LESSON PLAN FOR EVEN SEM SESSION

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1 LESSON PLAN FOR EVEN SEM SESSION NAME OF ASSISTANT PROFESSOR :MS.HIMANI MADAAN CLASS/SECTION : B.SC. II(SEC.-C) SUBJECT :CHEMISTRY UNIT/PART I DATE DATE DATE DATE DATE DATE DATE DATE DATE DAY 10 DATE DATE Separation of a m ixture of primary, seco ndary and tertiary amines. Structural features affecting basicity o f am ines Preparation o f alkyl and aryl amines (reductio n o f nitro com pounds, nitriles, reductive aminatio n of aldehydic and ketonic com pounds Gabriel-phthalimide reactio n, Hofmann brom am ide reactio n electro philic arom atic substitutio n in aryl am ines, reactio ns o f am ines with nitro us acid Molecular vibrations, Hooke's law, selectio n rules 2 DATE DATE DATE DATE intensity and position of IR bands. SPORTS DAY 1

2 DAY 16 DATE UNIT/PART II DATE DATE DATE DATE m easurem ent o f IR spectrum, fingerprint region characteristic abso rptions o f various functional groups interpretation o f IR spectra o f simple o rganic com pounds. DATE DATE DATE DATE DATE DATE DATE DATE DATE DATE DATE ASSIGNMENT 1 Applications o f IR spectro sco py in structure elucidatio n o f sim ple o rganic com pounds Mechanism o f diazo tisation, structure o f benzene diazonium chloride Replacement o f diazo group by H, OH, F, Cl, Br, I, NO 2 and CN group UNIT/PART III DATE reductio n of diazonium salts to hyrazines 2

3 DATE DATE DATE DATE DATE DATE DATE DATE DAY 10 DATE DATE DATE DATE DATE DATE DAY 16 DATE DAY 17 DATE coupling reactio n and its synthetic application ASSIGNMENT 2 Nomenclature and structure of the carbonyl group Synthesis of aldehydes and ketones with particular reference to the synthesis of aldehydes from acid chlorides advantage of oxidation of alcohols with chromium trioxide (Sarett reagent) pyridinium chlorochromate (PCC) and pyridinium dichromate UNIT/PART IV DATE DATE

4 DATE DATE DATE DATE DATE DATE DATE DATE DATE DATE DATE DATE DATE Comparison of reactivities of aldehydes and ketones and their physical properties Mechanism of nucleophilic additions to carbonyl group with particular emphasis on benzoin, aldol Perkin and Knoevenagel condensations. Wittig reaction. Mannich reactio n Condensation with ammonia and its derivatives Oxidation of aldehydes, Baeyer Villiger oxidation of ketones, Cannizzaro reaction. MPV, Clemmensen Wolff-Kishner, LiAlH 4 and NaBH 4 reductions NAME OF ASSISTANT PROFESSOR CLASS/SECTION SUBJECT :MS. HIMANI :B.SC.III(A) :ORGANIC CHEMISTRY UNIT/PART I Introduction to organosulfur:methods of DATE formation,chem. Rxn. Of thiol andthioether Sulphonic acid DATE DATE Synthetic detergent DATE Introduction of heterocyclic compounds 4

5 DATE DATE DATE DAY 8 DATE DATE DATE DATE DATE UNIT/PART II DATE DATE DATE DATE DATE DATE DATE DATE DATE DATE DATE DATE UNIT/PART III DATE Methods of synthesis,chemical reaction of,mechanism of nucleophilic substitution in pyridine Comparision of basicity of pyridine,pyrolle and piperidine. SPORTS DAY Introduction to five and six membered heterocycles Preparation and reaction of indole and quinolone Skraup synthesis and bischler napieralski synthesis Introduction to ammino acids Preparation of ammino acids Structure of protein and classification of protein Peptide structure det. And classical peptide synthesis Structure of peptide and protein 5

6 DATE DATE DATE DATE DATE DAY 7 DATE DATE DATE DATE DATE DAY 12 DATE UNIT/PART IV DATE DATE DATE DATE DATE DATE DATE DATE DATE DATE DATE Synthesis of polymers:addition polymerisation Free radical polymerisation Polyester and polyammide Phenol formaldehyde resin Urea resin,epoxy resin and polyurathanes Chain growth polymerisation Vinyl polymerisation Synthesis of natural rubber Synthesis of synthetic rubber Organic synthesis via enolates,acidity of alpha hydrogen Alkylation of ethyl acetoacetate Synthesis of ethyl acetoacetate Claisen condensation Keto enol tautomeridm of ethyl acetoacetate Alkylation of diethyl malonate 6

7 2 DATE NAME OF ASSISTANT PROFESSOR CLASS/SECTION SUBJECT UNIT/PART I DATE DATE DATE DATE DATE DATE DATE DATE DATE DATE DATE UNIT/PART II DATE DATE DATE DATE DATE DATE DATE : MS.HIMANI : M.SC.(FINAL) :ORGANIC CHEMISTRY General aspects of structure determination of terpenoids Structure elucidation of geraniol Synthesis of geraniol Structure elucidation of alpha-terpiniol Synthesis of alpha-terpiniol Structure elucidation of alpha-pinene 7

8 5 DATE Day16 Date SESSIONAL DATE DATE DATE UNIT/PART III Synthesis of alpha-pinene DATE DATE DATE Structure of camphor DATE DATE DATE DAY 14 Synthesis of camphor DATE DATE DATE DATE Structure elucidation of squalene 2. DATE DATE UNIT/PART IV Synthesis of squalene DATE DATE DATE Biogenetic isoprene rule 8

9 DATE DATE DATE DATE DATE DATE DATE DATE DATE Biogenesis of terpinoids SESSIONAL 9

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