Curriculum for B.Tech in Chemical Engineering

Transcription

1 Curriculum for B.Tech in Chemical Engineering Semester 1 Semester 2 PH1010 Physics I 3 PH1020 Physics II 3 CY1010 Environmental Chemistry 3 CY1020 Dynamics of Chemical Systems 3 MA1010 Maths I 4 MA1020 Maths II 4 ID1011 Concepts in Engineering Design 4 BO1020 Concepts in Life Sciences 3 ID1021 Engineering Practice 4 CH1020 Engg. Thermodynamics 3 ID1035 Independent Project 1 ID 1061 Computational Engineering 3 PH1031 Physics Lab 2 CH1021 Intro. To Chem. Engg. : Lab. 2 CY1031 Chemistry Lab 2 CH1040 Perspective in Chem. Engg. 2 Total = 23 Total = 23 Semester 3 Semester 4 ID2030 Fluid Mechanics and Rate processes 4 CH2020 Chemical Reaction Engg. 3 CH2050 Material & Energy Balances 3 CH2040 Heat Transfer 3 CH2010 Applied Chemistry 3 CH2060 Process Control & Instrumentation 3 Math III 3 EE2010 Electrical & Magnetic Circuits 4 CH2070 Mechanical Operations 3 LA2xx0 Liberal Arts Elective 2 3 LA2xx0 Liberal Arts Elective 1 3 CH2021 Fluid & Mechanical Operation Lab. 2 CH2011 Applied Chemistry Lab. 2 CH2080 Energy Options 1 Total = 21 Total = 19 Semester 5 Semester 6 CH3010 Chemical Engg. Thermo. 3 CH3020 Transport Phenomena 3 CH3030 Adv. Chemical Reaction Engg. 3 CH3040 Bio- refinery 1 CH3064 Design with Transport Processes 3 CH3050 Mass Transfer 4 Core Elective I 3 CH3073 Numerical Methods 3 CH3080 Chemical Technology 3 CH3011 Heat & Mass Lab. 2 CH3100 Optimization Techniques 3 MS5060 Material Science & Metallurgy 3 CH3021 Reaction Engg. & Process Control Lab. 2 Total = 18 Total = 18 Honour's 1 3 Honour's 2 3

2 Semester 7 Semester 8 CH4010 Intro. To Biological Engg. 3 CH4020 Intro. To Environmental Engg. 3 CH4064 Core Elective II 3 Free Elective 3 Liberal Arts Elective 3 3 Core Elective IV 3 Process Systems Design & Feasibility 3 LA Elective Core- Elective III 3 CH4040 Professional Ethics 2 CH4011 Process Simulation Lab. 2 CH4030 Safety and Hazard in Chemical Industry 1 CH4084 Process Design Lab. 2 CH4050 Trends in Chemical Engg. 1 Honour's 3 (Project Stage- 1) 3 Total = 19 Total = 16 Honour's 4 (Project Stage- 2) 3 Total Major Credits (Compulsory) 157 Total Honour's Credits (Optional) 15 CH2020 : Chemical Reaction Engineering (3) Introduction: Definition of rate of reaction, molecularity, Transition state theory, types of reactors, industrial reactions and reactors; Basic Concepts in Chemical Kinetics: reaction rate constant, reaction order, elementary reactions and molecularity, reversible reactions, non- elementary reactions; Collection and Analysis of Rate Data: simple constant and variable volume reaction systems, differential and integral methods of kinetic analysis, half- lives, least- squares analysis; Non- elementary Homogeneous Reactions: reaction mechanisms, pseudo- steady state hypothesis, chain reactions, polymerization reactions, Biochemical Reaction systems (enzyme reactions); Isothermal Reactor Design: batch reactor, mixed flow reactor, plug flow reactor; multiple reactor systems; Design for Multiple Reactions in Isothermal Reactors: mass balances, selectivity and yield, parallel reactions, series reactions, complex reactions, best operating conditions for multiple reactions; Non- ideal flow: residence time distribution, tank- in- series model, dispersion model, applications to design 1. H. Scot Fogler, Elements of Chemical Reaction Engineering, Prentice Hall, Second edition, J.M. Smith, Chemical Engineering Kinetics, McGraw Hill, Third Edition, O. Levenspiel, Chemical Reaction Engineering, Wiley, Third Edition, CH3030: Advanced Chemical Reaction Engineering (3) Reaction Engineering. Overview of reaction engineering & emerging challenges, Stoichiometric table, reaction network analysis, effect of pressure drop on performance of plug flow vessels, energy balance and non- isothermal reactors design, optimal design for exothermic reversible reactions, stability and multiplicity of steady states in CSTR. Heterogeneous Catalysis: Adsorption kinetics, Kinetics of Catalytic reaction, Diffusion and Reaction in Porous Catalysts, Design of fixed bed reactors, Shrinking core model, catalyst deactivation, design for deactivating catalysts, fluid bed reactors, design of fluid bed reactors, applications, overview, and Design of slurry and trickle bed reactors. 1. H. Scot Fogler, Elements of Chemical Reaction Engineering, Prentice Hall, Second edition, 1986.

3 2. J.M. Smith, Chemical Engineering Kinetics, Mcgraw Hill, Third Edition, O. Levenspiel, Chemical Reaction Engineering, Wiley, Third Edition, Supplementary Reading: 1. G. F. Froment and K. B. Bischoff, Chemical Reactor Analysis and Design, John Wiley, C.G. Hill, An Introduction To Chemical Engineering Kinetics & Reactor Design, John Wiley & Sons, New York, J. Hagen, Industrial Catalysis- A Practical Approach, Wiley- Vch, L.D. Schmidt, The Engineering of Chemical Reactions, Oxford University Press, CH3020: Transport Phenomena (3) Mathematics: Vector and tensor algebra and calculus, curvilinear coordinates Momentum transport: Viscosity, stress tensor, mechanisms of momentum transport; shell momentum balance, unidirectional flow: couette flow, falling film, Hagen Poiseuille flow. Governing equations of fluid mechanics, equations of continuity and motion; substantial derivatives; dimensional analysis of the equations of change. Time dependent flows, analytical solutions of partial differential equations, method of similarity solutions, Sturm- Liouville problems. Introduction to flows with more than one non- vanishing velocity components, stream function, limiting cases: creeping flow, potential flow, and boundary layer theory. Energy transport: Thermal conductivity, governing equations of heat transfer, energy balance, energy equation. Conduction, forced convection, natural convection, steady heat conduction in laminar flow. Mass transport: Concentrations, velocities, and mass fluxes, diffusivity. Governing equations of mass transfer, equation of continuity, equations of change for multicomponent systems, diffusion and reaction; heat and mass transfer coefficients. Reference: 1. Bird, R.B., Stewart, W.E. and Lightfoot E.N., Transport Phenomena, Revised 2 nd edition, John Wiley and Sons, Additional reading 1. Deen W. M., Analysis of Transport Phenomena, Oxford University Press, Schlichting, H., Boundary Layer Theory, Revised 8 th edition, Springer, Leal, G.L., Advanced Transport Phenomena: Fluid Mechanics and Convective Transport Processes, Cambridge University Press, CH2080: Energy Options (1) Introduction to energy conversion and storage technologies; thermal energy conversion: coal, petroleum, natural gas; fossil fuel characterization; nuclear power generation; solar photovoltaic and solar thermal; hydroelectric, wind and tidal energy; biofuels; electrochemical energy conversion: fuel cells and batteries; current and future energy requirements in India and across the world. 1. V. Balzani and N. Armaroli, Energy for sustainable world, Wiley- VCH, Renewable Energy Editor G. Boyle, Oxford University Press, 2004

4 CH2070: Mechanical Operations (3) Presents engineering principles and unit operation involved in the particulate solid systems. It covers characterization of particulate solids, solids handling, mixing of solids, Comminution theory and devices, Flow through porous media, Fluidization, Gravity settling operations, Centrifugal separations, Gas solid separation processes, Filtration theory and equipments. 1. Warren L. McCabe, Julian Smith, Peter Harriott, Unit Operations of Chemical Engineering. McGraw- Hill 7 th Ed, Wills B.A. Napier- Munn, T.J., Mineral Processing Technology, 7 th Ed, Elsevier Publishers, Geankoplis C. J., Transport Processes and Separation Process Principles, Prentice Hall; 4 th Ed, 2003 CH2050: Material and Energy Balances (3) Review of basic concepts: units and dimension, material properties, process variables and stoichiometry; Techniques for problem solving; Steady state material balances for processes involving no reaction; Steady state material balances for processes involving reaction: species and elemental balances, combustion of fuels; Recycle, bypass and purge calculations; Steady state material balances involving multiple units; Steady state material balances in multiphase systems ; Steady state energy balances for processes with and without reaction; De- Coupled and coupled mass and energy balances; Analysis of degree of freedom in a steady state process ; Material and energy balances using process simulators; Unsteady state material and energy balances 1. D.M. Himmelblau and J.B. Riggs, Basic Principles and Calculations in Chemical Engineering 7th edition. Prentice Hall of India, New Delhi, G.V. Rekliatis, Introduction to Material & Energy Balances Wiley, New York, R.M. Felder and R.W. Rousseau, Elementary Principles of Chemical Processes, 3rd editionn. John Wiley and Sons (Asia) Pvt. Ltd., Singapore, B.I. Bhatt and S.B. Thakore, Stoichiometry 5th edition, Tata McGraw Hill, N.D., CH3010: Chemical Engineering Thermodynamics (3) Equations of state and generalized correlations, Pure component Phase equilibria, Theory of corresponding states, Real fluid equilibrium, Phase rule, Introduction to multicomponent multiphase equilibrium, Single phase mixtures and solutions: Ideal solutions, partial molar quantities, Gibbs- Duhem equation, phase equilibrium criteria, Non- ideal solutions, Residual and excess properties, Fugacity and activity coefficient models, Vapour- liquid equilibria (VLE) at low to moderate pressures, Raoult s law, Henry s law high- pressure, Liquid activity coefficient models, Chemical reaction equilibrium: Homogeneous and heterogeneous reactions, Multireaction equilibria, Combined phase and reaction equilibria, Basics of statistical thermodynamics. 1. S. Sandler, Chemical, Biochemical and Engineering Thermodynamics, 4 th Ed. John Wiley 2006

5 2. J. M. Smith, H. C. Van Ness and M. M. Abbott, Chemical Engineering Thermodynamics, 7 th Ed CH3040: Bio- refinery (1) Overview of petroleum refinery and petrochemicals, Scenario of energy and chemicals and need for renewable feedstock; Introduction and overview of bio- refinery, Fuels and chemicals from vegetable oils; Bio- alcohol as feedstock for fuels and chemicals; Synthesis gas from biomass, overview of gasification, pyrolysis, and reforming; Fuels and chemicals from synthesis gas; Fuels and chemicals from biomass. References 1. James H. Gary, Glenn E. Handwerk, Mark J. Kaiser, Petroleum Refining: Technology and Economics. CRC Press, 5th edition, Birgit Kamm, Patrick R. Gruber, Michael Kamm, Biorefineries - industrial processes and products: status quo and future directions, Volume 1&2, Wiley- VCH, Avelino Corma, Sara Iborra, and Alexandra Velty, Chemical Routes for the Transformation of Biomass into Chemicals. Chem. Rev.2007, 107, Yuguo Zheng,Xiaolong Chen, and Yinchu Shen, Commodity Chemicals Derived from Glycerol, an Important Biorefinery Feedstock.Chem. Rev. 2008, 108, ID2030: Fluid Mechanics & Rate processes (4) Fluid Mechanics: Introduction of fluids, Fluid statics: pressure as a scalar, monometry, forces on submerged surfaces. Description of flows: field approach, Euler acceleration formula, streamlines, streak lines, path lines. Reynolds transport theorem: Conservation of mass, stream function, linear momentum equation, Navier- Stokes (NS) equation: elementary derivation, application, Poiseuille flow, Couette flow, Energy equation- Bernoulli equation, applications including flow measurement (Pitot tube, Orifice meters), pipe flows and losses in fittings. Similitude and modeling: using non- dimensionalization of NS equations and boundary conditions, simplifications for cases without free surfaces and without cavitation. High Reynolds number flow: Prandtl s approximation, basic inviscid flow, need for boundary layer, Magnus effect, boundary layers- elementary results for flat plates, separation, flow past immersed bodies (bluff, streamlined). Heat transfer: Introduction, rate law and conservation law, conduction equation; non- dimensionalization, various approximations, steady state conduction- concept of resistances in series and of critical thickness of insulation, unsteady conduction; significance of Biot and Fourier numbers, Heissler charts; low Bi case; penetration depth, essential nature of convection: transpiration cooling; writing energy equation without dissipation and pressure terms; non- dimensionalisation, Nusselt number and correlations. Mass transfer: Simple ideas of mass transfer; definitions, similarity with heat transfer, Use of steady conduction, concept to solve simple steady cases in dilute solutions as well as in stationary solids.

6 Text books: 1. Som and Biswas, Introduction to fluid mechanics, McGraw- Hill 2. J. A. Fay, Introduction to Fluid Mechanics, MIT Press 3. F. M. White, Fluid Mechanics, McGraw- Hill 4. Lienhard and Lienhard, A heat transfer text book, 4 th Ed ( CH3100: Optimization Techniques (3) Nature and organization of optimization problems - model development for optimization - objective function formulation - Optimization Theory and techniques - single variable unconstrainted optimization - multi variable unconstrainted optimization - linear programming - constrained nonlinear programming - global optimization with continuous and discrete variables - chemical engineering applications (e.g. heat and energy conservation, separation processes, Fluid Flow, Reactor Design) 1. Numerical Optimization by Jorge Nocedal & Stephen J. Wright, Springer series in Operations Research, Optimization of Chemical Processes by Edger, Himmelblau & Lasdon, McGrawHill, 2001 CH3080 Chemical Technology (3) Introduction and overview of Chemical Process Technology. Preparation of process flow diagrams, Instrumentation diagrams and Process symbols. Petrochemical Industries: production of petrochemical feedstocks, olefins and aromatics, intermediates from olefins and aromatics. Inorganic Chemical Industries: chlor- alkali industries, manufacture of acids, ammonia, and fertilizers. Fermentation: manufacture of sugar, starch, and its derivatives, manufacture of industrial alcohols. Pulp, Paper, and Rayon industries. Edible oils: extraction and refining, fat splitting, soaps and detergents. 1. C.E. Dryden, Dryden s outlines of Chemical Technology for the 21st century, (Edited & revised by M.G. Rao and M. Sitting) G.T. Austin, Shreve s Chemical Process Industries, 5th edition, McGraw Hill Book Co., New York,1984. Additional Reading 1. R. E. Kirk, and D. F. Othmer, Encyclopaedia of Chemical Technology, 4th Ed., Interscience, New York, P. H. Groggins, Unit Processes in Organic Synthesis, 5th Ed., McGraw Hill, S.D. Shukla & G.N. Pandey, A Text Book of Chemical Technology, Vol. II, Sangam Books, W.V. Mark edited by S.C. Bhatia, Chemical Process Industries Vol. I & Vol. II 2nd edition, CBS Publisher and Distributor, CH2060: Process Control & Instrumentation (3)

7 Characteristics of control problems, Modelling of chemical processes, Linearization of nonlinear systems, Solutions to ODE by Laplace transforms, dynamic behavior of first order, second order, higher order systems, feedback control, stability and design of feedback controllers, design of controllers using frequency methods. Instrumentation: Pressure, level, flow, temperature, density, viscosity, ph measuring instruments Chemical Process Control: An Introduction to Theory and Practice by George Stephanapolous, Prentice Hall, Fundamentals of Industrial Instrumentation and Process Control by William C. Dunn, McGraw Hill, CH3050: Mass transfer (4) Classification of Mass Transfer Operations (Direct contact of immiscible phases, Membrane separation of phases, Direct & Indirect Operations), Diffusion & Mass Transfer, Gas- Liquid Operations (Bubble Columns, Multistage tray towers), Liquid- Liquid Operations, Solid- Liquid Operatons Reference: 1. Treybal, R.E., Mass- transfer Operations, 3rd Edition, McGraw Hill (1980). CH3073: Numerical Methods (3) Linear Algebraic Equations - Eigen Values and Eigenvectors of matrices - Nonlinear algebraic equations - Function evaluation - Ordinary Differential Equations Initial Value Problems - Ordinary Differential Equations Boundary Value Problems - Solution of relevant Chemical Engineering problems using these methods Reference: 1. Numerical Methods for Engineers by Prof. S. K. Gupta, 5- th Ed., New Age International, CH2040 Heat transfer (3) Conductive heat transfer - thermal conductivity stead state conduction critical insulation thickness transient heat conduction Convective heat transfer - heat transfer coefficients analogy to other transport processes Reynold s, Prandtl, and Colburn analogy heat transfer to fluids in laminar and turbulent flow boiling condensation Radiation heat transfer radiation between infinite planes view factor radiation from flames and gases pyrometry Heat exchangers classification and construction details LMTD and LMTD corrections over all heat transfer coefficients fouling effectiveness- NTU- pinch technology Evaporation- equipments and classification feeding scale formation performance factors 1. Hollman JP, Heat transfer, McGraw Hill, 10 th Ed., Datta BK, Heat transfer: principles and applications, Prentice Hall India, McCabe WL, Smith JC, and Harriott P, Unit Operation in Chemical Engineering, McGraw Hill, 7 th Ed., Kern DQ Process heat transfer, McGraw Hill, 1997

8 CH2010: Applied Chemistry (3) Surface & Colloidal Science, Wettability, Surface forces, Adhesion, Colloidal & Interfacial chemistry, Organic Chemistry Overview: Isomerism, Polymerization, Bio- chemistry overview, Applications in Chemical Engineering(Water, Lubricants, Polymers, Nano- chemistry, Catalysts) 1. Arthur Adamson, Physical Chemistry of Surfaces, 1997, 6 th Ed., Wiley Publications 2. Paul C. Hiemenz, Principles of solloid and surface chemistry, 1997, 3 rd Ed., Marcel Dekker, NY 3. Morrison & Boyd, Organic Chemistry, 1992, 6 th Ed., Prentice- Hall Inc.