Department of Chemical Science University of Padova 1, via Marzolo 35100, Padova, Italy
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1 Department of Chemical Science University of Padova 1, via Marzolo 35100, Padova, Italy Tel. (+39) Tel. mobile. (+39) Fax. (+39) Paolo Sgarbossa Personal Information Nationality: italian Date of birth: 18 may 1978 Place of birth: Castelfranco Veneto (TV), Italy Education Since genuary : Ph.D student in Chemical Science, Università di Padova, Italy. Thesis Title: Synthesis of Pt(II) Complexes as Lewis Acids in Catalysis. Supervisor: prof. M. Basato, Università di Padova, Italy. Chemist Qualifying Examination First section : Degree in Chemistry, Università di Padova, Italy. Thesis Title: Synthesis, Coordination to Transition Metals and Reactivity of N-functionalized Isocyanide Ligands. Supervisors: prof. M. Basato and prof. R. A. Michelin, Università di Padova, Italy. Research Experience Synthesis and characterisation of functionalized isocyanide ligands. Coordination to transition metals such as Pt(II), Pd(II), W(0), Cr(0) and Au(I), and reactivity. Synthesis of Pt(II) complexes with diphosphine ligands, of the type [Pt(µ-OH)(P-P)] 2 [X] 2. Spectroscopic characterisation and activity in the Baeyer-Villiger oxidation of cyclic ketones. Synthesis of cationic platinum(ii) complexes with hemilabile phosphane-phosphine oxide ligands. Spectroscopic, structural characterisation and catalytic properties in the Baeyer-Villiger oxidation of ketones with hydrogen peroxide. Synthesis of Pt(II) complexes bearing perfluorinated ligands of the type [Pt(C 6 F 5 )(solv)(p-p)]. Spectroscopic characterisation and catalytic activity in the epoxidation of terminal olefins. Work Experience Synthesis of water-soluble diphosphines of the type R(P(CH 2 OH) 2 ) 2. Coordination to Pt(II). Grant 1
2 March 2003 December 2003; theme: Novel Eco-efficient Oxidation Processes based on H 2 O 2 Synthesis on Catalytic Membranes ; supervisor: prof. G. Strukul; Department of Chemistry, Università di Venezia, Italy. Scientific Linguistic Technical Ability to work with high vacuum techniques using standard Schlenk techniques, under inert gas atmosphere. Nuclear Magnetic Resonance: multinuclear ( 1 H, 13 C, 31 P, 19 F); coupling and decoupling. Infrared Spectrometry (far e medium IR). UV- Vis Spectrometry. Thin layer chromatography Gas chromatography English: reading skills, good, writing skills, good, verbal skills, good. Systems: Windows. Programs: Word, Excel, Origin, Power Point, ChemWin, ChemDraw, IsisDraw, WinNMR, gnmr, Netscape. Scientific Contribution Pubblications G. Facchin, R.A. Michelin, M. Mozzon, S. Pugliese, P. Sgarbossa, A. Tassan Synthesis and transition metal coordination of 2- (azidomethyl)phenyl isocyanide Inorganic Chemistry Communication 5 (2002) M. Basato, G. Facchin, R.A. Michelin, M. Mozzon, S. Pugliese, P. Sgarbossa, A. Tassan Transition metal coordination and reactivity of 2- (azidomethyl)-, 2-(chloromethyl)- and 2-(iodomethyl)phenyl isocyanides Inorganica Chimica Acta 356 (2003) M. Basato, F. Benetollo, G. Facchin, R.A. Michelin, M. Mozzon, S. Pugliese, P. Sgarbossa, S. Mazzega Sbovata, A. Tassan The Staudinger reaction of platinum(ii)- and palladium(ii)-coordinated 2- (azidomethyl)phenyl isocyanide. X-ray structure of trans- [PtCl{CN(H)C 6 H 4-2-CH 2 N(H)}(PPh 3 ) 2 ][BF 4 ] CDCl 3 H 2 O Journal of Organometallic Chemistry 689 ()
3 G. Facchin, R.A. Michelin, M. Mozzon, P. Sgarbossa, A. Tassan Synthesis and cyclization reactions of platinum(ii)-coordinated arsonium-substituted phenyl isocyanides, o-(i R 3 As + CH 2 )C 6 H 4 N C Inorganica Chimica Acta 357 () A. Brunetta, P. Sgarbossa, G. Strukul Lewis acidic complexes of platinum(ii): a mechanistic study of the Baeyer Villiger oxidation of methylcyclohexanone with hydrogen peroxide catalyzed by [(triphospo)pt] 2+ species Catalysis Today 99 (2005) R.A. Michelin, E. Pizzo, A. Scarso, P. Sgarbossa, G. Strukul Baeyer- Villiger Oxidation of Ketones Catalyzed by Platinum(II) Lewis Acid Complexes Containing Coordinated Electron-Poor Fluorinated Diphosphines Organometallics 24 (2005) M. Basato, R.A. Michelin, M. Mozzon, P. Sgarbossa, A. Tassan Nheterocyclic carbenes from transition metal coordinated functional isocyanides of the type o-(ch 2 Y)C 6 H 4 N C (Y=OSiMe 3, OH; N 3 ; AsR 3 + ) Journal of Organometallic Chemistry 690 (2005) Communications P. Sgarbossa, Sintesi, coordinazione a metalli di transizione e reattività di isonitrili N-funzionalizzati G.I.C. Award 2003, VII Italian Seminar on Catalysis New Frontiers in Molecular Catalysis Venezia, Isola di S. Servolo 29 Giugno - 4 Luglio Baeyer-Villiger Oxidation of Ketones by Platinum(II) Lewis Acid Complexes with Coordinated Electron-Poor Diphosphines XIV Congresso Nazionale di Catalisi GIC Le Scienze Molecolari al Servizio dell Uomo Lerici (La Spezia), 6-10 Giugno P. Sgarbossa, A. Brunetta, G. Strukul, R.A. Michelin, R. Ros, E. Pizzo, S. Mazzega Sbovata, A. Tassan Cationic Platinum(II) Complexes with Electron-Poor Diphosphines as Catalysts for the Baeyer-Villiger Oxidation of Ketones with Hydrogen Peroxide VII Italian Seminar on Catalysis New Frontiers in Molecular Catalysis Venezia, Isola di S. Servolo 29 Giugno - 4 Luglio 2003 R.A. Michelin, E. Pizzo, S. Mazzega Sbovata, P. Sgarbossa, G. Strukul, A. Tassan Synthesis of Cationic Platinum(II) Complexes with Hemilabile Phosphine-Phosphine Oxide Ligands for the Baeyer-Villiger Oxidation of Ketones XIV Congresso Nazionale di Catalisi GIC Le Scienze Molecolari al Servizio dell Uomo Lerici (La Spezia), 6-10 Giugno Baeyer-Villiger Lewis Acid Oxidation Catalysts Based on Cationic Platinum(II) Complexes with Fluorinated 1,2-3
4 Bis(Bisdiphenilphosphino)ethane Ligands IX Scuola Nazionale per Dottorandi Chimica Organometallica La Chimica Organometallica e le Tecnologie Avanzate Venezia, Isola di S. Servolo 27 Giugno - 1 Luglio Catalytic Synthesis of Lactones from the Baeyer-Villiger Oxidation of Cyclic Ketones with Lewis Acid Platinum(II) Complexes XXXII Congresso Nazionale di Chimica Inorganica Roma, Settembre Selected catalytic Processes Promoted by Cationic Platinum(II) Lewis- Acid Complexes VI Co.G.I.C.O. Congresso del Gruppo Interdivisionale di Chimica Organometallica Cetraro (CS), 30 Settembre - 3 Ottobre P. Sgarbossa, R.A. Michelin, R. Bertani, M. Mozzon, S. Mazzega Sbovata, A. Venzo, The Reactions of Pt(II) Nitrile Complexes with Aliphatic Primary, Secondary Amines and NH 3 VI Co.G.I.C.O. Congresso del Gruppo Interdivisionale di Chimica Organometallica Cetraro (CS), 30 Settembre - 3 Ottobre Platinum(II) Complexes with Alkyl Diphosphines as Catalysts in the Baeyer-Villiger Oxidation of Cyclic Ketones VIII Seminario Italiano di Catalisi Catalisi per la Chimica Fine: una sfida per i ricercatori, un vantaggio competitivo per le industrie Pallanza-Verbania, Giugno 2005 R.A. Michelin, E. Pizzo, P. Sgarbossa, A. Scarso, G. Strukul, A. Tassan Bis-Phosphine Monoxide (BPMO) Patinum(II) and Palladium(II) Complexes as Catalysts in Diels-Alder Reactions VIII Seminario Italiano di Catalisi Catalisi per la Chimica Fine: una sfida per i ricercatori, un vantaggio competitivo per le industrie Pallanza-Verbania, Giugno 2005 P. Sgarbossa, G. Greggio, R.A. Michelin, E. Pizzo, A. Scarso, G. Strukul, A. Tassan Synthesis of Lactones from the Baeyer-Villiger Oxidation of Cyclic Ketones with Hydrogen Peroxide Catalyzed by Bis- Triflate Platinum(II) Complexes XXXIII Congresso Nazionale della Divisione di Chimica Inorganica della Società Chimica Italiana Siena, Luglio 2005 P. Sgarbossa, R.A. Michelin, E. Pizzo, A. Scarso, G. Strukul Epoxidation of Terminal Olefins with Hydrogen Peroxide Catalyzed by Cationic Pentafluorophenyl Platinum(II) Complexes XII ISHHC - International Symposium on relations between Homogeneous and Heterogeneous Catalysis Firenze, Luglio
5 A. Scarso, P. Sgarbossa, R.A. Michelin, G. Strukul Mild Catalytic Oxidation of Tertiary Amines to N-Oxides with H 2 O 2 Mediated by Pt(II) Catalyst XII ISHHC - International Symposium on relations between Homogeneous and Heterogeneous Catalysis Firenze, Luglio 2005 A. Scarso, P. Sgarbossa, E. Pizzo, R.A. Michelin, G. Strukul Terminal Alkenes Epoxidation with Hydrogen Peroxide Mediated by Pt(II) Catalysts DGMK/SCI International Conference Oxidation and Functionalization: Classical and Alternative Routes and Sources Milano, Ottobre 2005 In ottemperanza alla legge 675/96 autorizzo l utilizzo dei miei dati personali. 5
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