ABSTRACT :[ ]

Size: px

Start display at page:

Download "ABSTRACT :[ ]"

Kory Day
6 years ago
Views:

1 ..,..,..,.., :[ ] ABSTRACT,,,, -,,, ( ) %. -., -. -, ,,, -, - -., -, ,, -. - CAVITATION, RFH FIELD, OLEINIC ACID, FRE- QUENCY, ULTRASOUND, REFRACTION, INTERFACIAL ANGLE, TERMOSTATTING The article is aimed at nding regularities in the change of oleinic acid s properties as a result RFH eld s in uence and cavitation. It is established that the protective properties of the solutions of oleinic acid in the conditions of in uence of sulphurous anhydride and electrolyte depend not only on the processing mode of its RFH eld or cavitational in uence, but also on type of the corrosion environment. It is shown that the RFH eld in contrast to cavitational processing practically doesn't change an interfacial angle of oleinic acid, and the most noticeable changes of the wettability occur by using cavitational processing with termostatting. It is noted that the lack of a clear physical understanding of the mechanisms of in uence on the properties of the various compositions both RFH eld and cavitation doesn't allow to predict ef ciency of any in uence and demands further systematic experimental studies.,, ( ), - - :,, -,,. 168

2 - - ( ), - -,,, ( -, -, -, -. ), - - ( ) [1, 2]. - -,,,,. -,,, - -., :,, -, - -. [3], , - [4 7]., -, 350 ~ 1,5.,, , -.,, [6], %, ( ) %. 99,0 % - - : 199,7 ÎÍ/, 97,1 I 2 /100, 201,0 ÎÍ/, 6. ( 5,28 ) 1, 2, 4, 8, , 10, 15, 20, [8]. -,. 10 % , - ; - ( )., : - 169

3 ,, - 0,015 % 40± % 7 ; , -, %. ( ) n ( - 0,0002), n îáð n íåîáð , 10, / % 10, / 2, (. 1). - - : 2 30 %, -, 30 10, / 2, 1 10 %, 3 10 % 170

4 35 %. -., (. 2, 3)., -, : - 15, 20-2,5 4 (. 2) %, 25 1, ,0 2,2, (. 3).,, -, - ( ) n [9]., n,. - n -. (. 4),,,, (. 2)., -, - - (. 3). -.,, , - 5,,,,,., -,,

, / / 5 [10], - - - - - - - -,. [11] -,, -, -, -., - -, -. 1.,..,,..,,.. (1978), -,,, 1978,304. 2.,.. (1979), -,,, 1979, 256. 3.,.. (2002), - -, i i.. i., 2002, 1,. 30 37. 4.,.. (2001), - -, -, 2001,.

5 , / / 5 [10], ,. [11] -,, -, -, -., - -, -. 1.,..,,..,,.. (1978), -,,, 1978, ,.. (1979), -,,, 1979, ,.. (2002), - -, i i.. i., 2002, 1, ,.. (2001), - -, -, 2001,. XXXIII, REFERENCES 1. Shehter, Ju.N., Krejn, S.Je., Teterina, L.N. (1978), Maslorastvorimye poverhnostno-aktivnye veshhestva [Oil-soluble synthetic surface active substanceses], Moscow, Himija, 1978, 304 pages. 2. Shehter, Ju.N. (1979), Raboche-konservacionnye smazochnye materialy [Work-conserving lubricants], Moscow, Himija, 1979,256 pages. 3. Lishtvan, I.I. (2002), The in uence of physical and chemical parameters on on the ef ciency of oil-soluble inhibitors of corrosion [Vlijanie ziko-himicheskih parametrov na jeffektivnost' maslorastvorimyh ingibitorov korrozii], News NAS of Belarus. Section chem. of sciences, 2002, 1, P

6 5.,..,,.. (2008), -,, 2008, 4, ,..,,..,,.. (2002), -, -, 2002, 6, ,..,,..,,.. (2008), - -,, 2008, 3, ,.. (2010), - -, ,, 2010, ,.. (1983), -,,, 1983, ,.. (2012), - -, -, 2012,. 85, N 3, ,..,,.., -,.. (1983), - -,,., 1983, Teljashev, I.R. (2001), In uence of mechanical activation treatment on polydisperse structure of oil residues [Vlijanie mehanoaktivacionnoj obrabotki na polidispersnoe stroenie neftjanyh ostatkov], Petrochemistry and re ning, 2001, ed. XXXIII, Nesterenko, A.I., Berdizov, Ju.S. (2008), About the use of cavitation for cracking hydrocarbons [Ob ispol'zovanii javlenija kavitacii dlja krekinga uglevodorodov], Chemistry and technology of fuels and oils, 2008, 4, Pivovarova, N.A., Unger, F.G., Tumanjan, B.P. (2002), The in uence of a H- eld on paramagnetic activity of petroleum systems [Vlijanie magnitnogo polja na paramagnitnuju aktivnost' neftjanyh system], Chemistry and technology of fuels and oils, 2002, 6, Shirjaeva, R.N., Kudasheva, F.H., Gimaev, R.N. (2008), In uence on the rheological properties of high-viscosity oils, nonionic surfactants and H- elds [Vlijanie na reologicheskie svojstva vysokovjazkih neftej neionogennyh poverhnostno-aktivnyh veshhestv i magnitnogo polja],.., Chemistry and technology of fuels and oils, 2008, 3, Drebenkova, I.V. [and others]. (2010), Some features of change of the properties of oleinic acid after ultrasonic processing [Nekotorye osobennosti izmenenija svojstv oleinovoj kisloty posle ul'trazvukovoj obrabotki], Bulletin of the Vitebsk state technological University. Ed. 19, Vitebsk, 2010, Ioffe, B.V. (1983), Refraktometricheskie metody himii, [Refractometric methods of chemistry], Leningrad, Himija, 1983, 352 pages. 10. Belous, N.H. (2012), The in uence of magnetic and acoustic processing of solutions of supersofteners on properties of Portland cement concrete [Vlijanie magnitnoj i akusticheskoj obrabotki rastvorov superplasti katorov na svojstva portlandcementnyh betonov], 173

7 Engineering-physical journal, 2012,. 85, N 3, Kruglickij, N.N., Gorovenko, G.G., Maljushevskij, P.P. (1983), Fiziko-himicheskaja mehanika dispersnyh sistem v sil'nyh impul'snyh poljah [Physical and chemical mechanics of disperse systems in high pulsed eld], Kiev: Nauk. dumka, 1983, 192 pages. ill

:

. 2014. 3.. 295 302. DOI: 10.14258/jcprm.1403295 661.183+628.528:66.074.34. 1,. 1,. 2,. 1,. 1,. 1,. 2*,. 2,. 2 1,., 10,, 220114 ( ) 2,., 17,, 163002 ( ), e-mail: smssb@yandex.ru -.. «-».. :,,,,». ( 12