day 17) Rate Law from Mechanisms Arrhenius Eqn intro Basics Quiz: On reactions only Begins at 7:40.. end at 8:15 maximum. You can come into the room by 7:45 at the lastest. Arrhenius Eqn ΔT and ΔK

2 Oct (day 18) 3 (day 19) 4 (day 20) 5 (day 21) 6 (day 22) Integrated Rate law Basics INTRO NO HOMEWORK READ YOUR NOTES 9 (Thanksgiving) 16 (day 27) Einstein Photoelectric Effect Bohr Intro Bohr Details intro Integrated Rate law Basics Integrated Rate Law half life Catalysis 10 (day 23) 11 (day 24) Light Energy Basics EM spectrum/ Wave calculations Start Blackbody 17 (day 28) 18 (day 29) Bohr calculations details and examples Quiz on integrated rate law and ½ life lessons AT LUNCH 12 (day 25) Quiz on ln K vs 1/T graph ( 1 question, multiple parts) start at 7:40ish If you want, no later than 7:50) Quiz from PE upto basic arrhenius At lunch 13 (ABCD) (day 26) Blackbody Quantized Energy INTEGRATED RATE LAW ACTIVITY DUE BEGINNING OF NEXT CLASS Quiz on complex Arrhenius ie) comparing rates, and different temperatures with k value).calculations, know your ln rules, I will give a formula sheet. Do at end of class. 19 (day 30) 20 PRO-D INTEGRATED RATE LAW ACTIVITY DUE TODAY 23 (day 31) Quantum Numbers EC Balmer Lab,use spectrophotometer 30 (day 36) Orbitals wave idea (intro only, details at the end of the course) Went upto basic drawing of psi and psi squared. Inclass on on Bohr calculations, energy levels 24 (day 32) 25 (PT conference) (day 33) 31 (day 37) DeBroglie Heisenberg Intro to wave orbitals. Inclass: light, planck formula,einstein photoelectric UPDATED THE DEBROGLIE /HEISENBERG OP Page,in online package. ADD the following questions to your uncertainty notes in Heisenberg and try them out: 1)electron mass is 9.11x10-31 kg, and UNCERTAINTY in velocity of e - is 2.18x10 5 m/s. (About 10% of the actual velocity of 2.18x10 6 m/s) a)what is the value of the ΔX. ΔX= 266pm b)considering the atom diameter of the H atom is 240pm, explain the significance of the value of ΔX you calculated in (a). Position of e - has much uncertainty because the uncertainty is actually larger than the house (H-atom) it lives in! c)if decrease the ΔV to 2.00x10 2 m/s, what happens to the ΔX, calculate and briefly explain. ΔX=2.90x10 5 pm,since the uncertainty of velocity decreased, the uncertainty of the position increased!!! d)if Mr.K has a m=76.0kg, and his ΔV=0.1m/s, what is the ΔX? What does this mean about how well you know my position?δx=6.94x10-36 m. Very small unc inposition (mostly due to larger mass) so you know my position quite accurately. This is true for most large matter pieces. The Balmer lab is due on THURSDAY NEXT WEEK and DON T forget to study a little for the inclass on Monday (topic is listed on Monday s homework) AND LOOK UNDER EXTRA RESOURCES FOR SOME HELP VIDEOS FOR UNCERTANITY CALC AND BOHR CALC s 26(PT conference) (day 34) 27 (day 35)

3 Nov (day 38) 2 (day 39) 3 (ABCD) (day 40) Orbitals day 2. From psi squared to RPD and then shapes of various wavefunctions for different orbitals For extra practice, you can try to do psi squared and psi and RPD graphs for the given orbitals as well as drawing the orbitals on the online package sheets. Inclass: Quantum #,EC MOVED TO FRIDAY MORNING. CLASS ON FRIDAY STARTS AT 7:15. Inclass: Quantum #,EC MOVED TO FRIDAY MORNING.along with debroglie and Heisenberg inclass. CLASS ON FRIDAY STARTS AT 7:15. Periodic Trends Coulombic Force Periodic Trends NFA Periodic Trends Gr 11 Review Periodic Trends IE and exceptions Periodic Trends IE1, IE2. 6 (day 41) Periodic Trends Ea Also answer the question: generally as go across a row, the Ea will (inc/dec) and as you go down a column the Ea will (inc/dec) Mass Spec Basics 7 (day 42) 8 (day 43) Finish 1 example of mass spec Empirical Formula IR Spec Start PES DON T DO PES HW YET Inclass DeBroglie,Heisenberg 9 (day 44) 10 (day 45) Inclass: Orbital Basics (some drawings),maybe a bonus question on psi Inclass: trends IE exceptions and IE1, IE2 etc. 13 Remembrance day 20 (day 50) Edot s finish Resonance Formal Charge Bond Order Lewis acid and base Inclass PES(if not enough time, do it tomorrow either 8 am or lunch. About 10 minutes max) 27 (day 54) Hybrids sigma INCLASS: 1 edot question :draw edot, get shape, and polarity. and 2 multiple choice on IFA (similar to OP) 14 (day 46) 15 (day 47) Absorbance (Set up lab,work on it over the next several lunches) Inclass: Ea 21 (day 51) 22 (day 52) VBT/Hybrids intro Inclass,absorbance, 28 (day 55) 29 (day 56) ABS LAB: You must analyze your solutions and the Gatorade solution by Thursday of next week. Hybrids pi INCLASS: Resonance/FCharge/BO/: It will be 1 combined question. And 1 separate question on identifying Lewis acid and base from a GIVEN reaction. ABS LAB: complete the write up by Monday Dec 4 th NOTE stock solution blue dye [ ] = M And molar mass of blue dye (huge organic compound with lots of benzenes=conjugated double bonds so will absorb colour) is 793 g/mol 16 (day 48) 17 (ABCD) (day 49) Finish absorbance then IFA review EDot (Lewis) shape and polarity intro only Don t do any HW on this yet. ABS LAB: As a lab group, YOU MUST CREATE YOUR SOLUTIONS BY WED of next week, come mon lunch, tues AM, lunch or after school. I need to know your lab groups by today. Inclass:Emp F, mass spec 23 (day 53) 24 PRO-D 30 (day 57)

4 Dec (day 58) 4 (day 59) Hybrids ions and complex examples Hybrid review Inclass sigma hybrids and lab is due 5 (day 60) 6 (day 61) Resonance details (extra) Inclass Pi hybrids 7 Conference Day 8 (ABCD) (day 62) States and link to IFA States and names of Δphase Metallic Solids Alloys Some Liquids properties, S.Tension, Cap Action 11 (day 63) Gas intro: pressure NO INCLASS TODAY, WE HAVE SOME LABS AND A DEMO 12 (day 64) 13 (day 65) Ideal gas law Small inclass on metallic solids and alloys only. Inclass complex hybrids (ions, or just difficult hybrids) 14 (day 66) 15 (day 67) 18 (day 68) Dalton s Law of Partial Pressure Combined container 19 (day 69) 20 (day 70) Mole fraction Inclass on ideal gas law 21 (day 71) 22 (LAST DAY BEFORE BREAK) (day 72) NO AP ON THIS DAY Dalton s Law of Partial Pressure Manometer pressure conversions Dalton s Law of Partial Pressure Manometer No inclass today Break

5 Jan Break (school opens) (day 73) Gas lab do it in class. 8 (day 74) 10 (day 75) Gas KMT Gas KEavg and Temp Gas KE graph 11 (day 76) 12 (day 77) 15 (day 78) Gas RMS 16 (day 79) 17 (day 80) 18 (day 81) 19 (ABCD) (day 82) Gas Diffusion/Effusion Gas Deviation from Ideal PE review PE in nbonds,ifa and Zeff Quiz daltons law of partial pressure gas RMS ΔE idea Flux methods qualitative KE quick review Temperature,Thermal Internal Energy Basics 22 (day 83) First Law thermodynamics Heat detail Gas work detail 23 (day 84) 24 (day 85) 25 (Eng prov) Quiz Gas effusion/diffusion gas deviations 26 (Communications Prov) PV diagram basics Work and ideal gas law

6 Feb (day 1) 1 (day 2) 2 (ABCD) (day 3) Electrical work Calculations q,w,δh Enthalpy defined Rxn enthalpy 5 (day 4) Hess Law Enthalpy of Formations 6 (day 5) 7 (day 6) Bond dissociation Lab Data collection HCl and NaOH 8 Conference day Quiz on PE review electrical work 9 (day 7) 12 Family day 13 (day 8) 14 (day 9) Calorimetry Inro Calorimetry Heat Capacity Calorimetry and Chem rxn calc s Calorimetry and Salt dissolving 15 (day 10) 16 (ABCD) (day 11) Calorimetry and Physical Change Calorimetry and 2 different objects. 19 (day 12) Calorimetry Lab HCl and NaOH 20 (day 13) 21 (day 14) Entropy Intro 22 (day 15) Quiz on enthalpy 23 PRO-D 26 (day 16) 27 (day 17) 28 (day 18) Reversible Path Calculating ΔSprocess Entropy Physical changes Entropy and 2 nd Law Entropy Chemical Changes Third Law

7 March (day 19) 2 (day 20) Quiz on calorimetry 5 (day 21) 6 (day 22) 7 (day 23) 8 (day 24) 9 (ABCD) (day 25) Gibbs Energy Basics Calculations ΔG=ΔH-TΔS Quiz on entropy FED intro Calculations ΔGf Calculations Hess Law and ΔG 12 (day 26) FED and ΔG=ΔG 0 + RTlnQ 13 (day 27) (PT conference) 14 (day 28) (PT conference) Qc and Qp 15 (day 29) 16 Spring Break Starts

8 April Easter Monday 3 (day 30) 4 (day 31) 5 (day 32) 6 (day 33) Cell potential Quiz on gibbs energy basics Qc K and ΔG o Equilibrium(Keq value) and Gibbs Free Energy: Ksp LAB 9 (day 34) K and ΔG o finish E o and EQ Stoich and Cells 10 (day 35) 11 (day 36) Evaporation basics Clausius Claperyon Activity 12 (day 37) 13 (ABCD) (day 38) Boiling Point Solution Types Syringe BP activity 16 (day 39) 17 (day 40) 18 (day 41) 19 (day 42) 20 (day 43) Dissolving details (ionic) Hot pack lab. Solubility Quiz on cell potential to stoich and cells 23 (day 44) Separation Lab Techniques 24 (day 45) 25 (day 46) Chromatography Lab 26 (day 47) 27 Pro-D day 30 (day 48) Concentration Units

9 May (day 49) 2 (day 50) 3 (day 51) 4 (ABCD) (day 52) AP exam writers review AP exam writers review 7 (day 53) AP Chemistry exam 8 am. Quiz on Evaporation Basics Separation Lab Techniques 8 (day 54) 9 (day 55) Vitamin C titration 10 (day 56) 11 (day 57) 14 (day 58) KHP titration 15 (day 59) 16 (day 60) Advanced Orbitals Day 1: psi and parts 17 (day 61) Quiz on concentration units 18 Pro-D day 21 Victoria Day 28 (day 66) Advanced Orbitals Orbitals 2 Extra RPD informations 22 (day 62) 23 (day 63) Advanced Orbitals RPD and Nodes 29 (day 67) 30 (day 68) MOT day 1 sigma only Hand in Textbooks by today 24 (day 64) 25 (ABCD) (day 65) Advanced Orbitals orbitals 31 (day 69)

10 June (day 70) 4 (day 71) 5 (day 72) 6 (day 73) 7 (day 74) 8 (ABCD) (day 75) MOT day 2 pi Phase diagram 1 newman 1 basics Phase diagram 2 Newman 2 PE energies 11 (day 76) Sub rxns 12 (day 77) E/Z fischer 13 (day 78) Fischer polymer start 14 (day 79) polymers 15 (day 80) Extra Extra: particle in a box 18 (day 81) Particle in a box 19 (day 82) 20 (day 83) PV diagram reversible details 21 (day 84) 22 PV diagram carnot cycle

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