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1 34 EN %analyzer$ ' Stationary source emissions, Quality assurance of automated (BS EN )(measuring system Stationary source emissions, Automated measuring systems (BS EN *(Determination of low range mass concentration of dustpart 2 Air quality. Certification of automated measuring systems. ( EN Performance criteria and test procedures for automated measuring systems for,+(monitoring emissions from stationary sources & & && &) &*,'( -'*' /.,'(.,'(. ( 0( ' 1* ' %CEM - Continuous emission monitoring)' %analyzer$ /.IN-SITU /. EXTRACTIVE / / '( /101.3 KPa+/K ) ) )& )) )* )- )2 ), )1

2 34.%Standard Reference Methods'SRM$ / ) ' / ) ) EN * %QAL1$ * TÜV (Immissionsschutz und Energiesysteme GmbH)' * (Monitoring Certification Scheme)- MCERT,SIRA - Certification Service EN *& * 1 * % $ / + / * *& *) ** *- 1& * * * * %non-intrusive$ %$ % $ / %Intrusive$ %$ /

3 34& %$ / *& - *& *& 1)' %$ 1*.Serviceability %$ ' %$ % $ EXTRACTIVE. %$ 1- % $ 12' %$ 1,. %$ *& ' 11 %$ ISO ' ( %$ %$ %ma $ %$ (0( 11 %$ *3 1 %* $ & ' 11 %$

4 34) *& *& *& ( *& ( *&& ( 1( *&) %$*& *&* *) *) '( 0( T actual PO, norm y s i yˆ, i * * * * Pactual 21 PO, actual 100 P 2 H 2O, actual i ' ' ŷ i (0( i' ' y s, i ( 0( 0 % K $ 'T actual %kpa$ + ' P actual ' ' ' *) / )') %$ %$ P O2, norm P O2, actual P H 2O, actual *) *)& *))

5 34* ** ** / ** 2' *- *-. *-. %$ ' ' %$ ' 1 %$ /(( %$ %$ 1 & ) 'span *- % $ *3' %$ 3' * % $ )3' %$ 3'

6 34-11 * / ( *-& *-) *- *- 1)' %$ ' %$ % $ EXTRACTIVE ISO 2* ' ( 1&. %$ / %$%$ 1,. %$ ' %$ )3 )3 &3 *3 (( ' %$ 12 ( *- 1) *-& *' (

7 342 ' *-& 1)' %$ ' %$ % $ EXTRACTIVE 1*.Serviceability %$ ' %$ % $ 1- ' %$ 12 11'' %$ *-& ( %$ ( %$ ( 1( %$ *-&& %$ %$ %$ 1, %$ *2 *, *, /1 %$ / %$ / %$ ' %$ / ( / %$

8 34, %$ % $ & ) * *, %$ 11 *- ( %$ %$*- & *,& / %$ /** %$ *- %$ *2 *,) & ) %Serviceability$ * - 2, ' 1 ' (

9 341 & ( ) *

10 34 $.14 Performance characteristic Performance Criteria Gasses except O O B Response time <200 s (400 s for NH 3, HCl <200s and HF) Repeatability standard deviation at zero point <2.0% A <0.20% B Repeatability standard deviation at span point <2.0% A <0.20% B Lack-of-fit (linearity) <2.0% A <0.20% B Influence of ambient temperature change from 20 C within specified range at zero point Influence of ambient temperature change from 20 C within specified range at span point Influence of sample gas pressure at span point for a pressure change Ap of 3 kpa Influence of sample gas flow on extractive CEM for a given specification by the manufacturer Influence of voltage. at 15 % and at 10% from nominal supply voltage <5.0% A <0.50% B <5.0% A <0.50% B <2.0% A <0.20% B <2.0% A <0.20% B <2.0% A <0.20% B Influence of Vibration <2.0% A <0.20% B Cross-sensitivity <4.0% A <0.40% B Excursion of the measurement beans of crossstack in-situ CEM <2.0% A - Convener efficiency for CEM measuring NOx 95.0% - Determination coefficient of calibration function R² Availability 95 % 98.0% Lack-of-fit 2.0% A 0.20% B Zero drift. within maintenance interval 3.0% A 0.20% B Span drift within maintenance interval 3.0% A 0.20% B Reproducibility, R field 3.3% A 0.20% B A B Percentage value as percentage of the upper limit of the certification range Percentage value as oxygen volume concentration (volume fraction)

11 34 TOC '14 Performance Characteristic Performance Criteria Effect of Oxygen 2% A Range of response factors: methane 0.9 to 1.2 aliphatic hydrocarbon 0.90 to 1.10 aromatic hydrocarbon 0.8 to 1.1 dichloromethane 0.75 to 1.15 aliphatic alcohols 0.7 to 1.0 esters and ketones 0.7 to 1.0 organic acids 0.5 to 1.0 A Percentage value as percentage of the upper limit of the certification range. %5$.1&4 Criterion Class 1 Class 2 Class 3 Quantitative output (can be calibrated in mg/m3) Qualitative output Use for installation filling under the WID and LCPD Use for installations other than those under the WID and LCPD. where the emissions may normally exceed 50 % of the ELV Use for installations other than those under the WID and LCPD. where the emissions do not normally exceed % of the ELV Use for installations where there is no ELV expressed in mg/m3 to monitor changes in performance of dustarrestment plants + + ' %5$

12 34 '1)4 Performance Criteria Performance Characteristic Class 1 Class 2 Class 3 Response time <200s <200 s <200 s Repeatability standard deviation at zero point <2.0% A n.a. n.a. Repeatability standard deviation at span point Lack-of-fit (linearity) <5.0 % B n.a. n.a. <3.0 % A n.a. n.a. Zero shift due to ambient temperature change from 20 C within specified range <5.0% A <5.0% A <5.0% A Span shift due to ambient temperature change from 20 C within specified range <5.0% A n.a. n.a. Influence of voltage, at 15 0 and at - 10 o from nominal supply voltage <2.0 % A <2.0 % A <2.0 % A Determination coefficient of calibration function, R >0.90 >0.90 >0.80 Response time <200 s <200 s >200 s Lack-of-fit <3.0 % n.a na Zero drift, within maintenance interval <3.0 % <3.0 % <3.0% Span drift, within maintenance interval <3.0 % <3.0 % <3.0 % Availability >95.0 % >95.0 % >95.0 % Reproducibility, R field. <3.3 % <3.3 % <10.0 % A Percentage value as percentage of the upper limit of the certification range B Percentage value as oxygen volume concentration (volume fraction) '1*4 Performance Characteristic Performance Criteria Determination coefficient of calibration function R² >0.90 Response time <60 s Zero drift. within maintenance interval 2.0 % Span drift, within maintenance interval <4.0 % Availability >95.0 % Reproducibility. R field <3.3 % Response time <60 s Repeatability standard deviation at zero <2.0 % Lack-of-fit <3.0 % Zero shift due to ambient temperature change from 20 C within specified range <5.0 % Span shift due to ambient temperature change from 20 C within specified range <5.0 % Influence of voltage, at + 15 % and at - 10 % from nominal supply voltage <2.0 %

13 34& % (('( (' & ) * % $ & ) 4 + * & %4$ %4$

14 34) 11 + %4$ %3$ $ % $ 7 (($ 3 % 6 % (($ '

15 34* )' %( $ % (($ % (($ %( $ %4$ % ($ %3$ ' 1 2 3

16 34- & * *' ' ' * ' ' *3' + ( ( %$ ' % $ 4 ' % $ * ' ( + *' 6* %$ & * ) &'

17 342. % $ 4 ' + * ' *' 6. & 3

18 34, ( alignment of the measuring $ ' %system % $ %sampling probe$ %gas conditioning system$% $ % $ Serviceability %serviceability$ & ) * - 2, 1 % $ %certificate of analysis$ ISO 9000 & )

19 341 ) *+,+-.-/010.2 %=>?@'<7'7899:;9$ 3 % $ s r0 20 i1 ( x i0 x 1 0 ) 2 1 n ' s r0 i ' x i0 n ' x 0 %( $' n &3' &3' repeatability %lack-of-fit test$ 44 1 s rs 20 i1 ( x is x 1 s ) 2 1 n ' s rs i ' n ' xs %( $' n &3' 23' &3' x is

20 34 3 sampling probe %lag time $ (( % % ( ('( (' ( ('( (' %$ %$ %$13 3%$ %$ ' %$ -'

21 34 4 ( + *' ' 4444 EPA METHOD % $ ( 205 (,3-3)33 + % $,3'-3)33', 44 ) 1& B ' A Yi A BX i 1& i' CEM' 'Y i i ' ' X i B n i1 n i1 Yi ( X i X z ) 1) 2 ( X X ) n 1 A Y i BX z 1* n i1 ' X z %,$' n m 1 c Yc Yc, i 1- mc i1 %,3'-3)33$ ' c c 'Y c c i 'Y c, i i z

22 34,3'-3)33. &$ c ' m c % -' d c Yc A Bc12 c ' d c d c (% d c, rel $ d c % $ d c d c, rel *100% 1, cu c ' '' c u $ c ' *3' %,3'-3)33 d c, rel 5% d, c rel

23 34& &, 2 ' * *' *' *' * ' 4 / * 3 /*3' A *3. B,344/ %44 $ $ % * &3' $ )3' % ' & *3 y a i bx i 11

24 34) (0( i'' $( %( i ' ' x i %ma$ ' b ' a % % ymax y min $ % *3 ' 44A b ' a % C ELV $ b ' a *3' %$B A 5 y max ymin 0.15* CELV b N i1 i1 i xi x yi y 1 N x x a y bx 1 B 5 y max ymin 0.15* CELV y b 1 x Z a bz 1& ' y 1 y N N y i i1 ' N 1 x x i N i1 % *$ ' N ' Z x y i

25 34* %& yˆ i a bx i 1) i' ' ŷ i (0( i'' x i 1* kpa k$ % ' T actual PO, norm y s i yˆ, i * * * * 1* P actual 21 PO, actual 100 P 2 H 2O, actual i' ' y s, i ( 0( 0 % K $ 'T actual %kpa$ + ' P actual ' ' P O2, norm P O2, actual P H 2O, actual ' y y 0.1 y y yˆ yˆ max min min y s,max s,min 0, y min 0.1 y yˆ min 0, ymin 0 ' y s,max ( 0( ' ' y s,min ( 0( ' y max %variability test$ yˆ min s,max s,max y s,min s,min y max

26 34- D N i1 N 1 D D i ' D % *$ ' N i ' ' D i ( 0( i' ' D ( 0( ( Di i D 1 12 N D 0 * k v 1, % *$ ' k v 1* ' 0 N ( P C ELV ELV *100 1* ' P ELV 0( ' C ELV

27 A A A A % $ A $A % A A A X YA A A

28 34, & * 3' CEM & 1 3' &

29 341 % 1-% s rs ' s r0 $ % '$' n ( y0, i i y n n ' y 0 i' ' y 0,i % $ ' n yspan, i i yspan 1 1 n n ' y span i' ' y span, i % $ ' n y 0 '%$ ( 3* sr0 y0 m ( 3* sr0 y0 m ( 2 * sr0 y0 m ( 2 * sr0 y0 m n n

30 34& y span y span %$ 3* srs ( m ( 3* sr0 y0 m ( 2 * sr0 y0 m ( 2 * sr0 y0 m m 1' m

31 34& & ' *%$ *'2 *'*' * ' 4 & *3 / kpa k$ % ' T actual PO, norm y s i yˆ, i * * * * P actual 21 PO, actual 100 P 2 H 2O, actual i' ' y s, i ( 0( 0 % K $ 'T actual %kpa$ + ' P actual ' ' ' P O2, norm P O2, actual P H 2O, actual %variability test$ D N i1 N 1 D D i & ' D % *$ ' N

32 34& i ' ' ( 0( i' ' D ( 0( ( Di i D 1 N 1) D 0 * k v 9.25 % *$ ' k v 1* ' 0 N D i ( P C ELV ELV *100 1* ' P ELV 0( ' C ELV %calibration test$ D D t N 1 0 N 1*95%'Student t. t 0.95

33 34&& ( 5 A A A A A A A A A X YA A A $ A %

34 34&) %3$ P ELV & & ) ) %CO$' %SO 2 $' %NO$ %TOC$ %HCl$ %HF$ t0.95(n 1) kv(n) %N$