Organic: module 4 revision guide. Basic definitions to know. Drawing Displayed formulae
|
|
- Lucinda Abigail Davis
- 5 years ago
- Views:
Transcription
1 opyright Goalby Bancroft's School rganic: module 4 revision guide ydrocarbon is a compound consisting of hydrogen and carbon only Basic definitions to know Saturated: ontain single carbon-carbon bonds only Unsaturated: ontains a = double bond Molecular formula: The formula which shows the actual number of each type of atom Empirical formula: shows the simplest whole number ratio of atoms of each element in the compound General formula: algebraic formula for a homologous series e.g. n2n Structural formula (displayed formula): show all the covalent bonds present in a molecule omologous series are families of organic compounds with the same functional group and same general formula. They show a gradual change in physical properties (e.g. boiling point). Each member differs by 2 from the last. same chemical properties. Functional groupis an atom or group of atoms which when present in different molecules causes them to have similar chemical properties Drawing Displayed formulae When drawing organic compounds add the hydrogen atoms so that each carbon has 4 bonds Remember that the shape around the carbon atom is tetrahedral and the bond angle is o General rules for naming carbon chains ount the longest carbon chain and name appropriately Find any branched chains and count how many carbons they contain Add the appropriate prefix for each branch chain Eg - 3 methyl or ethyl 3 7 propyl code no of carbons meth 1 eth 2 prop 3 but 4 pent 5 3,5-dimethyl heptane hex 6 hept 7 oct 8 non 9 dec 10 When compounds contain more than one functional group, the order of precedence determines which groups are named with prefix or suffix forms. The highest precedence group takes the suffix, with all others taking the prefix form. owever, double and triple -bonds only take suffix form. rder of priority highest first: arboxylic acids >carboxylic acid derivative>nitriles>aldehydes>ketones>alcohols>amines
2 opyright Goalby Bancroft's School homologous series alkenes functional group prefix / suffix (* = usual use) suffix -ene example alcohols suffix* -ol prefix hydroxy- haloalkanes halogen prefix chlorobromoiodo- l aldehydes suffix -al prefix formyl- ketones suffix* -one prefix oxo- carboxylic acids suffix -oic acid nitriles suffix -nitrile prefix cyano- amines suffix* -amine prefix amino- 2 2 esters -yl oate Acyl chloride -oyl chloride 3 l l Amide -amide Acid Anhydrides R 3 R 3 2
3 General rules for naming functional groups The functional group is indicated by a prefix or suffix. e.g. chloroethane The position of the functional group is given by a number counting from the end that gives the functional group the lowest number. (for aldehydes, carboxylic acids & nitriles, the functional group is position 1) bromobutane We only include numbers if they are needed. methyl propane 2 l 2 dichloromethane Where there are two or more of the same groups, di-, tri- or tetra are used and. Words are separated by numbers with dashes If there is more than one functional group/substituent, numbers are separated by commas and the groups are listed in alphabetical order (ignoring di, tri, etc.) l l 2 3 2,3-dibromo-2-methylbutane. 2,2-dibromo-1-chlorobutane. 3-bromo-1-chlorobutane The suffix for alkenes can go in front of other suffixes. 2 l= 2 2-chlorobut-3-en-1-ol aloalkanes lass the halogen as a substituent on the chain and use the suffix -fluoro, -chloro, -bromo, or iodo. (Give the position number if necessary: bromobutane Alcohols These have the ending -ol in place of the last -e, and if necessary the position number for the group is added between the name stem and the ol Butan-2-ol If the compound has an group in addition to other functional groups that need a suffix ending then the can be named with the prefix hydroxy-): 3 2-hydroxypropanoic acid Aldehydes An aldehyde s name ends in al It always has the = bond on the last carbon of the chain so it does not need an extra number arboxylic acids These have the ending - oic acid in place of the last -e, but no number is necessary for the acid group as it must always be at the end of the chain. The numbering always starts from the carboxylic acid end opyright Goalby Bancroft's School Ethanal Ethanoic acid Ketones Ketones end in -one When ketones have 5 s or more in a chain then it needs a number to show the position of the double bond. E.g. pentan- 2-one The prefix oxo- should be used for compounds that contain a ketone group in addition to a carboxylic acid or aldehyde Propanone 3 2-oxopropanoic acid If there are carboxylic acid groups on both ends of the chain then it is called a - dioic acid Ethandioic acid
4 opyright Goalby Bancroft's School Amines These end in amine. There is, however, rather confusingly two ways of using this suffix. The exam board tend to use the common version where then the name starts propylamine. The IUPA version of the same chemical is propan-1-amine. If the amine is secondary and has two alkyl groups attached to the nitrogen the each chain is named 2 propylamine r propan-1-amine methylbutylamine r -methylbutan-1-amine If there is another functional group as well as the amine group then the prefix amino is used aminopropanoic acid Diethylamine r -ethylethanamine itriles These end in ile, but the of the group counts as one of the chain. ote the stem of the name is different to : butanenitrile and not butannitrile. butanenitrile hydroxy-2-methylpropanenitrile arboxylic acid derivatives Esters Esters have two parts to their names The bit ending in yl comes from the alcohol that has formed it and is next to the single bonded oxygen. The bit ending in anoate comes from the carboxylic acid. (This is the chain including the = bond) methylpropanoate Acid Anhydrides This is called ethanoic anhydride. It is ethanoic because it is two ethanoate groups joined together If the groups are different then each one is named e.g. ethanoic propanoic anhydride Acyl hlorides Take the carboxylic acid name, remove the oic acid bit of the 3 name and replace by oyl l chloride ethanoyl chloride l 2-methylpropanoyl chloride Amides Take the carboxylic acid name, remove the oic acid bit of the name and replace by amide 3 2 ethanamide Secondary and tertiary amides are named differently to show the two (or three) carbon chains 3 2 -methyl propanamide ,-dimethylpropanamide ,,2-trimethylpropanamide 4
5 opyright Goalby Bancroft's School Isomers Structural isomers: same molecular formula different structures (or structural formulae) Structural isomerism can arise from hain isomerism Position isomerism Functional group isomerism hain isomers: ompounds with the same molecular formula but different structures of the carbon skeleton pentane 2-methylbutane 2,2-dimethylpropane position isomers: ompounds with the same molecular formula but different structures due to different positions of the same functional group on the same carbon skeleton 1-bromopropane 2-bromopropane Functional group isomers: ompounds with the same molecular formula but with atoms arranges to give different functional groups ethanol: an alcohol Methoxymethane: an ether yclohexane- cyclo alkane = 2 hexene- alkene Stereoisomerism Stereoisomers have the same structural formulae but have a different spatial arrangement of atoms There are two types of stereoisomerism: geometrical (EZ isomerism) and optical isomerism Alkenes can exhibit a type of isomerism called E-Z stereoisomerism E-Z isomers exist due to restricted rotation about the = bond Single carbon-carbon covalent bonds can easily rotate E-Z stereoisomers arise when: (a) There is restricted rotation around the = double bond. (b) There are two different groups/atoms attached both ends of the restricted double bond
6 opyright Goalby Bancroft's School Z- but-2-ene two different groups attached either end of the restricted double bond- leads to EZ isomers But-1-ene two identical groups attached to one end of the restricted double bond no E-Z isomers E -but but-2-ene These are two isomers as the lack of rotation around the double bonds means one cannot be switched to the other But-1-ene is a structural isomer of But-2- ene but does not show E-Z isomerism aming E-Z stereoisomers n both sides of the double bond determine the priority group PRIRITY Group: The atom with the bigger A r is classed as the priority atom Priority group side 1 Priority group side 2 Z-1,2-dichloroethene E-1,2-dichloroethene If the priority atom is on the same side of the double bond it is labelled Z from the german zusammen (The Zame Zide!) If the priority atom is on the opposite side of the double bond it is labelled E from the german entgegen (The Epposite side!) ptical Isomerism ptical isomerism occurs in carbon compounds with 4 different groups of atoms attached to a carbon (called an asymmetric carbon). These four groups are arranged tetrahedrally around the carbon. A carbon atom that has four different groups attached is called a chiral (asymmetric) carbon atom This causes two Two compounds that are optical isomers of each other are called enantiomers. This causes two different isomers that are not superimposable to be formed. They are mirror images ptical isomers have similar physical and chemical properties, but they rotate plane polarised light in different directions. ne enantiomer rotates it in one direction and the other enantiomer rotates it by the same amount in the opposite direction. A mixture containing a 50/50 mixture of the two isomers (enantiomers) is described as being a racemate or racemic mixture. Many naturally occurring molecules contain chiral atoms, but are usually found in nature as a pure enantiomer Different systems of nomenclature are is existence for optical isomers. D/L or +/- are commonly used, but both have been superseded by the more useful and informative R/S system (this is not on the syllabus for information only). ne optical isomer will rotate light clockwise (+)(called dextrorotatory). The other will rotate it anticlockwise(-)(called laevorotatory). A mixture of equal amounts of the two optical isomers will not rotate plane-polarised light. The mixture is called a racemic mixture or a racemate (-)-enantiomer (anticlockwise rotation) (+)-enantiomer (clockwise rotation) (±)-racemate (no overall effect)
7 hemical Reactions and ptical Isomers opyright Goalby Bancroft's School Formation of a racemate A racemate will often be formed in a reaction when a trigonal planar reactant or intermediate is approached from both sides by an attacking species : 3 : 3 3 There is an equal chance of either enantiomer forming so a racemate forms. o optical activity is seen ucleophilic addition of to aldehydes and ketones (unsymmetrical) when the trigonal planar carbonyl is approached from both sides by the attacking species: results in the formation of a racemate Mechanism for the reaction (drawn the same for both enantiomers) A racemate can also be formed in the AS reaction of the electrophilic addition of to an unsymmetrical alkene δ + δ If the alkene is unsymmetrical, addition of hydrogen bromide can lead to isomeric products : : - The bromide can attack this planar carbocation from both sides leading to a racemate Drug action and optical isomers Drug action may be determined by the stereochemistry of the molecule. Different optical isomers may have very different effects Major product s 90% Minor product 10% Thalidomide Ibuprofen hiral carbon ne enantiomer of thalidomide causes birth defects in unborn children whilst the other had useful sedative problems. Unfortunately is was given in a racemic mixture when first used.
Empirical formula: shows the simplest whole number ratio of atoms of each element in the compound
3.7 rganic naming and Isomerism ydrocarbon is a compound consisting of hydrogen and carbon only Basic definitions to know Saturated: ontain single carbon-carbon bonds only Unsaturated : ontains a = double
More information3.7 Organic naming and Isomerism continued
3.7 rganic naming and Isomerism continued See chapter 3.1 for basic naming of organic molecules. This chapter extends the naming for functional groups met in next few chapters homologous series functional
More information3.1 Organic: Basic Concepts
. rganic: Basic oncepts ydrocarbon is a compound consisting of hydrogen and carbon only Basic definitions to know Saturated: ontain single carbon-carbon bonds only Unsaturated : ontains a = double bond
More informationIt is possible for organic molecules with the same molecular formula to have different structures
Isomerism It is possible for organic molecules with the same molecular formula to have different structures Definition- Structural isomers: same molecular formula different structures (or structural formulae)
More information3.1 Organic: Basic Concepts
3.1 rganic: Basic oncepts ydrocarbon is a compound consisting of hydrogen and carbon only Basic definitions to know Saturated: ontain single carbon-carbon bonds only Unsaturated : ontains a = double bond
More information4.1.1 Organic: Basic Concepts
.. rganic: Basic oncepts ydrocarbon is a compound consisting of hydrogen and carbon only Basic definitions to know Saturated: ontain single carbon-carbon bonds only Unsaturated : ontains a = double bond
More information4.1.1 Organic: Basic Concepts
.. rganic: Basic oncepts ydrocarbon is a compound consisting of hydrogen and carbon only Basic definitions to know Saturated: ontain single carbon-carbon bonds only Unsaturated : ontains a = double bond
More informationIntroduction to Organic Chemistry
Introduction to rganic hemistry rganic chemistry is the study of carbon compounds. It is such a complex branch of chemistry because carbon form a wide variety of compounds for the following reasons 1)
More informationOptical Isomerism. Types of isomerism. chemrevise.org 20/08/2013. N Goalby Chemrevise.org. Isomerism. Structural isomerism.
ptical Isomerism N Goalby hemrevise.org Types of isomerism Isomerism Structural isomerism Stereoisomerism Geometric isomerism ptical isomerism 1 ptical Isomerism ptical isomerism occurs in carbon compounds
More information3.1 Introduction to Organic Chemistry
3.1 Introduction to Organic hemistry Organic hemistry is the study of carbon chemistry as carbon has the ability to join together in chains, rings, balls etc. arbon also joins with other elements easily
More information17. Organic Chemistry II
17. rganic hemistry II A2 rganic naming ydrocarbon is a compound consisting of hydrogen and carbon only Basic definitions to know Saturated: ontain single carbon-carbon bonds only Unsaturated : ontains
More informationEmpirical formula: shows the simplest whole number ratio of atoms of each element in the compound
5. Further rganic A2 rganic naming ydrocarbon is a compound consisting of hydrogen and carbon only Basic definitions to know Saturated: ontain single carbon-carbon bonds only Unsaturated : ontains a =
More informationCH 3 CH 2 CH 2 CH 2 CH 2 CH 2 OH
03SEP 18:00 19:00 ORGANIC MOLECULES STUDY NOTES ORGANIC MOLECULES Important features of Carbon Carbon has a valency of 4 (can form 4 bonds), and has 4 valence electrons (outermost energy level). Carbon
More informationIsomerism CH 4 C 2 H 6 C 3 H 8 C 4 H 10 C 5 H 12. Constitutional isomers...
Isomerism 4 2 6 3 8 4 10 5 12 onstitutional isomers... 3 8 Positional isomers... Functional isomers... ow many constitutional isomers are there for the formula 4 8? arbon atoms are often classified as
More informationUnit 5: Organic Chemistry
Unit 5: Organic Chemistry Organic chemistry: discipline in chemistry focussing strictly on the study of hydrocarbons compounds made up of carbon & hydrogen Organic compounds can contain other elements
More informationFAMILIES of ORGANIC COMPOUNDS
1 SCH4U October 2016 Organic Chemistry Chemistry of compounds that contain carbon (except: CO, CO 2, HCN, CO 3 - ) Carbon is covalently bonded to another carbon, hydrogen and possibly to oxygen, a halogen
More informationRules for Naming Organic Molecules. Nomenclature II
Rules for Naming Organic Molecules Nomenclature II 1 Why? The carbon atom is unique in its bonding in that it can form stable molecules consisting of chains of carbon atoms of any length Coupled with the
More informationNaming for Chem 201 CH 4
Naming for Chem 201 Functional groups are referred to as such because they function or react differently and give the molecule different properties. Here s a list of the groups you need to be able to name
More informationComplete Tutor Notes. OCR AS Chemistry A H032 for first assessment in 2016
R AS hemistry A 032 for first assessment in 206 omplete Tutor Notes www.boomerchemistry.com Section: 4.. Basic concepts of organic chemistry Naming organic compounds page hemical formulae page Structural
More informationBasic definitions for organic chemistry
rganic hemistry - Introduction 81 1 Basic definitions for organic chemistry Scope rganic chemistry is a vast subject so it is easier to split it into small sections for study. This is usually done by studying
More informationRevision Guide Unit 2. Module 1 Organic Chemistry
Revision Guide Unit 2 Module 1 Organic Chemistry Types of formulae Types of formula you need to know 1. Empirical 2. Molecular 3. Displayed 4. Structural 5. Skeletal 6. General DefiniJons empirical formula
More informationOrganic Chemistry. A. Introduction
Organic Chemistry A. Introduction 1. Organic chemistry is defined as the chemistry of CARBON compounds. There are a huge number of organic compounds. This results from the fact that carbon forms chains
More information12.01 Organic Chemistry
12.01 rganic hemistry hemistry of arbon An Introduction to nomenclatures, structures and reactions Dr. Fred mega Garces hemistry 100 Miramar ollege 1 rganic hemistry What is rganic hemistry? rganic hemistry:
More informationAlkenes. Alkenes are unsaturated aliphatic hydrocarbons.
Alkenes Alkenes Each member contains one double covalent bond between two C atoms. Draw condensed structural formulas of first three members of alkenes family. Alkenes are unsaturated aliphatic hydrocarbons.
More informationChapter 11. Introduction to Organic Chemistry
hapter 11 Introduction to rganic hemistry Properties of arbon and its compounds 2 Properties of arbon and its compounds 3 Properties of arbon and its compounds 4 Properties of arbon and its compounds 5
More informationUnit 7 Part 1 Introduction to Organic Chemistry Nomenclature and Isomerism in Simple Organic Compounds UNIT 7 INTRODUCTION TO ORGANIC CHEMISTRY
Unit 7 Part 1 Introduction to Organic hemistry Nomenclature and Isomerism in Simple Organic ompounds UNIT 7 INTRODUTION TO ORGANI EMISTRY PART 1 NOMENLATURE AND ISOMERISM IN SIMPLE ORGANI MOLEULES ontents
More informationOrganic Chemistry. Nomenclature: Alkanes
Organic Chemistry Nomenclature: Alkanes Alkanes Hydrocarbon chains where all the bonds between carbons are SINGLE bonds Name uses the ending ane Examples: Methane, Propane, Butane, Octane, 2-methylpentane
More informationOrganic Chemistry. FAMILIES of ORGANIC COMPOUNDS
1 SCH4U September 2017 Organic Chemistry Is the chemistry of compounds that contain carbon (except: CO, CO 2, HCN, CO 3 2- ) Carbon is covalently bonded to another carbon, hydrogen and possibly to oxygen,
More informationObjectives. Organic molecules. Carbon. Hydrocarbon Properties. Organic Chemistry Introduction. Organic versus Hydrocarbon 1/1/17
Objectives Organic Chemistry Introduction 8.1 To determine the properties of organic molecules and recognize a hydrocarbon. Use table P and Q to write structural and molecular formulas for hydrocarbons.
More informationTopic 1.5 INTRODUCTION TO ORGANIC CHEMISTRY. Introduction to Organic Chemistry Nomenclature Isomerism
Topic 1.5 INTRODUTION TO ORGANI EMISTRY Introduction to Organic hemistry Nomenclature Isomerism 1. arbon compounds INTRODUTION TO ORGANI EMISTRY Organic chemistry is the chemistry of carbon compounds.
More informationTopic 10.1: Fundamentals of Organic Chemistry Notes
Topic 10.1: Fundamentals of Organic Chemistry Notes Terminology Hydrocarbon: compounds that contain mostly hydrogen and carbon Homologous Series: compounds with the same general formula Molecular Formula:
More informationISOMERISM - A general survey
Isomerism 1 ISOMERISM - A general survey STRUTURAL ISOMERS have the same molecular formula but different structural formulae They occur due to variations in... the carbon skeleton AIN ISOMERISM 2 2 positions
More informationChapter 4 Alkanes and Cycloalkanes.! Structure, Nomenclature and Conformations
hapter 4 Alkanes and ycloalkanes Structure, Nomenclature and onformations arbon Bonding Structural Representation of Simple Alkanes Name Kekule structure ondensed structure Model methane ethane propane
More informationFunctional Groups. Functional groups: special groups of atoms attached to a hydrocarbon skeleton; the most common sites of chemical reactivity.
Functional Groups Functional groups: special groups of atoms attached to a hydrocarbon skeleton; the most common sites of chemical reactivity. Organic halides: a hydrogen is replaced by a halogen fluoro-,
More informationORGANIC MOLECULES (LIVE) 10 APRIL 2015 Section A: Summary Notes and Examples Naming and Functional Groups
ORGANIC MOLECULES (LIVE) 10 APRIL 2015 Section A: Summary Notes and Examples Naming and Functional Groups Important Features of Carbon There are different allotropes (same element, same phase, different
More informationAlkanes 3/27/17. Hydrocarbons: Compounds made of hydrogen and carbon only. Aliphatic (means fat ) - Open chain Aromatic - ring. Alkane Alkene Alkyne
Alkanes EQ 1. How will I define Hydrocarbons? 2. Compare and contrast the 3 types of hydrocarbons (Alkanes, alkenes, alkynes). Hydrocarbons: Compounds made of hydrogen and carbon only. Aliphatic (means
More informationCarbon Bonding Isomers Naming Reference Tables Functional Groups. Reactions
arbon Bonding Isomers Naming Reference Tables Functional Groups 2 Reactions Not electrolytes; they do not generally conduct electricity. Low melting points; they are nonpolar with weak forces of attraction.
More informationHydrocarbons and their Functional Groups
Hydrocarbons and their Functional Groups Organic chemistry is the study of compounds in which carbon is the principal element. carbon atoms form four bonds long chains, rings, spheres, sheets, and tubes
More informationAlkanes and Cycloalkanes
Alkanes and Cycloalkanes Families of Organic Compounds Organic compounds can be grouped into families by their common structural features We shall survey the nature of the compounds in a tour of the families
More informationIUPAC Nomenclature Chem12A, Organic Chemistry I
IUPAC Nomenclature ChemA, rganic Chemistry I IUPAC PEFIXES Prefix Substituent Group Number of Carbons meth- methyl eth- ethyl prop- propyl but- butyl pent- pentyl hex- hexyl hept- heptyl 7 oct- octyl 8
More informationMODULE-16 HYDROCARBONS. Hydrocarbons can be classified according to the types of bonds between the carbon atoms:
MODULE-16 YDROARBONS SATURATED AND UNSATURATED YDROARBONS:- ydrocarbons can be classified according to the types of bonds between the carbon atoms: (i) Saturated hydrocarbons have only single bonds between
More informationThe International Union of Pure and Applied Chemistry has developed a system of rules for naming organic molecules.
HYDRCARBNS AND THEIR DERIVATIVES The field of organic chemistry includes the study of hydrocarbons (compounds composed of carbon and hydrogen atoms covalently bonded together) and their derivatives (variations
More informationMasters for transparencies. 5.1 Matter and materials
Masters for transparencies 5.1 Matter and materials KNWLEDGE AREA: MATTER AND MATERIALS rganic molecules rganic molecules Plastic and polymers UNIT 1 RGANI MLEULES Alkanes ycloalkanes rganic compounds
More informationNaming Organic Compounds: Alkanes
Naming Organic Compounds: Alkanes Chemical nomenclature assigns compounds a unique name that allows them to be easily identified and structurally understood. The International Union of Pure and Applied
More informationChirality, Carbonyls and Carboxylic Acids
hirality, arbonyls and arboxylic Acids Questions on this unit may include material from UNIT 2 see syllabus Isomerism Structural isomerism. Structural isomerism was dealt with in UNIT 2. All isomers are
More informationNomenclature of Organic Compounds Identification of Functional Groups
Hydrocarbons Nomenclature of Organic ompounds Identification of Functional Groups Alkanes - also known as saturated hydrocarbons or the paraffin series because all bond sites between carbon atoms and between
More informationBasic Organic Chemistry Nomenclature CHEM 104 B
Basic Organic Chemistry Nomenclature CHEM 104 B I have gone ahead and compiled all of the basic naming rules that we will be dealing with into one worksheet. I hope this will be helpful to you as you work
More informationOrganic Chemistry. Introduction to Organic Chemistry 01/03/2018. Organic Chemistry
Organic Chemistry Chemistry 30 Ms. Hayduk Introduction to Organic Chemistry https://www.youtube.com/watch?v=i9r1dmhh2m0 Organic Chemistry Study of compounds that contain carbon as the main element Relevant
More informationORGANIC CHEMISTRY. Organic molecules are everywhere! The Alkanes (See pages 25-4 and 25-5) Naming Alkanes (See pages 25-7 to 25-10)
RGANI EMISTRY hemistry 11 rganic molecules are everywhere! Some common examples: Sucrose (sugar) Methane (natural gas) Butane (lighter fluid) Plastic Acetic Acid (vinegar) Ethanol (fuel additive) What
More informationINTRODUCTION TO ORGANIC CHEMISTRY
INTRODUTION TO ORGANI EMISTRY GENERAL DESRIPTION OF ORGANI EMISTRY The Study of arbon ompounds GENERAL DESRIPTION OF ORGANI EMISTRY The Study of arbon ompounds Organic Man-made Substances Plant or Animal
More informationUnit 9. Organic compounds
Unit 9. Organic compounds Index 1.- How to Name Organic Compounds...2 2.- Types of Compounds...3 Exercises...6 Practice exam...9 Page 1 of 11 The IUPAC Naming (nomenclature) System 1.- How to Name Organic
More information3. Organic Compounds: Alkanes and Cycloalkanes
3. Organic Compounds: Alkanes and Cycloalkanes Based on McMurry s Organic Chemistry, 6 th edition, Chapter 3 2003 Ronald Kluger Department of Chemistry University of Toronto 1 Families of Organic Compounds!
More informationChapter 22. Organic and Biological Molecules
Chapter 22 Organic and Biological Molecules The Bonding of Carbon Organic chemistry is the chemistry of compounds containing carbon. Because carbon can form single, double, and triple bonds, the following
More informationSummary Chapter 13-14
Summary Chapter 1-1 Nomenclature 1 prefix + + prefix,- dimethyl 1,5- First give locajon and type of subsjtuents Second give locajon of double bond How many carbons in longest chain? How many of the funcjonal
More informationUNIT (7) ORGANIC COMPOUNDS: HYDROCARBONS
UNIT (7) RGANI MPUNDS: YDRARBNS rganic chemistry is the study carbon containing compounds. 7.1 Bonding in rganic ompounds rganic compounds are made up of only a few elements and the bonding is almost entirely
More informationBRCC CHM 102 Class Notes Chapter 11 Page 1 of 9
BRCC CHM 102 Class Notes Chapter 11 Page 1 of 9 Chapter 11 Alkanes and Cycloalkanes hydrocarbons compounds that contain only carbon and hydrogen * 4 families: 1) alkanes only single bonds (includes cycloalkanes)
More informationHONORS: Naming Organic Compounds
HONORS: Naming Organic Compounds Organic chemistry centers around the element carbon. Hydrocarbons (compounds made of the elements hydrogen and carbon are the basic building foundation of organic chemistry.
More informationCHEMISTRY - TRO 4E CH.21 - ORGANIC CHEMISTRY.
!! www.clutchprep.com TOPI: ORGANI EMISTRY Organic hemistry is the study of carbon and the other common nonmetals it is connected to:,, &. Some organic molecules are made of just carbons and hydrogens
More informationINTRODUCTORY ORGANIC CHEMISTRY
INTRODUCTORY ORGANIC CEMISTRY Introduction Organic chemistry is the study of carbon compounds excluding carbon monoxide, carbon dioxide and carbonates. Carbon atoms usually form four bonds. They have the
More informationvideo 14.4 isomers isomers Isomers have the molecular formula but are rearranged in a structure with different properties. Example: Both C 4 H 10
video 14.4 isomers isomers Isomers have the molecular formula but are rearranged in a structure with different properties. Example: Both C 4 H 10 Butane Methylpropane 1 match the isomers drawing an isomer
More informationWorksheet Chapter 10: Organic chemistry glossary
Worksheet 10.1 Chapter 10: Organic chemistry glossary Addition elimination reaction A reaction in which two molecules combine with the release of a small molecule, often water. This type of reaction is
More informationChemistry 102 Organic Chemistry: Introduction to Isomers Workshop
Chemistry 102 Organic Chemistry: Introduction to Isomers Workshop What are isomers? Isomers are molecules with the same molecular formula, but different arrangements of atoms. There are different types
More informationChapter 3. Organic Compounds: Alkanes and Their Stereochemistry
Chapter 3. Organic Compounds: Alkanes and Their Stereochemistry Functional Group: Be able to identify and name any of the functional groups listed on Table 3.1, pages 76-77. Summary of important functional
More informationUnit 12 Organic Chemistry
Unit 12 Organic Chemistry Day 138 5/5/14 QOD: What is Organic Chemistry? Do Now: True or false? 1. Electrochemical cells generate electricity. 2. Electrons flow from left to right in a battery. 3. Redox
More informationCommon Elements in Organic Compounds
Organic hemistry ommon Elements in Organic ompounds lassification of ydrocarbons Alkanes Alkanes have the general formula n 2n+2 where n = 1,2,3, only single covalent bonds saturated hydrocarbons because
More informationAmides, Amino acids and Chirality
R hemistry A 432 Amides, Amino Acids & hirality Amides, Amino acids and hirality aming of Amides The amide functional group consists of a carbonyl group bonded to the nitrogen of an amine. Like amines,
More informationChemistry 20 Chapters 2 Alkanes
Chemistry 20 Chapters 2 Alkanes ydrocarbons: a large family of organic compounds and they contain only carbon and hydrogen. ydrocarbons are divided into two groups: 1. Saturated hydrocarbon: a hydrocarbon
More informationAlkanes and Cycloalkanes
Chapter 3 Alkanes and Cycloalkanes Two types Saturated hydrocarbons Unsaturated hydrocarbons 3.1 Alkanes Also referred as aliphatic hydrocarbons General formula: CnH2n+2 (straight chain) and CnH2n (cyclic)
More information2. Large biomolecules ( ) can be constructed!
Ch. 22 Organic Chemistry I. The chemistry of II. Carbon can bond with up to four other atoms 1. Because of this, many combinations can occur. 2. Large biomolecules ( ) can be constructed! III. Properties
More informationNomenclature SORACHAI SAELIM SORACHAI SAE-LIM
1 Nomenclature SORAAI SAELIM SORAAI SAE-LIM 2 Nomenclature of Alkanes 1. Common name 2. IUPAC name (International Union of Pure and Applied Chemistry) Shapes of Alkanes 3 Number of Carbon atoms Meth C=1
More informationAP Chemistry Chapter 22 - Organic and Biological Molecules
AP Chemistry Chapter - Organic and Biological Molecules.1 Alkanes: Saturated Hydrocarbons A. Straight-chain Hydrocarbons 1. Straight-chain alkanes have the formula C n H n+. Carbons are sp hybridized The
More informationORGANIC NOMENCLATURE
RGAI MELATURE Introduction onfusion can arise in organic chemistry because of the variety of names that have been applied to compounds; common names, trade names and systematic names are prevalent. For
More informationChapter 3: Organic Compounds: Alkanes and Cycloalkanes
hapter : rganic ompounds: Alkanes and ycloalkanes >11 million organic compounds which are classified into families according to structure and reactivity Functional Group (FG): group of atoms which are
More informationHISTORY OF ORGANIC CHEMISTRY
ISTORY OF ORGANI EMISTRY In the early days of chemistry, scientists classified chemical substances into 2 groups: 1. Inorganic: those that were composed of minerals, such as rocks and nonliving matter.
More informationIsomerism in Alkanes, Haloalkanes, and Alkenes using Molecular Models
EXPERIMENT 1 Isomerism in Alkanes, aloalkanes, and Alkenes using Molecular Models Materials Needed - Molecular model kit Relevant Textbook Reading Denniston, chap 11.2-11.4, 12.1-12.3 Background In uncharged,
More informationCHEM J-10 June The structure of ( )-linalool, a commonly occurring natural product, is shown below.
CEM1102 2014-J-10 June 2014 The structure of ( )-linalool, a commonly occurring natural product, is shown below. 4 What is the molecular formula of ( )-linalool? C 10 18 O Which of the following best describes
More informationAlkenes CnH2n Ethene Propene But-2-ene But-1-ene exposed high electron density one sigma (σ) bond and one pi (π) bond.
Alkenes Alkenes are unsaturated hydrocarbons General formula is n2n Alkenes contain a carboncarbon double bond somewhere in their structure Ethene Propene Numbers need to be added to the name when positional
More informationAlkanes, Alkenes and Alkynes
Alkanes, Alkenes and Alkynes Hydrocarbons Hydrocarbons generally fall into 2 general groupings, aliphatic hydrocarbons and aromatic hydrocarbons. Aliphatic hydrocarbons contain chains and rings of hydrocarbons,
More informationLecture 4: 12.4 Isomerism
Lecture 4: 12.4 Isomerism Learning Outcomes: At the end of the lesson the students should be able to : Define isomerism. Explain constitutional isomerism. chain isomers positional isomers functional group
More informationFamiliarize yourself with the principal functional groups of organic chemistry
Chemistry 261 Laboratory Experiment 1: Model Building Reading from Zubrick, 10 th Edition (for Live Labs Beginning Next Week) Safety, pages 1-10 Keeping a Notebook, pages 11-24 Mining Your Own Data, pages
More informationCounterclockwise (Leftward turning) S. 3 2 Clockwise (Rightward turning) R
Stereochemistry I and S in Alkanes A chiral carbon has four different groups attached to it, the differences may be several bonds away, but so long as they are different in any way the groups are considered
More informationQuickTime and a TIFF (Uncompressed) decompressor are needed to see this picture. Organic Chemistry. QuickTime and a are needed to see this picture.
QuickTime and a TIFF (Uncompressed) decompressor are needed to see this picture. Organic Chemistry QuickTime and a TIFF (Uncompressed) decompressor are needed to see this picture. Organic Chemistry Has
More informationChapter 25 Organic and Biological Chemistry
Chapter 25 Organic and Biological Chemistry Organic Chemistry The chemistry of carbon compounds. Carbon has the ability to form long chains. Without this property, large biomolecules such as proteins,
More informationModule 4 revision guide: Compounds with C=O group
opyright N Goalby Bancroft's School Module 4 revision guide: ompounds with = group arbonyls: Aldehydes and Ketones arbonyls are compounds with a = bond, they can be either aldehydes or ketones. 3 ethanal
More informationCHAPTER 2. Structure and Reactivity: Acids and Bases, Polar and Nonpolar Molecules
CHAPTER 2 Structure and Reactivity: Acids and Bases, Polar and Nonpolar Molecules 2-1 Kinetics and Thermodynamics of Simple Chemical Processes Chemical thermodynamics: Is concerned with the extent that
More informationOrganic Chemistry. Organic chemistry is the chemistry of compounds containing carbon.
Organic Chemistry Organic Chemistry Organic chemistry is the chemistry of compounds containing carbon. In this chapter we will discuss the structural features of organic molecules, nomenclature, and a
More informationChapter 22. Organic and Biological Molecules
hapter 22 Organic and Biological Molecules hapter 22 Preview Organic and Biological Molecules Alkanes: Saturated ydrocarbons Isomerism, Nomenclature, Reactions of alkanes, yclic alkanes Alkenes, Alkynes,
More information1. Find the highest priority group. These are listed in order of priority in the table of functional groups (next page).
General Strategy For aming Simple rganic ompounds (Bare bones summary sheets). Find the highest priority group. These are listed in order of priority in the table of functional groups (next page).. Find
More informationChem 1075 Chapter 19 Organic Chemistry Lecture Outline
Chem 1075 Chapter 19 Organic Chemistry Lecture Outline Slide 2 Introduction Organic chemistry is the study of and its compounds. The major sources of carbon are the fossil fuels: petroleum, natural gas,
More information1.8. Organic Chemistry. Practice Exam Organic Chem. System LENGTH: VOLUME MASS Temperature. 1 gal = 4 qt. 1 lb = 16 oz.
rganic hemistry Practice Exam rganic hem Name (last) (First) Read all questions before you start. Show all work and explain your answers to receive full credit. Report all numerical answers to the proper
More informationAssigning Stereochemistry I What is stereochemistry?
S. Lievens, March 0 University of alifornia, Davis For use in UDavis hemistry 8/8 Series Assigning Stereochemistry I What is stereochemistry? Types of isomers As organic molecules get larger (more than
More informationAn Introduction to Organic Chemistry
An Introduction to rganic hemistry rganic hemistry Is Not That Scary rganic hemistry - General Description A. The Study of arbon ompounds B. rganic reminds us of plant or animal origins 1. Natural medicines:
More informationChapter 25: The Chemistry of Life: Organic and Biological Chemistry
Chemistry: The Central Science Chapter 25: The Chemistry of Life: Organic and Biological Chemistry The study of carbon compounds constitutes a separate branch of chemistry known as organic chemistry The
More informationExplain how the structure and bonding of carbon lead to the diversity and number of organic compounds.
Section 1 Organic ompounds Objectives Explain how the structure and bonding of carbon lead to the diversity and number of organic compounds. ompare the use of molecular and structural formulas to represent
More informationOrganic Chemistry Unit Review Package
Name: Worksheet 7.viii Organic Chemistry Unit Review Package Generalized Organic Chemistry Naming Procedure Grouped into three general phases. 1. Identification phase (finding all important/correct information)
More information2/25/2015. Chapter 4. Introduction to Organic Compounds. Outline. Lecture Presentation. 4.1 Alkanes: The Simplest Organic Compounds
Lecture Presentation Outline Chapter 4 Introduction to Organic Compounds 4.2 Representing Structures of Organic Compounds Julie Klare Fortis College Smyrna, GA Alkanes are structurally simple organic compounds
More informationOrganic Chemistry Notes. Chapter 23
Organic Chemistry Notes Chapter 23 What is so special about carbon? Carbon has 4 valence electrons so carbon will always form 4 covalent bonds The simplest organic compound is a hydrocarbon Hydrocarbon
More informationChapter 12 Alkanes Based on Material Prepared by Andrea D. Leonard University of Louisiana at Lafayette
Chapter 12 Alkanes Based on Material Prepared by Andrea D. Leonard University of Louisiana at Lafayette Copyright The McGraw-Hill Companies, Inc. Permission required for reproduction or display. 1 Introduction
More informationNomenclature Problems Guidelines and summary page on last two pages.
Nomenclature Problems Guidelines and summary page on last two pages... 3. 4. 5. Z:\classes\34\34 Special andouts\34 Nomenclature lect probs only.doc 6. 7. 8. 9. 0. Z:\classes\34\34 Special andouts\34 Nomenclature
More informationCHEMISTRY FOR THE IB DIPLOMA CAMBRIDGE UNIVERSITY PRESS
10 rganic chemistry Revision checklist I am able to: explain, using an example, what is meant by the term homologous series sketch a graph of boiling point against number of carbons for the straight-chain
More information