AP Chemistry

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1 AP Chemistry Patrick Hemmingsen Telephone Course Description: The AP Chemistry course is designed to be the equivalent of the general chemistry course usually taken during the first year of college. During this course, students will attain a deep understanding of fundamentals and a reasonable competence in dealing with chemical problems. The course will also contribute to the development of the students ability to think clearly and express their ideas, orally and in writing, with clarity and logic. The course will provide instruction on the structure of matter (atomic theory and structure, chemical bonding, and nuclear chemistry), states of matter (gasses, liquids, solids, and solutions), and reactions (reaction types, stoichiometry, equilibrium, kinetics, and thermochemistry). There will be an emphasis on chemical calculations, mathematical formulation of principles, and laboratory work. Texts: Brown, Theodore L., et al. Chemistry: The Central Science, Eleventh Edition. Upper Saddle River: Pearson Education Inc., Nelson, John H. and Kemp, Kenneth C. Laboratory Experiments for Chemistry: The Central Science, Eleventh Edition. Upper Saddle River: Pearson Education Inc., Venderbrink, Sally. Laboratory Experiments for AP Chemistry. Batavia: Flinn Scientific, Grading Policy: Homework: Tests/Quizzes: Term grades will be calculated as a weighted average of the following. Exams 50% Quizzes 20% Labs 20% Homework 10% Homework must be completed in a timely manner to prepare the student for discussion. The majority of homework will require calculations and mathematical formulations of principles like calculating empirical formula, percent composition, equilibrium and rate constants, Gibbs free energy, etc. Quizzes will occur every Friday. They will cover any homework, assigned reading or laboratories done that week. Some of the quiz problems will be directly from the homework and others will be the same with different numbers used in the problems. There will be a test at the end of every unit. The tests will be similar in format to the AP Chemistry exam with a multiple choice and free response section.

2 Labs: The labs will be hands-on/ wet labs with possibly a few teacher demonstrations. The labs completed require following processes and procedures, making and recording observations, and data manipulation. Students will need to communicate and work collaboratively in groups in the lab but each student is required to write a laboratory report in their lab notebook for every lab they perform. See Laboratory Notebook page for more information. Semester Grades: Semester grades will be 90% term grade and 10% semester final as per school policy. Study Assistance: Throughout the year times will be posted or announced for study assistance. If you feel you are getting lost please get help from me as soon as possible. I also recommend that you form a study group with fellow students to work on problem solving and test preparation.

3 Course Outline Unit 1 Chemistry Basics (Chapter 1 and 2) ~ 2 weeks Properties of matter, accuracy and precision, significant figures, atomic theory and structure, formulas and nomenclature. 1. Separation and qualitative determination of cations and anions (AP Lab 14). 2. Liquid Chromatography (AP Lab 18). Unit 2 Stoichiometry and Chemical Reactions (Chapters 3 and 4) ~ 4 weeks Balancing equations, mole concept, percent composition, molecular and empirical formulas, limiting reagents, solution Stoichiometry, reactions combination, decomposition, combustion, precipitation, acid/base, oxidation/reduction, net ionic equations. 3. Gravimetric analysis of a metal carbonate (AP Lab 16). 4. Determination of the empirical formula of silver oxide (AP Lab 1). 5. Determining the Stoichiometry of chemical reactions (AP Lab 9). 6. Analysis of alum (AP Lab 2). 7. Oxidation-Reduction titration (AP Lab 8). NOTE: Some of these labs will be performed during Units 3 and 4 due to time limitations. Unit 3 Atomic Structure and Periodic Properties (Chapters 6 and 7) ~ 2 weeks Atomic spectra, Bohr model, quantum numbers, atomic orbitals, electron configurations, atomic and ionic radii, ionization energy, electron affinity. 8. Atomic spectra and atomic structure. Unit 4 Chemical Bonding and Molecular Geometry (Chapters 8 and 9) ~ 3 weeks Ionic bonding, covalent bonding, Lewis structures, molecular shapes, polarity, VSEPR model, hybrid orbitals. 9. Molecular geometries of covalent molecules: Lewis structures and the VSEPR model.

4 Unit 5 Gasses, Liquids and Solids (Chapters 10, 11 and 13) ~ 3 weeks Ideal gas law, partial pressures, kinetic theory of gasses, Graham s law, Van der Waals equation, intermolecular forces, phase changes and diagrams, bonding in solids, solubility, concentration, colligative properties, colloids. 10. Determination of molar mass of gasses and volatile liquids (AP Lab 3). 11. Determination of molar volume of a gas (AP Lab 5). 12. Molar mass of freezing point depression (AP Lab 4). Unit 6 Kinetics and Chemical Equilibrium (Chapter 14 and 15) ~ 3 weeks Reaction rate, rate law, order of reactions, activation energy, reaction mechanisms, catalysis, equilibrium constants (K c and K p ) calculating, interpreting and applying Le Châtelier s principle. 13. Kinetics of a reaction (AP Lab 12). 14. The determination of K c of FESCN + (AP Lab 17) Unit 7 Acids/Bases and Aqueous Equilibria (Chapters 16 and 17) ~ 3 weeks Arrhenius, Bronsted-Lowry and Lewis acid/base theories, K w, ph, K a and K b, acid/base titrations, common ion effect, buffers, K sp. 15. Acid/base titration (AP Labs 6 and 7). 16. Determining the K a of a weak acid (AP Lab 10). 17. ph properties of buffer solutions (AP Lab 19). 18. Selecting indicators of acid-base titrations (AP Lab 11). Unit 8 Thermodynamics (Chapters 5 and 19) ~ 2 weeks Law of thermodynamics, enthalpy, calorimetry, Hess s law, entropy, Gibbs free energy, state functions. 19. Enthalpy of reaction and Hess s law (AP Lab 13).

5 Unit 9 Electrochemistry (Chapter 20) ~ 2 weeks Oxidation states, oxidation and reduction half reactions, balancing by half reaction method, voltaic cells, standard reduction potential (EMF), Nernst equation, EMF and free energy, electrolysis, Faraday s laws. 20. An activity series (AP Lab 20). 21. Electrochemical cells (AP Lab 21). Unit 10 Nuclear and Organic Chemistry (Chapters 21 and 25) ~ 2 weeks Radioactivity, nuclear equations, half-life, fission, fusion and other applications, introduction to alkanes, alkenes, alkynes and organic functional groups. 22. Synthesis, isolation and purification of an ester (AP Lab 22). Unit 11 Coordination Compounds (Chapter 24) ~ 2 weeks Metal complexes, monodentate ligands, polydentate ligands, nomenclature, isomerism. 23. Synthesis and analysis of a coordination compound (AP Lab 15). AP Chemistry Test Review (from end of Unit 11 until test date)

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