Give the major organic product(s) of the following reaction.
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1 Give the major organic product(s) of the following reaction. 1) NaNO2, HCl 0 o C 2) CuCN Q1 A D B C E F There is no reaction or the correct product is not listed here. 5 of 7
2 Give the major organic product(s) of the following reaction. 1) NaNO2, HCl 0 o C 2) CuCN Q1 A D B C E F There is no reaction or the correct product is not listed here. 5 of 7
3 Chem 234 Exam 1 Fall 2016 Distribution Count 189 Average 73.5% Max 100.0% Min 25.5% % 10.0% 20.0% 30.0% 40.0% 50.0% 60.0% 70.0% 80.0% 90.0% 100.0%
4 Number of Test Takers Tuesday Wednesday Thursday
5 Exam Average 82.00% 80.00% 78.00% 76.00% 74.00% 72.00% 70.00% 68.00% 66.00% Exam Average Tuesday Wednesday Thursday
6 Exam 2 Time: Tuesday, October 18: 7:00 9:00PM OR Wednesday, October 19: 7:00 9:00PM OR Thursday, October 20: 7:00 10:00PM Location Soc/Anthro Testing Center Chapters will be covered in this order: Chapter 19, 12 Practice Exams are Posted Ex Practice Exam 2A Ex Practice Exam 2B Deadline for alternate arrangements is Monday, 10/17/2016 at 4:30 PM (i.e., close of business) An oral make-up exam will be required for making up the exam for all students not taking the exam on the above dates or having already made prior arrangements
7 Order of Coverage (Exam 2) Homework Assignment Due Date 1 Ex2-01-B A Aryl Side Chain Rxns Saturday, September 24, Ex2-01-B B Aryl Side Chain Rxns Sunday, September 25, Ex2-02-B A Arylamines Monday, September 26, Ex2-02-B B Arylamines Tuesday, September 27, Ex2-03-B A Grignard Rxns Wednesday, September 28, Ex2-03-B B Grignard Rxns Thursday, September 29, Ex2-04-B A Hydride Reductions Friday, September 30, Ex2-04-B B Hydride Reductions Saturday, October 1, Ex2-05-B A Naming Carboxylic Acids Sunday, October 2, Ex2-05-B B Naming Carboxylic Acids Monday, October 3, Ex2-06-B A Prep Carbox Acids Tuesday, October 4, Ex2-06-B B Prep Carbox Acids Wednesday, October 5, 2016
8 Order of Coverage (Exam 2) Homework Assignment Due Date 13 Ex2-07-B A Carbox Acid Rxns Thursday, October 6, Ex2-07-B B Carbox Acid Rxns Friday, October 7, Ex2-08-B A Naming Carbox Acid Derivatives 16 Ex2-08-B B Naming Carbox Acid Derivatives Saturday, October 8, 2016 Sunday, October 9, Ex2-09-B A Rxns Acid Chlorides Monday, October 10, Ex2-09-B B Rxns Acid Chlorides Tuesday, October 11, Ex2-10-B A Rxns Esters Wednesday, October 12, Ex2-10-B B Rxns Esters Thursday, October 13, Ex2-11-B A Rxns Amides Friday, October 14, Ex2-11-B B Rxns Amides Saturday, October 15, Ex2-12-B A Step Growth Polymers Sunday, October 16, 2016 Exam 2 October 18, 19, 20
9 Reactions of C=O E + X Addition of electrophiles Addition of nucleophiles
10 Grignard Reagents R--X Mg - + R-Mg-X Restrictions: None! Aryl, vinyl Tertiary (3 o ) Secondary (2 o ) Primary (1 o ) Benzylic, Allylic All React!!!!! Mostly review from Organic I
11 Reactions of Grignard Reagents Watch out for N-H or OH!!!! Acid/Base reactions are always faster than anything else!
12 Grignard Reactions with Aldehydes or Ketones Second Step: Addition of Acid H +
13 Give the major organic product(s) of the following reaction. 1) CH3CH2MgBr 2) H3O Q5 A D B E C F. There is no reaction or the correct product is not listed here.
14 Give the major organic product(s) of the following reaction. 1) CH3CH2MgBr 2) H3O Q5 A D B E C F. There is no reaction or the correct product is not listed here.
15 Grignard Reactions with Esters H + H +
16 Grignard Reactions with Esters H + H +
17 Give the major organic product(s) of the following reaction. A D 1) 2) H3O Q6 G. There is no reaction or the B C correct product is not listed E F here.
18 Give the major organic product(s) of the following reaction. A D 1) 2) H3O Q6 G. There is no reaction or the B C correct product is not listed E F here.
19 Give the major organic product(s) of the following reaction. CO2 1) PhMgBr 2) H3O Q3 A B C D E F. There is no reaction or the correct product is not listed here.
20 Explanation H +
21 Give the major organic product(s) of the following reaction. CO2 1) PhMgBr 2) H3O Q3 A B C D E F. There is no reaction or the correct product is not listed here.
22 Give the major organic product(s) of the following reaction. CO2 PhMgBr H3O Q7 A B C D E F. There is no reaction or the correct product is not listed here.
23 Explanation H + Note the difference in reagents and conditions PhMgBr H 3 O + is not the same as 1) PhMgBr 2) H 3 O +
24 Give the major organic product(s) of the following reaction. CO2 PhMgBr H3O Q7 A B C D E F. There is no reaction or the correct product is not listed here.
25 Give the major organic product(s) of the following reaction. 1) CH3MgBr 2) H3O Q2 A B C D E F G H
26 Give the major organic product(s) of the following reaction. 1) CH3MgBr 2) H3O Q2 A B C D E F G H
Give the major organic product(s) of the following reaction.
Give the major organic product(s) of the following reaction. 1) CH3CH2MgBr 2) H3O 2016-09-26 Q1 + E. There is no reaction or the correct product A B is not listed here. C D Explanation CH3CH2MgBr 1) CH3CH2MgBr
Give a common name for the following compound.
Give a common name for the following compound. A. Benzyl Phenoate B. Phenyl Phenoate C. Benzyl Benzoate D. Phenyl Benzoate E. Phenyl Phenylacetate F. Phenyl Phenylethanoate G. Phenyl Benzylacetate 2016-10-07
A B C D Q1
Think about this reaction in terms of mechanism. All of the intermediates of the reaction are provided. Give the intermediates in order of their appearance along the reaction coordinate. (Example: xxxx
H3O+ heat I Q1
Give the major organic product(s) of the following reaction. Give your answer as a text answer, with the correct answers being listed in alphabetical order. (Example: xxxx a b) H3O + heat A B C D E F G
Give the major product(s) of the following reaction.
Give the major product(s) of the following reaction. HNO3 H2SO4 2016-09-12 Q1 A B E. There is no reaction or the correct product is not listed here. C D Give the major product(s) of the following reaction.
A B C D E F Q1
Give the major organic product(s) of the following reaction. Give your answer as a text answer, with the correct answers being listed in alphabetical order. (Example: xxxx a b) 1) Li 2) 2016-11-11 Q1 3)
A B C D E F G Q1. heat
Give the final product of the following reaction. Give your answer as a text answer. If more than one species is correct, put your answers in alphabetical order. HNO3 H2SO4 A B C D E F G 2016-09-09 Q1
Q1. Intensity of M+1 peak x Intensity of M peak 2.57% x 46.60% Number of carbon atoms = Number of carbon atoms =
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