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1 DOI: /jcprm : ,. 1,. 2,. 1,. 1,. 1,. 2*,. 2,. 2 1,., 10,, ( ) 2,., 17,, ( ), smssb@yandex.ru -.. «-».. :,,,,». ( ), ( ) ( ),,, nature@ecology.basnet.by,, altom@ecology.basnet,,, bogolitsyn@iepn.ru,, nature@ecology.basnet.by,, nature@ecology.basnet.by, nature@ecology.basnet.by,,, smssb@yandex.ru,, solombalka@yandex.ru,, mtrufanova@ya.ru -,, -.,, - - -,, [1]. - -, - -,,, -. [2] -, *.
2 296.,.,... [2, 3]. [4], (, ). ( - R = 40%, = 2,2% = 1,2-1 ) ( - R = 20%, = 5,8%, = 0,6-1 ) ( ),., 2.5 : 1 5 : 1. - [5, 6]. ( 11,0-13,6%) -, [7]., [8] [9].,, - [10]., [11], -., 1 2,, - ( 3 4,5 ). 6,4 39,7%. -.,, - [2, 3].,.,. - ( - ) : 1, ,, 1, - 1,5-1, ( ) (2,5 : 1) ) 1-1, )
3 ,, -3, %, ,0 11,8 3,7 ( = ), 2,5 : ,0 11,9 4,0 ( = ), 5 : ,8 12,0 4,1 ( = ), 2,5 : ,0 12,2 4,8 ( = ), 5 : ,0 12,6 4, ,8 14,9 4, ,8 15,1 4,2 = ), 2,5 : ,6 15,4 4, ,5 15,2 4, ,6 15,0 4, ,0 15,2 4,9 = ), 2,5 : ,0 15,9 5, ,4 15,6 5,2 -,, -3, %, ,0 16,5 2,8 ( = ), 2.5 : ,1 14,7 3,1 ( = ), 5 : ,4 16,5 3,2 ( = ), 2,5 : ,0 14,9 3,4 ( = ), 5 : ,7 16,4 3, ,0 17,6 2, ,0 17,4 3,0 =10 2 ), 2,5 : ,0 18,3 3, ,0 18,4 3,2 =10 4 ), 1:2, ,0 17,9 3,2 = ), 1: ,0 18,7 3,2 = ), 2,5 : ,0 18,0 3, ,0 18,6 3,5
4 298.,.,... ( 3, 4) [9]. -. ( 0 ) [9]. ( ) ( ) Fe 3+, [9]. - ( ~100, g=4,3), ( = ) g=2,2,. Fe 3+, -. Fe 3+ -,. ( - 0 ). - Fe 3+,,,, ,. g- ( g 0,0004±0,0002 0,0003±0,0001 ), -., Fe 3+ (g = 4,3). 3. *, I, g -1 ** g=4,3 g=2,2 / 0 0,1 50, I., 10 6, I., ,0 4,0 2,0032 6,0 3, ,4 NH 3 46,5 5,6 7,3 2, ,8 2, ,4 43,5 4,0 4,8 2,0039 6,1 2, ,4 NH 3 42,0 5,8 7,3 2, ,2 2, ,3 43,5 3,7 4,8 2,0032 6,0 3, ,4 NH 3 43,5 5,6 6,6 2, ,9 3, ,3 =10 2 ), 2,5 : 1 39,0 3,8 5,6 2,0033 6,2 2, ,3 NH 3 46,5 5,6 6,6 2, ,9 3, ,4 42,0 4,0 4,8 2,0037 7,7 2, ,3 NH 3 44,0 6,3 7,2 2, ,1 3, ,3, - ( = ), 2,5 : 1 43,5 4,0 4,3 2,0037 7,1 3, ,3 NH 3 44,0 5,5 6,4 2, ,2 2, ,3, - ( = ), 2,5 : 1 45,0 3,9 5,0 2,0039 7,8 2, ,3 NH 3 46,0 5,3 5,4 2, ,2 2, ,4 : * ; ** / 0, 50 0,1. Fe 3+
5 *, I, g -1 ** g=4,3 g=2,2 / 0 0,1 50, I., 10 6, I., ,0 6,8 7,0 2,0035 3,1 4, , ,15 NH 3 46,5 7,0 8,5 2,0036 6,1 5, , ,13 42,5 6,6 7,2 2,0040 2,8 5, , ,83 NH 3 46,5 7,2 8,5 2,0040 5,5 5, , ,82 45,5 6,6 7,2 2,0037 2,8 5, , ,73 NH 3 47,0 7,1 7,4 2,0040 5,6 5, , ,68 = ) 2,5 : 1 39,5 6,9 7,3 2,0038 3,2 4, , ,70 + NH 3 46,5 7,0 8,5 2,0036 6,1 5, , ,75 42,0 6,2 6,3 2,0038 2,7 5, , ,75 NH 3 46,0 7,1 9,0 2,0041 5,5 6, , ,73, - ( = ), 2,5 : 1 40,0 6,4 8,0 2,0039 5,1 4, , ,68 NH 3 47,0 7,2 7,6 2,0040 9,4 5, , ,67, - ( = ) 2,5 : 1 43,0 5,8 6,3 2,0036 5,7 4, , ,74 NH 3 47,0 7,1 7,8 2,0038 6,6 5, , ,95 : * ; ** / 0, 50 0,1.,,, -, ( )., , - ( ) ). - [12].,., g [12] [13]. = 2, : 1-2 [12]... [14] - - ( ). -,. Fe 3+
6 300.,.,..,. -, -,.. -, [12, 13],,.. -,., -,..,, -,..,.,, -, «-». - 4). (g = 4,3). Fe 3+, - g = 2,2 [15]., -, - (. 1, 2)., , -. [16], - [17]. - 2 [18]., ( ),. - [13],.,.,,,. -,,.
7 301 -,,,,.) ,..., ,.,.,.,. // ( ). /.,.,., ,.,.,.,.,.,.,.,. // ,.., ,., , ,.,.. // , ,.,.,. // ,. // :...., Erchak D.P., Efimov V.G., Stelmakh V.F. // Phys. Status Solidi. B Vol. 203, N ,.,. - // , ,.,. //... -., , : , , ,..., ,..,
8 302.,.,.. Tsyganov A.R. 1, Tomson A.E. 1, Bogolicyn K.G. 1. Sokolova T.V. 1, Strigutskiy V.P. 1, Pekhtereva V.S. 1, Selyanina S.B. 2*, Parfenova L.N. 2, Trufanova M.V. 2 CREATION OF SORPTION MATERIALS BASED ON PEAT 1 Institute for Nature Management NAS of Belarus, street F. Skoriny, 10, Minsk, (Republic of Belarus), nature@ecology.basnet.by 2 Institute of Environmental Problems of the North of the Ural Branch of RAS, Severnoy Dviny Emb., 23, Arkhangelsk, (Russia), smssb@yandex.ru The scientific fundamentals of sorption materials peat-based solutions to the problems of air purification are obtained. Modification peat with low concentrations weak acids leads to the increase sorption activity and improved technological characteristics of peat sorbents. It is a consequence of transforming polyconjugation systems with restructuring of organic-mineral complexes. The interaction of modifying acids with organic matrix of peat arises by the mechanism «makrocoordination». The feasibility of using peat sorbents for decontamination of agricultural enterprises profile of ammonia are substantiated production tests. Keywords: eat polymer matrix, sorption, polyconjugation system, ammonia sorbtion, mechanism "makrocoordination". References 1. Pljashhenko S.I., Hohlov I.I. Mikroklimat i produktivnost' zhivotnyh. [Microclimate and productivity of animals]. Leningrad, 1987, 64 p. (in Russ.). 2. Zhukov V.K., Tomson A.Je., Samsonova A.S., Sokolova T.V., Nikolaenkov A.I. Prirodopol'zovanie, no. 8, pp (in Russ.). 3. Patent 7747 (BY) Cyganov A.R., Tomson A.Je., Bogolicyn K.G., Sokolova T.V., Striguckij V.P., Pehtereva V.S., Seljanina S.B., Parfenova L.N., Trufanova M.V. Fundamental'nye issledovanija, 2013, no. 4, Ch. 2, pp (in Russ.). 5. Lishtvan I.I., Korol' N.T. Osnovnye svojstva torfa i metody ih opredelenija. [The basic properties of peat and methods of their determination]. Minsk, 1975, 320 p. (in Russ.). 6. Golovach A.A., Kuptel' G.A., Terent'ev A.A. Laboratornyj praktikum po fizike i himii torfa. Ch. 1. Fizi-kotehnicheskie svojstva torfa. [Laboratory workshop on the physics and chemistry of peat. Part 1. Physical and technical properties of peat]. Minsk, 1980, 69 p. (in Russ.). 7. Tomson A.Je., Sokolova T.V., Navosha Ju.Ju. i dr. Prirodopol'zovanie, 2001, no. 7, pp (in Russ.). 8. GOST Udobrenija organicheskie. Metody opredelenija obshhego azota. [Organic fertilizers. Methods for determination of total nitrogen]. Moscow, (in Russ.). 9. Striguckij V.P., Bambalov N.N., Prohorov S.G., Smirnova V.V. Khimiia tverdogo topliva, 1996, no. 6, p. 29. (in Russ.). 10. Lishtvan I.I., Striguckij V.P. Tezisy dokladov Mezhdunarodnoj konferencii «Kolloidnaja himija v reshenii problem jekologii». [Abstracts of the International Conference «Colloidal chemistry in solving the problems of ecology»]. Minsk, 1994, p (in Russ.). 11. Erchak D.P., Efimov V.G., Stelmakh V.F. Phys. Status Solidi. B, 1997, vol. 203, no. 2, p Liogon'kij B.I., Lishtvan I.I., Ljubchenko L.S. Doklady AN SSSR, 1986, vol. 288, no. 6, pp (in Russ.). 13. Navosha Ju.Ju., Parmon S.V., Prohorov S.G. Tezisy dokladov Mezhdunarod-nogo simpoziuma maja 1995 g. [Abstracts of the International Symposium May 15-19, 1995]. Minsk, 1995, p. 17. (in Russ.). 14. Zhorobekova Sh.Zh. Makroligandnye svojstva guminovyh kislot. [Makroligandnye properties of humic acids]. Frunze, 1987, 194 p. (in Russ.). 15. Striguckij L.V. Vlijanie centrov s korotkimi vremenami relaksacii na spektry JePR uglerodnyh materia-lov: Avtoref. diss. kand. fiz.-mat. nauk. [Influence centers with short relaxation times on the EPR spectra of carbon materials: Candidate of Physical and Mathematical Sciences diss.]. Minsk, 1999, 21 p. (in Russ.). 16. Himicheskij jenciklopedicheskij slovar'. [Encyclopedic Dictionary of Chemistry]. Moscow, 1983, p (in Russ.). 17. Rabinovich V.A., Havin V.Ja. Kratkij himicheskij spravochnik. [A brief chemical handbook]. Leningrad, (in Russ.). 18. Gamajunov N.I., Gamajunov S.N. Sorbcija v gidrofil'nyh materialah. [Sorption in hydrophilic materials]. Tver', 1997, 159 p. (in Russ.). Received September 13, 2013 Revised October 22, 2013 * Corresponding author.
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