LANDOLT-BORNSTEIN. New Series Editor in Chief: K.-H. Hellwege. Group III : Crystal and Solid State Physics. Volume 16

Transcription

1 LANDOLT-BORNSTEIN Numerical Data and Functional Relationships in Science and Technology New Series Editor in Chief: K-H Hellwege Group III : Crystal and Solid State Physics Volume 16 Revised, Updated and Extended Edition of Volumes III/3 and III/9 Ferroelectrics and Related Substances Subvolume a: Oxides T Mitsui S Nomura M AdachiaJ Harada-T Ikeda E Nakamura- E Sawaguchi T Shigenari Y Shiozaki I Tatsuzaki K Toyoda T Yamada and K Gesi Y Makita - M Marutake T Shiosaki K Wakino Editors : K-H Hellwege and A M Hellwege Springer-Verlag Berlin l Heidelberg New York 1981 l

2 ISBN 3-54O I (Berlin Heidclbcrg New York): ISBN l (New York, Heidelberg Berlin) This ~vork is subject to copyright All rights arc rescrvcd, whcthcr the whole or part of the material is concerned specifically those of translation reprinting rc-use of illustrations broadcasting reproduction by photocopying mnchinc or similar means and storage in data banks Under 5 54 of the German Copyright Law whcrc topics arc made for other than private use a fee is pnyablc to,,verwertungsgcscllschaft Wart, by Springer-Vcrlag Berlin-Heidclbcrg 1981 Printed in Germany The use of registered names trademarks, etc in this publication dots not imply, even in the absence of a specific statcmcnt that such names arc cxcmpt from the rclcvant protective law and regulations and thcrcfore free for gcncral USC Typesettin_c printing and bookbinding: Briihlschc Universitiitsdruckerei 6300 Gicsscn 2163/

3 Contributors - Mitarbeiter Adachi, Masatoshi, Kyoto University, Kyoto, Japan Pyroelectricity, index of substances Gesi, Kazuo, Japan Atomic Energy Research Institute, Tokai-mura, Ibaraki-ken, Japan Dielectric properties, inelastic neutron scattering Harada, Jimpei, Nagoya University, Nagoya, Japan Structure of oxide crystals, inelastic neutron scattering Ikeda, Takuro, Tohoku University, Sendai, Japan Solid solutions, electromechanical and elastic properties Makita, Yasuharu, Science University of Tokyo, Shinjuku-ku, Tokyo, Japan Thermal properties, thermal expansion Marutake, Masakazu, University of Electra-Communications, Chofu, Tokyo, Japan Electromechanical and elastic properties Mitsui, Toshio, Osaka University, Toyonada, Osaka, Japan Introduction, systematization Nakamura, Eiji, Hiroshima University, Hiroshima, Japan Dielectric dispersion, dielectric constants in infrared region, paraelectric resonance Nomura, Shoichiro, Tokyo Institute of Technology, Meguro-ku, Tokyo, Japan Perovskite-type oxides of complex composition, magnetic properties, Mossbauer study Sawaguchi, Etsuro, Hokkaido University, Sapporo, Japan Electrical transport phenomena (semiconductive and photoconductive properties, etc) Shigeuari, Takeshi, University of Electra-Communications, Chofu, Tokyo, Japan Raman scattering, infrared spectroscopy Shiosaki, Tadashi, Kyoto University, Kyoto, Japan Thin film, acoustic surface wave Shiozaki, Yoichi, Hokkaido University, Sapporo, Japan Structures of crystals, diffuse X-ray scattering, thermal expansion, references

4 Tatsuzaki, Itaru, Hokkaido University, Sapporo, Japan Ultrasonic properties, Brillouin scattering, Rayleigh scattering, properties studied by means of NMR NQR, ESR and ENDOR Toyoda, Koichi, Shizuoka University, Hamamatsu, Japan Crystal growth optical properties in ultraviolet region, domain structure, dynamical properties of domains surface layer, radiation damage (including ESR), references W akino, Kikuo Murata Manufacturing Co, Ltd, Nagaokakyo, Kyoto, Japan Pyroelectricity Yamada, Tomoaki, The Electrical Communication Laboratories, Musashino, Tokyo, Japan Linear and nonlinear optical properties, electromechanical properties

5 Preface The grooving number of publications on ferroelectrics with their increasing amount of valuable data requires the publication of a complete new compilation This new volume III/l6, the first subvolume of which is presented herewith, contains revised updated and extended information on ferroclectric, antiferroelectric and closely related substances The compilation is as complete as possible and as detailed as reasonable All reliable data on both pure compounds and solid solutions published between 1921 and 1979 arc critically evaluated and included As well as the dielectric and ferroelectric bchaviour all other propcrtics relevant to the characterization of these crystals are presented in tables and figures The arrangcmcnt and scope of information is the same as in the previous volumes III/3 and III 9 These will still be useful to follow the lines of historical development, and as sources of additional data All values in this volume are given in SI units A table of conversion factors between the traditional and the SI units is added to the introduction For technical reasons the new volume has been divided as follows: subvolume 111/16a, presented hercnith, covers the oxides, and subvolumc III/16b, due in 1981, will deal with the non-oxides, ie the remaining inorganic substances, the organic crystals, some liquid crystals polymers, and crystals of uncertain ferroelectric behaviour We wish to thank all authors for their quick, thorough and competent work, the Landolt-Blirnstein office, especially Dr W Polzin and Frau B Ade, for their reliable checking of manuscripts and galleys, and Springer-Verlag for their understanding help in the final preparation This subvolumc as all volumes of Landolt-Biirnstein, has been published without any support from other sources Darmstadt October 1980 The Editors

6 Table of contents Ferroelectrics and related substances (Following the title of each chapter, the name of the author responsible for the manuscript preparation of the chapter is given) Subvolume a: Oxides I Introduction [T Mitsui] A General remarks B Definition of ferroelectrics and antiferroelectrics C Remarks on some fundamental concepts and quantities D Symbols and units E Survey of contents 1 Arrangement of data in each section 2 Two-dimensional survey of contents F Publications on ferroelectrics [K Toyoda] II Data Oxides 45 1 Perovskite-type oxides [M Adachi, J Harada, T Ikeda, S Nomura, E Sawaguchi, T Yamada] 45 A Simple perovskite-type oxides 45 B Complex perovskite-type oxides 87 C Solid solutions with perovskite-type oxides as end members 108 a Solid solutions with simpleperovskite-type oxides as end members 108 b Solid solutions with complex perovskite-type oxides as end members 130 c Ternarysolidsolutions, etc with perovskite-type oxides as constituents WO, [K Toyoda] 147 A Pure compound LiNbO, family [T Yamada] 149 A Pure compounds 149 B Solid solutions YMnO, family [S Nomura] 164 A Pure compounds 164 B Solid solutions SrTeO, family [T Yamada] 169 A Purecompound 169 B Solid solutions Tungsten-bronze-type oxides [T Yamada] 170 A Pure compounds of simple type 170 B Complex compounds 173 C Solid solutions with simple compounds as end members 198 D Solid solutions with complex compounds as end members Pyrochlore-type oxides [S Nomura] 214 A Purecompounds 214 B Anion deficient compounds 217 C Solid solutions 219

7 8 Sr,Nb20, family [T Ike&l] A Pure compounds B Solid solutions 9 Layer-structure oxides [E Sawaguchi] A Pure compounds ofsimplc tppc B Solid solutions and complex compounds IO BaAlzO,-type osiclcs [T Ike&] A Pure compounds B Solid solutions 11 Pb,Ge,O,, family [T Yamada] A Pure compound B Solid solutions 12 GM0 (Gdz(MoO,),) family [T Shigcnari] A Pure compounds B Solid solutinns, 13 Borncite-type family [S Nomura] A Pure compounds Inhaltsverzeichnis III Figures 285 Ii v A B A B References 615 Testbooks review articles and procccdings 615 Research papers 623 Indesofsuhstances 663 Pure compounds 663 Solid solutions 670